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Tytuł:
Spectral correlations and antimicrobial activities of some 1-pyrenyl chalcones
Autorzy:
Arulkumaran, R.
Vijayakumar, S.
Sundararajan, R.
Sakthinathan, S.P.
Kamalakkannan, D.
Suresh, R.
Ranganathan, K.
Rajakumar, P.R.
Powiązania:
https://bibliotekanauki.pl/articles/411776.pdf
Data publikacji:
2013
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
substituted styryl 1-pyrenyl ketones
UV spectra
IR spectra
NMR spectra
substituent effects
antimicrobial activities
Opis:
A series of 1-pyrenyl chalcones have been synthesized by Crossed-Aldol condensation of 1-acetylpyrene and substituted benzaldehydes. The purities of these chalcones have been checked by their physical constants, UV, IR, NMR and MASS spectral data. The spectral data of these chalcones have been correlated with Hammett sigma constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents on the spectral group frequencies have been discussed. The anti-microbial activities of these chalcones have been evaluated using Bauer-Kirby method.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2013, 5; 21-38
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Assessment of substituent effects on β-naphthyl based isoxazoles by IR and NMR spectra
Autorzy:
Thirunarayanan, G.
Sathiyendiran, V.
Arulkumarn, R.
Sundararrajan, R.
Manikandan, R.
Vanangamud, G.
Powiązania:
https://bibliotekanauki.pl/articles/1194022.pdf
Data publikacji:
2015
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Correlation analysis
IR spectra
NMR spectra
β-naphthyl dihydroisoxazoles
Opis:
A series containing thirteen 3-(2-naphthyl)-5-(substituted phenyl)-4,5-dihydroisoxazole have been synthesized and examined their purities by their data reported earlier. The characteristic infrared νC=N (cm-1) stretches, NMR chemical shifts (δ, ppm) of H4,4׳, H5 protons, C3-5 carbons were assigned and correlated with Hammett substituent constants and Swain-Lupton’s parameters using single and multi- regression analysis. From the results of regression analysis the effect of substituents on the spectral data have been studied.
Źródło:
World Scientific News; 2015, 9; 35-58
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structure parameter correlation of some quinoxaline derivatives through IR and 13C NMR spectra
Autorzy:
Thirunarayanan, G.
Muthuvel, I.
Sathiyendiran, V.
Powiązania:
https://bibliotekanauki.pl/articles/412003.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Quinoxalines
IR spectra
NMR spectra
Hammett Correlation
substituent effects
Opis:
A series of 6-substituted quanoxaline derivatives have been synthesized and examined their purities by literature method. The infrared and 13>/Sup>C NMR spectral data of these quinoxalines were correlated with Hammett substituent constants, F and R parameters using single and multi-regression analysis. From the results of statistical analysis, the effect of substituents on the spectral frequencies has been studied.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 19, 2; 198-207
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, spectroscopic characterization and antimicrobial evaluation of some (E)-N-(4-substitutedbenzylidene)-4-fluorobenzenesulfonamides
Autorzy:
Jayanthi, P.
Jesu Retna Raj, G.
Sekar, M.
Thanikachalam, V.
Powiązania:
https://bibliotekanauki.pl/articles/1113828.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
4-fluorobenzenesulfonamide
Bauer-Kirby
IR spectra
NMR spectra
antimicrobial activities
Opis:
In the present study, six numbers of Schiff bases (1-6) have been synthesized by the condensation of 4-fluorobenzenesulfonamide and substituted aromatic aldehyde. The purities of these Schiff bases have been checked by their physical constants, IR, 1H NMR and 13CNMR spectral data. The antimicrobial activities of these Schiff bases have been evaluated using Bauer-Kirby method.
Źródło:
World News of Natural Sciences; 2017, 13; 101-112
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectral correlation analysis and antimicrobial activities of some 2,4-dimethoxy phenyl chalcones
Autorzy:
Joseph, S. J.
Arulkumaran, R.
Kamalakkannan, D.
Sakthinathan, S. P.
Sundararajan, R.
Suresh, R.
Vijayakumar, S.
Ranganathan, K.
Kalyanasundaram, N.
Vanangamudi, G.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/412661.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
substituted styryl 2
4-dimethoxy phenyl ketones
UV spectra
IR spectra
NMR spectra
substituent effects
antimicrobial activities
Opis:
A series of 2,4-dimethoxy phenyl chalcones have been synthesized by Crossed-Aldol condensation of 2,4-dimethoxy phenyl and various substituted benzaldehydes. The purities of these chalcones have been checked by their physical constants, UV, IR, NMR and MASS spectral data. The spectral data of these chalcones have been correlated with Hammett sigma constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effects of substituents on the spectral group frequencies have been discussed. The anti-microbial activities of these chalcones have been evaluated using Bauer-Kirby method.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 4; 48-65
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hammett spectral correlations in benzofuranyl flavonols
Autorzy:
Thirunarayanan, G.
Sekar, K. G.
Powiązania:
https://bibliotekanauki.pl/articles/412326.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Benzofuranyl flavonols
Hammett equation
IR spectra
NMR spectra
Regression analysis
Opis:
A series containing eleven benzofuranyl flavonols have been prepared by cyclization of 3-hydroxybenzofuranyl chalcones with 30 % hydrogen peroxide in the presence of sodium bicarbonate. The synthesized flavonols were characterized by their physical constants, analytical and spectroscopic data. The infrared spectral νOH, CO stretches(cm-1), NMR chemical shifts of OH, CO(δ, ppm) of these flavonols were assigned and correlated with Hammett substituent constants, F and R parameters using single and multi linear regression analysis. From the results of statistical analyses, the effects of substituents on the above group frequencies were discussed.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 6; 39-47
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Assessment of substituent effects and antimicrobial activities of some 2ʹ,5ʹ-dimethyl phenyl chalcones
Autorzy:
Joseph, S. J.
Kamalakkannan, D.
Arulkumaran, R.
Sakthinathan, S. P.
Suresh, R.
Sundararajan, R.
Vijayakumar, S.
Ranganathan, K.
Vanangamudi, G.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/412597.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
substituted styryl 2
5ʹ-dimethyl phenyl chalcones
UV spectra
IR spectra
NMR spectra
substituent effects
antimicrobial activities
Opis:
Some 2ʹ,5ʹ-dimethyl phenyl chalcones have been synthesized by Crossed-Aldol condensation between 2,5-dimethyl acetophenone and various substituted benzaldehydes using catalytic amount of sodium hydroxide and ethanol. The yields of the chalcones are more than 93 %. The purities of these chalcones have been checked by their physical constants, UV, IR, NMR and MASS spectral data. The spectral data of these chalcones have been correlated with Hammett sigma constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effects of substituents on the spectral group frequencies have been discussed. The anti-microbial activities of these chalcones have been evaluated using Bauer-Kirby method.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 5; 99-123
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
IR and NMR spectral studies of some 4-(6-methoxy-2-naphthyl)-5,6-dihydro-6-(substituted phenyl)-4H-1,3-oxazine-2-amines: Assessment of substituent effects
Autorzy:
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/412242.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Oxazine-2-amines
IR spectra
NMR spectra
Hammett correlation
Substituent constans
Opis:
A series containing thirteen title compounds were synthesized and recorded IR and NMR spectra. The infrared νNH, C=N(cm-1)stretches, 1H NMR δNH, 13C NMR δC=N(ppm) chemical shifts of synthesized oxazine amines were assigned and correlated with Hammett substituent constants, F and R parameters. From the results of statistical analyses, the effect of substituents on the above spectral frequencies can be discussed.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 4; 109-116
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation and luminescent properties of KBr-TlBr systems
Autorzy:
Bobkova, I.
Kompaniets, T.
Powiązania:
https://bibliotekanauki.pl/articles/173475.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
KBr:Tl
luminescence spectra
excitation spectra
low-dimensional KBr-TlBr system
Opis:
Luminescence and excitation spectra of the systems on the basis of the nanoporous glass impregnated with KBr-TlBr and TlBr solutions as well as KBr single crystals surface-doped with thallium were studied in visible and ultraviolet regions at T = 77 K. It was shown that each of the studied systems has its peculiar optical properties, which differ from those of the corresponding macroscopic single crystals. The results are discussed taking into account the physicochemical features of the thallium insertion in the preparation of samples from solutions.
Źródło:
Optica Applicata; 2018, 48, 2; 285-296
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, spectral studies and antimicrobial activities of some substituted (E)-1-benzylidene-2-(4-bromophenyl)hydrazines
Autorzy:
Rajarajan, M.
Senbagam, R.
Vijayakumar, R.
Manikandan, V.
Balaji, S.
Vanangamudi, G.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1194024.pdf
Data publikacji:
2015
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Antimicrobial study
Hammett equation
Hydrazone
IR spectra
NMR spectra
Synthesis
UV
Opis:
A series of nine number of (E)-1-benzylidene-2-(4-bromophenyl)hydrazine compounds have been synthesized by the condensation reaction of 4-bromo phenylhydrazine with varies m- and p- substituted benzaldehydes using acetic acid catalyst were refluxed for 4h with 20 mL of absolute ethanol. The yield of synthesized (E)-1-benzylidene-2-(4-bromophenyl)hydrazine compounds are more than 80%. The synthesized (E)-1-benzylidene-2-(4-bromophenyl)hydrazines have been characterized by UV, IR, 1H and 13C spectral data. These UV, IR and NMR spectral data have been correlated with varies Hammett substituted constant and Swain-Lupton F and R parameters using single and multi- regression analysis. From the results of statistical analysis, the effects of substituent have been studied. The antimicrobial activity of all the synthesized substituted (E)-1-benzylidene-2-(4-bromophenyl)hydrazines have been evaluated using Bayer-Kirby method.
Źródło:
World Scientific News; 2015, 9; 144-160
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectral studies of some (5-substituted phenyl) isoxazole based sydnones: Assessment of substituent effects
Autorzy:
Thirunarayanan, G.
Vanangamudi, G.
Sathiyendiran, V.
Powiązania:
https://bibliotekanauki.pl/articles/1194034.pdf
Data publikacji:
2015
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Hammett substituent constants
IR spectra
NMR spectra
Spectral LFER
Sydnone isoxazole
Opis:
About ten 4-(N-(4-(5-phenylisoxazol-3-yl)phenylsufamyl)-3-(p-tolyl)-1,2,3,-oxadiazol-3-ium-5-olates were synthesised and examined their purities by literature method. The infrared and NMR spectral data of above synthesised isoxazoles were assigned and correlated with Hammett substituent constants and Swain-Lupton’s constants using regression analysis. From statistical analyses results, the effects of substituents on the spectral data have been discussed.
Źródło:
World Scientific News; 2015, 11; 44-64
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, spectral correlations and biological activities of some (E)-[4-(substituted benzylidene amino)phenyl] (phenyl) methanones
Autorzy:
Mayavel, P.
Thirumurthy, K.
Dineshkumar, S.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/412136.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Schiff's bases
fly-ash
PTS
IR spectra
NMR spectra
Hammett correlation
Opis:
A series of Schiff’s bases have been synthesized by fly-ash:p-toluenesulfonic acid (fly-ash:PTS) catalyzed microwave assisted oxidative coupling of arylamines and substituted benzaldehydes under solvent-free condition. The synthesized Schiff’s bases are characterized by their physical constants, analytical and spectroscopic data. The group frequencies of imines such as IR (v, cm–1) and NMR (δ, ppm) spectral data was correlated with Hammett substituent constants, F and R parameters using single and multi-linear regression analysis. The antimicrobial activities of these Schiff’s bases have been studied using Bauer-Kirby method.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 20, 2; 145-159
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectral correlation analysis of Hammett substituent constants and biological activities of some (E)-1-(4-phenoxyphenyl)-3-phenylprop-2-en-1-ones
Autorzy:
Kalyanasundaram, N.
Sakthinathan, S. P.
Suresh, R.
Kamalakkannan, D.
Joseph, S. J.
Vanangamudi, G.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/412539.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
substituted styryl 4-phenoxyphenylketones
UV-spectra
IR spectra
NMR spectra
Hammett constants
substituent effects
regression analysis and antimicrobial activities
Opis:
A series of aryl chalcones have been synthesized from 4-phenoxyacetophonone with various substituted benzaldehydes. The purity of all chalcones has been checked using their physical constants and spectral data. These spectral data have been correlated with Hammett substituent constants and F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents on the above spectral data has been studied. The single parameter correlation with few Hammett constants and F and R parameters gave satisfactory correlation coefficients whereas all multiple correlations gave satisfactory correlation coefficients with Resonance, Field and Swain-Lupton’s parameters. The antimicrobial activities of all chalcones have been studied using Bauer-Kirby method.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 9; 23-47
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectral LFER in some aryl azine derivatives
Autorzy:
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1191375.pdf
Data publikacji:
2016
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Aryl hydrazines
Hammett correlations
IR spectra
NMR spectra
Swain-Lupton’s parameters
Opis:
About ten (Z)-1-(1-(substitutedphenyl)ethylidene)-2-(diphenylmethylene)hydrazines were prepared and their purities were examined by literature method. The infrared and NMR spectra of these hydrazines were recorded. The characteristics C=N and N-N stretches (ν, cm-1) and the chemical shifts (δ, ppm) of methyl protons and carbons were assigned. These spectral have been correlated with Hammett substituent constants, F, R and Swain-Lupton’s parameters using single and multi-regression analysis. From the results of statistical analyses, the effects of substituent on the spectral data have been studied.
Źródło:
World Scientific News; 2016, 33; 79-95
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Symulacja widm absorpcyjnych azobenzenu i jego pochodnych
Spectra visualization of azobenzene and its derivatives
Autorzy:
Połubok, A.
Kaczmarek, H.
Powiązania:
https://bibliotekanauki.pl/articles/2072290.pdf
Data publikacji:
2013
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
azobenzen
widmo UV-Vis
widmo IR
azobenzene
UV-Vis spectra
IR spectra
Opis:
Wykonano wizualizację widm absorpcyjnych azobenzenu i jego pochodnych na superkomputerze NOVA. Uzyskane dane: energia poszczególnych stanów wzbudzonych, energia pobudzenia i siła oscylatorów pozwoliły wnioskować o położeniu i intensywności pasm w widmie UV-Vis, Na podstawie częstości drgań harmonicznych wyznaczono widmo IR. Otrzymane widmo dobrze pokrywa się z danymi literaturowymi. Możliwość generowania kształtu widm jest użyteczna w przypadku trudności w ich rejestracji metodami tradycyjnymi.
Visualization of azobenzene spectra and its derivatives using numerical simulation on the NOVA supercomputer was carried out. Data obtained, such as calculating energy of individual excited states, energy stimulation and oscillator strength enabled one to find a position and intensity of bands in UV-Vis spectra. The IR spectra were determined on basis of harmonic vibration frequency. The obtained spectra corresponded quite well with literature data thus offering alternative for the application of traditional methods.
Źródło:
Inżynieria i Aparatura Chemiczna; 2013, 5; 469--470
0368-0827
Pojawia się w:
Inżynieria i Aparatura Chemiczna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, effect of substituents and antimicrobial activities of some 4-bromophenyl chalcones
Autorzy:
Vijayakumar, S.
Vanangamudi, G.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1191238.pdf
Data publikacji:
2016
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
(E)-1-(4-bromophenyl)-3-(substituted phenyl)-2-propen-1-ones
UV spectra
IR spectra
NMR spectra
Substituent effects
Antimicrobial activities
Opis:
Elven (E)-1-(4-bromophenyl)-3-(substituted phenyl)-2-propen-1-ones are formed using sodium hydroxide catalyzed Aldol condensation between 4-bromoacetophenone and substituted benzaldehyde. The production of these chalcone compounds are above 90%. These α, β unsaturated ketones were specified by their physical constants and spectral data (UV, IR, 1H and 13C-NMR). Hammett substituted constants (σ, σ+, σI & σR and F and R parameters have been used for correlating the spectral values of these α, β unsaturated ketones by using single and multi-linear regression analysis. The impacts of substituents on the spectral data have been known on statistical analysis. By using Bauer-Kirby method the anti-microbial activities of these (E)-1-(4-bromophenyl)-3-(substituted phenyl)-2-propen-1-ones compounds are estimated.
Źródło:
World Scientific News; 2016, 54; 132-152
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Infrared and ¹³C NMR spectral studies of some aryl hydrazides: Assessment of substituent effects
Autorzy:
Thirunarayanan, G.
Sekar, G. K.
Lakshmi Narayanan, R.
Powiązania:
https://bibliotekanauki.pl/articles/412577.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
substituted aryl benzohydrazide
IR spectra
NMR spectra
hammett equation
substituent constants
correlation analysis
Opis:
A series of some aryl hydrazides have been synthesized. These hydrazides purities were analyzed by physical constants and spectral data. The assigned spectral group frequencies were correlated with Hammett substituent constants and Swain-Lupton parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents on the spectral group frequencies has been discussed.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 13, 1; 88-94
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hammett spectral correlations in some aryl 1,3-oxazine-4-thione derivatives
Autorzy:
Thirunarayanan, G.
Sekar, K. G.
Powiązania:
https://bibliotekanauki.pl/articles/412394.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
1,3-oxazine-4-thiones
IR spectra
13C NMR spectra
Hammett correlation
Opis:
A series of some aryl 1,3-oxazine-4-thione derivatives have been synthesized by 1-methyl imidazole catalyzed three component one pot synthetic method in room temperature. The purities of these thiones were studied by their physical constants and spectroscopic data. The infrared and 13C NMR spectral data of CN and CS were correlated with Hammett substituent constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituent on the spectral data was studied.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 17, 2; 193-200
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectrophotometric investigations of nitrobenzene liquidmembrane oscillator with hexadecyltrimethylammonium bromide
Autorzy:
Szpakowska, M.
Czaplicka, I.
Powiązania:
https://bibliotekanauki.pl/articles/347013.pdf
Data publikacji:
2003
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Tematy:
oscillations
liquid membrane oscillator
liquid membrane
cationic surfactant
nitrobenzene absorption spectra
picric acid spectra
Opis:
The oscillations of electrochemical potential difference between aqueous phases of a liquid membrane oscillator containing cationic surfactant are presented. By UV-VIS spectroscopy, the concentrations of liquid membrane components (nitrobenzene and picric acid) in the both aqueous phases were established during the oscillation process. It was shown that nitrobenzene molecules are transferred to the aqueous phases from the beginning of that dynamic process. Picric acid molecules are not observed in the donor phase, meanwhile, from the beginning of the process they are transported to the acceptor phase. It can be concluded that the transport of the liquid membrane components to the aqueous phases is not responsible for the observed oscillations of electrochemical potential difference.
Źródło:
Ars Separatoria Acta; 2003, 2; 64-70
1731-6340
Pojawia się w:
Ars Separatoria Acta
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectral QSAR and QPR study of some (E)-4-(((2 hydroxy-6-(substituted phenyl)-1,6 dihydropyrimidin 4-yl)methyl)diazenyl)benzoic acid derivatives
Autorzy:
Thirunarayanan, G.
Sekar, K. G.
Powiązania:
https://bibliotekanauki.pl/articles/412619.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Dihydropyrimidines
Diazenyl benzoic acids
IR spectra
NMR spectra
Hammett correlation
QSAR and QPR study
Opis:
A series of titled compounds were synthesized and recorded the infrared and NMR spectra. The assigned spectral group frequencies were correlated with Hammett substituent constants, F and R parameter. From the statistical analysis results, the effect of substituents on the spectral group frequencies has been studied.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 17, 1; 10-20
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectral correlations in some substituted styryl (E)-4-((2-oxopropyl) diazenyl) benzoic acids
Autorzy:
Sathiyendiran, V.
Sekar, K. G.
Thirunarayanan, G.
Arulkumaran, R.
Sundararajan, R.
Kamalakkannan, D.
Suresh, R.
Manikanadan, V.
Vijayakumar, R.
Vanangamudi, G.
Powiązania:
https://bibliotekanauki.pl/articles/412199.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Oxo-propyl diazenyl benzoic acid chalcones
IR spectra
NMR spectra
Hammett equation
Regression analysis
Opis:
A series of titled compounds were prepared and analyzed their purities by literature method. The infrared and NMR spectral group frequencies of the compounds were assigned and correlated with Hammett substituent constants, F and R constants using single and multi linear regression analysis. From the results of statistical analysis, the effect of substituents on the above spectral frequencies was discussed.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 11, 1; 33-43
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and spectral correlation study of some 3-(3,4-dichlorophenyl)-5-(substituted phenyl)-4,5-dihydro-1H-pyrazole-1-yl-ethanones
Autorzy:
Thirunarayanan, G.
Ravi, K.
Powiązania:
https://bibliotekanauki.pl/articles/412390.pdf
Data publikacji:
2013
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Solvent-free cyclization cum acetylation
N-acetyl pyrazoles
IR spectra
NMR spectra
Hammett correlations
Opis:
Some N-acetyl pyrazoles including 3-(3,4-dichlorophenyl)-5-(substituted phenyl)-4,5-dihydro-1H-pyrazole-1-yl-ethanones have been synthesised by solvent free cyclization cum acetylation of chalcones including substituted styryl 3,4-dichlorophenyl ketones using hydrazine hydrate and acetic anhydride in presence of catalytic amount of fly-ash: H2SO4 catalyst. The yield of these N-acetyl pyrazole derivatives are more than 75 %. The synthesised N-acetyl pyrazoline derivatives were characterized by their physical constants and spectral data. The infrared spectral νC=N and C=O (cm-1) frequencies, NMR chemical shifts (δ, ppm) of Ha, Hb, Hc, CH3 protons, C=N, C=O and CH3 carbons of 1-(3-(3,4-dichlorophenyl)-5-(substitutedphenyl)-4,5-dihydro-1H-pyrazole-1-yl) ethanones have been assigned and correlated with Hammett substituent constants and Swain-Lupton’s parameters using single and multi-regression analysis. From the results of statistical analyses the effect of substituents on the above group frequencies and chemical shifts of the acetylated pyrazoles were discussed.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2013, 14; 44-57
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A hint at quark deconfinement in 200 GeV Au+Au data at RHIC
Autorzy:
Csanád, M.
Csörgo, T.
Lörstad, B.
Ster, A.
Powiązania:
https://bibliotekanauki.pl/articles/147382.pdf
Data publikacji:
2004
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Buda-Lund hydro spectra
HBT multiplicity
Opis:
We give the emission function of the axially symmetric Buda-Lund hydro model and present its simultaneous, high quality fits to identified particle spectra, two-particle Bose-Einstein or HBT correlations and charged particle pseudorapidity distributions as measured by BRAHMS and PHENIX in 0 30% central, square root sNN = 200 GeV Au+Au collisions at RHIC. The best fit is achieved when the most central region of the particle emitting volume is superheated to T0 = 200 š 9 MeV greater-than or equal to Tc = 172 š 3 MeV, a 3sigma effect.
Źródło:
Nukleonika; 2004, 49,suppl.2; 49-55
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nanocrystallization studies of rapidly quenched Fe85.4-xCoxZr6.8-yNbyB6.8Cu1 (x = 0 or 42.7, y = 0 or 1) alloys
Autorzy:
Olszewski, J.
Zbroszczyk, J.
Ciurzyńska, W.
Fukunaga, H.
Wysłocki, B.
Perduta, K.
Łukiewska, A.
Młyńczyk, A.
Lelątko, J.
Świerczek, J.
Powiązania:
https://bibliotekanauki.pl/articles/148787.pdf
Data publikacji:
2003
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Mössbauer spectra
nanocrystalline Fe-Co alloys
Opis:
The microstructure of amorphous and nanocrystalline Fe42.7Co42.7Zr6.8-xNbxB6.8Cu1 (x = 0 or 1) alloys was investigated. We have stated that the nanocrystalline samples consist of the crystalline alfa-FeCo grains about 8 nm in diameter embedded in an amorphous matrix which is rich in cobalt. From Mössbauer spectroscopy studies we have found that the crystalline alfa-FeCo phase in the nanocrystalline samples obtained by the conventional annealing is atomically ordered. Moreover, the order degree depends on the annealing time. As for the samples partially crystallized during rapid quenching, the crystalline alfa-FeCo phase is atomically disordered.
Źródło:
Nukleonika; 2003, 48,suppl.1; 49-52
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Uptake of photofrin II, a photosensitizer used in photodynamic therapy, by tumour cells in vitro
Autorzy:
Chwiłkowska, Agnieszka
Saczko, Jolanta
Modrzycka, Teresa
Marcinkowska, Anna
Malarska, Anna
Bielewicz, Julita
Patalas, Dorota
Banaś, Teresa
Powiązania:
https://bibliotekanauki.pl/articles/1043629.pdf
Data publikacji:
2003
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
photofrin II
photodynamic therapy
fluorescence spectra
Opis:
Photosensitizing dyes are used in fluorescence diagnostics and photodynamic therapy (PDT). These usually hematoporphyrin derivatives (HpD) accumulate preferentially within neoplastic tissues. HpD is a mixture of ether and ester linked porphyrins. Its partially purified form is known under the commercial name of photofrin II (PII). PII emission spectra were studied in a hydrophilic (PBS) and a lipophilic (PC liposomes) environment. Red shift was observed in their emission maxima from 615 nm in buffer solution to 635 nm in lipid. Identical red shift was obtained when the intracellular fluorescence of two cancer cell lines, MCF 7 and Jurkat, incubated with PII was investigated. Thus, intramembrane localization of PII may be suggested. As determined from the total fluorescence intensity, the uptake of PII was only slightly higher for Jurkat than for MCF 7 cells. Nevertheless the kinetics of the uptake was found to be different for both cell lines.
Źródło:
Acta Biochimica Polonica; 2003, 50, 2; 509-513
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectroscopic Methods Studies in Polymer
Autorzy:
Rahi, Saad Khalid
Hassan, Ehssan Salah
Abd, Ahmed N.
Powiązania:
https://bibliotekanauki.pl/articles/1190136.pdf
Data publikacji:
2016
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
ESCA
polymer
Fluorescence spectra
Excitation wavelength
Opis:
The physico – chemical changes induced in polymers following to radiation can be studied by a range of spectroscopic techniques. Recent developments in instrumentation and data analysis procedures in electronic, vibrational and magnetic resonance spectroscopes have provided considerable new insights, into polymer structure and behavior. The applications of these spectroscopic methods in polymer studies are reviewed with emphasis on their utility in investigations of radiation effects on macromolecules
Źródło:
World Scientific News; 2016, 42; 41-53
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Estimation of dynamic response of buildings with load bearing walls using response spectra and neutal networks
Ocena drgań budynków ścianowych na podstawie spektrów odpowiedzi z wykorzystaniem SSN
Autorzy:
Kuźniar, K.
Powiązania:
https://bibliotekanauki.pl/articles/281546.pdf
Data publikacji:
2002
Wydawca:
Polskie Towarzystwo Mechaniki Teoretycznej i Stosowanej
Tematy:
neural network
response spectra
dynamic response
Opis:
The paper deals with application of neural networks and response spectra for estimation of dynamic response of medium-height buildings with load bearing walls. Averaged spectra are also used. Computed results are compared with experimental ones on actual structures. Results from the study show that effects of the neural network analysis are quite satisfactory.
W pracy podjęto próbę zastosowania sztucznych sieci neuronowych oraz przemieszczeniowych spektrów odpowiedzi do wyznaczenia dynamicznej odpowiedzi ścianowych budynków prefabrykowanych o średniej wysokości. Wykorzystano również uśrednione spektra odpowiedzi. Wyniki obliczeń porównano z rezultatami badań doświadczalnych na obiektach rzeczywistych.
Źródło:
Journal of Theoretical and Applied Mechanics; 2002, 40, 2; 483-495
1429-2955
Pojawia się w:
Journal of Theoretical and Applied Mechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The impact of heat treatment on the components of plant biomass as exemplified by Junniperus sabina and Picea abies
Autorzy:
Drygaś, B.
Depciuch, J.
Puchalski, Cz.
Zaguła, G.
Powiązania:
https://bibliotekanauki.pl/articles/411289.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Oddział w Lublinie PAN
Tematy:
torrefaction
biomass
FTIR spectra
changes
biochars
Opis:
Torrefaction is the process of drying biomass at high temperatures in order to transform it into biofuels with properties and composition resembling carbon. The impact of high temperature breaks the chains of hemicellulose, lignin and cellulose and degrades the biomass to simpler organic compounds. The aim of this publication was to specify the impact of the duration of the heat treatment on the stability of biomass structures such as lignocellulose illustrated with examples of selected species of conifers. The research material consisted of shoot tips of Junniperus sabina and Picea abies. The material used in the process was air-dried, dried at 150oC and torrefied at temperatures of 200, 250 and 300oC in a LECO camera – TGA 701 apparatus for 30 minutes. Fresh needles and their torrefied products were measured spectroscopically using FTIR Vertex 70v made by Bruker. Microscopic photographs of samples were taken in the scales 10 μm, 20 μm, and 50 μm using the TESCAN VEGA3 scanning electron microscope. The unprocessed plant material did not differ significantly from one another – the FTIR spectra of both plants exhibited the same functional groups. The biomass heat treatment led to significant changes in its chemical composition and topographic changes in the obtained biochars.
Źródło:
ECONTECHMOD : An International Quarterly Journal on Economics of Technology and Modelling Processes; 2016, 5, 3; 41-50
2084-5715
Pojawia się w:
ECONTECHMOD : An International Quarterly Journal on Economics of Technology and Modelling Processes
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
IR and 1H NMR spectral studies of some 2-Amino-4-isopropyl-6-methoxy-N-phenylpyrimidine-5-carboxamides: Assessment of substituent effects
Autorzy:
Arulkumaran, R.
Sundararajan, R.
Manikandan, V.
Sathiyendiran, V.
Pazhamalai, S.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/412343.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
2-Amino-4-isopropyl-6-methoxy-N-phenylpyrimidine-5-carboxamides
IR spectra
NMR spectra
substituent effects
Opis:
A series of 2-Amino-4-isopropyl-6-methoxy-N-phenylpyrimidine-5-carboxamide compounds have been synthesized from various substituted dithioacetal and guanidine. The purities of these compounds were checked by their physical constants, UV, IR, NMR and MASS spectral data. The IR and 1HNMR spectral data of these compounds have been correlated with Hammett sigma constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effects of substituents on the spectral group frequencies have been discussed.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 19, 1; 15-25
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The maximum entropy method in the analysis of the Mössbauer spectra
Autorzy:
Dobrzyński, L.
Szymański, K.
Satuła, D.
Powiązania:
https://bibliotekanauki.pl/articles/147136.pdf
Data publikacji:
2004
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Bayesian logic
maximum entropy method
Mössbauer spectra
Opis:
The paper shows the possibility of reconstruction of the distribution of hyperfine field parameters without prior assumptions concerning correlations between parameters. The method used is the maximum entropy method and the distributions considered concern the magnetic field and isomer shift. The results obtained are very encouraging and show the feasibility of the proposed method.
Źródło:
Nukleonika; 2004, 49,suppl.3; 89-93
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Studies of chrysoprase and microcrystalline silica varieties from serpentinites of Szklary Massif (Foresudetic Block, SW Poland) by Raman spectroscopic technique – preliminary results
Autorzy:
Korybska-Sadło, I.
Powiązania:
https://bibliotekanauki.pl/articles/89152.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Wydział Geoinżynierii, Górnictwa i Geologii. Instytut Górnictwa
Tematy:
Silica group
chrysoprase
Szklary
moganite
Raman spectra
Opis:
The mineralogical properties of green colored chalcedony varieties from weathering cover of slightly serpentinized peridotites (harzburgites) occurring near Szklary village on Foresudetic Block (SW Poland) are studied using Raman spectroscopy in the 200 – 1600-1 wavenumber region . The obtained results show, that in examined samples, the peaks like: 206, 265, 355, 394, 464, 696, 796, 808 cm-1, characteristic for α-quartz were ascertained. In one sample, the characteristic moganite peak (502 cm-1) was found. It implies that presence of other polymorphs of SiO2 in crystalline structure, considered a proof for presence of moganite intergrowths with α-quartz. It indicate, that intensity of green color of measured samples of chrysoprase are not correlated with Raman spectroscopic data. It can be conclude, that examination of Raman spectra can be useful only to recognition of internal phase composition of green cryptocrystalline silica polymorphs occurring in weathering cover of serpentinized peridotites.
Źródło:
Mining Science; 2015, 22, Special Issue 2; 39-45
2300-9586
2353-5423
Pojawia się w:
Mining Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Corona Theorem and isometries
Autorzy:
Rudol, K.
Powiązania:
https://bibliotekanauki.pl/articles/2050192.pdf
Data publikacji:
2004
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
Hardy classes
Taylor's joint spectra
cluster sets
Opis:
The aim of this note is to discuss a new operator theory approach to Corona Problem. An equivalent operator problem invariant under unitary equivalence is stated. The related condition involves certain joint spectra of commuting subnormal operators. A special case leading to isometries is studied. As a result one obtains a relatively short proof of Corona Theorem for a wide class of domains in the plane, where Marshall's Theorem on the approximation by inner functions holds.
Źródło:
Opuscula Mathematica; 2004, 24, 1; 123-131
1232-9274
2300-6919
Pojawia się w:
Opuscula Mathematica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Engine fuel characterisation based on excitation-emission spectra
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/246580.pdf
Data publikacji:
2017
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
fuel
diesel
engine
excitation-emission spectra
fluorescence
Opis:
Considering that correctly functioning of diesel ship engine depends on the composition of applied fuel, it is necessary to easy characterise fuels in terms of quality. Therefore taking into account above mentioned, appropriate analyses have been undertaken and the intention of this article is to inform that characterisation of fuel used in marine transport can be described by the specific parameter based on fluorescence excitation-emission spectroscopy. Therefore, for this study fuel typically used in ship engine – Diesel fuel – is considered. For analysis, Diesel fuel dissolved in n-hexane was used and several oil samples for various oil concentration were prepared. Spectrofluorometer Aqualog Horiba was used to record the excitation-emission spectra (EEMs). EEM spectra determined for each of oil concentration were described by two specific peaks for this kind of oil. Based on registered EEMs, the specific indicator - the wavelength-independent fluorescence maximum – coded in two specific wavelengths – excitation and emission, respectively, described as Exmax/Emmax was determined for considered oil concentration. Obtained results indicate the independence from oil concentration only for one detected peak described by Exmax/Emmax = 240/332. Taking into account obtained results, we can conclude that the wavelength-independent fluorescence maximum detected for excitation wavelength at 240 nm corresponds to the emission wavelength at 332 nm due to the independence from the oil concentration, could be a good indicator to characterise this kind of oil – Diesel fuel. We can conclude that the changes in the composition of fuel could be detected in EEM spectra by the change of detected peaks position.
Źródło:
Journal of KONES; 2017, 24, 2; 25-30
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Monte Carlo study of medium-energy electron penetration in aluminium and silver
Autorzy:
Aydın, A.
Peker, A.
Powiązania:
https://bibliotekanauki.pl/articles/146550.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
angular distribution
electron
energy spectra
penetration
transmission
Opis:
Monte Carlo simulations are very useful for many physical processes. The transport of particles was simulated by Monte Carlo calculating the basic parameters such as probabilities of transmitted–reflected and angular-energy distributions after interaction with matter. Monte Carlo simulations of electron scattering based on the single scattering model were presented in the medium-energy region for aluminium and silver matters. Two basic equations are required the elastic scattering cross section and the energy loss. The Rutherford equation for the different screening parameters is investigated. This scattering model is accurate in the energy range from a few keV up to about 0.50 MeV. The reliability of the simulation method is analysed by comparing experimental data from transmission measurements.
Źródło:
Nukleonika; 2015, 60, 2; 361-366
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hammett spectral LFER of some antioxidant substituted benzylidene hydrazines
Autorzy:
Thirunarayanan, G.
Manikandan, V.
Arulkumaran, R.
Rajarajan, M.
Sathiyendiran, V.
Powiązania:
https://bibliotekanauki.pl/articles/1182556.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
(E)-(2
5-dinitrophenyl)-2-(substituted benzylidene)hydrazines
Hammett correlations
IR spectra
NMR spectra
antioxidant activity
hydroxy apatite
Opis:
About nine (E)-(2,5-dinitrophenyl)-2-(substituted benzylidene)hydrazines have been synthesized by hydroxy apatite catalyzed condensation of 2,4-dinitrophenyl hydrazine and substituted benzaldehydes under microwave irradiation conditions. The obtained yields of these hydrazines are more than 85%. The purities of synthesized hydrazines are examined by the analytical and spectroscopic data reported earlier. The infrared spectral C=N, NH frequencies (v, cm-1) and the NMR spectral chemical shifts of CH, NH protons and carbons are assigned and are correlated with Hammett substituent constants, F and R parameter using single and multi-regression analysis. From the results of statistical analysis the effects of substituent on the group frequencies have been discussed. The antioxidant activities of these synthesized hydrazines were measured using DPPH radical scavenging method. The hydroxy- and methoxy- substituted hydrazines shows significant antioxidant activity.
Źródło:
World Scientific News; 2017, 69; 201-219
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of MoO3 on the Structure of Lithium Aluminum Phosphate Glasses
Autorzy:
Saddeek, Y. B.
Abo-Naf, S. M.
Powiązania:
https://bibliotekanauki.pl/articles/176650.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
phosphate glasses
IR
infrared spectra
density
elastic properties
Opis:
IR spectroscopy, density and ultrasonic velocity measurements have been carried out for aluminum lithium phosphate glasses with and without MoO3. The observed changes in the FTIR spectra of the glasses were related to the modifier/former role of molybdenum ions. The results revealed that the density increases with increasing MoO3 content, which was attributed to the increase in the compactness and packing of the glass network. The ultrasonic data were analyzed in terms of creation of new bonds of MoO3 attached to phosphate units. The new bonds increased the average crosslink density and the number of network bonds per unit volume along with a strengthening of the different modes of vibrations which in its turn increased the ultrasonic velocity, the rigidity and hence the elastic moduli of the glasses.
Źródło:
Archives of Acoustics; 2012, 37, 3; 341-347
0137-5075
Pojawia się w:
Archives of Acoustics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Weyls theorems and continuity of spectra in the class of p-hyponormal operators
Autorzy:
Djordjević, S.
Duggal, B.
Powiązania:
https://bibliotekanauki.pl/articles/1205933.pdf
Data publikacji:
2000
Wydawca:
Polska Akademia Nauk. Instytut Matematyczny PAN
Tematy:
p-hyponormal operators
Weyl's theorem
continuity of spectra
Opis:
We show that p-hyponormal operators obey Weyl's and a-Weyl's theorem. Also, we show that the spectrum, Weyl spectrum, Browder spectrum and approximate point spectrum are continuous functions in the class of all p-hyponormal operators.
Źródło:
Studia Mathematica; 2000, 143, 1; 23-32
0039-3223
Pojawia się w:
Studia Mathematica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Equivalential algebras with conjunction on the regular elements
Autorzy:
Przybyło, Sławomir
Powiązania:
https://bibliotekanauki.pl/articles/1797189.pdf
Data publikacji:
2021-07-30
Wydawca:
Uniwersytet Pedagogiczny im. Komisji Edukacji Narodowej w Krakowie
Tematy:
Fregean varieties
equivalential algebras
free algebras
free spectra
Opis:
We introduce the definition of the three-element equivalential algebra R with conjunction on the regular elements. We study the variety generated by R and prove the Representation Theorem. Then, we construct the finitely generated free algebras and compute the free spectra in this variety.
Źródło:
Annales Universitatis Paedagogicae Cracoviensis. Studia Mathematica; 2021, 20; 63-75
2300-133X
Pojawia się w:
Annales Universitatis Paedagogicae Cracoviensis. Studia Mathematica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reflectance spectroscopy in geology and soil sciences: Literature review
Autorzy:
Badura, Ireneusz
Dąbski, Maciej
Powiązania:
https://bibliotekanauki.pl/articles/15804610.pdf
Data publikacji:
2022
Wydawca:
Uniwersytet im. Adama Mickiewicza w Poznaniu
Tematy:
reflectance spectroscopy
mineral spectra
geological mapping
soil studies
Opis:
This article presents a literature review of studies utilising reflectance spectroscopy in geological research. We describe a variety of available spectral libraries together with providing examples of spectral reflectance diagrams, and explain the basic spectral ranges. Geologists can use different methods of data collection, for example, sensors mounted on satellites, airborne [including unmanned aerial vehicle (UAV) platforms] or portable spectroradiometers, and different ways of data processing. Most geological mapping based on reflectance spectroscopy is performed in the Arctic region, where vegetation does not obscure images. However, mineral mapping, studies of hot spring deposits, and rock/soil weathering alterations are also performed in lower latitudes. The development, combination and unifi-cation of all spectral data acquisition methods open up new possibilities for applications in a variety of geological and soil studies.
Źródło:
Quaestiones Geographicae; 2022, 41, 3; 157-167
0137-477X
2081-6383
Pojawia się w:
Quaestiones Geographicae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative Analysis of the Load Spectra Recorded During Photogrammetric Missions of Lightweight Uavs in Tailless and Conventional Configurations
Autorzy:
Rodzewicz, Mirosław
Głowacki, Dominik
Hajduk, Jaroslaw
Powiązania:
https://bibliotekanauki.pl/articles/24201177.pdf
Data publikacji:
2022
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Lotnictwa
Tematy:
load spectra
fatigue life
unmanned aircraft
photogrammetry mission
Opis:
The purpose of this article is to present the results of the investigation regarding the differences of the load spectra of two unmanned fixed-wing aircraft performing photogrammetry missions: X-8 (flying wing) and PW-ZOOM (conventional configuration). The focus was on the analysis of a number of load cycles for various load increments within the range of the operational loads. The load spectra were determined using the acceleration signal recorded in the autopilot logs as an input. This signal was transferred to the chain of local extreme values scaled in the form of discrete load levels, and then the transfer arrays were derived with use of the rainflow counting algorithm. On this basis, the incremental load spectra were determined for each flight. These load spectra were subjected to statistical analyses to determine the load spectra representative of the flight sessions in a few ways between non-conservative (i.e., focused on average load histories) and conservative (i.e., focused on the worst load histories observed during the flight session). Finally, the fatigue life was calculated by having the structural element of the assumed fatigue properties subjected to the load spectra of both airplanes. A large (exceeding one order of magnitude) difference in the number of load cycles for larger load increments in the analyzed load spectra was shown. This difference is related to the different dynamic characteristics of the two aircraft, in particular the gust response. As a result, there is a several-fold difference in fatigue life.
Źródło:
Fatigue of Aircraft Structures; 2022, 14; 114--134
2081-7738
2300-7591
Pojawia się w:
Fatigue of Aircraft Structures
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Automation of Aircraft Fatigue Life Estimation
Autorzy:
Gajek, Stanisław
Powiązania:
https://bibliotekanauki.pl/articles/24201179.pdf
Data publikacji:
2022
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Lotnictwa
Tematy:
Aircraft Fatigue
Rainflow Cycle Counting
Load Spectra
UAV
Opis:
The fatigue is an important factor in aircraft operation. A correct estimation of structure fatigue life is crucial for user and payload safety. However, due to high amount of data gathered during a typical recording of load spectra for different types of flights, the overall results become prone to human error. The paper describes development of a software able to perform an automated, in-depth analysis of data recorded with onboard accelerometers. Using the Rainflow Cycle Counting method, it transforms received data points into a Markov matrix. The prepared array is then recalculated into a half-cycle matrix, which can be collapsed into scalar value of fatigue level using the Palmgren-Miner rule. The method was tested with loads recorded during a typical flight conducted according to the Polish NSTS-06 flight scenario and simulated camera mounting fixed to a multirotor.
Źródło:
Fatigue of Aircraft Structures; 2022, 14; 83--103
2081-7738
2300-7591
Pojawia się w:
Fatigue of Aircraft Structures
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectrofluorymetry in application to oil-in-water emulsion characterization
Autorzy:
Otremba, Z.
Baszanowska, E.
Toczek, H.
Powiązania:
https://bibliotekanauki.pl/articles/246063.pdf
Data publikacji:
2011
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
oil
fuels
lubricants
aquatic environment protection
fluorescence spectra
Opis:
The question of identifying the type of oil in exploitation of engine room is associated with both the quality of ship consumables (fuels and lubricants) and the composition and origin of oil in settling tanks or in dumping water. Related issue is the possibility of determining the origin of oil, which is detected in the marine environment. The key question is how oils vary in their ability to fluorescence, understood as the shapes of fluorescence spectra obtained for different wavelengths of light exciting fluorescence. In this paper we present spectra of fluorescence for six chosen oils. Those oils were previously dispersed (emulsified) in the seawater, then extracted into hexane. Fluorescence spectra were obtained using fluorescence spectrometer Perkin Elmer LS55, for excitation wavelengths in the range from 240 nm to 500 nm, and emission wavelengths from 300 nm to 790 nm. In this paper there is shown that in general both total intensity of fluorescence and shapes of spectra of fluorescence depend on the excitation wavelength and are differ for various kinds of oil. In order to visually show the differences in fluorescence abilities of various oils, the results of measurement were placed on a chart of fluorescence intensities in the function of both variables: the excitation wavelength and the emission wavelength (so called the total fluorescence spectra). Analyses of results of the described studies confirm that the different oils fluoresce differently and identification of type of oil is possible by fluorescence spectrophotometry.
Źródło:
Journal of KONES; 2011, 18, 3; 317-321
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of fluorometric signatures of oil residues in both marine environment and in organic diluent
Autorzy:
Otremba, Z.
Baszanowska, E.
Powiązania:
https://bibliotekanauki.pl/articles/243211.pdf
Data publikacji:
2015
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
oil pollution
seawater
excitation-emission spectra
fluorescence spectroscopy
Opis:
The significant part of petroleum substances is transferred to the marine environment after technical activities (inevitable exploitive spills, illegal discharges). However a certain part of petroleum in seawater coming from the natural sources. Therefore, to develop the safety of natural marine environment it is necessary to track not only the anthropogenic pollutants but also the natural sources of petroleum. To distinguish both source of oil the fluorescence properties of oil can be used as the tools to oil identification. The aim of the study is to describe the optical properties of crude oil after it contact with aquatic environment based on fluorescence spectroscopy. For the study, crude oil ‘Petrobaltic’ type potentially found in marine environment due to coming from natural source was applied. To dissolve oil, two different solvent – hexane and Baltic seawater form the Gdynia coast were used. To measure the excitation-emission spectra (EEMs) of oil spectrofluorometer Hitachi F-7000 FL was applied. In the paper, we discuss the changes of oil EEMs in two cases for oil dissolved in n-hexane and for oil dissolved in seawater for various oil concentration. Obtained EEMs for oil dissolved in seawater indicate that EEMs spectrum contain the main peak – describing by the wavelength – independent fluorescence maximum, which was detected for oil dissolved in n-hexane (typical for this kind of oil). However, the intensity of oil fluorescence decreases after oil contact with seawater. This approach could allow expanding the description of complex mixtures of oils as a possible tool proposed for identification the type and origin of oil found in marine environment.
Źródło:
Journal of KONES; 2015, 22, 3; 175-179
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Accommodation of L2 Speech in a Repetition Task: Exploring Paralinguistic Imitation
Autorzy:
Burin, Léa
Powiązania:
https://bibliotekanauki.pl/articles/620558.pdf
Data publikacji:
2019-01-11
Wydawca:
Uniwersytet Łódzki. Wydawnictwo Uniwersytetu Łódzkiego
Tematy:
imitation
convergence
vowel spectra
vowel duration
creaky voice
Opis:
Phonetic convergence is the process by which a speaker adapts his/her speech to sound more similar to his/her interlocutor. While most studies analysing this process have been conducted amongst speakers sharing the same language or variety, this experiment focuses on imitation between non-native and native speakers in a repetition task. The data is a fragment from the ANGLISH corpus designed by Anne Tortel (Tortel, 2008). 40 French speakers (10 male intermediate, 10 male advanced, 10 female intermediate and 10 female advanced learners) were asked to repeat a set of 20 sentences produced by British native speakers. Segmental (vowel quality), suprasegmental (vowel duration) and voice quality were analysed. Level of proficiency, gender and model talker were taken as independent variables. Level appeared not to be a relevant parameter due to a high amount of inter-individual variability amongst groups. Somewhat contradictory results were observed for vowel duration and F1-F2 distance for male learners converged more than female learners. Our hypothesis that low vowels display a higher degree of imitation, and especially within the F1 dimension (Babel, 2012), was partially validated. Convergence in vowel duration in order to sound more native-like was also observed (Zając, 2013). Regarding the analysis of voice quality, and more particularly of creaky voice, observations suggest that some advanced female learners creaked more than the native speakers and more in the reading task, which indicate, both linguistic idiosyncrasy and accommodation towards the native speakers. Low vowels seem also to be more likely to be produced with a creaky voice, especially at the end of prosodic constituents.
Źródło:
Research in Language; 2018, 16, 4
1731-7533
Pojawia się w:
Research in Language
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of single and X-wire measurements of streamwise velocity fluctuations in turbulent boundary layer
Autorzy:
Dróżdż, A.
Elsner, W.
Powiązania:
https://bibliotekanauki.pl/articles/281655.pdf
Data publikacji:
2014
Wydawca:
Polskie Towarzystwo Mechaniki Teoretycznej i Stosowanej
Tematy:
turbulent boundary layer
energy spectra
hot-wire spatial resolution
Opis:
The paper discusses the problem of measuring velocity fluctuations of a turbulent boundary layer using single and X-wire probes. It seems that the difference between the streamwise fluctuating component of these two probes results not only from spatial resolution, but also from influence of the wall-normal fluctuating component, which is usually not considered. It was shown that the vector summing these two components obtained from X-wire probe gives the shape of fluctuation distribution obtained from a single-wire probe. It implies that the underestimation of the near-wall peak of streamwise fluctuating component in X-wire measurements results from disregarded wall-normal fluctuations, which is obviously taken in the case of a single-wire probe. Moreover, it was shown that the criteria for wire length i.e. l+ ≤ 20 could not be sufficient to properly estimate the streamwise and wall-normal fluctuations.
Źródło:
Journal of Theoretical and Applied Mechanics; 2014, 52, 2; 499-505
1429-2955
Pojawia się w:
Journal of Theoretical and Applied Mechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
NMR Spectral correlations in some Tröger’s bases
Autorzy:
Thirunarayanan, G
Suresh, M.
Powiązania:
https://bibliotekanauki.pl/articles/412650.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
tröger’s bases
NMR spectra
hammett correlations
substituent effects
Opis:
Some Tröger’s bases have been synthesised from substituted anilines and paraformaldehyde in presence of Lewis acid catalyst such as anhydrous AlCl3, through electrophilic substitution reaction. The purities of these Tröger’s bases have been checked by their physical constants and spectroscopic data published earlier in the literature. The NMR chemical shift (δ, ppm) of methylene protons and carbon were assigned. The assigned methylene protons and carbon chemical shifts (δ, ppm) of synthesised Tröger’s bases have been correlated with Hammett substituent constants, F and R parameters using single and multi-regression analyses. From the results of statistical analyses, the effects of substituent on methylene protons and carbon were discussed.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 4; 1-11
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nano-Structural Features, Raman Spectra and New Trend of 3D-AFM Investigations for High Performance Ni-Super-alloy
Autorzy:
Elsabawy, Khaled M.
Elbagoury, N. H.
Powiązania:
https://bibliotekanauki.pl/articles/1191356.pdf
Data publikacji:
2016
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
3D-microstructre
AFM
Casting
Raman Spectra
SEM
Synthesis
Opis:
The synthesized Ni-alloy was prepared via conventional casting technique under vacuum and highly superheated treatment route. The casting parameters such as solidification cooling rate (SCR) was monitoring by both of AFM and SEM .Micro-structural investigations within different spots in the same sample indicated that γ matrix is the domain phase besides minor phases as MC carbides, σ phase and η phase which was observed to solidify in two forms as plate-like and blocky shape. The volume fraction (Vf) of σ and η phases was increased as the solidification cooling rate decreases. 3D-microstructural imaging map of the Ni-based super-alloy was constructed depending upon AFM-data evaluating that the morphology of the alloy-surface is a function of casting parameters .Furthermore raman spectra of highly superheated casted Ni-based super-alloy was performed to confirm existence of different phases recorded via SEM and EDX-elemental analysis with their corresponding different vibrational modes such as Ni-O vibrating modes in the region 360-510 cm-1 and Mo-O vibrating mode which lies at 1005 cm-1.
Źródło:
World Scientific News; 2016, 34; 34-50
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectrofluorimetry of chosen distillates of oil after pyrolysis of scrap tires
Autorzy:
Otremba, Z.
Ambrosewicz-Walacik, M.
Powiązania:
https://bibliotekanauki.pl/articles/245271.pdf
Data publikacji:
2018
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
fuels
used car tires
pyrolysis
fluorescence
excitation-emission spectra
Opis:
One of way to obtain liquid hydrocarbons can be pyrolysis of scrap tires. The hydrocarbon substances produced by this method may be an addition to traditional fuels, i.e. gasolines or fuels for diesel engines. In laboratory conditions at Department of Mechatronics of University of Warmia and Mazury there were obtained pyrolytic products and prepared three distillates related to temperatures 160, 204 and 350ºC. Analyses of shapes of fluorescence spectra were carried out in Department of Physics of Gdynia Maritime University. Spectra of fluorescence were prepared applying the spectrofluorimeter Hitachi F-7000 FL, which allows applying of excitation wavelength from 200 nm until 600 nm, whereas analysing of emitted, can be performed until 750 nm. In here reported study excitation and emission range for the most intense fluorescence are presented. There were prepared four solutions of pyrolytic products in the n-hexane: 4 ppm, 20 ppm, 100 ppm and 500 ppm. In order to show dependence of intensity fluorescence and shapes of excitation-emission spectra on type of distillate and concentration both kind of visualization – three-dimensional and as contour maps – are shown in this article. In analysed range of wavelengths, intensity of fluorescence grows with concentration of oil, whereas structure of the shape of spectra simplify when concentration increases. The presented effects associated with the fluorescence of pyrolysis products allow to predict the possibility of developing a method for determining the content of these substances in mixtures with petroleum refining products and other liquid hydrocarbons.
Źródło:
Journal of KONES; 2018, 25, 2; 262-268
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rock type discrimination using Landsat-8 OLI satellite data in mafic-ultramafic terrain
Autorzy:
Tamilarasan, Kuppusamy
Anbazhagan, Siddan
Ranjithkumar, Sundararajan
Powiązania:
https://bibliotekanauki.pl/articles/27310138.pdf
Data publikacji:
2023
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
remote sensing
Landsat-8
lithology
ultramafic
spectra
SVM classification
Opis:
The mafic-ultramafic terrain of the Bhavani complex in southern India is considered for lithological mapping. The Landsat-8 OLI satellite data was used for the interpretation of different rock types in the study area. The satellite data were digitally processed using ENVI 5.6 image processing software. In the OLI data, excluding bands 8 and 9, the remaining seven bands were used for the generation of colour composite images, band ratios, principal component analysis and SVM classification. Reflectance spectral measurements were carried out in laboratory conditions for five rock samples collected from the study area. The XRF analysis was carried out to estimate the composition of major oxides present in the rock samples. The results obtained from XRF analysis were compared with the rock spectra in characterizing the spectral features of the rock types. The colour composite images (B543, B567, B456, and B457), PCA composite image (PC312 and PC456), band ratios (BR5/5 and BR4/3), colour composite images from band ratios, and SVM classified output are useful in delineation various rock types in the terrain.
Źródło:
Geology, Geophysics and Environment; 2023, 49, 3; 281--298
2299-8004
2353-0790
Pojawia się w:
Geology, Geophysics and Environment
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, spectral correlation analysis and evaluation of biological activities of some substituted hydrazones
Autorzy:
Vijayakumar, Renganathan
Senbagam, Rajamohan
Rajarajan, Murugan
Balaji, Selvaraj
Manikandan, Venkatesan
Vanangamudi, Ganesan
Thirunarayanan, Ganesamoorthy
Powiązania:
https://bibliotekanauki.pl/articles/764124.pdf
Data publikacji:
2015
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
Hydrazones
UV
IR & NMR spectra
Correlation analysis
Antimicrobial activities
Opis:
Some novel substituted hydrazone derivatives of amino guanidine have been synthesized with different substituted benzaldehydes by condensation method. The synthesized hydrazones were characterized by their physical constants, UV, IR and NMR spectra. The spectral data have been correlated with Hammett substituent constants and Swain–Lupton parameters. From the result of statistical analysis, the effects of substituents on the spectral data have been predicted. The antimicrobial activities of these synthesized hydrazone compounds have been screened by Bauer-Kirby method using human pathogenic bacteria and fungal species. The antimicrobial activities of all synthesized hydrazone compounds have shown significant activity.
Źródło:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2015, 70, 2
2083-358X
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
FT-IR, 1H and 13C NMR QSAR and molecular docking study on some (E)-2-(2-((aryl)(phenyl)methylene) hydrazinyl)benzo[d]thiazoles
Autorzy:
Muthuvel, I.
Thirunarayanan, G.
Manikandan, S.
Powiązania:
https://bibliotekanauki.pl/articles/1066169.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
(E)-2-(2-((aryl)(phenyl)methylene)hydrazinyl)benzo[d]thiazoles
Docking analysis
Hammett equation
IR spectra
NMR spectra
QSAR study
Schiff’s bases
Opis:
About six (E)-2-(2-((aryl)(phenyl)methylene)hydrazinyl)benzo[d]thiazoles have been synthesized and characterized by literature data. The infra-red stretching frequencies (ν, cm-1) of NH, CN, C=C and the NMR chemical shifts (δ, ppm) of NH, C=N and ipso carbons were assigned. These spectroscopic data were correlated for studying the QSAR employing Hammett equation with various Hammett substituent constants, Swain-Lupton’s F and R parameters using single and multi-regression analysis. From the results of regression analysis, the QSAR will be predicted by means of effects of substituents on the spectroscopic data of the functional group frequencies. The molecular docking character was evaluated by Schrodinger program, probing analogue docking in Topoisomerase enzymes. The crystallographic enzyme ligand complex (PDB entry 3TTZ) was obtained from the RCSB Protein Data Bank.
Źródło:
World Scientific News; 2019, 131; 54-74
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Testing of the synchronous fluorescence in application to used lubricate oil characterisation
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/243560.pdf
Data publikacji:
2016
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
marine fleet exploitation
lubricate oil
fluorescence spectroscopy
synchronous fluorescence spectra
Opis:
Reliability of the ship propulsion system depends, inter alia, on the quality of lubricate oils. Research indicates that exploitive features of oil are reduced with it runtime in the ship engine circuit. At the present the basic parameters representing exploitive features of oil are: water content, total acid number and total base number or viscosity vs. temperature, anti-wear performance, further: content of additives and their concentrations, reaction products, and other contaminating substances, also magnetically separated large ferromagnetic particles, the size, the shape, the composition and concentration of the abnormal wear particles. Additional properties of oil are described based on atomic emission spectroscopy, granulometry of separated from the lubricant sample by magnets and gravity, permeability changes, as well as rheometric and tribometric characteristics. Complexity of composition of lubricate oil raises the idea to use changes of relative content of any compounds for characterization of oil exploitive features. Fluorescence method is possible to use for oil properties characterisation due to the presence mono and polycyclic compounds in oil that induces fluorescence phenomenon. Therefore identification the fluorescence spectra when exploitation time of oil increases could be novel indicator to monitor of lubricate oil exploitive quality. In this study we present changes of oil fluorescence expressed by synchronous spectra, taking into account working time of exemplary lubricate oil in the ship engine.
Źródło:
Journal of KONES; 2016, 23, 2; 39-44
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fluorescence spectra of oil after it contacts with aquatic environment
Autorzy:
Baszanowska, E.
Otremba, Z.
Toczek, H.
Rohde, P.
Powiązania:
https://bibliotekanauki.pl/articles/245054.pdf
Data publikacji:
2013
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
oil pollution
fluorescence spectroscopy
excitation-emission spectra
seawater
environment protection
Opis:
The main task for natural marine environment protection is to prevent the inflow of various contaminants including oil substances and the real challenge is the ability to rapidly detect these pollutants. Moreover important is to find the source or the maker of the oil spill. In this paper, we consider fundamental physical aspects in the area of possibility of monitoring the natural marine ecosystem based on fluorescence spectroscopy. We utilize the fluorescence ability of numerous oil components – mainly polycyclic hydrocarbons. The paper concerns the spectrofluorimetric characterization of oils have been in use during exploitation of the marine fleet, i.e. lubricate oil, fuels, transformer and hydraulic oils as well as crude oils or their residues. Every kind of oil has a chance to enter the marine environment, especially in a case of ship emergency or after collision with other vessel ore shoreline structure as well as when ship enters the stranding. After discharge of oil, some of oil components are dissolved in the water, bacteria or photochemical reactions, which results in transformation of composition of oil, degrade some. Fluorescence spectrometer Perkin Elmer LS55 was applied to obtain the fluorescence spectra using different excitation wavelength in the range from 240 nm to 500 nm. We discuss the changes of the shapes of excitationemission spectra (EEMs) of various types of oil and the EEMs spectra after contact of oil with seawater as an oil-inwater emulsion, which is the most frequent form of oil in the water column. Significant changes in the shape of spectra and displacement of the peaks are observed.
Źródło:
Journal of KONES; 2013, 20, 3; 29-34
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optical Properties of Soda-Lime-Silica Glasses Doped with Eggshell Powder
Autorzy:
Aktas, B.
Albaskara, M.
Yalcin, S.
Dogru, K.
Powiązania:
https://bibliotekanauki.pl/articles/1030117.pdf
Data publikacji:
2017-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
soda-lime-silica glass
eggshell powder
optical properties
FTIR spectra
Opis:
The optical properties of soda-lime-silica glasses doped with eggshell powder were investigated using UV-visible and the Fourier transform infrared spectroscopies. Pure soda-lime-silica glass, which is colorless and transparent, turned dark green after the addition of the eggshell powder. When the eggshell powder content was ≥ 3 wt%, the glass became translucent. The maximum wavelengths in the UV spectra of the soda-lime-silica glasses doped with 0.5, 1, 3, and 5 wt% eggshell powder were observed at 300.20, 277.40, 284.40, and 312.40 nm, respectively. The Fourier transform infrared spectra of the eggshell-doped soda-lime-silica glass samples were very similar to that of the base undoped glass. The bands at approximately 770-820 cm¯¹ could be attributed to the Si-O-Si symmetric stretching of the bridging oxygen between the tetrahedra, while the bands at approximately 970 cm¯¹ were related to the Si-O-Si antisymmetric stretching of the bridging oxygen within the tetrahedra.
Źródło:
Acta Physica Polonica A; 2017, 132, 3; 442-444
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Inversion of Remote Sensing Data Using Multiple Ratios of Spectral Radiation Intensities and Neural Networks
Autorzy:
Cięszczyk, S.
Powiązania:
https://bibliotekanauki.pl/articles/1032310.pdf
Data publikacji:
2017-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
remote sensing
infrared spectrometers
infrared spectra
computer modelling and simulation
Opis:
The article presents a method for determining the content and temperature on the basis of spectra from remote measurements. The technique uses measurements of a high resolution radiation spectrum that allows the visibility of the individual rotational lines of gases such as CO₂, used here in the range of 2470-2495 cm¯¹. At the same time a new algorithm is applied of pre-processing the spectrum, involving the use of multiple ratios of intensity at several wavenumbers as input to an inverse model based on neural networks. Due to it, the dimensionality of the input can significantly be reduced. Additionally, the data interpreted do not have to be measured in units of spectral radiance. Thus only the calibration of the sensitivity of the spectrometer at various wavelengths is required. The neural models were constructed on the basis of data from the simulation. The proposed method works with a uniform layer of radiating gas for determining the temperature and CO₂ content. For a non-uniform layer it is possible to determine the line-of-sight temperature profile and average gas content. The method can be extended to different spectral ranges and to other gases present in substantial quantities in the exhaust gases of various processes.
Źródło:
Acta Physica Polonica A; 2017, 131, 6; 1454-1459
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectral-based fatigue life analysis of bus structural steels with different nodes and operating tracks
Autorzy:
Dewa, Rando Tungga
Adinata, Daffa Mandala
Ekaputra, I. Made Wicaksana
Kepka, Miloslav
Powiązania:
https://bibliotekanauki.pl/articles/38890079.pdf
Data publikacji:
2023
Wydawca:
Instytut Podstawowych Problemów Techniki PAN
Tematy:
stress spectra
fatigue life
structure nodes
service track
testing ground
Opis:
This paper shows a study on the effect of different structure nodes and operating tracks on the loaded/emptied type of bus vehicle in the Czech Republic. Five different structural nodes are selected to represent the loading capacity of the bus. City track and testing ground data measurements are performed for comparison. Accelerated durability test for fatigue life assessment can be performed on the testing ground with determined test track composition. The results are expected to show different characteristics of stress spectra influencing the structure’s fatigue life. The fatigue life calculation is performed based on deterministic procedures for a structural component. The procedure is then statistically expanded to include mathematical extrapolation on the stress spectra for all measurements of the designed life.
Źródło:
Engineering Transactions; 2023, 71, 2; 229-240
0867-888X
Pojawia się w:
Engineering Transactions
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electromagnetic field of extremely low frequency has an impact on selected chemical components of the honeybee
Autorzy:
Koziorowska, A.
Depciuch, J.
Białek, J.
Woś, I.
Kozioł, K.
Sadło, S.
Piechowicz, B.
Powiązania:
https://bibliotekanauki.pl/articles/2087262.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Apis mellifera
ELF-EMF
FTIR
spectra analysis
body chemical composition
Źródło:
Polish Journal of Veterinary Sciences; 2020, 23, 4; 537-544
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, spectral (FT-IR, 1H and 13C NMR) and antimicrobial studies some of (E)-2-(2-((aryl)(phenyl)methylene)hydrazinyl)benzo[d] thiazole
Autorzy:
Manikandan, S.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1177421.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Aryl hydrazone
IR and NMR spectra
antibacterial and antifungal activities
Opis:
A series of (E)-2-(2-((aryl)(phenyl)methylene)hydrazinyl)benzo[d] thiazole compounds by condensation of substituted benzophenone with 2-hydrazinobenzothizol in the presence acetic acid. The synthesized compounds 1-6 were characterized by elemental, FT-IR, 1H and 13C NMR spectral data. From the IR and NMR spectra, the characteristic frequencies were assigned and the data used for confirmation of the formation hydrazones 1-6. All compounds were screened for their preliminary antibacterial and antifungal activities. The methoxy substituted compound 6 shows good antibacterial activity against their bacterial strains within the agreed mm of zone of inhibition. The methyl (5) and methoxy (6) substituted hydrazones show good antifungal activities against their fungal strains.
Źródło:
World Scientific News; 2018, 103; 1-18
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Solvent-free synthesis and assessment of substituent effects from IR & NMR spectra of some substituted benzylidene-5-ethyl-1,3,4-thiadiazole-2-amines
Autorzy:
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/411670.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Benzylidene-5-ethyl-1
3
4-thiadiazole-2-amines
solvent-free synthesis
SiO2
H3PO4
IR spectra
NMR spectra
Hammett correlation
Opis:
A series containing ten titled compounds were synthesized by SiO2:H3PO4 catalyzed solvent-free condensation of substituted benzaldehydes and 2-amino-5-ethyl-1,3,4-thiadiazole under microwave irradiation. The yields of prepared amines are more than 90 %. The synthesized amines were characterized by their physical constants and spectroscopic data reported in literature earlier for known compounds. The assigned spectral group frequencies such as infrared νC=N, C-S-C, N-N (cm-1) and NMR chemical shifts (δ, ppm) of CH, C=N have been correlated with Hammett substituent constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analyses, the effects of substituent on the above spectral data have been discussed.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 5; 89-98
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Silne wiązania wodorowe w kompleksach wybranych kwasów organicznych z tetrametylopirazyną
Strong hydrogen bonds in selected complexes of organic acids with teramethylpyrazine
Autorzy:
Bator, G.
Sobczyk, L.
Powiązania:
https://bibliotekanauki.pl/articles/171970.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
tetrametylopirazyna
kwas chloranilowy
kwas kwadratowy
rentgenografia
widma w podczerwieni
widma rozpraszania neutronów
tetramethylpyrazine
chloranilic acid
squaric acid
X-ray diffraction
infrared spectra
neutron scattering spectra
Opis:
In the present review our interest is focused on the hydrogen bonded complexes of tetramethylpyrazine (TMP) with strong proton donors, in particular with chloranilic (CLA) or squaric (H2SQ) acid. The x-ray diffraction studies show that, depending on the proton donor, various assemblies with the acid are formed, e.g. the infinite O-H…N hydrogen bonded chains without proton transfer in the case of the complex with CLA. On the other hand with H2SQ the assemblies of [HSQ]2 2–-2TMPźH+ composition are created, in which the ionized HSQ–1 molecules are present in the form of dimers. These dimers are bound with the TMPźH+ cations on its both sides via the +N-H…O– hydrogen bonds. Picric acid forms with TMP the complex of the 2:1 composition with a double protonated TMP molecule. In the case of HI3 acid the interesting units of the (TMPźH+)2źTMP composition are formed, in which two TMPźH+ cations are coordinated with one TMP molecule through the +N-H…N bridges. In the infrared spectra of the TMP complexes, both with CLA and H2SQ, the similar absorption continua are observed. They can be interpreted in terms of an asymmetric potential for the proton motion, with either the double minimum or the single broad minimum potential for the CLA and H2SQ complexes, respectively. An analysis of the neutron scattering spectra concerns the phenomena of the tunneling splitting, quasielastic neutron scattering (QNS) and inelastic (INS) scattering. In the case of tunneling splitting neat TMP does not show any tunneling transitions in the ěeV energy region, because they are overlapped by the elastic scattering band. In the case of the TMPźCLA complex four tunneling transitions are seen corresponding to the four crystallographically nonequivalent CH3 groups in the TMP molecule. In the spectrum of the complex with squaric acid the observed two transitions are ascribed to the two different CH3 groups. The two remaining CH3 group tunneling transitions are overlapped by the elastic scattering. The measurements in various low temperature ranges yield information about the shape of the CH3 group rotational potential. The shape of the potential is also reflected in the spectra of quasielastic scattering. In particular the temperature dependence of the quasielastic band allows us to find the activation energy for the CH3 rotations. Finally the inelastic neutron scattering spectra are analyzed in the energy range of the CH3 torsional modes (below 200 cm–1 = 25 meV). The analysis shows that for the complexes the torsional vibration frequencies are markedly lower than those for neat TMP. In the case of the TMPźCLA complex frequencies found are particularly low. They are close to the frequencies calculated for the TMP+ cation. A general conclusion can be drawn that in the complexes the CH3 groups behave more loosely than in neat TMP.
Źródło:
Wiadomości Chemiczne; 2011, 65, 9-10; 869-885
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Determination of space charge region width and diffusion length in Cu(In,Ga)(S,Se)2 absorber from solar cell spectral characteristics
Autorzy:
Tivanov, M.
Patryn, A.
Powiązania:
https://bibliotekanauki.pl/articles/118474.pdf
Data publikacji:
2014
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
CdS
CIGSS
space-charge region width
diffusion length
photocurrent spectra
photovoltage spectra
CD
szerokość obszaru ładunku przestrzennego
długość drogi dyfuzji
widma fotoprądu
widma ogniwa słonecznego
Opis:
In this work we present simple non-destructive method for extracting of Cu(In,Ga)(S,Se)2-based solar cell parameters (space-charge region width and diffusion length of minority charge carriers in Cu(In,Ga)(S,Se)2 absorber) from the analysis of solar cell spectral characteristics. This method is based on one-dimensional model of a solar cell when the change of in-depth distribution of the photogenerated carriers and, hence, the change of its photoresponse with the variation of excitation wave-length in solar cell is taking into account. The following assumptions are accepted: the reflection of charge carriers from back contact and the «drawing» fields in the quasi-neutral area of the absorber layers are negligible; window and buffer layers are transparent in the analyzed of spectrum range; the injection level of minority charge carriers is low; the recombination losses at the metallurgical p-n-junction interface of the studied photosensitive structure are dependent linearly on the photocurrent density.
W pracy przedstawiono prostą metodę nieniszczącego wyznaczenia parametrów (szerokość obszaru ładunku przestrzennego i długość drogi dyfuzji mniejszościowych nośników ładunku w absorberze) dla ogniw słonecznych na bazie Cu(In,Ga)(S, Se)2 z analizy charakterystyk widmowych ogniw słonecznych. Metoda opiera się na jednowymiarowym modelu ogniwa słonecznego, kiedy zmiana rozkładu generowanych optycznie nośników jest prostopadła do powierzchni i zmiana fotoodpowiedzi ze zmianą długości fali światła wzbudzającego jest brana pod uwagę. Przyjęto poniższe założenia: odbicie nośników ładunku od tylnego kontaktu oraz zmiana pola profilu w okolicy quasi-neutralne warstw absorbera są nieistotne; warstwy czołowa i buforowa są przezroczyste w analizowanym zakresie widmowym; poziom generacji mniejszościowych nośników ładunku jest niski; straty rekombinacyjne w bazowym n-p złączu badanej struktury są uzależnione światłoczułych liniowo od gęstości fotoprądu.
Źródło:
Zeszyty Naukowe Wydziału Elektroniki i Informatyki Politechniki Koszalińskiej; 2014, 6; 69-76
1897-7421
Pojawia się w:
Zeszyty Naukowe Wydziału Elektroniki i Informatyki Politechniki Koszalińskiej
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Computational characterization of (E)-N-(3-bromo-4-fluorobenzylidene)-4-nitrobenzenamine compound
Autorzy:
Premalatha, R.
Santhi, N.
Powiązania:
https://bibliotekanauki.pl/articles/1179594.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
DFT
HOMO-LUMO and NBO
IR and Raman spectra
Schiff base
Opis:
Schiff bases are aldehyde- or ketone-like compounds in which the carbonyl group is replaced by an imine or azomethine group. In this work, (E)-N-(3-bromo-4-fluorobenzylidene)-4-nitrobenzenamine have been synthesized and characterized by IR, 1H and 13C NMR spectral studies. Density functional theory (DFT) has been used to optimize geometrical parameters, atomic charges, vibrational wavenumbers and intensity of vibrational bands. The molecular properties HOMO-LUMO, NBO were calculated using B3LYP/6-311G (d, p) basis set. The polarizability and first order hyperpolariza-bility of the title Compound was calculated and interpreted.
Źródło:
World Scientific News; 2017, 74; 121-140
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cu2+/Zeolite catalyzed synthesis and evaluation of antimicrobial activities of some chalcones
Autorzy:
Thirunarayanan, G.
Kumar, N. Dinesh
Powiązania:
https://bibliotekanauki.pl/articles/1179609.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Antimicrobial activities
Aryl chalcones
Cu2+/Zeolite
IR and NMR spectra
Opis:
Some aryl chalcones have been synthesized by Cu2+/Zeolite catalyzed aldol condensation of aryl methyl ketones and substituted benzaldehydes under microwave irradiation conditions. The yields of the synthesized chalcones are more than 85%. These chalcones were characterized by their physical constants and spectroscopic data. The antimicrobial activities of synthesized chalcones were studied by Bauer-Kirby disc diffusion method.
Źródło:
World Scientific News; 2017, 74; 251-266
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cyclic temperature and precipitation fluctuations in Poland in the 19th-21st centuries
Autorzy:
Boryczka, Jerzy
Stopa-Boryczka, Maria
Szmajda, Dorota
Powiązania:
https://bibliotekanauki.pl/articles/2032472.pdf
Data publikacji:
2006-06-01
Wydawca:
Uniwersytet Warszawski. Wydział Geografii i Studiów Regionalnych
Tematy:
air tem perature
precipitations
NAO
spectra
periods
tendency
solar activity
forecast
Opis:
The objective of the work is to determine the periodicity and trends of change in air temperature and precipitation in Poland in the time period of the 18th-20th centuries, together with the forecast for the 21st century. There are interesting diagrams of the temporal changes of solar activity and North Atlantic Oscillation (NAO) indicator, with the forecast reaching the year 2100. The forecasts were obtained on the basis of interpretations of the Wolf number and NAO indicator cycles, determined with the method of ”regression sinusoids”. The fluctuations of the air temperature and precipitations during w inter in Warsaw and in Cracow are closely correlated.
Źródło:
Miscellanea Geographica. Regional Studies on Development; 2006, 12; 43-53
0867-6046
2084-6118
Pojawia się w:
Miscellanea Geographica. Regional Studies on Development
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Badanie i analiza widm fluorescencyjnych do identyfikacji potencjalnych czynników zagrożenia biologicznego
Fluorescence spectra application and analysis for discrimination of potential biological warfare agents
Autorzy:
Kaliszewski, M.
Włodarski, M.
Kwaśny, M.
Młyńczak, J.
Kopczyński, K.
Trafny, E.
Szpakowska, M.
Mularczyk-Oliwa, M.
Bombalska, A.
Zawadzki, Z.
Mierczyk, Z.
Powiązania:
https://bibliotekanauki.pl/articles/210768.pdf
Data publikacji:
2010
Wydawca:
Wojskowa Akademia Techniczna im. Jarosława Dąbrowskiego
Tematy:
fluorescencja bakterii
aerozole biologiczne
autofluorescencja
bacteria fluorescence spectra
biological aerosols
autofluorescence
Opis:
W pracy zaprezentowano i porównano charakterystyki wzbudzeniowo-emisyjne aminokwasów, białek, bakterii, bakteriofaga MS2 oraz pyłków roślin. Pokazane zostały różnice pomiędzy drobnoustrojami hodowanymi i przygotowanymi w różnych warunkach. Rejestrowanie i analiza charakterystyk fluorescencyjnych możliwie licznej grupy związków i czynników biologicznych jest etapem niezbędnym do opracowania aparatury wykrywającej w czasie rzeczywistym chorobotwórcze drobnoustroje obecne w powietrzu.
The paper presents excitation-emmision maps of aminoacids, proteins, bacteria, bacteriophage MS2 and pollens. It shows differences between microorganisms grown and prepared in different conditions. The fluorescence data recorded in the study are necessary for the development of devices based on laser induced fluorescence that will be used for real time identification of airborne pathogenic microorganisms.
Źródło:
Biuletyn Wojskowej Akademii Technicznej; 2010, 59, 2; 363-374
1234-5865
Pojawia się w:
Biuletyn Wojskowej Akademii Technicznej
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rheological scaling properties of starch solutionsin dimethylsulfoxide
Autorzy:
Ptaszek, P.
Ptaszek, A.
Łukasiewicz, M.
Grzesik, M.
Powiązania:
https://bibliotekanauki.pl/articles/185788.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
lepkosprężystość
model Maxwella
skrobia
viscoelasticity
Maxwell model
continuous relaxation spectra
starch
Opis:
The possibility of scaling viscoelastic properties of starch solutions in relation to biopolymer concentration was presented in this study. An application of this empirical method enabled to widen the observation horizon of viscoelastic properties. It was also determined that the scope of its applicability is limited by amylose content in the solution. In high amylose solutions, for which up to 40% (w/w) concentration was the highest one obtained, calibration caused the formation of master curve in the widest frequency range. Determined values of scaling coefficients aC changed exponentially in starch concentration function in the solution. For waxy starch solutions of maximum concentration equal to 20% (w/w), scaling did not significantly widen the observation window. Based on master curves constructed in such way, continuous relaxation spectra H([lambda]) were determined using Tikhonov regularisation method. Their structure indicates advantageous of viscous elements in the process of viscoelastic phenomena formation.
Źródło:
Chemical and Process Engineering; 2012, 33, 3; 323-333
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
IR and NMR spectral LFER study on 3-benzoicacid based sulfonamides
Autorzy:
Dineshkumar, Selvakumar
Thirunarayanan, Ganesamoorthy
Powiązania:
https://bibliotekanauki.pl/articles/1182898.pdf
Data publikacji:
2016
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
3-(substituted phenylsulfonamido)benzoic acids
ir and nmr spectra
correlation analysis
Opis:
A series containing nine 3-(substituted phenylsulfonamido)benzoicacids) have been synthesized and examined their purities by their data reported earlier. The characteristic infrared (NH, SO(as), SO(sym) and CO(as) cm-1) stretches, NMR chemical shifts (δ, ppm) of NH protons, CO carbons were assigned and correlated with Hammett substituent constants and Swain-Lupton’s parameters using single and multi-regression analysis. From
Źródło:
World Scientific News; 2016, 53, 3; 367-384
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Experimental and Theoretical Investigation to Study the Molecular Structure, Electronic Properties, UV–Vis Spectra of Coumarin 102
Autorzy:
Mohi, Ali T.
Abood, Tareq H.
Hadi, Hasan A.
Karim, Mahmood S.
Mutlik, Falah A-H.
Alwan, Tariq J.
Powiązania:
https://bibliotekanauki.pl/articles/1178533.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
DFT
Ionization potential
TDDFT
electron affinity
energy gap and UV spectra
Opis:
In this work, we study the structure, electronic properties and electronic spectra of Coumarin 102 (C102) dissolved in ethanol as an experimental-theoretical investigation. The various properties of the ground and excited electronic states of coumarins 102 using density functional theory (DFT) and time-dependent density functional theory (TDDFT) was calculated by the B3LYP density functional model with 6-31G(d,p) basis set by Gaussian 09 W program. Spectral characteristics of coumarin 102 have been probed into by methods of experimental UV-visible, and quantum chemistry. The UV spectrum was measured in Ethanol. The optimized structures, total energies, electronic states (HOMO- LUMO), energy gap, ionization potentials, electron affinities, chemical potential, global hardness, softness, global electrophilictity, dipole moment and electrostatic potential was calculated. were calculated. We find good agreement between experimental data of UV spectrum and TDDFT excitation energies.
Źródło:
World Scientific News; 2017, 70, 2; 216-229
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characteristics of physicochemical and rheological properties of chitosan hydrogels based on selected hydroxy acids
Autorzy:
Zavyalova, Olga
Gajewska, Sandra
Dąbrowska-Wisłocka, Dominika
Sionkowska, Alina
Powiązania:
https://bibliotekanauki.pl/articles/2058389.pdf
Data publikacji:
2021
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
chitosan
lactobionic acid
mandelic acid
rheology
FTIR spectra
chitozan
reologia
hydrożele
Opis:
Chitosan is a natural cationic polymer that dissolves in an acidic environment and forms gels. Its properties depend on the degree of deacetylation and molecular weight. It is a bioactive compound with antibacterial and film-forming properties that allow to increase the regenerative capacity of the skin. Moreover, it is biodegradable, biocompatible, non-toxic, and stable. In this research, chitosan was combined with mandelic and lactobionic acids which are characterized by biological activity and low toxicity. This combination not only has a positive effect on the chitosan solubility, but it also allows to obtain new biomaterials whose positive features of the base ingredients are enhanced by their synergistic effect. The obtained hydrogels were assessed regarding the interaction of chitosan and hydroxy acid molecules, and the stability of the resulting structures was examined. The research was performed by using rheological methods and IR spectroscopy. Chitosan hydrogels made with mandelic acid are characterized by higher viscosity values, as compared to hydrogels containing lactobionic acid. The samples of the obtained hydrogels stored for 7 days showed no signs of degradation and their viscosity values were constantly increasing, which proves the ongoing process of creating new bonds between hydroxy acid molecules and chitosan chains. After this time, the hydrogels with mandelic acid revealed higher viscosity values in comparison to hydrogels made with lactobionic acid. Based on the obtained IR spectra, the shifts of the characteristic chitosan bands as a result of interaction with the tested hydroxy acids were analyzed.
Źródło:
Engineering of Biomaterials; 2021, 24, 161; 2--7
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
State equations in the mathematical model of dynamic behaviour of multihull floating unit
Autorzy:
Królicka, A.
Powiązania:
https://bibliotekanauki.pl/articles/259453.pdf
Data publikacji:
2010
Wydawca:
Politechnika Gdańska. Wydział Inżynierii Mechanicznej i Okrętownictwa
Tematy:
dynamics of multihull floating unit
sea waves
stochastical processes
wave spectra
Opis:
This paper concerns dynamic behaviour of multihull floating unit of catamaran type exposed to excitations due to irregular sea waves. Dynamic analysis of multihull floating unit necessitates, in its initial stage, to determine physical model of the unit and next to assume an identified mathematical model. Correctly elaborated physical models should contain information on the basis of which a mathematical model could be built. Mathematical models describe mutual relations between crucial quantities which characterize a given system in time domain. The dynamic analysis of multihull unit was performed under assumption that the unit’s model has been linear and exposed to action of irregular sea waves. Mathematical model of such dynamic system is represented by state equations. The formulated equations take into account encounter of head wave which generates symmetrical motions of the unit, i.e. surge, heave and pitch. For solving the equations the following three wave spectra were taken into consideration: - ISSC (International Ship Structures Congress) spectrum - Pierson-Moskowitz spectrum - Paszkiewicz spectrum.
Źródło:
Polish Maritime Research; 2010, 1; 33-38
1233-2585
Pojawia się w:
Polish Maritime Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Infrared and NMR spectral Hammett correlations in 4-(2-naphthyl)-5,6-dihydro-6-(substituted phenyl)-4H-1,3-oxazine-2-amines
Autorzy:
Thirunarayanan, G.
Pazhamalai, S.
Sekar, K. G.
Powiązania:
https://bibliotekanauki.pl/articles/411654.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Oxazine-2-amines
IR and NMR spectra
Hammett equation
Correlation analysis
Opis:
A series containing ten titled compounds have been synthesised and recorded the IR and NMR spectra. From the spectra the infrared νNH, C=N, C-O-C stretches, NMR chemical shifts of (δ, ppm) NH and C=N were assigned and correlated with Hammett substituent constants, F and R parameters using single regression analysis. From the results, the effects of substituent on the above spectral frequencies were discussed.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 8; 38-46
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Opracowanie parametrów generowania aerozoli bakteryjnych do badań przyrządem UVAPS
Determination of parameters of bacterial aerosol for measurement with UVAPS device
Autorzy:
Kaliszewski, M.
Włodarski, M.
Lewandowski, R.
Kwaśny, M.
Kopczyński, K.
Trafny, E. A.
Szpakowska, M.
Mularczyk-Oliwa, M.
Powiązania:
https://bibliotekanauki.pl/articles/210032.pdf
Data publikacji:
2010
Wydawca:
Wojskowa Akademia Techniczna im. Jarosława Dąbrowskiego
Tematy:
fluorescencja bakterii
aerozole biologiczne
autofluorescencja
bacteria fluorescence spectra
biological aerosols
autofluorescence
Opis:
W pracy przedstawione zostały wyniki wstępnych testów analizatora fluorescencji pojedynczych cząsteczek UVAPS 3314 firmy TSI. Celem pracy było testowanie unikalnej w skali kraju aparatury, określenie optymalnych dla pomiarów stężeń drobnoustrojów w aerozolu oraz metody generowania bioaerozoli. Badania wykazały, że wytwarzanie bioaerozolu z zawiesiny wodnej lub soli fizjologicznej w zamkniętej komorze powoduje powstawanie zbyt małego stężenia aerozolu bakterii w stosunku do całkowitej liczby cząstek. Efektem tego jest niemożność pomiaru fluorescencji przez przyrząd. Eksperymenty pozwoliły na wstępne oszacowanie możliwości pomiarowych UVAPS 3314.
The paper presents preliminary results of Ultraviolet Aerodynamic Particle Sizer's (UVAPS 3314, TSI) testing. The aim of work was testing the device that is probably unique in Poland, determination of concentration of microorganisms in aerosol optimal for measurements, and methodology of aerosol generation. Experiments showed that aerosol generated in closed chamber from water suspension or NaCl shows too low concentration of bacterial particles comparing to total amount of particles. As a result, it is not possible to record fluorescence signal of bacteria with UVAPS 3314 device. Performed experiments allowed for preliminary assessment of measurement capabilities of UVAPS.
Źródło:
Biuletyn Wojskowej Akademii Technicznej; 2010, 59, 3; 395-405
1234-5865
Pojawia się w:
Biuletyn Wojskowej Akademii Technicznej
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zastosowanie przybliżonych modeli SSI w przypadku wstrząsów górniczych
Application of approximate SSI models in case of mining tremors
Autorzy:
Kuźniar, K.
Tatara, T.
Powiązania:
https://bibliotekanauki.pl/articles/167333.pdf
Data publikacji:
2015
Wydawca:
Stowarzyszenie Inżynierów i Techników Górnictwa
Tematy:
wstrząsy górnicze
model SSI
interakcja dynamiczna podłoże-budynek
spektra odpowiedzi
transmisja spektrów odpowiedzi
mining tremors
SSI model
soil-structure interaction
response
spectra
transmission of response spectra
Opis:
W pracy dokonano przeglądu wybranych, proponowanych w literaturze, przybliżonych, prostych modeli uwzględniających zjawisko współpracy podłoże-budynek (j. ang.: soil-structure interaction – SSI) podczas trzęsień ziemi. Analizowano przydatność tych modeli do prognozowania różnic między jednocześnie zachodzącymi drganiami gruntu obok budynku i fundamentu budynku, których źródłem były wstrząsy górnicze w Legnicko-Głogowskim Okręgu Miedziowym (LGOM). Skupiono się na ocenie dokładności modeli w przypadku ich stosowania do wyznaczania relacji odpowiednich spektrów odpowiedzi: bezwymiarowych przyśpieszeniowych spektrów odpowiedzi (β) oraz wymiarowych przyśpieszeniowych spektrów odpowiedzi (Sa) od drgań poziomych. Pod uwagę wzięto różnego typu budynki.
This paper presents the selected, proposed in the literature, approximate, simple models which take into account the phenomenon of soil-structure interaction (SSI) during earthquakes. The usefulness of these models for the prediction of the differences between mine-induced vibrations in the Legnica-Glogow Copperfield (LGOM) occurring at the same time on the ground near the buildings and building foundations is analysed. The focus is on the evaluation of the accuracy of the models in the case of their application for the estimation of the relation (ratio) between the corresponding response spectra: non-dimension acceleration response spectra (β) as well as dimension averaged acceleration response spectra (Sa) from the horizontal vibrations. Various types of buildings are taken into account.
Źródło:
Przegląd Górniczy; 2015, 71, 10; 25-30
0033-216X
Pojawia się w:
Przegląd Górniczy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wpływ typu budynku na transmisję spektrów odpowiedzi od drgań górniczych z gruntu na fundamenty
The influence of building type on the transmission of response spectra of vibrations induced by mining tremors from the ground to building foundations
Autorzy:
Kuźniar, K.
Tatara, T.
Powiązania:
https://bibliotekanauki.pl/articles/166663.pdf
Data publikacji:
2015
Wydawca:
Stowarzyszenie Inżynierów i Techników Górnictwa
Tematy:
wstrząsy górnicze
spektra odpowiedzi
budynek mieszkalny
drgania gruntu
drgania fundamentu
transmisja spektrów odpowiedzi
mining tremors
response spectra
apartment building
ground vibrations
foundation vibrations
transmission of response spectra
Opis:
Praca dotyczy analizy wyników badań doświadczalnych (pomiarów drgań) pod kątem wpływu konstrukcji budynku mieszkalnego na przekazywanie drgań pochodzenia górniczego opisanych za pomocą spektrów odpowiedzi, z gruntu na fundamenty. Rozważono trzy typy budynków mieszkalnych: niski, średniej wysokości i wysoki. Źródłem drgań były wstrząsy górnicze w Legnicko-Głogowskim Okręgu Miedziowym (LGOM). Analizowano wpływ typu budynku na transmisję spektrów odpowiedzi od drgań górniczych z gruntu na fundamenty. Oceny tego wpływu dokonano poprzez badanie relacji (stosunku) spektrów odpowiedzi od drgań gruntu i fundamentów budynków (RRS). Rozważono bezwymiarowe przyśpieszeniowe spektra odpowiedzi (β) i odpowiednie spektra wymiarowe (Sa) od drgań poziomych. Stwierdzono, że daje się zauważyć wpływ konstrukcji budynku na postać krzywych relacji (stosunku) spektrów odpowiedzi od jednocześnie mierzonych drgań gruntu i fundamentów budynków. Różnice te są wyraźniej widoczne w przypadku krzywych RRS (β), wyznaczonych z użyciem bezwymiarowych przyśpieszeniowych spektrów odpowiedzi β, niż w przypadku krzywych RRS (Sa), obliczanych dla analogicznych par spektrów wymiarowych Sa.
This paper presents the analysis of the experimentally obtained results (measurements of vibrations) in terms of the influence of apartment building structure on the transmission of mine-induced vibrations described by the response spectra, from the ground to the building foundation. Three types of apartment buildings were considered: low building, medium-height building and tall building. Rockbursts in the mining region Legnica-Glogow Copperfield (LGOM) were the sources of vibrations. The influence of the type of building on the transmission of response spectra from the mine-induced ground vibrations to building foundations was analysed. Estimation of this influence was performed by examining the relationship (ratio) between the response spectra from the ground and building foundations vibrations (RRS). Non-dimension acceleration response spectra (β) as well as dimension acceleration response spectra (Sa) from the horizontal vibrations were taken into account. It was stated that the influence of building structures on the form of the response spectra curve of relationship (ratio) can be observed. These differences are clearly more evident in the case of curves RRS (β) determined by use of non-dimension acceleration response spectra β than in the case of curves RRS (Sa) computed for the corresponding pairs of dimensional spectra Sa.
Źródło:
Przegląd Górniczy; 2015, 71, 10; 31-36
0033-216X
Pojawia się w:
Przegląd Górniczy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Recent ion measurements within the modified DPF-1000U facility
Autorzy:
Kwiatkowski, R.
Czaus, K.
Skladnik-Sadowska, E.
Sadowski, M. J.
Zaloga, D. R.
Paduch, M.
Zielinska, E.
Powiązania:
https://bibliotekanauki.pl/articles/148249.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
DPF-1000U facility
ion beams
ion energy spectra
ion pinhole images
Opis:
In this note we describe measurements of ion beams emitted along the z-axis of the DPF-1000U facility operated at 23 kV, 334 kJ, and with the initial deuterium pressure of 1.6–2 hPa. The DPF-1000U device was recently renewed and equipped with a dynamic gas-puff valve placed inside the inner electrode. The investigated ions were recorded by means of ion pinhole cameras equipped with solid state nuclear track detectors of the PM-355® (PADC) type. The energy spectra of ions were determined using a Thomson spectrometer placed on the symmetry axis at a distance of 160 cm from the electrodes outlets. The ion images recorded during discharges performed under different experimental conditions show that the ion beams have a complex structure, usually in the form of a central bunch and an annular stream composed of many micro-beams. Energies of the registered deuterons have been in the range of 30–700 keV, while the fast protons (which originated from the hydrogen remnants) had energies in the range of 300–850 keV.
Źródło:
Nukleonika; 2015, 60, 2; 297-302
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Infrared study of copper(II) complexes with pyridine-3-carboxamide derivatives in chloride media
Autorzy:
Borowiak-Resterna, A.
Olszanowski, A.
Powiązania:
https://bibliotekanauki.pl/articles/346901.pdf
Data publikacji:
2004
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Tematy:
infrared spectra
solvent extraction
copper(II)
pyridine-3-carboxamide derivatives
benzamide derivatives
Opis:
The extraction studies for copper(II) from chloride solutions by mono- and dialkyl derivatives of benzamide and pyridine-3-carboxamide show that the coordination of copper by amide groups is very weak, weaker than by chloride ions. N,N-dialkyl derivative of benzamide does not extract copper from chloride media but N-alkylbenzamide eliminates a small amount of copper (a great deal smaller than pyridine-3-carboxamide derivatives) only from diluted chloride aqueous solutions ([Cl-] < 0.1 M). Infrared studies of copper complexes with mono- and dialkylpyridine-3-carboxamides show that coordination of the ligand molecules to copper(II) ions takes place mainly by the pyridine nitrogen. More stable monoalkylpyridinecarboxamides complexes with CuCl2 are formed probably by intermolecular hydrogen bonds between monomeric molecules of CuCl2L2 complex (L – the amide). However, weak coordination of copper(II) by the amide group may take place.
Źródło:
Ars Separatoria Acta; 2004, 3; 105-113
1731-6340
Pojawia się w:
Ars Separatoria Acta
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oil identification based on total synchronous spectra
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/246342.pdf
Data publikacji:
2014
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
fluorescence spectroscopy
total synchronous spectra
lubricate oil
vessel engine room
marine environment
Opis:
Contribution of marine carriage in the global transport is in permanent developing. It leads to increase the unintentional oil spills, which may induce serious disturbances in functioning of the natural marine ecosystem, especially when it interferes with other technical activities in the marine space. That fact contributes to increase the interest in searching of new research techniques to protect the natural ecosystem. Therefore, the main task of marine international organisations concentrates on the effective and rapid detection of oil spill and on the possibility of identifying oil pollutants as well as on origin of pollution. The purpose of the study is to characterise the oil belonging to the vessel engine lubricate oils. We analyse the stage results of investigations based on one of types of fluorescence spectroscopy, namely: synchronous spectra. To characterise the oil, the Aqualog Horiba spectrofluorometer was applied, which allows performing precise measurement in a short time. Based on the measured excitation-emission spectra, total synchronous fluorescence spectra for oil were obtained using various wavelength intervals. Total synchronous fluorescence spectra of petroleum substances allow finding wavelength interval typical for particular type of oil. This approach could allow obtaining of complex mixtures, such as oils, more efficient description. We discuss the total synchronous fluorescence spectra for engine oil (Marinol type) dissolved in n-hexane in various concentrations of oil as a possible tool proposed to oil type identification. We present changes and variation of the total synchronous fluorescence spectra for oil with various oil concentrations.
Źródło:
Journal of KONES; 2014, 21, 2; 15-20
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Properties of the Baltic crude oil in the oil-in-water emulsion form : excitation-emission spectra
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/246400.pdf
Data publikacji:
2018
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
crude oil
excitation-emission spectra
fluorescence
seawater
ropa naftowa
fluorescencja
woda morska
Opis:
Due to the fact that marine environment contamination by oil substances are not uncommon, it is necessary to improve the ability of determine their origin. Therefore, research on the possibility of recognizing the type of oil using its individual characteristic manifested in the processes of fluorescence excitation has been undertaken. Oil pollutants present in seawater mainly coming from ship drives, tankers, pipelines or sea bottom seeps, moreover oil leaks from offshore extraction equipment also are possible. For this reason, the crude oil extracted from the Baltic Sea deposit in the Polish Maritime Areas has been chosen for tests. Fluorescence properties of water containing small amounts of oil (concentrations from 5.59 to 55.4 ppm) in the form of oil-in-water emulsion were tested. Individual samples were assigned matrices of fluorescent values for different wavelengths, while excited by monochromatic light also for different wavelengths. The obtained matrices were visualized as a contour maps and 3D charts. For considered concentrations of crude oil dispersed in water, the wavelength-independent fluorescence maximum was determined. Obtained result indicates that in the studied wavelength range, the total fluorescence intensity is proportional to the oil concentration only for the lowest oil concentrations. The analysis of the objective parameter of the difference between the shapes of spectra indicates the similarity of the spectral shape for the lowest oil concentrations. These results are the methodological suggestion, that for the purpose of identifying the type of oil dispersed in water, spectra should be determined for sequences of different dilutions, until the excitation-emission spectra shapes become independent from the oil concentration.
Źródło:
Journal of KONES; 2018, 25, 1; 7-14
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
FT-IR and NMR spectral LFER model analysis on some 3-(1-naphthyl)-1-substituted phenyl chalcones
Autorzy:
Sekar, K. G.
Janaki, P.
Muthuvel, I.
Sathiyendiran, V.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1031827.pdf
Data publikacji:
2020
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
1-Naphthyl styryl ketone
Aldol condensation
IR and NMR Spectra
LFER Model
Opis:
In this investigation, the authors predicted the effects of substituents on the functional groups of the titled chalcones using Linear Free Energy Relationship through Hammett equation with its constants and Swain-Lupton parameters. The LFER model statistical analysis was carried out using single and multi-linear regression analysis in MS Office 365 XL package. From the LFER analysis outcome, the influence of substituents on the spectroscopic functionality were discussed with their electronic effects such as, polar, inductive, resonance, field and conjugation. The titled compounds were prepared by solvent-free Aldol-Condensation method. The prepared compounds were characterised by their physical constants, micro analysis and spectroscopic data (FT-IR, NMR and Mass).
Źródło:
World Scientific News; 2020, 147; 88-103
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and spectral correlation studies of some substituted (E)-1-Benzylidene-2-(diphenylmethylene) hydrazines
Autorzy:
Arulkumaran, R.
Manikandan, V.
Christuraj, P.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1182844.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
(e)-1-benzylidene-2-(diphenylmethylene) hydrazine
ir and nmr spectra
hammett correlations
Opis:
About ten substituted (E)-1-Benzylidene-2-(diphenylmethylene) hydrazine compounds have been synthesized. They are characterized by their analytical, ultraviolet, infrared and NMR spectral data. From infrared spectra, the CN and N+N vibrational frequencies (cm-1) of the hydrazines have been assigned. From NMR spectra, the chemical shifts (, ppm) of CH proton and C(C6H5)2 carbons of the hydrazines have been assigned. These data are correlated with Hammett substituent constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents on the spectral data have been discussed.
Źródło:
World Scientific News; 2017, 62; 93-110
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Izomery porfiryny : podobieństwa i różnice
Porphyrin isomers : similarities and differences
Autorzy:
Waluk, Jacek
Powiązania:
https://bibliotekanauki.pl/articles/1409873.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
porfirynoidy
widma elektronowe
wiązanie wodorowe
tautomeria
porphyrinoids
electronic spectra
hydrogen bond
tautomerism
Opis:
Porphyrins, “pigments of life”, are extremely popular objects of fundamental research and as candidates for diverse applications. The prerequisite for a successful application is the understanding of the electronic structure. For that purpose, it is instructive to compare the properties of porphyrin with those of its isomers. To date, six such isomers have been synthesized. In this work, we compare the characteristics of all “nitrogen-in”, N-confused- and neo-confused porphyrin isomers, including three structures that have not yet been obtained. We discuss the electronic spectra, intramolecular hydrogen bonding, and tautomerism. Analysis of the energy pattern of frontier orbitals allows predicting the redox properties, as well as the pattern of electronic absorption and magnetic circular dichroism (MCD) spectra. In turn, the geometry of the inner cavity is the factor that determines the strength of hydrogen bonds and, in consequence, the kinetics of tautomerization.
Źródło:
Wiadomości Chemiczne; 2021, 75, 5-6; 631-652
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
20 years of experience in cathodoluminescence research at the PGI-NRI
20 lat doświadczeń w badaniach katodoluminescencji w PIG-PIP
Autorzy:
Sikorska-Jaworowska, Magdalena
Powiązania:
https://bibliotekanauki.pl/articles/2061597.pdf
Data publikacji:
2019
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
cathodoluminescence studies
CL images
CL spectra
badania katodoluminescencyjne
obrazy CL
widma CL
Opis:
The use of catholuminescence analysis in scientific research at the PGI-NRI has a 20-year history. The method, combined with other analytical techniques, has become an effective tool in widely understood mineralogical and petrographic investigation reported in numerous publications.
Wykorzystanie analizy katodoluminescencyjnej w badaniach naukowych w PIG-PIB ma już 20-letnią historię. Metoda ta, w połączeniu z innymi technikami analitycznymi, stała się skutecznym narzędziem w szeroko pojętych badaniach mineralogiczno-petro¬graficznych. Potwierdzają to liczne publikacje.
Źródło:
Biuletyn Państwowego Instytutu Geologicznego; 2019, 474; 85--90
0867-6143
Pojawia się w:
Biuletyn Państwowego Instytutu Geologicznego
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wpływ zużycia rozpylaczy płaskostrumieniowych na wielkość śladów kropel
The effect of oblate flan nozzle wear on drop size spectrum
Autorzy:
Koszel, M.
Sawa, J.
Powiązania:
https://bibliotekanauki.pl/articles/239116.pdf
Data publikacji:
2005
Wydawca:
Instytut Technologiczno-Przyrodniczy
Tematy:
technika opryskiwania
zużycie
rozpylacz
ślad kropel
spraying technique
nozzle wear
drop spectra
Opis:
Analizowano zmiany poziomu natężenia wypływu cieczy z rozpylaczy szczelinowych oraz wielkość średniej średnicy śladu kropli wytworzonego przez rozpylacze. Badano rozpylacze nowe i powszechnie użytkowane przez rolników. Wraz ze wzrostem natężenia wypływu cieczy następuje również zmiana kategorii oprysku. Stwierdzono wzrost natężenia wypływu cieczy w zależności od wielkości szczeliny wylotowej rozpylacza, jak również od czasu pracy rozpylaczy oraz wzrost wielkości śladu kropli wraz ze wzrostem stopnia zużycia. Powoduje to ekologiczne zagrożenia dla środowiska.
The changes in intensity of liquid outflow from flattened fan nozzles and the average diameter of drop spectra were analysed. New sprayer nozzles as well as the nozzles commonly used by the farmers were tested. The increase of outflow rate was followed by changes in the category of spraying. It was observed that increased rate of liquid outflow depended on the size of sprayer nozzles and their working life. The size of drop spectra rose with increasing the wear of nozzles. This was a reason of arising ecological threats to the environment.
Źródło:
Problemy Inżynierii Rolniczej; 2005, R. 13, nr 2, 2; 17-23
1231-0093
Pojawia się w:
Problemy Inżynierii Rolniczej
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectrum of light absorption as the indicator of lubricate oil dispsersed in the natural water
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/247346.pdf
Data publikacji:
2016
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
lubricate oil
absorption
absorption spectra of dispersed oil oil-in-water emulsion
Opis:
Oil pollutants in the natural water masses – especially in the seawater column – can be found in two forms, namely as dissolved oil or as dispersed one. With a broad set of methods, for studying the complex structure of petroleum products, due to the ability of petroleum products to absorb UV-light, absorbance spectra could be a relevant indicator to oil identification in aquatic environment and could support methods provided by the fluorescence technique. The intention of the study described in this article is to characterise the absorption properties of lubricate oil possible to found in the marine environment. Two types of oil as the representative of lubricate oils using in the ship engines are considered. One form of oil possible to found in the marine environment – oil-in-water emulsion was taken into account for analysis. Dispersed in water lubricate oil samples were prepared for several oil concentration for each type of oil. Spectrofluorometer Aqualog Horiba was used to register the absorbance spectra of oils. Based on the Lambert-Beer law the absorbance spectra were derived and specific parameter – absorption coefficient – for each wavelength of excitation, in the range 240-600 nm, was determined. Obtained results indicate decreasing of the oil absorbance value when excitation wavelength increases. Moreover, basing on the absorbance spectra it could be concluded that the main maximum for this kind of oils is located below 240 nm. However, in the considered range of excitation wavelength small flat peak, centred about 265 nm for both types of oils, was detected. Therefore one could conclude that absorbance of oils could be used as the indicator to detect of oil pollution in the natural environment omitting the labour intensive chemical methodology.
Źródło:
Journal of KONES; 2016, 23, 1; 61-66
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of mechanical activation in synthesizing multiferroic Pb(Fe1/2Nb1/2)O3 powders
Wykorzystanie mechanicznej aktywacji do syntetyzowania multiferroikowych proszków Pb(Fe1/2Nb1/2)O3
Autorzy:
Bochenek, D.
Dercz, G.
Oleszak, D.
Powiązania:
https://bibliotekanauki.pl/articles/352621.pdf
Data publikacji:
2011
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
aktywacja mechaniczna
multiferroics
PFN
spektroskopia Mössbauera
mechanical activation
PFN ceramics
Mössbauer spectra
Opis:
In the study, the method of high-energy powder milling - mechanical activation (MA) was used for synthesizing Pb(Fe1/2Nb1/2)O3 (PFN) powders. For the purpose of comparing the influence of high-energy milling on PFN synthesis, two groups of powder samples were used. The first mixture consisting of simple oxide powders; the second one consisting of compound oxide powders. The obtained powders were subjected to structural analysis with the use of XRD and Mőssbauer spectroscopy. Tests revealed that during the process of high-energy milling of initial constituents a partial synthesis of PFN material phases occurs. By comparing the two methods of PFN synthesizing it may be stated that mechanical activation in the case of a simple oxide mixture (PFN1) is equally effective as for a compound oxide mixture (PFN2).
W pracy, w procesie technologicznym, wykorzystano metodę wysokoenergetycznego mielenia proszków – mechanicznej aktywacji (MA) do syntezowania proszków Pb(Fe1/2Nb1/2)O3 (PFN). Do porównania wpływu wysokoenergetycznego mielenia na synteze PFN wykorzystano dwie grupy próbek proszkowych. Pierwsza mieszanine stanowiły proszki prostych tlenków (jednoetapowa metoda otrzymywania – PFN1), druga stanowiły proszki złozonych tlenków (dwuetapowa metoda otrzymywania – PFN2). Otrzymane proszki poddano analizie strukturalnej przy użyciu XRD i spektroskopii Mossbauera. Badania potwierdziły, ze podczas procesu wysokoenergetycznego mielenia składników wyjsciowych zachodzi czesciowa synteza faz materiału PFN. Porównujac dwie metody syntetyzowania PFN można stwierdzić, że mechaniczna aktywacja jest jednakowo skuteczna w przypadku mieszaniny prostych tlenków (PFN1) jak i dla mieszaniny złożonych tlenków (PFN2).
Źródło:
Archives of Metallurgy and Materials; 2011, 56, 4; 1015-1015
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analiza widm spektroskopii emisyjnej za pomocą wielowymiarowych metod statystycznych
Analysis of emission spectra using multivariate statistic methods
Autorzy:
Skrzeczanowski, W.
Antonik, A.
Powiązania:
https://bibliotekanauki.pl/articles/159792.pdf
Data publikacji:
2012
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Elektrotechniki
Tematy:
analiza czynnikowa
główne składowe
widmo emisyjne
principal components
factorial analysis
emission spectra
Opis:
W pracy przedstawiono przykłady zastosowania wielowymiarowych metod statystycznych w badaniach widm spektroskopii emisyjnej. Krótko scharakteryzowano najistotniejsze właściwości dwóch metod, takich jak Analiza Czynnikowa (FA - Factorial Analysis) i Analiza Głównych Składowych (ang. PCA - Principal Components Analysis). Zastosowano je do analizy widm emisyjnych uzyskanych ze źródeł ciągłych i impulsowych. Stwierdzono, że obróbka widm za pomocą metod FA/PCA pozwala wyznaczyć stopień podobieństwa widm, co z kolei umożliwia określenie różnic w charakterze źródeł, których emisja jest rejestrowana. W pracy zestawiono wyniki analizy FA/PCA widm LIBS (spektroskopii emisyjnej ze wzbudzeniem laserowym) w zastosowaniu badań stratygraficznych, identyfikacji różnych gatunków papieru, analizy powierzchniowej korozji wyrobów ze stopów stali o różnej strukturze powierzchni, wyładowań w gazie i żarówek. Zaprezentowano próby zastosowania metody FA do konstrukcji krzywych kalibracyjnych, umożliwiających badania ilościowe stopów metali, bez konieczności korzystania z danych atomowych właściwych składnikom stopów.
The most important characteristics of the Principal Components Analysis and Factorial Analysis are briefly described. They were applied to analysis of emission spectra obtained from stationary and pulse sources. It was stated that processing of spectra using PCA/FA methods reveals similarity level of the spectra, which in turn allows for determination of differences between analysed sources which emission is measured. Results of PCA/FA analysis of LIBS spectra applied to stratigraphy measurements, identification of paper sort, corrosion process of surface layers of iron alloys, discharges in gas and light bulbs are shown. Attempts of the use of the FA method for construction of calibration curves is presented which can be applied in quantitative measurements without need of use of atomic data.
Źródło:
Prace Instytutu Elektrotechniki; 2012, 255; 175-195
0032-6216
Pojawia się w:
Prace Instytutu Elektrotechniki
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pomiary temperatury łuku palącego się w szczelinie międzystykowej aparatów elektrycznych za pomocą spektrofotometru światłowodowego
Spectrophotometric testing of an electric arc of alternating current
Autorzy:
Żukowski, P.
Kozak, C.
Karwat, C.
Powiązania:
https://bibliotekanauki.pl/articles/153223.pdf
Data publikacji:
2008
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
łączniki
łuk elektryczny
temperatura
widma
spektrofotometr
switches
electric arc
temperature
spectra
spectrophotometer
Opis:
W artykule opisano spektrofotometryczną metodę określania temperatury łuku elektrycznego palącego się w szczelinie międzystykowej łącznika na podstawie zarejestrowanych widm ciągłych, oraz wpływ rodzaju materiału styków i ich cech konstrukcyjnych na jej wartość.
The article presents a spectrophotometric method for determining temperature of electric arc burning in an inter-contact gap of a switch based on recorded continuous spectra. Influence of the material and design of the contacts on the temperature values is also discussed.
Źródło:
Pomiary Automatyka Kontrola; 2008, R. 54, nr 10, 10; 682-685
0032-4140
Pojawia się w:
Pomiary Automatyka Kontrola
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, assessment of substituent effect and antimicrobial activities of some substituted (E)-Nbenzylidene- 5-bromopyridin-2-amines
Autorzy:
Senbagam, Rajamohan
Vanangamudi, Ganesan
Thirunarayanan, Ganesamoorthy
Powiązania:
https://bibliotekanauki.pl/articles/763969.pdf
Data publikacji:
2015
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
E-imines
UV
IR and NMR spectra
Spectral QSAR study
Antimicrobial activities
Opis:
A series of substituted (E)-N-benzylidene-5-bromopyridin-2-amine compounds have been synthesized from 5-bromo-2-aminopyridine with different substituted benzaldehydes. The structure of the adducts was confirmed by their physical constants, UV, IR and NMR spectral data. The observed UV absorption maximum λmaxC=N(nm), IR frequencies νC=N(cm-1), The 1H and 13C NMR δ(ppm) chemical shifts values have been correlated with Hammett substituent constants and F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents on the spectral data has been studied. The antimicrobial activities of all synthesized imines have been studied using Bauer-Kirby method.
Źródło:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2015, 70, 2
2083-358X
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Detrital zircon analysis of metasedimentary rocks of the Staré Město Belt, Sudetes : implications for the provenance and evolution of the eastern margin of the Saxothuringian terrane, NE Bohemian Massif
Autorzy:
Śliwiński, Marek
Jastrzębski, Mirosław
Sláma, Jiří
Powiązania:
https://bibliotekanauki.pl/articles/2187195.pdf
Data publikacji:
2022
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
detrital zircon age spectra
provenance
Variscan terranes
Staré Mìsto Belt
Bohemian Massif
Opis:
The Staré Město Belt (SMB) in the Central Sudetes forms a Variscan tectonic boundary zone that is located between the Saxothuringian and Brunovistulian terranes of the Bohemian Massif. The three thrust-bounded upper, middle and lower lithotectonic units of the SMB are composed of metasedimentary and Late Cambrian metavolcanic rocks. A new LA-ICP-MS zircon geochronology supported by zircon typology studies of the mica schists of the upper unit and the migmatitic paragneisses of the middle unit provides new insights into the provenance and evolution of the SMB. Our new data were obtained from metasedimentary rocks and compared to the previously published zircon ages of the SMB metavolcanic rocks. The results indicate that the metasedimentary and bimodal metavolcanic rocks in the separate lithotectonic units of the SMB originally formed Late Cambrian volcano-sedimentary successions. The source areas of the sedimentary basins studied were dominated by Neoproterozoic and Paleoproterozoic crystalline rocks that were presumably located near the West African Craton of Gondwana. A comparison of the detrital age spectra obtained with those previously published from the region indicates a strong association of the entire SMB with the Saxothuringian terrane of the Bohemian Massif. During partial melting of the metasedimentary rocks of the middle unit of the SMB, Cambrian and older zircon grains were affected by solid-state transformations that caused partial resetting of the U-Pb dates, changes in internal zircon textures and reductions in Th/U ratios.
Źródło:
Geological Quarterly; 2022, 66, 2; art. no. 21
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ultrasonicated Synthesis of Bio-potent Sulphonamides
Autorzy:
Thirunarayanan, Ganesamooorthy
Powiązania:
https://bibliotekanauki.pl/articles/1075695.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Antimicrobial activity
Antioxidant activity
Aryl sulfonamides
IR and NMR spectra
Sodium acetate
Ultrasonication
Opis:
About more than 85% yields of some aryl sulphonamides were synthesised by sodium acetate catalysed ultrasonication promoted condensation of aryl amines and benzene sulfonyl chlorides in room temperature. The synthesised sulfonamides were analysed with their physical constants, micro analysis and spectral techniques. The antioxidant potential of these sulfonamides were assessed by DPPH radical scavenging activity measurement using L-ascorbic acid as a standard. Antimicrobial activities of these sulfonamides have been assessed by disc diffusion method against their antimicrobial stains. Most of the sulfonamides shows antimicrobial activity. Many of the hydroxy and methoxy substituted sulfonamides showed significant antioxidant activity.
Źródło:
World Scientific News; 2019, 119; 125-138
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and spectral correlation studies of some (E)-N′-1-(substituted benzylidene) benzohydrazides
Autorzy:
Manikandan, V.
Balaji, S.
Senbagam, R.
Vijayakumar, R.
Rajarajan, M.
Vanangamudi, G.
Arulkumaran, R.
Sundararajan, R.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1162032.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
(E)-N’-1-(substituted benzylidene) benzohydrazides
IR and NMR spectra and Correlations
UV
Opis:
About ten substituted (E)-N’-1-(substituted benzylidene) benzohydrazides have been synthesized. They are characterized by their analytical, ultraviolet, infrared and NMR spectral data. The effects of substituent on these data have been studied using Hammett equation.
Źródło:
World Scientific News; 2018, 111; 26-39
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Greener synthesis and Hammett spectral Linearity’s of some 1-{[3-(furan-2-yl)-5-phenyl-4,5-dihydro-1,2-oxazol-4-yl]methyl}-4-methyl piperazines
Autorzy:
Thirunarayanan, G.
Rajarajan, M.
Sekar, K. G.
Sathiyendiran, V.
Powiązania:
https://bibliotekanauki.pl/articles/1179600.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Hammett equation and Regression analyses
Hammett substituent constants
IR and NMR spectra
Piperazines
Opis:
We have synthesized eleven numbers of 1-{[3-(furan-2-yl)-5-phenyl-4,5-dihydro-1,2-oxazol-4-yl]methyl}-4-methyl piperazines by hydroxyapatite catalyzed microwave assisted condensation method. The synthesized 1-{[3-(furan-2-yl)-5-phenyl-4,5-dihydro-1,2-oxazol-4-yl]methyl}-4-methyl piperazine compounds were characterized by means of their IR and NMR spectral data. The assigned infrared spectral νC=N, νC-O-C stretches(cm-1), NMR chemical shifts of isoxazoline (d) proton, isoxazoline (m) proton, N-CH3, C=N, C-NH2 and C-NH3 (δ, ppm) of these 1-{[3-(furan-2-yl)-5-phenyl-4,5-dihydro-1,2-oxazol-4-yl]methyl}-4-methyl piperazines were assigned and correlated with Hammett substituent constants, F and R parameters using single and multi linear regression analysis. From the results of statistical analyses, the effects of substituents on the above group frequencies were discussed.
Źródło:
World Scientific News; 2017, 74; 164-180
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Association of model peptides and dehydropeptides: N-acetyl-l-butyrine and (Z)-dehydrobutyrine N',N'-dimethylamides
Autorzy:
Broda, Małgorzata
Rzeszotarska, Barbara
Powiązania:
https://bibliotekanauki.pl/articles/1041295.pdf
Data publikacji:
2006
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
ab initio/DFT calculations
hydrogen bonds
dimer
IR spectra
α,β-dehydroamino acids
Opis:
These comparative studies on the aggregation behaviour of Ac-(Z)-ΔAbu-NMe2 and Ac-L-Abu-NMe2 in carbon tetrachloride were performed by the analysis of their FTIR spectra and by theoretical calculations. The percentage of the monomeric form (α) decreased as concentration increased and this occurred to a higher degree for the (Z)-ΔAbu derivative than for its saturated analogue. The dimerization constant KD, calculated on the basis of the intensity of the monomer and associate bands in the νs(N-H) vibration region, is by three orders of magnitude larger for Ac-(Z)-ΔAbu-NMe2 than for Ac-L-Abu-NMe2. The obtained dimer geometries of the dehydro- compound were calculated by the B3LYP/6-31+G** method.
Źródło:
Acta Biochimica Polonica; 2006, 53, 1; 221-226
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanizm sorpcji jonów Cu2+ na chitozanie uformowanym w postaci mikrogranulek
Mechanism of Cu2+ ions sorption in chirosan microgranules
Autorzy:
Modrzejewska, Z.
Dorabialska, M.
Zarzycki, R.
Powiązania:
https://bibliotekanauki.pl/articles/2070685.pdf
Data publikacji:
2009
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
mikrogranulki
chitozan
suszenie nadkrytyczne
widma IR
NMR
microgranules
chitosan
supercritical drying
IR spectra
Opis:
W pracy przedstawiono badania mechanizmu sorpcji jonów Cu + w mi-krogranulkach wytworzonych w procesie suszenia w warunkach nad-krytycznych na podstawie widm IR w podczerwieni oraz przy wykorzystaniu metody magnetycznego rezonansu jądrowego NMR. Badania potwierdzają główny udział grup NH2 i OH wskazując na zmiany przy wiązaniach glikozydowych.
The FTIR and NMR methods were used to study the structure of chitosan microgranules formed via supercritical drying chelated by Cu ions. Analysis of the spectra confirmed major participation of NH2 and OH groups indicating the changes in glycosidic bonds.
Źródło:
Inżynieria i Aparatura Chemiczna; 2009, 5; 77-78
0368-0827
Pojawia się w:
Inżynieria i Aparatura Chemiczna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, Assessment of substituent effect and Antimicrobial activities of some substituted (E)-N-benzylidene-4H-1,2,4-triazol-4-amines
Autorzy:
Senbagam, R.
Rajarajan, M.
Vijayakumar, R.
Manikandan, V.
Balaji, S.
Vanangamudi, G.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1194005.pdf
Data publikacji:
2015
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
IR and NMR spectra
QSAR study
UV
antimicrobial study
heterocyclic Schiff bases
synthesis
Opis:
Schiff H., Justus Liebigs Annalen der Chemie. 131(1) (1864) 118-9. [2] Lau K. Y., Mayr A., Cheung K. K., Inorgnic Chimica Acta. 285 (1999) 223-232. [3] Shawali A. S., Harb N. M. S., Badahdah K. O., Journal of Heterocyclic Chemistry. 22 (1985) 1397-1403. [4] Gupta K. C., Sutar A. K., Coordination Chemistry Review. 252 (2008) 1420-1450. [5] Yuan M., Zhao F., Zhang W., Wang Z. M., Gao S., Inorgnic Chemistry. 46 (2007) 11235-42. [6] Nakaic T., Meddu S., Kurahashi T., Japan Patent. 7389932 (1973); Chemical Abstracts. 81(1974) 65182. [7] Quraishi Harion M. A., Sharma K., Journal of Materials Chemistry and Physics. 78 (2002) 18-21. [8] Ramesh S., Rajeshwari S., Elctrochimica Acta. 49 (2004) 811-820. [9] Colter R. J., Matzner M., Ring terming poly, Part B-1, ‘Heterocyclic Ring’ Academic, New Youk, (1972). [10] Popp. F. D., Journal of Organic Chemistry. 26 (1961) 1566-1568. [11] Rao X., Huang X., He L., Song J., Song Z., Shang S., Combinatorial Chemistry & High Throughput Screening. 15 (2012) 840-844. [12] Hadjipavlou-litina D. J., Geronikaki A. A., Letters in Drug Design & Discovery. 15 (1996) 199-206. [13] Tiwary M., Naik S. N., Tiwari D. K., Mittal P. K., Yadav S., Journal of vector Brone Diseases. 44 (2007) 198-204. [14] Solak N., Rollas S., Arkivoc. (2006) 173-181. [15] Wadher S. J., Puranik M. P., Karande N. A., Yeole P. G., International Journal of Pharm Tech Research 1 (2009) 22-33. [16] Cates A. L., Rasheed S. M., Pharmaceutical Research 6 (1984) 271-273. [17] Sakthinathan S. P., Suresh R., Mala V., Sathiyamoorthi K., Kamalakkannan D., Ranganathan K., John Joseph S., Vanangamudi G., Thirunarayanan G., International Journal of Scientific Research and Knowledge, 1(11) (2013) 472. [18] Sakthinathan S. P., Suresh R., Mala V., Sathiyamoorthi K., Kamalakkannan D., Ranganathan K., Arulkumaran R., Vijayakumar S., Sundararajan R., Vanangamudi G., Thirunarayanan G., International Letters of Chemistry, Physics and Astronomy. 6 (2013) 77. [19] Suresh R., Kamalakkannan D., Ranganathan K., Arulkumaran R., Sundararajan R., Sakthinathan S. P., Vijayakumar S., Sathiyamoorthi K., Mala V., Vanangamudi G., Thirumurthy K., Mayavel P., Thirunarayanan G., Spectrochim. Acta, 101A (2013) 239. [20] Arulkumaran R., Vijayakumar S., Sakthinathan S.P., Kamalakkannan D., Ranganathan K., Suresh R., Sundararajan R., Vanangamudi G., Thirunarayanan G., Journal of Chilean Chemical Society. 2 (2013) 58. [21] Thirunarayanan G., Gopalakrishnan M., Vanangamudi G., Spectrochemica Acta 67A (2007)1106-1112 [22] Swain C. G., Lupton E. C., Journal of American Chemical Society. 90 (1968) 4328-4337. [23] Bauer A. W., Kirby W. M. M., Sherris J. C., Truck M., American Journal of Clinical Pathology. 45 (1966) 493-498.
Źródło:
World Scientific News; 2015, 8; 176-191
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Hammett spectral correlation studies of some substituted cyanopyridine compounds
Autorzy:
Arulkumaran, R.
Manikandan, V.
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/1179260.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Hammett constants
IR and NMR spectra
Single and multi-correlation analysis
Substituted cyanopyridine
Opis:
About ten substituted cyanopyridine compounds have been synthesized and the purities of these pyridines were examined with their physical constants, analytical and spectroscopic data provided in the literature. They are characteristic infrared stretches and NMR chemical shifts were assigned and they are correlated with Hammett substituent constants using single and multi-linear regression analysis. From the results, the effect of substituents on the spectral data of cyanopyridine has been discussed.
Źródło:
World Scientific News; 2017, 80; 239-255
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and characterization of copper(II) complex of 3-methyl-2,6-diphenylpiperidin-4-one oxime
Autorzy:
Thirunarayanan, G.
Lakshmanan, K.
Powiązania:
https://bibliotekanauki.pl/articles/1076144.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Complexation
Copper chloride
Piperidine-4-one
Piperidine-4-oneoxime
UV and IR spectra
Opis:
A novel six membered heterocyclic oxime namely 3-methyl-2,6-diphenylpiperidin-4-oneoxime was prepared from the condensation of 3-methyl-2,6-diphenylpiperidin-4-one and hydroxylamine hydrochloride. The obtained oxime was characterized by their physical, analytical and spectroscopic data. This oxime was utilized as ligand for preparation of the copper complex. The oxime belongs to bidentate ligand nature. The copper complex of this oxime was prepared by the conventional heating of ethanolic solution of this oxime and copper chloride pentahydrate. The obtained copper complex was analyzed by their physical constants, analytical, pH measurements, UV and IR spectral data. These physicochemical analysis results confirmed, the structure of the complex was octahedral.
Źródło:
World Scientific News; 2019, 116; 102-114
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Infrared spectral analysis of waste pet samples
Autorzy:
Vijayakumar, S.
Rajakumar, P. R.
Powiązania:
https://bibliotekanauki.pl/articles/411833.pdf
Data publikacji:
2012
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
butelki PET
ABS
FTIR
mieszanki kompozytowe
PET bottles
FT-IR spectra
blended composites
Opis:
There are fifteen waste pet bottles and a commercial grade ABS was collected from local supplier of Chidambaram town. The ABS was used to study the mechanical properties of PET blend composites. This study was performed by FT-IR spectroscopy. From the characteristics infra-red stretching bands the mechanical properties of samples were discussed.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2012, 4; 58-65
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
IR & NMR spectral studies of some 7-substituted 9H-fluorenacyl bromides: Assessment of substituent effects
Autorzy:
Thirunarayanan, G.
Powiązania:
https://bibliotekanauki.pl/articles/412017.pdf
Data publikacji:
2013
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
9H-Fluorenacyl bromides
IR and NMR spectra
Hammett substituent constants
Correlation analysis
Opis:
A series of some 2-bromo-1-(2-substituted 9H-fluorene-7-yl)ethanones have been prepared. The purities of these ethanones have been checked by their physical constants and spectroscopic data. The spectral group frequencies of these enones have been assigned and correlated with Hammett substituent constants, F and R parameters. From the results of statistical analyses, the effects of substituent have been discussed.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2013, 9, 2; 152-161
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spektroskopia NIR - modelowanie kwantowo-mechaniczne widm jako narzędzie w badaniach podstawowych i wsparcie zastosowań analitycznych
NIR spectrometry - spectra simulation as a potent tool in basic research and analytical applications
Autorzy:
Beć, Krzysztof B.
Grabska, Justyna
Powiązania:
https://bibliotekanauki.pl/articles/27310036.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
modelowanie kwantowo-mechaniczne widm
spektroskopia absorpcyjna w zakresie bliskiej podczerwieni (NIR)
interpretacja widm
nadtony
pasma drgań kombinacyjnych
przypisania pasm
spectra simulation
near-infrared (NIR)
spectra interpretation
overtones
combination bands
band assignments
Opis:
Near-infrared (NIR) spectroscopy is a powerful technique that has been extensively used for the qualitative and quantitative analysis of a broad range of chemical compounds in various fields, such as pharmaceuticals, food, and environmental monitoring. However, the interpretation of NIR spectra is often challenging due to the complex line shape and overlapping signals that make it difficult to assign the bands to specific molecular vibrations. In recent years, significant advancements in theoretical methods have enabled the calculation of NIR spectra for a variety of molecules, paving the way for the integration of computational chemistry and NIR spectroscopy. This emerging field offers a wealth of opportunities to improve our understanding of the spectral features and to provide detailed molecular fingerprints that are essential for fundamental research and practical applications. Accurate simulation of NIR bands unlocks new potential in exploring the solvent effect or intermolecular interactions, in which cases interpreted overtones and combination bands provide unique information, complementary to that extracted from the fundamental bands observed in mid-infrared (MIR) region. In the area of applications, by reproducing the spectra of molecules with complex structures, theoretical calculations can provide new physical insights into the nature of the vibrational modes that contribute to the spectral signals. This knowledge can be used to improve the accuracy and reliability of chemometric models that are commonly used in quantitative analysis.
Źródło:
Wiadomości Chemiczne; 2023, 77, 7-8; 719--743
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-100 z 171

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