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Wyszukujesz frazę "Partial Least Squares Discriminant Analysis" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Efficiency of linear and non-linear classifiers for gas identification from electrocatalytic gas sensor
Autorzy:
Kalinowski, P.
Woźniak, Ł.
Strzelczyk, A.
Jasinski, P.
Jasinski, G.
Powiązania:
https://bibliotekanauki.pl/articles/221796.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
electrocatalytic sensor
cyclic voltammetry
data pre-processing
support vector machine (SVM)
Partial Least Squares Discriminant Analysis
Opis:
Electrocatalytic gas sensors belong to the family of electrochemical solid state sensors. Their responses are acquired in the form of I-V plots as a result of application of cyclic voltammetry technique. In order to obtain information about the type of measured gas the multivariate data analysis and pattern classification techniques can be employed. However, there is a lack of information in literature about application of such techniques in case of standalone chemical sensors which are able to recognize more than one volatile compound. In this article we present the results of application of these techniques to the determination from a single electrocatalytic gas sensor of single concentrations of nitrogen dioxide, ammonia, sulfur dioxide and hydrogen sulfide. Two types of classifiers were evaluated, i.e. linear Partial Least Squares Discriminant Analysis (PLS-DA) and nonlinear Support Vector Machine (SVM). The efficiency of using PLS-DA and SVM methods are shown on both the raw voltammetric sensor responses and pre-processed responses using normalization and auto-scaling.
Źródło:
Metrology and Measurement Systems; 2013, 20, 3; 501-512
0860-8229
Pojawia się w:
Metrology and Measurement Systems
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Discrimination of Selected Cold-Pressed and Refined Oils by Untargeted Profiling of Phase Transition Curves of Differential Scanning Calorimetry
Autorzy:
Islam, Mahbuba
Magdalena, Montowska
Emilia, Fornal
Jolanta, Tomaszewska-Gras
Powiązania:
https://bibliotekanauki.pl/articles/16538550.pdf
Data publikacji:
2023-08-02
Wydawca:
Instytut Rozrodu Zwierząt i Badań Żywności Polskiej Akademii Nauk w Olsztynie
Tematy:
authentication
plant oils
chemometrics
multivariate data analysis
melting profiles
orthogonal partial least squares-discriminant analysis
differential scanning calorimetry
Opis:
The authenticity assessment of edible oils is crucial to reassure consumers of product compliance. In this study, a new approach was taken to combining untargeted profiling by using differential scanning calorimetry (DSC) with chemometric methods in order to distinguish cold-pressed oils (flaxseed, camelina, hempseed) from refined oils (rapeseed, sunflower, soybean). The whole spectrum of DSC melting profiles was considered as a fingerprint of each oil. Flaxseed and hempseed oils exhibited four endothermic peaks, while three peaks with one exothermic event were detected for camelina seed oil. In the case of refined oils, two endothermic peaks were detected for rapeseed oil, three for sunflower oil and four for soybean oil. Thermodynamic parameters, such as peak temperature, peak heat flow and enthalpy, differed for each type of oil. Principal component analysis (PCA) and orthogonal partial least squares-discriminant analysis (OPLS-DA) were used for processing data consisting of the whole spectrum of heat flow variables of melting phase transition. PCA demonstrated a clear separation between refined and cold-pressed oils as well as six individual oils. The OPLS-DA showed a distinct classification in six classes according to the types of oils. High OPLS-DA coefficients including R2X(cum)=0.971, R2(cum)=0.916 and Q2X(cum)=0.887 indicated good fitness of the model for oil discrimination. Variables influence on projection (VIP) plot indicated the most significant variables of the heat flow values detected at temperatures around −29°C, −32°C, −14°C, −10°C, −24°C and −41°C for the differentiation of oils. The study ultimately demonstrated great potential of the untargeted approach of using the whole melting DSC profile with chemometrics for the discrimination of cold-pressed and refined oils.
Źródło:
Polish Journal of Food and Nutrition Sciences; 2023, 73, 3; 224-232
1230-0322
2083-6007
Pojawia się w:
Polish Journal of Food and Nutrition Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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