Informacja

Drogi użytkowniku, aplikacja do prawidłowego działania wymaga obsługi JavaScript. Proszę włącz obsługę JavaScript w Twojej przeglądarce.

English (EN)·Polski (PL)·Yкраїнський (UK)
Przejdź do strony domowej biblioteki Centralna Biblioteka Wojskowa Link otwiera się w nowym oknie Logo biblioteki Prolib Integro - strona głównaCentralna Biblioteka Wojskowa

Wyszukujesz frazę "TOF" wg kryterium: Temat

  Lista filtrów
Wyrównaj
Wyświetlanie 1-15 z 41
Tytuł:
Testing ToF Sensors for Use in Obstacle Detection Systems
Badania czujników ToF pod kątem ich wykorzystania w systemach detekcji przeszkód
Autorzy:
Szczepański, Grzegorz
Shmyk, Aliaksandra
Powiązania:
https://bibliotekanauki.pl/articles/2082111.pdf
Data publikacji:
2022
Wydawca:
Wojskowa Akademia Techniczna im. Jarosława Dąbrowskiego
Tematy:
distance measurement
ToF sensor
obstacle detection
pomiar odległości
czujnik ToF
detekcja przeszkód
Opis:
ToF (Time of Flight) sensors have been gaining popularity in recent times as a cheap and accurate way to take distance measurements. They may prove to be a key component of obstacle detection systems in the near future. This paper presents a stepper motor system with two measurement modules containing ToF sensors. The results of distance measurements made with these modules relative to a flat surface for different sensor modes are presented. Standard deviations were determined for the measurement results and a polynomial fitting was performed using the linear least squares method. The results were used to select the sensor for further work in terms of its use in an obstacle detection system.
Czujniki ToF w ostatnich czasach zdobywają popularność jako tani i dokładny sposób na dokonanie pomiarów odległości. W niedalekiej przyszłości mogą okazać się kluczowym komponentem systemów detekcji przeszkód. W ramach niniejszego artykułu przedstawiono układ z silnikiem krokowym na którym zainstalowano dwa moduły pomiarowe zawierające czujniki ToF. Zaprezentowano wyniki pomiarów odległości przeprowadzonych przy użyciu tych modułów względem płaskiej powierzchni dla różnych trybów działania czujników. Dla wyników pomiarów wyznaczono odchylenia standardowe oraz dokonano dopasowania wielomianu za pomocą liniowej metody najmniejszych kwadratów. Wyniki posłużyły do doboru czujnika do dalszych prac pod kątem jego wykorzystania w systemie detekcji przeszkód.
Źródło:
Problemy Mechatroniki : uzbrojenie, lotnictwo, inżynieria bezpieczeństwa; 2022, 13, 2 (48); 65--74
2081-5891
Pojawia się w:
Problemy Mechatroniki : uzbrojenie, lotnictwo, inżynieria bezpieczeństwa
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Surface characterization of different particles arising as a result of coal combustion process in selected power plants from Central Poland using ToF-SIMS
Autorzy:
Grams, J.
Bawolak, K.
Powiązania:
https://bibliotekanauki.pl/articles/778599.pdf
Data publikacji:
2007
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
ToF-SIMS
cząstka
spalanie węgla
elektrownia
TOF-SIMS
particle
coal combustion
power plant
Opis:
The aim of this work was the ToF-SIMS investigations of different particles arising as a result of a coal combustion process in selected power plants from Central Poland. The chemical composition and distribution of particular compounds on the studied surfaces were determined. Moreover, the ratio of the quantity of aromatic and aliphatic hydrocarbons adsorbed on the surface of the particles was estimated. A qualitative analysis of the studied samples demonstrated the presence of a big number of various compounds, including heavy metals such as Pb, Cd and As on the investigated surfaces. In the prevailing number sample components were distributed non-homogenously on the surface and the larger areas richer in a certain type of ions were observed.
Źródło:
Polish Journal of Chemical Technology; 2007, 9, 4; 77-80
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative proteomic analysis of Bombyx mori hemolymph and fat body after calorie restriction
Autorzy:
Chen, Huiqing
Li, Yijia
Chen, Keping
Yao, Qin
Li, Guohui
Wang, Lin
Powiązania:
https://bibliotekanauki.pl/articles/1040312.pdf
Data publikacji:
2010
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
calorie restriction
Bombyx mori
two-dimensional gel electrophoresis
proteomic analysis
MALDI-TOF/TOF MS
Opis:
Calorie restriction (CR) is known to extend life span from yeast to mammals. To gain an insight into the effects of CR on growth and development of the silkworm Bombyx mori at protein level, we employed comparative proteomic approach to investigate proteomic differences of hemolymph and fat body of the silkworm larvae subjected to CR. Thirty-nine differentially expressed proteins were identified by MALDI TOF/TOF MS. Among them, 19 were from the hemolymph and 20 from the fat body. The hemolymph of the CR group contained two down-regulated and 17 up-regulated proteins, whereas the fat body contained 15 down-regulated and five up-regulated ones. These proteins belonged to those functioning in immune system, in signal transduction and apoptosis, in regulation of growth and development, and in energy metabolism. Our results suggest that CR can alter the expression of proteins related to the above four aspects, implying that these proteins may regulate life span of the silkworm through CR.
Źródło:
Acta Biochimica Polonica; 2010, 57, 4; 505-511
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
ToF-SIMS studies of the surface of Pd/ZrO2-TiO2 catalyst used in the hydrodechlorination process
Autorzy:
Grams, J.
Góralski, J.
KLeczewska, J.
Szczepaniak, B.
Paryjczak, T.
Powiązania:
https://bibliotekanauki.pl/articles/777893.pdf
Data publikacji:
2007
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
ToF-SIMS
pallad
kataliza
wodoroodchlorowanie
ZrO2
TiO2
TOF-SIMS
palladium
catalysis
hydrodechlorination
Opis:
Time-of-flight secondary ion mass spectrometry (ToF-SIMS) was used in order to obtain the information about the surface composition of Pd/ZrO2-TiO2 catalyst and to estimate the changes in the concentration of particular components on its surface during the hydrodechlorination of CCl4. The results demonstrated that the hydrodechlorination process led to the increase in the concentration of chlorine and the drop in the amount of surface accessible palladium, while the quantity of Pd-Cl bounds did not change considerably. It suggested that the presence of ZrO2 protected the surface of the studied catalyst against the formation of PdCI2.
Źródło:
Polish Journal of Chemical Technology; 2007, 9, 3; 81-85
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of the TOF-SIMS and SEM-EDS methods to assess the influence of dusting from a phosphate waste deposal place based on hair analysis
Autorzy:
Szynkowska, M.I.
Leśniewska, E.
Pawlaczyk, A.
Rogowski, J.
Paryjczak, T.
Powiązania:
https://bibliotekanauki.pl/articles/778695.pdf
Data publikacji:
2007
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
fosfogips
analiza powierzchni
włos
SEM-EDS
ToF-SIMS
phosphogypsum
surface analysis
hair
TOF-SIMS
Opis:
In this work, scanning electron microscopy with energy dispersive X-ray spectrometry (SEM-EDS) and the time-of-flight secondary ion mass spectrometry (TOF-SIMS) were used to study the particles present on the hair surface of the inhabitants of Wislinka (people environmentally exposed due to the closeness of a dump) in order to obtain the information about the possible influence of dusting from a phosphate waste deposal place. Additionally, the morphology and the composition of fresh phosphogypsum were analyzed. Waste phosphogypsum is formed in the process of a wet phosphoric acid production and there is still a problem with its storage. A thorough understanding of the composition and chemistry of phosphogypsum seems to be necessary to evaluate its environmental impact comprehensively. The results obtained from these two techniques turned out to be complementary and revealed the information expected.
Źródło:
Polish Journal of Chemical Technology; 2007, 9, 4; 85-90
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization Of Oxide Layers Produced On The AISI 321 Stainless Steel After Annealing
Charakterystyka warstw tlenkowych powstałych na stali nierdzewnej AISI 321 po wyżarzaniu
Autorzy:
Bochnowski, W.
Dziedzic, A.
Adamiak, S.
Berchenko, M.
Trzyna, M.
Cebulski, J.
Powiązania:
https://bibliotekanauki.pl/articles/356285.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
depth profile
oxide layer
stainless steel
TEM
TOF-SIMS
warstwa tlenkowa
stal nierdzewna
TOF SIMS
Opis:
In this study, the structure, chemical composition and topography of oxide layers produced on the surface of the AISI 321 austenitic steel in the annealing process were analyzed. Heat treatment was done at 980°C temperature for 1 hour time in different conditions. The annealing was done in a ceramic furnace in oxidation atmosphere and in vacuum furnaces with cylindrical molybdenum and graphite chambers. The analysis was carried out using the following methods: a scanning electron microscope (SEM) equipped with an energy-dispersive X-ray spectrometer (EDX), a transmission electron microscope (TEM) equipped with an energy-dispersive X-ray spectrometer (EDX), an X-ray diffractometer (XRD), a secondary ion mass spectrometer with time-of-flight mass analyzer (TOF SIMS) and an atomic force microscope (AFM). The oxide layer formed during annealing of the AISI 321 steel at 980°C consisted of sub-layers, diversified in the chemical composition. The thickness of the oxidized layer is depended on the annealing conditions. In a ceramic furnace in oxidation atmosphere, the thickness of the oxide layer was of 300-500 nm, in a vacuum furnace with molybdenum and graphite heating chambers, it ranged from 40 to 300 nm and from a few to 50 nm, respectively. TOF SIMS method allows to get average (for the surface of 100 μm × 100 μm) depth profiles of concentration of particular elements and elements combined with oxygen. In oxide layers formed in vacuum furnaces there are no iron oxides. Titanium, apart from being bounded with carbon in carbides, is a component of the oxide layer formed on the surface of the AISI 321 steel.
W pracy analizowano strukturę, skład chemiczny oraz topografię warstwy tlenków powstałych na powierzchni stali austenitycznej AISI 321 w procesie wyżarzania. Obróbkę cieplną prowadzono w temperaturze 980°C w czasie 1 godziny w zróżnicowanych warunkach. Wyżarzanie prowadzono w piecu ceramicznym w atmosferze powietrza oraz w piecach próżniowych z cylindryczną komorą molibdenową i grafitową. W prowadzonej analizie wykorzystano skaningowy mikroskop elektronowy (SEM) wyposażony w spektrometr promieniowania X (EDX), transmisyjny mikroskop elektronowy (TEM) wyposażony w spektrometr promieniowania X (EDX), dyfraktometr rentgenowski (XRD X-Ray Diffraction), spektrometr mas jonów wtórnych z analizatorem czasu przelotu (TOF SIMS) oraz mikroskop sił atomowych (AFM). Warstwa tlenków powstała w wyniku wyżarzania stali AISI 321 w temperaturze 980°C składała się z podwarstw różniących się składem chemicznym. O grubości warstwy utlenionej w decydowały warunki wyżarzania. W piecu ceramicznym z atmosferą powietrza grubość warstwy tlenków wynosiła 300-500 μm, w piecu próżniowym z grafitową i molibdenową komorą grzejną grubości wynosiły odpowiednio od 40 nm do 300 nm oraz kilka nm do 50 nm. Badania TOF SIMS pozwalają otrzymać uśrednione profile koncentracji pierwiastków metalicznych oraz profile koncentracji pierwiastków metalicznych będących w kontakcie z tlenem. W warstwach tlenków powstałych w piecach próżniowych nie obserwowano tlenków żelaza. Tytan oprócz roli związania węgla w węglikach, wchodzi w skład warstwy tlenków tworzonych w piecu próżniowym na powierzchni stali AISI 321.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 3; 2327-2334
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Localization of the attachment site of oligoglucans to Mesorhizobium loti HAMBI 1148 murein
Autorzy:
Karaś, Magdalena
Russa, Ryszard
Powiązania:
https://bibliotekanauki.pl/articles/1040650.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
oligoglucan
murein
MALDI-TOF
deamination
Mesorhizobium
Opis:
The location and nature of the linkage between peptidoglycan and oligoglucans in the cell wall of Mesorhizobium loti HAMBI 1148 have been defined by the analysis of nitrous acid deamination of peptidoglycan glucosaminyl residues. The MurNH2-Glcn fraction was obtained after converting deaminoacylated and N-deacetylated muramyl residues in the cell wall preparation to lactam forms which were stable during subsequent deamination, followed by reduction and opening of the lactams. GC/MS analysis of this material, subjected to partial hydrolysis and reduction or to methanolysis followed by peracetylation, confirmed the presence of glucosyl residues glycosidically attached to muramic acid. The MALDI-TOF spectroscopic analysis of the deaminated material also revealed the presence of [M-H]- or [M+Na-2H]- ions representing fragments containing muramic acid with one to three linked glucose residues. The analysis of fully methylated neutral oligosaccharides released from the peptidoglycan with lysozyme followed by borohydride reduction showed the presence of di- and trisaccharides lacking the reducing end.
Źródło:
Acta Biochimica Polonica; 2009, 56, 1; 155-160
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
THE RADIOSTABILITY OF BETAMIPRON IN THE SOLID STATE
Autorzy:
Zalewski, Przemysław
Kilińska, Karolina
Cielecka-Piontek, Judyta
Skibiński, Robert
Miklaszewski, Andrzej
Bednarski, Waldemar
Powiązania:
https://bibliotekanauki.pl/articles/895691.pdf
Data publikacji:
2019-08-30
Wydawca:
Polskie Towarzystwo Farmaceutyczne
Tematy:
EPR
radiation sterilization
radiostability
Q-TOF
betamipron
Opis:
The influence of ionising radiation on physicochemical properties of betamipron in solid state was studied. No changes for betamipron irradiated with a dose of 25 kGy, required to attain sterility, was observed by spectroscopic and chromatographic methods. Solid betamipron has proven to be very stable on irradiation, and irradiation has been found to be a suitable method for its sterilization.
Źródło:
Acta Poloniae Pharmaceutica - Drug Research; 2019, 76, 4; 629-634
0001-6837
2353-5288
Pojawia się w:
Acta Poloniae Pharmaceutica - Drug Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
THE RADIOLYTIC STUDIES OF DORIPENEM MONOHYDRATE IN THE SOLID STATE
Autorzy:
Zalewski, Przemysław
Kilińska, Karolina
Piontek, Judyta C.
Skibiński, Robert
Szymanowska, Daria
Miklaszewski, Andrzej
Bednarski, Waldemar
Powiązania:
https://bibliotekanauki.pl/articles/895484.pdf
Data publikacji:
2018-10-31
Wydawca:
Polskie Towarzystwo Farmaceutyczne
Tematy:
doripenem
radiation sterilization
microbiological activity
radiostability
Q-TOF
Opis:
The influence of ionising radiation on physicochemical properties of doripenem in solid state was studied. No changes for doripenem irradiated with a dose of 25 kGy, required to attain sterility, was observed by FT-IR and chromatographic methods, although the presence of free radicals (7.7*1017 radicals/g) was detected by EPR. The antibacterial activity of doripenem irradiated with a dose of 25 kGy was unchanged. Solid doripenem has proven to be very stable on irradiation, and irradiation has been found to be a suitable method for its sterilization.
Źródło:
Acta Poloniae Pharmaceutica - Drug Research; 2018, 75, 5; 1127-1133
0001-6837
2353-5288
Pojawia się w:
Acta Poloniae Pharmaceutica - Drug Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nasal carriage of various staphylococcal species in small ruminant lentivirus-infected asymptomatic goats
Autorzy:
Moroz, A.
Szaluś-Jordanow, O.
Czopowicz, M.
Brodzik, K.
Petroniec, V.
Augustynowicz-Kopeć, E.
Lutyńska, A.
Roszczynko, M.
Gołoś-Wójcicka, A.
Korzeniowska-Kowal, A.
Gamian, A.
Mickiewicz, M.
Frymus, T.
Petelicka, H.
Kaba, J.
Powiązania:
https://bibliotekanauki.pl/articles/2087322.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
caprine arthritis-encephalitis
MALDI-TOF
PFGE
Staphylococcus aureus
Źródło:
Polish Journal of Veterinary Sciences; 2020, 23, 2; 203-209
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Identification of bacterial species in milk by MALDI-TOF and assessment of some oxidant-antioxidant parameters in blood and milk from cows with different health status of the udder
Autorzy:
Ozbey, G.
Cambay, Z.
Yilmaz, S.
Aytekin, O.
Zigo, F.
Ozçelik, M.
Otlu, B.
Powiązania:
https://bibliotekanauki.pl/articles/16539172.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
dairy cows
CMT
mastitis
malondialdehyde
glutathione
MALDI-TOF
Opis:
This study aimed to identify bacterial pathogens in milk samples from dairy cows with subclinical and clinical mastitis as well as to assess the concentrations of oxidant-antioxidant parameters [malondialdehyde (MDA), reduced glutathione (GSH), and total GSH levels] in both blood and milk samples. From a total of 200 dairy cows in 8 farms, 800 quarter milk samples obtained from each udder were tested in the laboratory for the presence of udder pathogens. Cultivated bacteria causing intramammary infection from milk samples were identified by Matrix-Assisted Laser Desorption/Ionization-Time of Flight (MALDI-TOF). In addition, from tested animals 60 cows were selected includıng 20 healthy cows that were CMT negative, 20 cows with subclinical mastitis (SM), and 20 cows with clinical mastitis (CM) for detection of MDA, GSH, and total GSH levels in blood and milk samples. Three hundred and eighty (47.5%; 380/800), 300 (37.5%; 300/800), and 120 (15%; 120/800) of milk samples, respectively were CMT positive or SM and CM, and those positives were cows from different farms. We observed that 87.4% (332/380), 25.3% (76/300), and 34.2% (41/120) of cows with CMT positive, CMT negative, and CM had bacterial growth. The most predominantly identified bacteria were Staphylococcus chromogenes (18.7%) obtained mainly from SM and Staphylococcus aureus (16.7%) as the most frequent cause of CM. According to our results, dairy cows with CM had the highest MDA levels, the lowest GSH, and total GSH levels in both blood and milk samples however, high MDA levels and low GSH levels in milk samples with SM were observed. Based on our results, lipid oxidant MDA and antioxidant GSH could be excellent biomarkers of cow’s milk for developing inflammation of the mammary gland. In addition, there was no link between nutrition and MDA and GSH levels.
Źródło:
Polish Journal of Veterinary Sciences; 2022, 25, 2; 269-277
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Processing optimization with parallel computing for the J-PET scanner
Autorzy:
Krzemień, W.
Bała, M.
Bednarski, T.
Białas, P.
Czerwiński, E.
Gajos, A.
Gorgol, M.
Jasińska, B.
Kamińska, D.
Kapłon, Ł.
Korcyl, G.
Kowalski, P.
Kozik, T.
Kubicz, E.
Niedźwiecki, S.
Pałka, M.
Raczyński, L.
Rudy, Z.
Rundel, O.
Sharma, N. G.
Silarski, M.
Słomski, A.
Stola, K.
Strzelecki, A.
Trybek, D.
Wieczorek, A.
Wiślicki, W.
Zieliński, M.
Zgardzińska, B.
Moskal, P.
Powiązania:
https://bibliotekanauki.pl/articles/148285.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
data aquisition system (DAQ)
parallel computing
TOF-PET
Opis:
The Jagiellonian Positron Emission Tomograph (J-PET) collaboration is developing a prototype time of flight (TOF)-positron emission tomograph (PET) detector based on long polymer scintillators. This novel approach exploits the excellent time properties of the plastic scintillators, which permit very precise time measurements. The very fast fi eld programmable gate array (FPGA)-based front-end electronics and the data acquisition system, as well as low- and high-level reconstruction algorithms were specially developed to be used with the J-PET scanner. The TOF-PET data processing and reconstruction are time and resource demanding operations, especially in the case of a large acceptance detector that works in triggerless data acquisition mode. In this article, we discuss the parallel computing methods applied to optimize the data processing for the J-PET detector. We begin with general concepts of parallel computing and then we discuss several applications of those techniques in the J-PET data processing.
Źródło:
Nukleonika; 2015, 60, No. 4, part 1; 745-748
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
THE RADIATION STERILIZATION OF IMIPENEM AND CILASTATIN IN THE SOLID STATE
Autorzy:
Zalewski, Przemysław
Kilińska, Karolina
Piontek, Judyta C.
Miklaszewski, Andrzej
Szymanowska, Daria
Skibiński, Robert
Bednarski, Waldemar
Powiązania:
https://bibliotekanauki.pl/articles/895601.pdf
Data publikacji:
2019-06-28
Wydawca:
Polskie Towarzystwo Farmaceutyczne
Tematy:
imipenem
radiation sterilization
microbiological activity
radiostability
Q-TOF
Opis:
One of the best sterilization methods for chemically unstable drugs, such as carbapenems, is irradiation. The chemical and physical properties of radiosterilized imipenem and cilastatin were analyzed using spectrophotometric and chromatographic methods. Unstable free radicals were presented in samples after irradiation; their mean lifetime was 142±64 h. The antibacterial activity of cefozopran hydrochloride irradiated with a dose of 25 kGy changed for Klebsiella pneumoniae and Escherichia coli. Imipenem and cilastatin in the solid state are not resistant to radiation sterilization; therefore, this method cannot be used for sterilization of this compound.
Źródło:
Acta Poloniae Pharmaceutica - Drug Research; 2019, 76, 3; 431-438
0001-6837
2353-5288
Pojawia się w:
Acta Poloniae Pharmaceutica - Drug Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
DFT and TOF-SIMS study of the interaction between hydrogen sulfide ion and malachite (–201) surface
Autorzy:
Mao, Yingbo
Wu, Dandan
Huang, Lingyun
Powiązania:
https://bibliotekanauki.pl/articles/1447053.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
malachite
hydrogen sulfide ions
sulfidation
DFT
TOF-SIMS
Opis:
In this paper, the mechanism of interaction between hydrogen sulfide ions and malachite was investigated using density functional theory (DFT) calculations and time of flight secondary ion mass spectrometry (TOF-SIMS). The DFT calculations showed that HS− adsorption on the malachite (−201) surface was stronger than that of S adsorption resulting from the higher number of electron transfers in the solution which accelerated the sulfidation reaction rate. Density of states (DOS) analysis showed that the near Fermi level was jointly contributed to by the Cu 3d, O 2p, O 2S, and S 3P orbits after adsorption of HS− on the malachite (–201)surface. It was found that the 2p orbital of O and the 3p orbital of S overlapped, indicating that S not only reacted with Cu, but also with O. The TOF-SIMS detected S− and CuS2− fragment ion peaks in the 0−150 m/z negative segment of mass spectra. TOF-SIMS also showed that copper sulfide films of certain thicknesses were formed, demonstrating the effectiveness of hydrogen sulfide sulfidation in flotation processes.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 5; 71-79
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The radiolytic studies of panipenem in the solid state
Autorzy:
Zalewski, Przemysław
Rosiak, Natalia
Kilińska, Karolina
Skibiński, Robert
Szymanowska, Daria
Tykarska, Ewa
Piekara-Sady, Lidia
Lewandowska, Kornelia
Miklaszewski, Andrzej
Piontek, Judyta C.
Powiązania:
https://bibliotekanauki.pl/articles/895501.pdf
Data publikacji:
2020-04-29
Wydawca:
Polskie Towarzystwo Farmaceutyczne
Tematy:
HPLC
FT-IR
EPR
radiation sterilization
Q-TOF
panipenem
Opis:
The influence of ionizing radiation on the physicochemical properties of panipenem in solid state was studied. In the first part of our studies, we evaluated the possibility of applying radiosterilization to obtain sterile panipenem. Spectroscopic (FT-IR, Raman), chromatography (HPLC and HPLC-MS) and X-ray powder diffraction (XRPD) studies have shown that irradiation of ertapenem with the 25 kGy, the dose required to achieve sterility, does not change the physicochemical properties of the studied compound. The antimicrobial activity of panipenem irradiated with the dose of 25 kGy was reduced for three species. It was confirmed that the decrease in antimicrobial activity might be related to isomerization of panipenem.
Źródło:
Acta Poloniae Pharmaceutica - Drug Research; 2020, 77, 2; 241-250
0001-6837
2353-5288
Pojawia się w:
Acta Poloniae Pharmaceutica - Drug Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 41

Ta witryna wykorzystuje pliki cookies do przechowywania informacji na Twoim komputerze. Pliki cookies stosujemy w celu świadczenia usług na najwyższym poziomie, w tym w sposób dostosowany do indywidualnych potrzeb. Korzystanie z witryny bez zmiany ustawień dotyczących cookies oznacza, że będą one zamieszczane w Twoim komputerze. W każdym momencie możesz dokonać zmiany ustawień dotyczących cookies