- Tytuł:
- Greener synthesis and Hammett spectral Linearity’s of some 1-{[3-(furan-2-yl)-5-phenyl-4,5-dihydro-1,2-oxazol-4-yl]methyl}-4-methyl piperazines
- Autorzy:
-
Thirunarayanan, G.
Rajarajan, M.
Sekar, K. G.
Sathiyendiran, V. - Powiązania:
- https://bibliotekanauki.pl/articles/1179600.pdf
- Data publikacji:
- 2017
- Wydawca:
- Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
- Tematy:
-
Hammett equation and Regression analyses
Hammett substituent constants
IR and NMR spectra
Piperazines - Opis:
- We have synthesized eleven numbers of 1-{[3-(furan-2-yl)-5-phenyl-4,5-dihydro-1,2-oxazol-4-yl]methyl}-4-methyl piperazines by hydroxyapatite catalyzed microwave assisted condensation method. The synthesized 1-{[3-(furan-2-yl)-5-phenyl-4,5-dihydro-1,2-oxazol-4-yl]methyl}-4-methyl piperazine compounds were characterized by means of their IR and NMR spectral data. The assigned infrared spectral νC=N, νC-O-C stretches(cm-1), NMR chemical shifts of isoxazoline (d) proton, isoxazoline (m) proton, N-CH3, C=N, C-NH2 and C-NH3 (δ, ppm) of these 1-{[3-(furan-2-yl)-5-phenyl-4,5-dihydro-1,2-oxazol-4-yl]methyl}-4-methyl piperazines were assigned and correlated with Hammett substituent constants, F and R parameters using single and multi linear regression analysis. From the results of statistical analyses, the effects of substituents on the above group frequencies were discussed.
- Źródło:
-
World Scientific News; 2017, 74; 164-180
2392-2192 - Pojawia się w:
- World Scientific News
- Dostawca treści:
- Biblioteka Nauki
Artykuł