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Tytuł:
Tunnel support design by comparison of empirical and finite element analysis of the Nahakki Tunnel in Mohmand Agency, Pakistan
Autorzy:
Riaz, A.
Jamil, S. M.
Asif, M.
Akhtar, K.
Powiązania:
https://bibliotekanauki.pl/articles/178620.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
rock mass strength parameters
rock mass classification
FEM analysis
Phase2
tunnel support design
Opis:
The paper analyses the geological conditions of study area, rock mass strength parameters with suitable support structure propositions for the under construction Nahakki tunnel in Mohmand Agency. Geology of study area varies from mica schist to graphitic marble/phyllite to schist. The tunnel ground is classified and divided by the empisical classification systems like Rock mass rating (RMR), Q system (Q), and Geological strength index (GSI). Tunnel support measures are selected based on RMR and Q classification systems. Computer based finite element analysis (FEM) has given yet another dimension to design approach. FEM software Phase2 version 7.017 is used to calculate and compare deformations and stress concentrations around the tunnel, analyze interaction of support systems with excavated rock masses and verify and check the validity of empirically determined excavation and support systems.
Źródło:
Studia Geotechnica et Mechanica; 2016, 38, 1; 75-84
0137-6365
2083-831X
Pojawia się w:
Studia Geotechnica et Mechanica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
High-Velocity Impact of 2-Phase WC/Co Composite Plate - Beginning of the Process
Autorzy:
Postek, E.
Sadowski, T.
Powiązania:
https://bibliotekanauki.pl/articles/351505.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
2-phase composites
cermet
Johnson-Cook plasticity
impact
numerical modelling
Opis:
2-phase composites are often used for high demanding parts that can undergo impact loads. However, most of the papers on dynamic loading concerns layered composites. In our opinion, the impact loads are not considered thoroughly enough. Good examples of 2-phase composites are: (1) a WC/Co cermet or (2) a monolithic ceramic Al2 O3 /ZrO2 . The WC/Co cermet is often modelled as having ductile elasto-plastic Co matrix and ideally elastic WC grains. It is because of very high crushing resistivity of the WC. In this paper, we present an extension to earlier elaborated models ([44]) with the assumption of ideal elasticity of the grains. The new and general numerical model for high-velocity impact of the 2-phase composites is proposed. The idea of this novelty relies on the introduction of crushability of grains in the composite and thermo-mechanical coupling. The model allows for description of the dynamic response both composite polycrystals made of: (1) 2 different purely elastic phases (e.g. Al2 O3 /ZrO2 ) or (2) one elastic phase and the second one plastic (e.g. cermet WC/Co), or (3) 2 elasto-plastic phases with different material properties and damage processes. In particular, the analysis was limited to the cases (2) and (3), i.e. we investigated the WC/Co polycrystal that impacted a rigid wall with the initial velocity equal to 50 m/s.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 1; 265-274
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fabrication of Mo-Si-B Intermetallic Compound Powders Under Different Heat Treatment Conditions
Autorzy:
Park, J. H.
Lee, S.
Kim, D.
Kim, Y.
Yang, S. H.
Lee, S. H.
Powiązania:
https://bibliotekanauki.pl/articles/353369.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Mo-Si-B alloys
intermetallic compounds
reitveld refinement
T2 phase
A15 phase
Opis:
In this research, we investigated the effects of reduction atmospheres on the creation of the Mo-Si-B intermetallic compounds (IMC) during the heat treatments. For outstanding anti-oxidation and elevated mechanical strength at the ultrahigh temperature, we fabricated the uniformly dispersed IMC powders such as Mo5SiB2 (T2) and Mo3Si (A15) phases using the two steps of chemical reactions. Especially, in the second procedure, we studied the influence of the atmospheres (e.g. vacuum, argon, and hydrogen) on the synthesis of IMCs during the reduction. Furthermore, the newly produced IMCs were observed by SEM, XRD, and EDS to identify the phase of the compounds. We also calculated an amount of IMCs in the reduced powders depending on the atmosphere using the Reitveld refinement method. Consequently, it is found that hydrogen atmosphere was suitable for fabrication of IMC without other IMC phases.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 3; 1509-1512
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A Mössbauer and structural study of disordered alloys Fe3-xTixAl (0 < x < 1)
Autorzy:
Brząkalik, K.
Frąckowiak, J.
Powiązania:
https://bibliotekanauki.pl/articles/148880.pdf
Data publikacji:
2003
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Fe2TiAl Heusler phase
Fe-Ti-Al system
Mössbauer spectroscopy
Opis:
A series of the disordered Fe3-xTixAl (x = 0, 0.2, 0.45, 0.55, 0.65, 0.70, 0.75, 1) alloys obtained by arc-melting were studied. Directly after melting the samples were mechanically crashed and in that form examined by the structural and Mössbauer effect methods. The alloys were strongly disordered, but it was possible to identify, apart from Fe-bcc phase, the origins of forming such phases as Fe2TiAl Heusler phase, Fe3Al with DO3 structure, FeAl and FeTi with B2 structure and non-stechiometric Fe2Ti Laves phase with hexagonal C14 structure. For Ti concentration up to x = 0.45, the disordered Fe-bcc phase dominates. For Ti concentration from x = 0.55 to x = 1, the Fe2TiAl phase coexists with FeAl phase (for x = 0.55, 0.65) and with FeTi phase (x = 0.7 and 0.75). In a sample with the nominal Fe2TiAl composition of Fe2TiAl Heusler phase, a non-stoichiometric Fe2Ti Laves phase with hexagonal C14 structure was observed.
Źródło:
Nukleonika; 2003, 48,suppl.1; 13-16
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Quantum-inspired evolutionary optimization of SLMoS2 two-phase structures
Autorzy:
Kuś, Wacław
Mrozek, Adam
Powiązania:
https://bibliotekanauki.pl/articles/29520072.pdf
Data publikacji:
2022
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
quantum-inspired evolutionary algorithm
optimization
nanostructure
two-phase SLMoS2
molecular dynamics
molecular statics
atomic potential
ReaxFF
material properties
Opis:
The paper focuses on applying a Quantum Inspired Evolutionary Algorithm to achieve the optimization of 2D material containing two phases, 2H and 1T, of Molybdenum Disulphide (MoS2). The goal of the optimization is to obtain a nanostructure with tailored mechanical properties. The design variables describe the shape of inclusion made from phase 1T in the 2H unit cell. The modification of the size of the inclusions leads to changes in the mechanical properties. The problem is solved with the use of computed mechanical properties on the basis of the Molecular Statics approach with ReaxFF potentials.
Źródło:
Computer Methods in Materials Science; 2022, 22, 2; 67-78
2720-4081
2720-3948
Pojawia się w:
Computer Methods in Materials Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of Cooling Rate after Homogenization on the Microstructure and Properties of 2017a Alloy Billets for Extrusion with Solution Heat Treatment on the Press
Autorzy:
Woźnicki, A.
Leśniak, D.
Włoch, G.
Pałka, P.
Leszczyńska-Madej, B.
Wojtyna, A.
Powiązania:
https://bibliotekanauki.pl/articles/355500.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
2017A alloy
cooling rate after homogenization
θ (Al2Cu) phase particles precipitation
Opis:
The influence of cooling rate after homogenization on the 2017A alloy microstructure was analysed. The capability of the θ (Al2Cu) particles, precipitated during various homogenization coolings, for rapid dissolution was estimated. For this purpose, the DSC test was used to determine the effect of the cooling rate after homogenization on the course of melting during a rapid heating. Moreover, the samples after solution heat treatment (with short time annealing) and ageing, were subjected to the microstructure investigations and the microhardness of grains interiors measurements. It was found that cooling after homogenization at 160 °C/h is sufficient for precipitation of fine θ phase particles, which dissolve during the subsequent rapid heating. The cooling at 40 °C/h, causes the precipitation of θ phase in the form of large particles, incapable of further fast dissolution.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 3; 1663-1670
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sucrose uptake and transport are inhibited by okadaic acid during regeneration of the sugar-starved Vicia faba root meristem cells
Autorzy:
Polit, J.T.
Zabka, A.
Powiązania:
https://bibliotekanauki.pl/articles/79845.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
conference
sucrose
transport
okadaic acid
regeneration
Vicia faba
root meristem cell
principal control point
G1 phase
G2 phase
sucrose synthase
hexokinase
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 3
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ocena korozji stali podczas geologicznej sekwestracji dwutlenku węgla
Assessment of steel corrosion during geological carbon sequestration
Autorzy:
Masłowski, Mateusz
Powiązania:
https://bibliotekanauki.pl/articles/31343912.pdf
Data publikacji:
2023
Wydawca:
Instytut Nafty i Gazu - Państwowy Instytut Badawczy
Tematy:
korozja
ocena
stal
dwutlenek węgla
faza nadkrytyczna CO2
sekwestracja dwutlenku węgla
corrosion
steel
assessment
carbon dioxide
CO2 supercritical phase
carbon dioxide sequestration
Opis:
W artykule przedstawiono tematykę związaną z korozją stali podczas geologicznej sekwestracji dwutlenku węgla. Ma to związek z tworzeniem się środowiska korozyjnego w obecności wody w środowisku CO2. Następuje wówczas pogorszenie się właściwości stali w wyniku jej reakcji z otaczającym środowiskiem i przechodzeniem wolnego metalu w związki, co wpływa w znacznym stopniu na bezpieczeństwo pracy urządzeń oraz stan rur stalowych. Opracowaną procedurę symulacji zjawiska korozji, metodykę badań, analiz i oceny korozji zweryfikowano testami laboratoryjnymi. Do testów zastosowano próbki stali L-80 (13Cr) wycięte z rury eksploatacyjnej. Natomiast środowisko korozyjne stanowił wilgotny czysty dwutlenek węgla o zawartości wody destylowanej wynoszącej 5000 ppm. Testy korozji przeprowadzono dla dwóch temperatur (40°C i 80°C) i dwóch ciśnień (8 MPa i 20 MPa), umożliwiających uzyskanie CO2 w fazie nadkrytycznej. Na podstawie wykonanych fotografii powierzchni stali nie stwierdzono widocznej korozji. Po testach korozji powierzchnie kuponów miały nadal charakter metaliczny, błyszczący. Wyznaczone na podstawie ubytku masy wartości szybkości korozji także nie wykazały procesu korozji stali w środowisku zawilgoconego CO2 dla zadanych warunków T i P. Dodatkowo wykonane obrazowanie i analiza powierzchni stali pod mikroskopem optycznym pozwoliły na zaobserwowanie początku tworzenia się korozji ogólnej (równomiernej) i wżerowej (miejscowej). Określono wielkości charakteryzujące wżery (średnią i maksymalną głębokość). Głębokość powstałych wżerów była rzędu od 0,00569 mm do 0,017 mm. Największą głębokość uzyskano w teście 4 (T = 80°C i P = 20 MPa). Na tej podstawie wyznaczono wartości szybkości korozji oraz wykonano dodatkową teoretyczną analizę głębokości korozji po 1 roku, 10, 50 i 100 latach. Pozwoliła ona stwierdzić, że niebezpieczna głębokość wżerów dla stali L-80 (13Cr) pojawi się po okresie 10 lat.
This paper discusses steel corrosion during geological sequestration of carbon dioxide. It is caused by formation of a corrosive environment in the presence of water in the CO2 environment. A deterioration of steel properties is a result of its reaction with the surrounding environment and the transition of free metal into compounds. This has a significant impact on the operational safety of equipment and steel pipes. The developed procedure for simulating the phenomenon of corrosion, the methodology of research, analysis and corrosion assessment were verified by laboratory tests. L80 (13Cr) steel samples cut from a service pipe were used for the tests. The corrosive environment was humid pure carbon dioxide with a content of distilled water of 5000 ppm. Corrosion tests were carried out for two temperatures (40 and 80°C) and two pressures (8 and 20 MPa), enabling CO2 to be obtained in the supercritical phase. No visible corrosion was found on the basis of the photographs of the steel surface. After the corrosion tests, the surfaces of the coupons were still metallic and shiny. The corrosion rate values determined on the basis of mass loss also did not show the corrosion process of steel in an environment moistened with CO2 for the given conditions T and P. Additional imaging and analysis of the corrosion pit surface under the optical microscope made it possible to observe the beginning of the formation of general (uniform) and pitting (local) corrosion. The values characterizing the pits (average and maximum depth) were determined. The depth of the resulting pits ranged from 0.00569 mm to 0.017 mm. The greatest depth was obtained in test 4 (T = 80°C and P = 20 MPa). On their basis, it was suggested to determine the value of the corrosion rate and perform an additional theoretical analysis of the corrosion depth after 1, 10, 50 and 100 years. This would enable the emergence of dangerous depth of pits for steel L-80 (13Cr) after a period of 10 years to be observed.
Źródło:
Nafta-Gaz; 2023, 79, 5; 326-337
0867-8871
Pojawia się w:
Nafta-Gaz
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of the anatase to rutile transformation kinetics of the modified TiO2
Autorzy:
Grzmil, B.
Gleń, M.
Kic, B.
Lubkowski, K.
Powiązania:
https://bibliotekanauki.pl/articles/779360.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
TiO2
anatase
rutile
modification
phase transformation kinetics
Opis:
TiO2 attracts much interest because of its many potential applications. The use of titanium dioxide strongly depends on its polymorphic form: brookite, anatase, or rutile. Only rutile and anatase play an important role in industry. Anatase as a metastable form undergoes a non-reversible transformation into rutile. Understanding the kinetics of phase transformation and the processes of crystal growth of a material is essential for controlling its structure and, thus, its specific properties. The main purpose of this paper is to explain the anatase to rutile recrystallization kinetics in the modified TiO2 calcined from industrial hydrated titanium dioxide. The apparent activation energy of anatase to rutile transformation and the average size of titanium dioxide crystallites were determined for the unmodified TiO2 and TiO2 modified with P, K, Al, B, Zn, Zr, Ce, Sn, or Sb introduced in the amount of 0.5 mol% and 1.0 mol% when recalculated for their oxides. The growth of TiO2 crystallites during calcination was strongly inhibited by P, Ce and Zr, and inhibited to a lesser degree by Al, Sn and Sb. B and Zn did not affect the investigated process and K accelerated crystallites growth. The values of apparent activation energy depending on a modifier formed a relationship: Al
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 2; 73-80
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The phase separation phenomenon in the Na2O–B2O3–SiO2–Fe2O3 glass-forming system and its application for producing porous glasses
Autorzy:
Konon, Marina
Antropova, Tatyana
Polyakova, Irina
Anfimova, Irina
Dikaya, Lidiya
Semenova, Ekaterina
Kurilenko, Ludmila
Powiązania:
https://bibliotekanauki.pl/articles/173829.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
Na2O–B2O3–SiO2–Fe2O3 glass-forming system
phase separation
crystallization
phase separation diagram
chemical durability
magnetite
leaching
porous glass
Opis:
Glasses in the Na2O–B2O3–SiO2–Fe2O3 system with a constant SiO2 content 70 mol% were synthesized using conventional melting in platinum crucibles in SiC-furnace in air. After synthesis and annealing, glasses were heat treated at 550°C for 96–144 hrs to promote phase separation. A tentative region of phase separation for this temperature was outlined. X-ray powder diffractometry results showed three iron-containing phases (Fe3O4, FeSiO3 and β-Fe2O3) forming in the investigated glasses with magnetite being the main phase as it is observed in most of the glasses. Chemical durability studies showed that compositions of phase-separated glasses suitable for synthesis of porous glasses, both iron-free and iron-containing lie in between 4 and 8 mol% of Na2O. Bulk samples of porous glasses were obtained within the chosen region having the following parameters: specific surface area 40–185 m2/g, porosity 30%–45%, pore diameter 3–14 nm. The parameters of porous structure of iron-containing porous glasses are of the same order of magnitude as the porous glass used for the multiferroic nanocomposite synthesis.
Źródło:
Optica Applicata; 2019, 49, 3; 437-444
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
CFD modelling of CO2 capture in a packed bed by chemical absorption
Autorzy:
Asendrych, D.
Niegodajew, P.
Drobniak, S.
Powiązania:
https://bibliotekanauki.pl/articles/185228.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
carbon dioxide
carbon capture and storage (CCS)
2-phase flow
chemical absorption
computational fluid dynamics (CFD)
dwutlenek węgla
wychwytywanie i składowania dwutlenku węgla (CCS)
strumień 2-fazowy
absorpcja chemiczna
dynamika płynów (CFD)
Opis:
The paper deals with numerical modelling of carbon dioxide capture by amine solvent from flue gases in post-combustion technology. A complex flow system including a countercurrent two-phase flow in a porous region, chemical reaction and heat transfer is considered to resolve CO2 absorption. In order to approach the hydrodynamics of the process a two-fluid Eulerian model was applied. At the present stage of model development only the first part of the cycle, i.e. CO2 absorption was included. A series of parametric simulations has shown that carbon dioxide capture efficiency is mostly influenced by the ratio of liquid (aqueous amine solution) to gas (flue gases) mass fluxes. Good consistency of numerical results with experimental data acquired at a small-scale laboratory CO2 capture installation (at the Institute for Chemical Processing of Coal, Zabrze, Poland) has proved the reliability of the model.
Źródło:
Chemical and Process Engineering; 2013, 34, 2; 269-282
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Simulation of Xe redistribution in UO2
Autorzy:
Trujillo, L.
Powiązania:
https://bibliotekanauki.pl/articles/1934014.pdf
Data publikacji:
2011
Wydawca:
Politechnika Gdańska
Tematy:
UO2
grain boundaries
finite element method
phase field model
Opis:
The transport of fission gases in UO2 based nuclear fuels has a significant effect on the fuel performance. They can induce swelling of the fuel by the nucleation of gas bubbles within the fuel, and increase the mechanical interaction between the UO2 pellet and the cladding; also these bubbles can escape through the grain boundaries and contribute to the gaseous atmosphere in the fuel pin. We propose a model for the redistribution of xenon in the presence of different sinks, including nucleation and growth of gas bubbles. The finite element method has been implemented for the numerical solution of the model.
Źródło:
TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk; 2011, 15, 2; 157-190
1428-6394
Pojawia się w:
TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructure Formation of Al-5 mass%Mg Alloy Melts by Interaction with Silica
Autorzy:
Kim, Sun-Ki
Ha, Seong-Ho
Kim, Bong-Hwan
Yoon, Young-Ok
Lim, Hyun-Kyu
Kim, Shae K.
Kim, Yong-Jig
Powiązania:
https://bibliotekanauki.pl/articles/2049152.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Al-Mg system
silica
reduction
Mg2Si
phase diagram
Opis:
Dissolution of Si in Al-5 mass%Mg alloy melt by the reduction of SiO2 and its effect on microstructure formation of the alloy after solidification were investigated. Al-5 mass%Mg alloy without silica powder had approximately 0.05 mass%Si as an impurity. No significant difference in Si content was observed after the reaction with silica for 10 min, while the Si content increased up to about 0.12 mass% after 30 min. From the microstructure analysis and calculation of Scheil-Gulliver cooling, it was considered that as-cast microstructures of Al-5 mass%Mg-1 mass% SiO2 alloys had the distribution of eutectic phase particles, which are comprised of β-Al3Mg2 and Mg2Si phases. Based on the phase diagrams, only limited amount of Mg can be selectively removed by silica depending on the ratio of Si and Mg. Addition of silica of more than approximately 1.5 mass% in Al-5 mass%Mg alloy led to the formation of spinel and removal of both mg and Al from the melt.
Źródło:
Archives of Metallurgy and Materials; 2021, 66, 4; 947-950
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The impact of semester-abroad experiences on post-sojourn L2 motivation
Autorzy:
Du, Xujia
Powiązania:
https://bibliotekanauki.pl/articles/780569.pdf
Data publikacji:
2019
Wydawca:
Uniwersytet im. Adama Mickiewicza w Poznaniu
Tematy:
L2 motivation
L2 learning experience in study abroad
post-sojourn phase
critical reflection
Opis:
Numerous studies have examined sojourners’ L2 motivation during their stay abroad. Much remains unknown about the impact of study abroad (SA) experiences on their L2 motivation after they return to the home environment. This study tracked the English learning motivation of three Chinese university students from immediately after their semester-long exchange program in an English-speaking country until six months after the sojourn. The participants were requested to complete a questionnaire and took part in an interview immediately following their re-entry and another interview six months later. The participants’ post-sojourn English learning motivation was influenced by their L2 selves and the context they were situated in. The motivational capacity of SA experiences was manifested in its profound impact on the participants’ ideal L2 self-images. Satisfactory SA experiences contributed to an ideal L2 self with higher L2 proficiency and international posture, whereas unsatisfactory experiences led to a lessening role of L2 in the participants’ future work and life. The findings also reveal that the participants’ understandings of both their positive and negative SA experiences became fossilized after the sojourn. Some practical implications were discussed for higher education institutions to optimize the post-sojourn motivational impact of SA programs.
Źródło:
Studies in Second Language Learning and Teaching; 2019, 9, 1; 117-155
2083-5205
2084-1965
Pojawia się w:
Studies in Second Language Learning and Teaching
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of the substitution of Ti for Y on structural properties and hyperfine interactions in Y1-xTixFe2 compounds
Autorzy:
Surowiec, Z.
Sarzyński, J.
Budzyński, M.
Wiertel, M.
Powiązania:
https://bibliotekanauki.pl/articles/971534.pdf
Data publikacji:
2004
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
hyperfine interactions
Mössbauer effect
quasibinary Laves phase
Y1 xTixFe2
Opis:
Abstract Room temperature 57Fe Mössbauer spectroscopy and X-ray diffraction measurements are reported for a series of Y1 xTixFe2 polycrystalline samples. Our research shows that except for x = 0 and x = 1, the samples are a mixture of two C15 and C14 pseudobinary Laves phases. Some Ti atoms occupy the crystallographic positions 8a characteristic of the Y atoms in the cubic C15 structure while the rest of them form the hexagonal C14 phase. However, the lattice constant dependencies on concentration x suggest the occurrence of Y atoms in the positions 4f characteristic of Ti atoms in the hexagonal C14 structure. The partial substitution of Ti atoms for Y atoms is responsible for the HMF changes in the cubic phase. Contrary to the situation taking place in the Zr1 xTixFe2 compounds, magnetic arrangement in the pseudobinary hexagonal phases is not observed at room temperature.
Źródło:
Nukleonika; 2004, 49,suppl.3; 17-21
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 38

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