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Wyszukujesz frazę "Structural properties" wg kryterium: Temat


Tytuł:
A computational approach to structural properties of glycoside hydrolase family 4 from bacteria
Autorzy:
Craciun, Dana
Vlad-Oros, Beatrice
Filimon, Nicoleta
Ostafe, Vasile
Isvoran, Adriana
Powiązania:
https://bibliotekanauki.pl/articles/1039444.pdf
Data publikacji:
2013
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
glycosidases
structural properties
specific interactions
Opis:
Structural bioinformatics approaches applied to the alpha- and beta-glycosidases from the GH4 enzyme family reveal that, despite low sequence identity, these enzymes possess quite similar global structural characteristics reflecting a common reaction mechanism. Locally, there are a few distinctive structural characteristics of GH4 alpha- and beta-glycosidases, namely, surface cavities with different geometric characteristics and two regions with highly dissimilar structural organizations and distinct physicochemical properties in the alpha- and beta-glucosidases from Thermotoga maritima. We suggest that these structurally dissimilar regions may be involved in specific protein-protein interactions and this hypothesis is sustained by the predicted distinct functional partners of the investigated proteins. Also, we predict that alpha- and beta-glycosidases from the GH4 enzyme family interact with difenoconazole, a fungicide, but there are different features of these interactions especially concerning the identified structurally distinct regions of the investigated proteins.
Źródło:
Acta Biochimica Polonica; 2013, 60, 4; 553-564
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structural characteristics of thermosensitive chitosan glutaminate hydrogels
Autorzy:
Modrzejewska, Zofia
Nawrotek, Katarzyna
Zarzycki, R
Douglas, Timothz
Powiązania:
https://bibliotekanauki.pl/articles/1035319.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
chitosan
hydrogel
natural polymer
structural properties
Opis:
Hydrogels that possess the ability of gelling in response to changes in the local environment, such as pH or temperature, have been examined extensively recently. In this paper the properties of thermosensitive chitosan hydrogels prepared with the use of chitosan glutaminate and -glycerophosphate are presented. The sol/gel transition point was determined based on the rheological properties. The structure of gels was observed under the Scanning Electron Microscopy (SEM) and was investigated by thermogravimetric (TG) and differential themogravimetric (DTG) analy¬sis and infrared (IR) spectroscopy. The crystallinity of gel structure was determined by X-ray Diffraction analysis (XRD).
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2013, 18, 18; 93-105
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structural and optical properties of nanostructured bismuth oxide
Autorzy:
Ali, R. S.
Powiązania:
https://bibliotekanauki.pl/articles/412556.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
thin films’ bismuth oxide
optical properties
structural properties
Opis:
Thin films of bismuth oxide have been prepared utilizing vacuum evaporation. XRD anyalysis reveal that all the films were tetragonal polycrystalline structure with a preferred orientation along (002) plane. SEM images indicate that the grain size fall in the category of nanosize. AFM results assure that the nanonstructure behavior of thin films. Optical studies show that these films have a direct transition with optical energy gap equal to 2.5 eV.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 15; 64-72
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Advanced biocomposites based on silica and lignin precursors
Autorzy:
Klapiszewski, Ł.
Nowacka, M.
Szwarc-Rzepka, K.
Jesionowski, T.
Powiązania:
https://bibliotekanauki.pl/articles/110719.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
biocomposites
silica
lignin
physicochemical and structural properties
Opis:
A new method is proposed for obtaining biocomposites based on a combination of silica and lignin precursors. Amorphous silica was produced by two methods: one based on hydrolysis and condensation of tetraethoxysilane (sol–gel method) and the other involving precipitation in a polar medium. Additionally, the commercial silica known under the name of Syloid®244 was used. The silica surface was modified to ensure better affinity of the support to activated lignin. The biocomposites obtained were carefully characterised by determination of their physicochemical and dispersive–morphological properties. Electrokinetic stability of the biocomposites was evaluated on the basis of zeta potential dependence on pH. Thermal stability of the biocomposites and their porous structure parameters (surface area, pore diameter and pore volume) were established. The results indicate that silica/lignin biocomposites are much promising for application in many areas of science and industry.
Źródło:
Physicochemical Problems of Mineral Processing; 2013, 49, 2; 497-509
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Research on quantifying the hydrophilicity of leached coals by FTIR spectroscopy
Autorzy:
Wang, J.
He, Y.
Yang, Y.
Xie, W.
Ling, X.
Powiązania:
https://bibliotekanauki.pl/articles/110191.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
chemical-structural properties
macerals
hydrophilicity
functional group
Opis:
Surface properties play important roles in characterization of structural parameters and the hydrophilicity index. Accurate analysis of the macerals rather than the average properties of the macerals and minerals are crucial for these parameters and indexes. In order to improve the accuracy of analyzing coal surface property, HF/HCl acid leaching was applied to eliminate the interference of minerals. FTIR was used to characterize the differences in surface chemical composition between raw and processed coal. Moreover, each functional group was analyzed quantitatively. Based on these quantitative data, the structural parameters and hydrophilicity indexes were calculated. From the results of FTIR, the peaks of mineral cover up the types of the organic peaks, such as -COOH and aromatic CH stretching. In addition, they decrease the intensity of the peak such as C=C and aromatics CHx out-of-plane deformation in the spectra of raw coals. However, it provided the accurate types and contents of organic functional groups of the macerals after acid leaching. The structural parameter results indicate that the values cannot reflect the coal ranks through the surface properties of raw coals while they show a good relationship with the degree of coalification in the analysis of processed coals. Besides, the hydrophilicity indexes are verified by the natural floatability of coal macerals of the processed coals. It is also found that the processed lignite coal cannot be floated despite elimination of the hydrophilic minerals. The main reason of hard-to-float property of lignite coal lies in a strong hydrophilicity of macerals.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 1; 227-239
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption behavior of Zn(II) onto natural minerals in wastewater. A comparative study of bentonite and kaolinite
Autorzy:
Chai, W.
Huang, Y.
Su, S.
Han, G.
Liu, J.
Cao, Y.
Powiązania:
https://bibliotekanauki.pl/articles/109926.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
adsorption
Zn(II)
wastewater
clay minerals
structural properties
Opis:
In order to remove the harmful metal ions in lead-zinc mineral processing wastewater, two natural clay minerals (bentonite and kaolin) were used as adsorbents and Zn(II) ions were the emphasis in this work. The adsorption behaviors including kinetics and isotherms were investigated by batch experiments. In addition, the adsorption mechanisms were studied by means of zeta potential testing, optical microscope and XRD analysis. The results show that the adsorption process can be best described as the pseudo-second order kinetic model. The adsorption equilibrium data of bentonite and kaolinite can be respectively fitted best by Langmuir and Freundlich models. Thermodynamic studies display that the adsorption of Zn(II) onto clays is non-spontaneous and endothermic. The maximum capacity of Zn(II) adsorbed on bentonite and kaolinite respectively reaches to 79.2 mg·g-1 and 6.35 mg·g-1 at 25 °C. The structural differences of bentonite and kaolinite result in the differences in adsorption behavior and mechanism. The interaction mechanisms of Zn(II) with bentonite and kaolinite involve electrostatic attraction, cation exchange, surface complex and precipitation. Bentonite as adsorbent has the potential to remove Zn2+ better than kaolinite.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 1; 264-278
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of molarity on the structural and optical properties of ZnO thin films deposit by CSP
Autorzy:
Habubi, Nadir F.
Abood, Ziad M.
Algamel, Ahmed N.
Powiązania:
https://bibliotekanauki.pl/articles/1193915.pdf
Data publikacji:
2015
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Urbach energy
ZnO
ZnO thin films
optical properties
structural properties
Opis:
ZnO thin films have been prepared by chemical spray pyrolysis technique CSP). XRD pattern reveals that the preferred orientation was varied with concentration, topography analysis was done by AFM micrograph which confirm the existence of nonstructural films. The optical properties was done by recorded the transmittane and absorbance which were affected by an increase in concentration. The values of optical energy gap obtained from Tauc relation were 3.17, 3.18 and 3.19 eV for 0.05, 0.1 and 0.5 M respectively. Urbach energy confirms the decrease in band tail as the concentration increase.
Źródło:
World Scientific News; 2015, 22; 55-69
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structural and Electrical Properties of SnO₂:F Thin Films Prepared by Chemical Vapor Deposition Method
Autorzy:
Najafi, N.
Rozati, S.
Powiązania:
https://bibliotekanauki.pl/articles/1030319.pdf
Data publikacji:
2017-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
chemical vapor deposition
SnO₂:F thin films
structural properties
electrical properties
Opis:
Fluorine doped tin oxide (FTO) thin films were deposited onto glass substrate at different substrate temperatures by a simple and inexpensive method of air pressure chemical vapor deposition. The substrate temperature was kept constant at about 500°C as the optimum temperature, and air was used as both a carrier gas and the oxidizing agent. A very simple method of characterization were carried on to investigate the electrical and structural properties of the prepared thin films. The electrical parameters variations showed that these parameters vary with substrate temperature ranging from an insulator thin film to a highly conductive layer. X-ray diffraction also revealed the structure to be polycrystalline at higher temperatures compared to amorphous structure for lower temperatures.
Źródło:
Acta Physica Polonica A; 2017, 131, 2; 222-225
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Some structural properties of plant serine:glyoxylate aminotransferase?
Autorzy:
Truszkiewicz, Wiesław
Paszkowski, Andrzej
Powiązania:
https://bibliotekanauki.pl/articles/1041442.pdf
Data publikacji:
2005
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
structural properties
peroxisomes
wheat
photorespiration
serine : glyoxylate aminotransferase
maize
Opis:
The structural properties of photorespiratory serine:glyoxylate aminotransferases (SGAT, EC 2.6.1.45) from maize (Zea mays L.) and wheat (Triticum aestivum L.) leaves were examined. By means of molecular sieving on Zorbax SE-250 column and filtration through centrifugal filters it was shown that dimers of wheat enzyme (molecular mass of about 90 kDa) dissociate into component monomers (molecular mass of about 45 kDa) upon decrease in pH value (from 9.1 or 7.0 to 6.5). At pH 9.1 a 50-fold decrease of ionic strength elicited a similar effect. Under the same conditions homodimers of the maize enzyme (molecular mass similar to that of the wheat enzyme) remained stable. Immunoblot analysis with polyclonal antiserum against wheat seedling SGAT on leaf homogenates or highly purified preparations of both enzymes showed that the immunogenic portions of the wheat enzyme are divergent from those of the maize enzyme. The sequence of 136 amino acids of the maize enzyme and 78 amino acids of the wheat enzyme was established by tandem mass spectrometry with time of flight analyzer. The two enzymes likely share similarity in tertiary and quaternary structures as well as high level of hydrophobicity on their molecular surfaces. They likely differ in the mechanism of transport from the site of biosynthesis to peroxisomes as well as in some aspects of secondary structure.
Źródło:
Acta Biochimica Polonica; 2005, 52, 2; 527-534
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Describing Minor 5-Stars in 3-Polytopes with Minimum Degree 5 and No Vertices of Degree 6 or 7
Autorzy:
Batueva, Ts.Ch-D.
Borodin, O.V.
Ivanova, A.O.
Nikiforov, D.V.
Powiązania:
https://bibliotekanauki.pl/articles/32361718.pdf
Data publikacji:
2022-05-01
Wydawca:
Uniwersytet Zielonogórski. Wydział Matematyki, Informatyki i Ekonometrii
Tematy:
planar graph
structural properties
3-polytope
5-star
neighborhood
Opis:
In 1940, in attempts to solve the Four Color Problem, Henry Lebesgue gave an approximate description of the neighborhoods of 5-vertices in the class P5 of 3-polytopes with minimum degree 5. This description depends on 32 main parameters. (6, 6, 7, 7, 7), (6, 6, 6, 7, 9), (6, 6, 6, 6, 11), (5, 6, 7, 7, 8), (5, 6, 6, 7, 12), (5, 6, 6, 8, 10), (5, 6, 6, 6, 17), (5, 5, 7, 7, 13), (5, 5, 7, 8, 10), (5, 5, 6, 7, 27), (5, 5, 6, 6, ∞), (5, 5, 6, 8, 15), (5, 5, 6, 9, 11), (5, 5, 5, 7, 41), (5, 5, 5, 8, 23), (5, 5, 5, 9, 17), (5, 5, 5, 10, 14), (5, 5, 5, 11, 13) Not many precise upper bounds on these parameters have been obtained as yet, even for restricted subclasses in P5. In 2018, Borodin, Ivanova, Kazak proved that every forbidding vertices of degree from 7 to 11 results in a tight description (5, 5, 6, 6, ∞), (5, 6, 6, 6, 15), (6, 6, 6, 6, 6). Recently, Borodin, Ivanova, and Kazak proved every 3-polytope in P5 with no vertices of degrees 6, 7, and 8 has a 5-vertex whose neighborhood is majorized by one of the sequences (5, 5, 5, 5, ∞) and (5, 5, 10, 5, 12), which is tight and improves a corresponding description (5, 5, 5, 5, ∞), (5, 5, 9, 5, 17), (5, 5, 10, 5, 14), (5, 5, 11, 5, 13) that follows from the Lebesgue Theorem. The purpose of this paper is to prove that every 3-polytope with minimum degree 5 and no vertices of degree 6 or 7 has a 5-vertex whose neighborhood is majorized by one of the ordered sequences (5, 5, 5, 5, ∞), (5, 5, 8, 5, 14), or (5, 5, 10, 5, 12).
Źródło:
Discussiones Mathematicae Graph Theory; 2022, 42, 2; 535-548
2083-5892
Pojawia się w:
Discussiones Mathematicae Graph Theory
Dostawca treści:
Biblioteka Nauki
Artykuł

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