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Tytuł:
Characterization of granites by 57Fe Mössbauer spectroscopy
Autorzy:
Hassan, K. M.
Powiązania:
https://bibliotekanauki.pl/articles/2086557.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
granitic type
clinopyroxene
mica
amphibole
Mössbauer spectroscopy
oxygen fugacity
Western Desert
Opis:
Two granite complexes in Egypt, a sodic type and an aluminous type are characterized by Mössbauer spectroscopy. Mössbauer spectra (MS) of the sodic granite show a major doublet of ferric (Fe3+) iron that is attributable to octahedral coordination (M1) sites plus/minus a tetrahedron Fe3+ doublet plus/minus a doublet of ferrous (Fe2+) iron on the M1 sites plus/ minus another Fe2+ (M1) doublet and a sextet of Fe3+. The sextet is attributed to -Fe2O3 (hematite) and the other Fe components are due to NaCaFeSi2O6 (aegirine-augite) plus/minus minor contributions from (Ca2(Mg,Fe)5(Si,Al)8O22(OH)2 (magnesium-hornblende). Changes in the quadrupole splitting and width line of Fe2+ ions are likely composition-related. The MS of the aluminous-type granite, on the other hand, shows evidence only of single doublets containing Fe2+ or Fe3+ in the octahedral M1 sites, with parameters that remain almost constant. This consistency implies that the existing minerals – K(Mg,Fe2+)3 (Al,Fe3+)Si3O10(OH,F)2 (biotite), (Mg,Fe)6(Si,Al)4O10(OH)8 (clinochlore), (Na,K)Ca2(Fe,Mg)5(Al,Si)8O22(OH)2 (ferrohornblende and magnesiohornblende) – have similar iron positions. The intensity of iron oxidized (Fe3+/Fe) for the sodic granite is 79.1 to 100% and for the aluminous granite, 28.4 to 38.2%. The observed Fe3+/Fe differences between the two granites are source- -related and consistent with distributions of other redox-sensitive elements.
Źródło:
Mineralogia; 2009, 40, 1/4; 95--106
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization of granites by 57Fe Mössbauer spectroscopy
Autorzy:
Hassan, Kamaleldin M.
Powiązania:
https://bibliotekanauki.pl/articles/2086511.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
granitic type
clinopyroxene
mica
amphibole
Mössbauer spectroscopy
oxygen fugacity
Western Desert
Opis:
Two granite complexes in Egypt, a sodic type and an aluminous type are characterized by Mössbauer spectroscopy. Mössbauer spectra (MS) of the sodic granite show a major doublet of ferric (Fe3+) iron that is attributable to octahedral coordination (M1) sites plus/minus a tetrahedron Fe3+ doublet plus/minus a doublet of ferrous (Fe2+) iron on the M1 sites plus/ minus another Fe2+ (M1) doublet and a sextet of Fe3+. The sextet is attributed to -Fe2O3 (hematite) and the other Fe components are due to NaCaFeSi2O6 (aegirine-augite) plus/minus minor contributions from (Ca2(Mg,Fe)5(Si,Al)8O22(OH)2 (magnesium-hornblende). Changes in the quadrupole splitting and width line of Fe2+ ions are likely composition-related. The MS of the aluminous-type granite, on the other hand, shows evidence only of single doublets containing Fe2+ or Fe3+ in the octahedral M1 sites, with parameters that remain almost constant. This consistency implies that the existing minerals – K(Mg,Fe2+)3 (Al,Fe3+)Si3O10(OH,F)2 (biotite), (Mg,Fe)6(Si,Al)4O10(OH)8 (clinochlore), (Na,K)Ca2(Fe,Mg)5(Al,Si)8O22(OH)2 (ferrohornblende and magnesiohornblende) – have similar iron positions. The intensity of iron oxidized (Fe3+/Fe) for the sodic granite is 79.1 to 100% and for the aluminous granite, 28.4 to 38.2%. The observed Fe3+/Fe differences between the two granites are source- -related and consistent with distributions of other redox-sensitive elements.
Źródło:
Mineralogia; 2009, 40, 1/4; 95--106
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Deformation structures in the gneissic exotic pebbles from the area of Wołosate (Cisna sandstone, Dukla tectonic unit, Outer Carpathians, Poland)
Autorzy:
Kania, M.
Wolska, A.
Powiązania:
https://bibliotekanauki.pl/articles/191901.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
gneissic exotic pebbles
foliation
metamorphism
mica fish
Bieszczady Mts.
Outer Carpathians
Polska
Opis:
Gneissic exotic pebbles from the Cisna beds (Dukla tectonic unit) in the region of Wołosate (Bieszczady Mts., Eastern Carpathians) were investigated. These exotic pebbles are from 9.5 to 13 cm in size. Basing on the structural features, the following groups of exotic pebbles were distinguished: granitic gneisses, laminated gneisses, flaser gneisses and mylonitic gneisses. Granite - granodiorite protolith was deformed in the shear zone; strain partitioning was probably an important process during deformation. The observed structures allow to determine the temperature of metamorphism as 500-550°C. The lower limit of pressure was determined basing on phengite geobarometer as 5 kbar. The nature and localization of the source area can be similar to the Bretila sequence from the Romanian Eastern Carpathians.
Źródło:
Annales Societatis Geologorum Poloniae; 2009, 79, No 1; 41-52
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Deformation structures in the gneissic exotic pebbles from the area of Wołosate (Cisna sandstone, Dukla tectonic unit, Outer Carpathians, Poland)
Autorzy:
Kania, M.
Wolska, A.
Powiązania:
https://bibliotekanauki.pl/articles/191383.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
gneissic exotic pebbles
foliation
metamorphism
mica fish
Bieszczady Mts.
Outer Carpathians
Polska
Opis:
Gneissic exotic pebbles from the Cisna beds (Dukla tectonic unit) in the region of Wołosate (Biesz- czady Mts., Eastern Carpathians) were investigated. These exotic pebbles are from 9.5 to 13 cm in size. Basing on the structural features, the following groups of exotic pebbles were distinguished: granitic gneisses, laminated gneisses, flaser gneisses and mylonitic gneisses. Granite - granodiorite protolith was deformed in the shear zone; strain partitioning was probably an important process during deformation. The observed structures allow to determine the temperature of metamorphism as 500-550°C. The lower limit of pressure was determined basing on phengite geobarometer as 5 kbar. The nature and localization of the source area can be similar to the Bretila sequence from the Romanian Eastern Carpathians.
Źródło:
Annales Societatis Geologorum Poloniae; 2009, 79, No 2; 41-52
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Detection of fibrinogen monolayers on mica by the colloid enhancement
Autorzy:
Nattich-Rak, M.
Adamczyk, Z.
Wasilewska, M.
Radziszewska, M.
Powiązania:
https://bibliotekanauki.pl/articles/363140.pdf
Data publikacji:
2011
Wydawca:
Uniwersytet Warmińsko-Mazurski w Olsztynie
Tematy:
adsorpcja lateksu
fibrynogen
koloidalne wzmocnienie warstw białkowych
monowarstwy fibrynogenu na mikach
adsorpcja nieodwracalna
cząstki koloidalne
adsorption of latex
fibrinogen
colloid enhancement of protein layers
fibrinogen monolayers by mica
irreversible adsorption
colloid particles
Opis:
Physicochemical properties of bovine plasma fibrinogen (Fb) in electrolyte solutions were characterised, comprising the diffusion coefficient (hydrodynamic radius), electrophoretic mobility (zeta potential) and the isoelectric point, found to be at pH=5.8. Similar electrokinetic measurements were performed for the mica substrate using the streaming potential cell. The kinetics of Fb adsorption on mica under diffusion-controlled transport was also studied. The surface concentration of Fb on mica was determined directly by AFM counting. By adjusting the time of adsorption, and bulk Fb concentration, monolayers of desired coverage were produced. It was confirmed that Fb adsorbed irreversibly on mica both at pH=3.5 and pH=7.4 (physiological value). It was postulated that in the latter case, where both the substrate and fibrinogen molecules were negatively charged, adsorption was due to heterogeneous charge distribution over the protein molecule. In order to check this hypothesis, monolayers of Fb on mica were studied using the colloid enhancement (CE) method, in which negatively and positively charged latex particles were used. Results of these experiments were quantitatively interpreted in terms of the fluctuation theory assuming that adsorption sites consisted of two and three Fb molecules, for pH=3.5 and 7.4, respectively. This allowed one to determine limits of applicability of the classical DLVO theory and confirm a heterogeneous charge distribution over the Fb molecule. It was also concluded that the CE method can be used for a sensitive determination of the Fb bulk concentration for the range inaccessible for other methods, i.e., for 0.1ppm and below. Another effect of vital significance confirmed in this work was that for some range of fibrinogen coverage both the negative and positive latexes efficiently adsorbed. This indicates the formation of superadsorbing surfaces having potential significance for various filtration processes.
Źródło:
Environmental Biotechnology; 2011, 7, 1; 1-11
1734-4964
Pojawia się w:
Environmental Biotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fast and unique Tucker decompositions via multiway blind source separation
Autorzy:
Zhou, G.
Cichocki, A.
Powiązania:
https://bibliotekanauki.pl/articles/201572.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Multiway Blind Source Separation (MBSS)
Multilinear Independent Component Analysis (MICA)
Constrained tensor decompositions
Tucker models
Nonnegative Tucker Decomposition (NTD)
Opis:
A multiway blind source separation (MBSS) method is developed to decompose large-scale tensor (multiway array) data. Benefitting from all kinds of well-established constrained low-rank matrix factorization methods, MBSS is quite flexible and able to extract unique and interpretable components with physical meaning. The multilinear structure of Tucker and the essential uniqueness of BSS methods allow MBSS to estimate each component matrix separately from an unfolding matrix in each mode. Consequently, alternating least squares (ALS) iterations, which are considered as the workhorse for tensor decompositions, can be avoided and various robust and efficient dimensionality reduction methods can be easily incorporated to pre-process the data, which makes MBSS extremely fast, especially for large-scale problems. Identification and uniqueness conditions are also discussed. Two practical issues dimensionality reduction and estimation of number of components are also addressed based on sparse and random fibers sampling. Extensive simulations confirmed the validity, flexibility, and high efficiency of the proposed method. We also demonstrated by simulations that the MBSS approach can successfully extract desired components while most existing algorithms may fail for ill-conditioned and large-scale problems.
Źródło:
Bulletin of the Polish Academy of Sciences. Technical Sciences; 2012, 60, 3; 389-405
0239-7528
Pojawia się w:
Bulletin of the Polish Academy of Sciences. Technical Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation of quartz flotation from decarburized vanadium bearing coal
Autorzy:
Ren, L.
Zhang, Y.
Bian, Y.
Liu, X.
Liu, C.
Powiązania:
https://bibliotekanauki.pl/articles/110937.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
mica
vanadium-bearing coal
flotation
quartz
ion dissolution
calcium ion
Opis:
Ether diamine (Fm 2835-2L) was used as a collector for flotation of quartz. It allows flotation of quartz from mica and calcite. The adsorption mechanism of Fm 2835-2L on quartz was investigated by flotation tests, zeta-potential measurements and infra-red (FTIR) spectra measurements. Results show that Fm 2835-2L adsorbs on the quartz surface in physical adsorption with no new products, changing its zeta potentials, and increasing its hydrophobicity. The effect of calcium ions on flotation of quartz was investigated by flotation tests and zeta-potential measurements. Results show that under neutral or weakly acidic conditions calcium cation can adsorb onto the surfaces of quartz, increase the zeta potential of quartz particles, which in turn causes weaker aggregation of quartz particles and lower flotation recovery of quartz. Under the alkaline conditions the hydrolytic components of calcium are also adsorbed on the quartz surface and increase the zeta potential of quartz particles, which causes stronger aggregation of quartz particles and higher flotation recovery of quartz. However, the hydrolytic components such as CaOH+, Ca(OH)2(aq) and Ca(OH)2(s) were not formed in significant amounts in the best flotation tests.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 2; 755-767
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Badania możliwości otrzymywania lakierów metalizujących na bazie żywic utwardzanych promieniami UV
Obtaining metal effect varnish based on UV cured resins
Autorzy:
Synowiec, B.
Gebel, R.
Karaś, A.
Powiązania:
https://bibliotekanauki.pl/articles/392384.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Ceramiki i Materiałów Budowlanych
Tematy:
lakier
efekt metaliczny
podłoże szklane
podłoże ceramiczne
żywica akrylowa
utwardzanie UV
pigment na bazie miki
właściwości powłok
varnish
metallic effect
glass substrate
ceramic substrate
acrylic resin
UV curing
mica based pigment
coating properties
Opis:
W trakcie realizacji tematu wytypowano medium błonotwórcze firmy Ferro, zdolne do wytwarzania trwałej powłoki po naświetlaniu promieniami UV, oraz pigmenty firmy Merck, umożliwiające uzyskanie powierzchni metalizujących. Doświadczalnie ustalono ilości medium i pigmentu niezbędnego do uzyskania lakieru o reologii zapewniającej jego drukowość. Lakiery, naniesione metodą sitodruku bezpośredniego na płytce szklanej i szkliwionej płytce ceramicznej, naświetlano promieniami UV w celu utwardzenia powierzchni, określając czas niezbędny do utwardzenia powłoki lakieru. Wydrukowane i utwardzone powierzchnie lakieru poddano ocenie wizualnej pod kątem jednorodności powierzchni, gładkości, siły krycia i efektu metalizującego. Wykonano badania odporności chemicznej i twardości utrwalonej powłoki oraz badania starzeniowe nieutwardzonych lakierów.
For the purpose of the research we selected a medium by Ferro able to form durable coatings after UV curing, and Merck pigments giving metal effect to surfaces. By means of experiments the correct amounts/of the medium and the pigments, required to obtain varnish with rheological properties ensuring its printability. After screen printing onto a glass plate or a glazed ceramic tile the varnishes were exposed to UV rays in order to harden the surface thus establishing the time necessary to harden the varnish coating. Next the printed and hardened surfaces were examined visually with regard to their surface homogeneity, smoothness, hiding power and metal effect quality. Aging tests and chemical resistance tests of the UV cured surfaces were also carried out.
Źródło:
Prace Instytutu Ceramiki i Materiałów Budowlanych; 2016, R. 9, nr 25, 25; 53-62
1899-3230
Pojawia się w:
Prace Instytutu Ceramiki i Materiałów Budowlanych
Dostawca treści:
Biblioteka Nauki
Artykuł

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