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Wyszukujesz frazę "Thermodynamics" wg kryterium: Temat


Tytuł:
O siłach napędowych w przyrodzie : koncepcje, interpretacje, nieporozumienia
About driving forces in nature : concepts, interpretations and misunderstandings
Autorzy:
Orlik, Marek
Powiązania:
https://bibliotekanauki.pl/articles/2200428.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
termodynamika chemiczna
entropia
entalpia swobodna
energia swobodna Helmholtza
współrzędna reakcji
reguła Le Chateliera-Brauna
chemical thermodynamics
entropy
free Gibbs energy
free Helmholtz energy
reaction coordinate
Le Chatelier-Braun principle
Opis:
Prepared for presentation within the Didactic Section of Polish Chemical Society, the study summarizes selected problems and concepts of teaching the basics of chemical reaction energetics as part of chemical undergraduate studies. The following problems are discussed: 1) indication of misunderstandings related to the definition of standard states in thermodynamics, with particular emphasis on the unfortunate assignment of the temperature of 298.15 K as "standard temperature", 2) problems with the interpretation of entropy as a "measure of disorder", with a recommendation regarding for understanding entropy as a measure of the number of ways to distribute the total energy of the system between the available degrees of freedom of motions, in terms of the quantum representation, i.e. the energy characteristics of a substance through sequences of energy levels, 3) a proposal to introduce the issue of thermodynamic driving forces of a chemical reaction based on the characteristics of the water evaporation process under different conditions, which favors the distinction of any reaction driving force from its standard driving force, as well as the distinction of such forces for isochoric and isobaric systems, both one- and multi-component, (4) the necessity to take into account the entropy of mixing of reagents to deepen the understanding of changes in the driving force of the reaction on the way to the state of chemical equilibrium, and 5) various interpretations of the influence of temperature on the equilibrium composition of the reacting system (Le Chatelier-Braun rule), with a recommendation for molecular interpretation, showing the role of differences in energies and sequences of energy levels of reactants and products for the value and direction of changes of the equilibrium constants of the reaction with temperature, taking into account also the principles of statistical thermodynamics. An additional aim of the article is to emphasize the importance of elementary mathematical education for mastering the basic laws governing the course of physicochemical processes, as well as for true understanding of chemistry, in general.
Źródło:
Wiadomości Chemiczne; 2023, 77, 1-2; 1--34
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The influence of activity coefficient and equilibrium constant models on the speciation of aqueous solutions of H2SO4–MgSO4–Al2(SO4)3 at 235 and 250 °C
Autorzy:
Dickson, Okechukwu Vincent
Deleau, Thomas
Coquelet, Christophe
Espitalier, Fabienne
Lombart, Julien
Tardy, Antoine
Powiązania:
https://bibliotekanauki.pl/articles/24085644.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
activity coefficient
equilibrium constant
hydrometallurgy
speciation
thermodynamics
Opis:
Supersaturation occurs in many industrial applications promoting reactive crystallisation between the reactants to form solutes. These solutes accumulate during precipitation, leading to the formation of scales on the inner walls of the reactor and particularly around the stirrer, causing modifications in the hydrodynamics. This encrustation is responsible for process shutdowns in continuous crystallisation processes. Supersaturation control is essential for industrial processes aimed at controlling or inhibiting the formation of these solids. Knowledge of mineral solubility and chemical speciation is required to account for the composition of the complexes in the system in their various solid or aqueous forms. This speciation is obtained by considering the thermodynamic equilibrium constants of the dissociation/complexation reactions involved in the system, the pressure, and the activity coefficients of the chemical species in their molecular or electrolyte form. From these thermodynamic quantities and the state of the system, we can predict the direction of the reaction. This study highlights the risk of the lack of experimental information on equilibrium constants at high temperatures and moderate pressures. Our goal is to evaluate the accuracy of existing models classically used to predict the equilibrium constant in such very hard conditions encountered in hydrometallurgical processes. Furthermore, we demonstrate the influences of equilibrium constants estimation and activity coefficient models on the speciation of H2SO4–Al2(SO4)3–MgSO4 systems, forming hydronium alunite and kieserite in the laterite liquor of hydrometallurgical processes.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 5; art. no. 167497
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermodynamic relationships between time, capital, and labour
Termodynamiczne relacje między czasem, kapitałem i pracą
Autorzy:
Dobija, Mieczysław
Renkas, Jurij
Powiązania:
https://bibliotekanauki.pl/articles/36412132.pdf
Data publikacji:
2023
Wydawca:
Uniwersytet Rzeszowski. Wydawnictwo Uniwersytetu Rzeszowskiego
Tematy:
czas
kapitał
praca
termodynamika
stała ekonomiczna
time
capital
labour
thermodynamics
economic constant
Opis:
In the theoretical achievements of economics, the past has left many insinuations, not always accurate terms and also controversies. This does not burden the scholars whose diligent efforts fell on the immature ground of general knowledge, in particular the lack of thermodynamics. The categories of capital, profit, labour are basic examples. There was also a lack of understanding of the nature of time. This issue was as if left to physicists, despite the fact that the use of present and future value was and is a significant achievement in economics and accounting. On the other hand, among those engaged in physics, there are divergences about time travel. The great idea of the economy as a game with nature with a non-zero positive sum has also not spread in economic theory, reinforcing the aspiration to belong to the natural sciences. Therefore, we take up the consideration of the capital-labour-time triad as an important basic element of economic knowledge. In our view, this correctly understood triad will correctly illuminate many economic issues and can form the hard core of a scientific program for improving economic and accounting theory. Thus, the epistemology of I. Lakatos defines the methodology of ongoing research, in which positive heuristics and empirical verification are the engine of scientific action.
W teoretycznych dokonaniach ekonomii przeszłość pozostawiła wiele niedomówień, nie zawsze trafnych określeń, a także kontrowersji. Nie obciąża to uczonych, których rzetelne wysiłki padały na niedojrzały grunt wiedzy ogólnej, w szczególności na brak termodynamiki. Kategorie kapitału, zysku, pracy to podstawowe przykłady. Brakowało też zrozumienia natury czasu, ta kwestia została jakby zostawiona fizykom, mimo że posługiwanie się wartością teraźniejszą i przyszłą było i jest znaczącym osiągnięciem ekonomii i rachunkowości. Natomiast wśród zajmujących się fizyką mają miejsce dywagacje o podróżach w czasie. Wielka idea gospodarki jako gry z naturą o sumie niezerowej dodatniej także nie upowszechniła się w teorii ekonomii wzmacniając dążenia do przynależności do nauk naturalnych. Dlatego podejmujemy rozważania o triadzie kapitał-praca-czas jako istotnym podstawowym elemencie wiedzy ekonomicznej. W naszym przekonaniu ta poprawnie rozumiana triada poprawnie naświetli wiele kwestii ekonomicznych i może stanowić twarde jądro naukowego programu doskonalenia teorii ekonomii i rachunkowości. Zatem epistemologia I. Lakatosa określa metodologię prowadzonych badań, w których pozytywna heurystyka i empiryczna weryfikacja stanowią motor naukowych działań.
Źródło:
Nierówności Społeczne a Wzrost Gospodarczy; 2023, 75; 5-28
1898-5084
2658-0780
Pojawia się w:
Nierówności Społeczne a Wzrost Gospodarczy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermodynamics-based measurement of the velocity of high-temperature smoke
Autorzy:
Wang, Haoyu
Powiązania:
https://bibliotekanauki.pl/articles/2204068.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
thermodynamics
smoke
flow velocity
measurement
Kalman filter
algorithm
Opis:
In view of the high cost and difficulty of ensuring the accuracy in the measurement of fire smoke velocity, the measurement system developed using platinum resistance temperature detectors and an 8-bit microcontroller, is used to realize the fast measurement of high-temperature fire smoke velocity. The system is based on the thermodynamic method and adopts the Kalman filter algorithm to process the measurement data, so as to eliminate noise and interference, and reduce measurement error. The experimental results show that the Kalman filter algorithm can effectively improve the measurement accuracy of fire smoke velocity. It is also shown that the system has high measurement accuracy, short reaction time, low cost, and is characterized by high performance in the measurement of high-temperature smoke velocity in experiments and practice.
Źródło:
Archives of Thermodynamics; 2023, 44, 1; 23--36
1231-0956
2083-6023
Pojawia się w:
Archives of Thermodynamics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
45 Years of Deliberations on the Thermo-Mechanical Interpretation of Friction and Wear. Part I: The Macroscopic Interpretation of the Tribological Process 4
45 lat rozważań o cieplno-mechanicznej interpretacji tarcia i zużywania. Część I: interpretacja makroskopowa procesu tribologicznego
Autorzy:
Sadowski, Jan
Powiązania:
https://bibliotekanauki.pl/articles/2134813.pdf
Data publikacji:
2022
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
thermodynamic system
friction couple
friction area
extensive parameters
wear
dissipation heat
work of mechanical dissipation
enthalpy
internal energy
specific work of wear
first law of thermodynamics
system termodynamiczny
para tarciowa
strefa tarcia
parametr ekstensywny
praca tarcia
zużywanie
ciepło dyssypacji
praca dyssypacji mechanicznej
entalpia
energia wewnętrzna
praca właściwa zużycia
pierwsza zasada termodynamiki
Opis:
This first part will consider the friction couple or its part, identified with the open thermodynamic system. Dependences among extensive parameters and energetic interactions in the system and its boundaries with the environment are described in analytical terms. The dimensions of the energy dissipation zone, where the friction of solids takes place, are established. The thermo-mechanical nature of the tribological process is demonstrated. The wear conditions and distribution of energy generated by its particular elements are determined. A new quantity is introduced – the specific work of wear, which characterises the wear resistance of the tribological system and its parts. The effect of the reciprocal cover of solids’ friction surfaces on the energy balance structure in calorimetric testing is analysed. The concept of generalised wear is introduced and standardised. The discussion is restricted to processes at the macroscopic level of matter organisation.
Przedmiotem rozważań w pierwszej części pracy jest para tarciowa lub jej fragment utożsamiona z systemem termodynamicznym otwartym. Opisano analitycznie zależności między parametrami ekstensywnymi i oddziaływaniami energetycznymi w systemie i na jego graniach z otoczeniem. Ustalono wymiary strefy dyssypacji energii, w której zachodzi tarcie ciał stałych. Wykazano cieplno-mechaniczną naturę procesu tribologicznego. Ustalono warunki zachodzenia zużywania i rozdziału energii rozproszonej przez poszczególne jego elementy. Wprowadzono nową wielkość – pracę właściwą zużycia, charakteryzującą odporność na zużywanie systemu tribologicznego i jego elementów. Zanalizowano wpływ wzajemnego przykrycia powierzchni tarcia ciał na strukturę bilansu energii w badaniach kalorymetrycznych. Wprowadzono pojęcie zużycia uogólnionego i jego standaryzację. Rozważania ograniczono do procesów zachodzących na makroskopowym poziomie hierarchicznym organizacji materii.
Źródło:
Tribologia; 2022, 2; 55--66
0208-7774
Pojawia się w:
Tribologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Classical irreversible thermodynamics versus extended irreversible thermodynamics. The role of the continuity equation
Autorzy:
Di Nucci, Carmine
Celli, Daniele
Fischione, Piera
Pasquali, Davide
Powiązania:
https://bibliotekanauki.pl/articles/2091376.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
classical irreversible thermodynamics
extended irreversible thermodynamics
elementary scales method
discrete approach
Opis:
This brief note focuses on a simple fluid, i.e., a homogeneous, chemically inert, and electrically neutral fluid, for which, in the linear nonequilibrium regime, the thermodynamic state is expressed by a relation between pressure, temperature, and density. The approach based on the elementary scales is used to check the validity range of both the classical irreversible thermodynamics and the extended irreversible thermodynamics. The achieved result reveals that the classical irreversible thermodynamics fails in providing an adequate response when the mechanical solicitations exceed limit values.
Źródło:
Archives of Thermodynamics; 2022, 43, 2; 119--127
1231-0956
2083-6023
Pojawia się w:
Archives of Thermodynamics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fundamental study of the photocatalytic reduction of CO2: A short review of thermodynamics, kinetics and mechanisms
Autorzy:
Gandhi, Romil
Moses, Aashish
Baral, Saroj Sundar
Powiązania:
https://bibliotekanauki.pl/articles/2173433.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
CO2 to fuels
hydrocarbon production
thermodynamics
photocatalysis
mechanism
CO2 do paliw
produkcja węglowodorów
termodynamika
fotokataliza
mechanizm
Opis:
On the off chance that methods which reduce the global CO2 content are unavailable and inefficient, the increasing CO2 levels will lead to a synchronized rise in temperature across the world. The conversion of this abundant CO2 into hydrocarbons like CH4, CH3OH, CO, HCOOH and hydrogen fuel using different techniques and their use for power could assist with the world’s energy deficiency and solve the CO2 reduction-energy nexus. In this study, photocatalytic CO2 conversion by sunlight will be of primary focus since this bears a resemblance with the regular photosynthesis phenomenon. This work also portrays the writings that have narrated the development of mixtures of two or more carbon ions (C2 ̧) within the photocatalytic reduction of CO2. This paper thus comprises the energy required for CO2 photoreduction, the kinetics mechanisms and thermodynamics requirements. The reaction of CO with water and the hydrogenation of CO2 are covered to understand the gap of Gibb’s free energy between both of the reactions. Likewise, the summary of different metal-based co-catalysts, metal-free co-catalysts and their selectivity towards CO2 reduction by photocatalysis and reduction of CO2 into various hydrocarbons, fuel and materials have also been examined.
Źródło:
Chemical and Process Engineering; 2022, 43, 2; 223--228
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Termodynamiczne ujęcie teorii godziwego wynagradzania
Thermodynamic approach to the theory of fair remuneration
Autorzy:
Renkas, Jurij
Powiązania:
https://bibliotekanauki.pl/articles/2216847.pdf
Data publikacji:
2022-09-30
Wydawca:
Uniwersytet Rzeszowski. Wydawnictwo Uniwersytetu Rzeszowskiego
Tematy:
płaca godziwa
termodynamika
stała ekonomiczna
zasady fundamentalne
fair wage
thermodynamics
economic constant
fundamental principles
Opis:
Ograniczając się w ramach niniejszego artykułu wyłącznie do zagadnień teorii godziwego wynagradzania, postawiono pytania kluczowe: jakie jest kryterium sprawiedliwego wynagrodzenia, skąd ono pochodzi i gdzie go szukać? Głównym celem niniejszego artykułu jest przedstawienie modelu wynagrodzenia godziwego w ujęciu fundamentalnych zasad termodynamiki. W interpretacji ekonomicznej jest to zasada zachowania kapitału oraz zasada jego spontanicznego i losowego rozpraszania się, co wiąże się z drugą zasadą termodynamiki. Na gruncie termodynamicznej wiedzy o funkcjonowaniu organizmu ludzkiego jako abstrakcyjnego silnika cieplnego przedstawiono termodynamiczny model godziwej płacy, polegający na wyrównaniu pracownikowi naturalnego rozproszenia jego personalnego kapitału. Potwierdzono, że w wyniku stosowania tej zasady wynagradzania zarobki dwojga pracujących rodziców pozwalają doprowadzić dwoje potomków do poziomu osiągniętego przez nich kapitału ludzkiego, czyli płaca ta gwarantuje zachowanie kapitału ludzkiego w rodzinie.
Limiting itself within the framework of this article only to the issues of the theory of fair remuneration, the key questions are: what is the criterion of fair remuneration, where does it come from, and where to look for it? The main purpose of this article is to present a model of a fair wage in terms of the fundamental principles of thermodynamics. In an economic interpretation, this is the principle of preservation of capital and the principle of its spontaneous and random dissipation, which is related to the second principle of thermodynamics. Based on thermodynamic knowledge of the functioning of the human body as an abstract heat engine, a thermodynamic model of a fair wage was presented, which consists in compensating the worker for the natural dissipation of their personal capital. It was confirmed that, as a result of the application of this principle of remuneration, the earnings of two working parents make it possible to bring two descendants to the level of human capital they have achieved: that is, this wage guarantees the preservation of human capital in the family.
Źródło:
Nierówności Społeczne a Wzrost Gospodarczy; 2022, 71; 25-37
1898-5084
2658-0780
Pojawia się w:
Nierówności Społeczne a Wzrost Gospodarczy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The behaviour of tannic acid adsorption on fluorite surface: isotherm, kinetic and thermodynamic studies
Autorzy:
Tangarfa, Mariam
Semlali Aouragh Hassan, Naoul
Powiązania:
https://bibliotekanauki.pl/articles/2146850.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
fluorite
tannic acid
adsorption
kinetic
modelling
isotherm
thermodynamics
reactional parameters
Opis:
Fluorite is an important mineral to produce hydrofluoric acid. As fluorite resources contain calcite as a gangue mineral, the separation between these two calcium containing minerals is difficult. Tannic acid is the most commonly used reagent as a depressant to separate fluorite from calcite by flotation. To enhance this separation, it is so primordial to understand tannic acid physicochemical reactivity via these minerals. Therefore, the aim of this work is to investigate the mechanism of tannic acid adsorption on the fluorite surface by experimental study using isotherm, kinetic and thermodynamic. Adsorption isotherm modelling results showed that the adsorption process is well described by Sips model. On the other hand, the kinetic and thermodynamic require firstly the adsorption study as a function of three main reactional parameters including initial tannic acid concentration, solution pH and temperature. This study showed that acidic pH as well as initial tannic acid concentration increase and temperature decrease promote the studied adsorption. These finding were then exploited to determine the adsorption mechanism by pseudo n order kinetic model adjustment to experimental kinetic data using nonlinear regression method. Obtained high correlation coefficient and low mean absolute error at 95 % confidence level showed good agreement of experimental kinetic data with the tested model. These results revealed that the mechanism of tannic acid adsorption onto fluorite was attributed to a chemical reaction. In addition, the thermodynamic study showed that the studied adsorption process was exothermic.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 1; 77--87
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermodynamics and Kinetics Analysis on Carbothermic Reduction of Calcined Magnesite in Vacuum
Autorzy:
Tang, Qifeng
Ao, Jinqing
Peng, Biyou
Guo, Biao
Yang, Tao
Powiązania:
https://bibliotekanauki.pl/articles/2125546.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
calcined magnesite
carbothermic reduction
vacuum
thermodynamics
kinetics
Opis:
The carbothermic reduction of calcined magnesite in vacuum was studied. By thermodynamic analysis, the starting temperature of reduction reaction dropped from 2173K to 1523K when system pressure dropped from 1 atmosphere to 100 Pa. The experiments were carried out at different conditions under 10~100 Pa and the experimental results shown that the reduction extent of MgO improved by increasing the reaction temperature and time, the pellet forming pressure as well as adding fluoride as catalyst. The rate-determining step of carbothermic reduction process was gas diffusion with the apparent activation energy of 241.19~278.56 kJ/mol.
Źródło:
Archives of Metallurgy and Materials; 2022, 67, 3; 1021--1026
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zrozumienie czasu konsekwencją rozwoju teorii kapitału ludzkiego
Understanding time as a consequence of the development of human capital theory
Autorzy:
Dobija, Mieczysław
Powiązania:
https://bibliotekanauki.pl/articles/2216848.pdf
Data publikacji:
2022-09-30
Wydawca:
Uniwersytet Rzeszowski. Wydawnictwo Uniwersytetu Rzeszowskiego
Tematy:
czas
termodynamika
energia życia
personalny kapitał ludzki
time
thermodynamics
life energy
personal human capital
Opis:
Nauki przyrodnicze i ekonomiczne mają przynajmniej jeden wspólny paradygmat, to jest dualizm materia – energia w fizyce i aktywa – kapitał w ekonomii. W naukach ekonomicznych, zwłaszcza teorii rachunkowości, dualizm jest fundamentalną zasadą, która prowadzi do wyjaśnienia abstrakcyjnej natury kapitału i identyfikacji termodynamicznych podstaw tej kategorii naukowej. Uświadomienie tych relacji przyczyniło się do rozwoju teorii kapitału, która dzięki temu weszła na nowe ścieżki jako teoria kapitału ludzkiego, zwłaszcza jej część dotycząca pomiaru i zachowania personalnego kapitału pracownika. W konsekwencji utwierdziła się wiedza o potencjalnej stałej ekonomicznego wzrostu, a ostatnio, dzięki bardziej precyzyjnemu zrozumieniu transformacji będących przedmiotem termodynamiki, pojawiła się konkluzja, że wspomniana stała wyznacza także tempo biegu czasu. Analizy i badania empiryczne potwierdzają tę hipotezę, co otworzyło drogę do sformułowania definicji czasu.
The natural and economic sciences share at least one paradigm, that is, the matter-energy dualism in physics and the asset-capital dualism in economics. In economic science, especially accounting theory, dualism is a fundamental principle that leads to the explanation of the abstract nature of capital and the identification of the thermodynamic basis of this scientific category. The realisation of these relations contributed to the development of the theory of capital, which thus entered new paths as the theory of human capital, especially its part on the measurement and behaviour of the employee’s personal capital. Consequently, the knowledge of the potential constant of economic growth has been solidified. More recently, thanks to a more precise understanding of the transformations that are the subject of thermodynamics, the conclusion has emerged that the aforementioned constant also determines the rate at which time runs. Analyses and empirical studies confirm this hypothesis, which has opened the way for the formulation of a definition of time.
Źródło:
Nierówności Społeczne a Wzrost Gospodarczy; 2022, 71; 7-24
1898-5084
2658-0780
Pojawia się w:
Nierówności Społeczne a Wzrost Gospodarczy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of mass transfer in marine engine with prechamber combustion spark ignition system
Autorzy:
Pielecha, Ireneusz
Powiązania:
https://bibliotekanauki.pl/articles/2128135.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
marine engine
prechamber combustion spark ignition
combustion process modeling
combustion thermodynamics
silnik morski
zapłon iskrowy spalania w komorze wstępnej
modelowanie procesu spalania
termodynamika spalania
Opis:
The development of combustion systems construction is associated with the possibility of increasing the thermal or overall efficiency of an internal combustion engine. The combustion systems currently in use (mainly related to direct fuel injection) are increasingly being replaced by hybrid systems, including direct and indirect injection. Another alternative is the use of prechambers in new combustion systems. This article concerns the thermodynamic aspect of this issue – namely, the assessment of the inter-chamber f low of a marine engine equipped with a prechamber combustion spark ignition system. The research was carried out using mainly one-dimensional simulation apparatus, and detailed analyses were presented using three-dimensional modeling. The tests included the engine model at medium load. Differences in mass f lows were shown at different diameters and different numbers of holes from the preliminary chamber (while maintaining the same cross-sectional area). Similar values of excess air coefficient during ignition of the fuel dose in the prechamber were observed, which resulted in changes in the f low between the prechamber and the main chamber. The differences in mass f low affected the temperatures achieved in the individual combustion chambers. Based on three-dimensional analyses, the mass transfer rate between the chambers and the temperature distribution were assessed during fuel ignition initiated in the prechamber.
Źródło:
Bulletin of the Polish Academy of Sciences. Technical Sciences; 2021, 69, 2; e136744, 1--8
0239-7528
Pojawia się w:
Bulletin of the Polish Academy of Sciences. Technical Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of mass transfer in marine engine with prechamber combustion spark ignition system
Autorzy:
Pielecha, Ireneusz
Powiązania:
https://bibliotekanauki.pl/articles/2173605.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
marine engine
prechamber combustion spark ignition
combustion process modeling
combustion thermodynamics
silnik morski
zapłon iskrowy spalania w komorze wstępnej
modelowanie procesu spalania
termodynamika spalania
Opis:
The development of combustion systems construction is associated with the possibility of increasing the thermal or overall efficiency of an internal combustion engine. The combustion systems currently in use (mainly related to direct fuel injection) are increasingly being replaced by hybrid systems, including direct and indirect injection. Another alternative is the use of prechambers in new combustion systems. This article concerns the thermodynamic aspect of this issue – namely, the assessment of the inter-chamber f low of a marine engine equipped with a prechamber combustion spark ignition system. The research was carried out using mainly one-dimensional simulation apparatus, and detailed analyses were presented using three-dimensional modeling. The tests included the engine model at medium load. Differences in mass f lows were shown at different diameters and different numbers of holes from the preliminary chamber (while maintaining the same cross-sectional area). Similar values of excess air coefficient during ignition of the fuel dose in the prechamber were observed, which resulted in changes in the f low between the prechamber and the main chamber. The differences in mass f low affected the temperatures achieved in the individual combustion chambers. Based on three-dimensional analyses, the mass transfer rate between the chambers and the temperature distribution were assessed during fuel ignition initiated in the prechamber.
Źródło:
Bulletin of the Polish Academy of Sciences. Technical Sciences; 2021, 69, 2; art. no. e136744
0239-7528
Pojawia się w:
Bulletin of the Polish Academy of Sciences. Technical Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Batch Adsorption Studies on Rice Husk with Methyl Violet Dye
Autorzy:
Omokpariola, Daniel Omeodisemi
Otuosorochi, Joy Njoku
Powiązania:
https://bibliotekanauki.pl/articles/1031501.pdf
Data publikacji:
2021
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Rice husks powder
adsorption
kinetics
methyl red dye
methyl violet
thermodynamics
Opis:
The potential of rice husks powder (RHP) for the removal of methyl violet dye from aqueous solution was investigated. Batch adsorption studies were conducted and various parameters such as contact time, adsorbent dosage, initial dye concentration, pH and temperature were studied to observe their effects in the dye adsorption process. The optimum conditions for the adsorption of MV onto the adsorbent (RHP) was found to be: contact time (100 min) pH (10.0) and temperature (303 K) for an initial dye concentration of 50 mg/l and adsorbent dose of 1.0 g respectively. The experimental equilibrium adsorption data fitted best and well to the Freundlich Isotherm model for both dyes adsorption. The maximum adsorption capacity was found to be 1.66 mg/g for the adsorption of MV dye. The kinetic data conformed to the pseudo second order kinetic model. Thermodynamic quantities such as Gibbs free energy (ΔGº), enthalpy (Δº) and entropy (ΔSº) were evaluated and the negative values of ΔGº, ΔHº and ΔSº obtained indicate the spontaneous and exothermic nature of the adsorption process.
Źródło:
World News of Natural Sciences; 2020, 33; 48-63
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biosorption of Pb(II) by the resistant Enterobacter sp. : Investigated by kinetics, equilibrium and thermodynamics
Autorzy:
Liu, Lei
Xia, Mengya
Hao, Jianwen
Xu, Haoxi
Song, Wencheng
Powiązania:
https://bibliotekanauki.pl/articles/2073764.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Pb(II)
biosorption
enterobacter sp.
kinetics
thermodynamics
Opis:
The Pb(II)-resistant bacterium was isolated from heavy metal-contained soils and used as a biosorbent to remove Pb(II). The strain was identified as Enterobacter sp. based on the 16S rRNA sequence analysis. The effect of biosorption properties (pH value, Pb(II) concentration, bacterial concentration and temperature) on Pb(II) was investigated by batch experiments. Results of FTIR and XPS showed that the biosorption process mainly involved some oxygen-containing groups (-OH and -COOH groups). The experimental results and equilibrium data were fitted by pseudo-second-order kinetic model and Langmuir model, respectively. The experimental biosorption isotherms fitted the Langmuir model, and the maximum biosorption capacity was 40.75 mg/g at 298 K. The calculated ΔGо and ΔHо were –4.06 and 14.91(kJ/mol), respectively, which indicated that biosorption process was spontaneous and endothermic. Results show that Enterobacter sp. will be an efficient biosorbent for Pb(II) removal.
Źródło:
Archives of Environmental Protection; 2021, 47, 3; 28--36
2083-4772
2083-4810
Pojawia się w:
Archives of Environmental Protection
Dostawca treści:
Biblioteka Nauki
Artykuł

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