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Wyświetlanie 1-15 z 29
Tytuł:
A non-singular description of parametrical resonance
Autorzy:
Romanów, F.
Hańćkowiak, J.
Powiązania:
https://bibliotekanauki.pl/articles/279246.pdf
Data publikacji:
2000
Wydawca:
Polskie Towarzystwo Mechaniki Teoretycznej i Stosowanej
Tematy:
stability
infinite chain of equations
truncation
Gibbs phenomenon
Opis:
Employing the Mathieu equations we present a method for construction of Ince-Strutt diagrams, in which no cut-off of the infinite chain of equations for Fourier coefficients is necessary.
Niesingularny opis rezonansu parametrycznego. Na przykładzie równania Mathieu przedstawiamy niesingularną metodę konstrukcji diagramów Incea-Strutta, które obrazują na płaszczyźnie F parametrów równania obszary stabilności i niestabilności. Niesingularność metody została osiągnięta dzięki nie obrywaniu nieskończonych łańcuchów równań dla współczynników Fouriera. Pozwala to na zachowanie pierwotnego charakteru rozważanych równań (zagadnienie początkowe). Przedstawione rozważania sugerują poszerzenie oszarów niestabilności.
Źródło:
Journal of Theoretical and Applied Mechanics; 2000, 38, 4; 879-892
1429-2955
Pojawia się w:
Journal of Theoretical and Applied Mechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Arrheniusan activation energy of separation for different parameters regulating the process
Autorzy:
Drzymała, J.
Powiązania:
https://bibliotekanauki.pl/articles/109713.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation
activation energy
separation
Gibbs potential
Arrhenius plot
Opis:
The Arrhenius model, that relates the activation energy with the kinetic constant and process temperature, was applied for flotation as a separation process, and next was extended to other incentive parameters such as the frother concentration, NaCl content and hydrophobicity. It was shown that determination of the activation energy caused by other incentive parameters (i.e. particle size, surface potential) was also possible. The units of the activation energy depend on the type of the separation process and incentive parameter. For contact angle regulating flotation the activation energy unit is mJ/m2, while for the frother concentration is J. It is known that instead in joules, the activation energy can also be expressed in J/mol and in kT or RT units, where k is the Boltzmann constant, R gas constant and T is absolute temperature in kelvins. Even though different formulas of the specific Gibbs potential were used for calculation of activation energy caused by various incentive parameters, there was generally a good agreement between the extend of changes of the first order kinetic constants of the process and activation energy value. It was found that for flotation of copper-bearing carbonaceous shale the activation energy was equal to 1.1 kT for NaCl as the incentive parameter, 3.0 kT for temperature and 32.7 kT for butyl diethylglycol ether used as a flotation frother. For methylated quartz the hydrophobicity-induced activation energy was 42 mJ/m2 for contact angle as the incentive parameter.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 4; 1152-1158
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A procedure of Arrhenius activation energy determination for salt flotation of particles in the vicinity of one molar salt aqueous solutions
Autorzy:
Ratajczak, Tomasz
Kurkiewicz, Szymon
Drzymala, Jan
Powiązania:
https://bibliotekanauki.pl/articles/1450643.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
activation energy
salt flotation
Arrhenius equation
Gibbs potential
Opis:
A modified Arrhenius equation, in which thermal energy is replaced with chemical (Gibbs) potential, and a special calculation procedure were used to evaluate the flotation activation energy for salt solutions in the one molar range of concentrations. The proposed formula overcomes the difficulties of calculating the salt flotation activation energy caused by mathematical problems of finding 1/(ln($c$/$c_o$)) for the standard salt concentration $C_o$ =1 M (1 kmol/m3 and when the applied salt concentration c is in the vicinity of 1 M. The salt flotation activation energy was calculated for flotation of copper-bearing carbonaceous shale in the 0.25, 0.50, 1.00 and 2.00 M NaCl solutions performed in a laboratory machine as equal to 1.9 RT for standard salt solution equal to 1 M.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 6; 1-5
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of single gene multitrait effects in livestock by the use of Gibbs sampling
Autorzy:
Dobek, A
Molinski, K.
Szydlowski, M.
Szwaczkowski, T.
Powiązania:
https://bibliotekanauki.pl/articles/2042024.pdf
Data publikacji:
2000
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
gene
gene frequency
major gene
livestock
Gibbs sampling
Źródło:
Journal of Applied Genetics; 2000, 41, 4; 275-283
1234-1983
Pojawia się w:
Journal of Applied Genetics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanism and Synthesis of Yttrium Iron (Y-Fe) Alloy by Low Temperature Process Using Calcium as Reductant
Autorzy:
Ilayaraja, Marimuthu
Berchmans, L. John
Sankaranarayan, Sankara Raman
Powiązania:
https://bibliotekanauki.pl/articles/355144.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Gibbs free energy
reaction kinetics
VSM
XRD
SEM
Opis:
In this paper, study the preparation of Y-Fe alloy by reduction-diffusion process, which is novel technique for producing an alloy from its ores directly at different temperatures. From this work, investigates the particles size and morphology structure of alloy by X-Ray Diffraction (XRD), Energy dispersive-X-ray analyzer (EDAX) and Scanning Electron Microscope (SEM) respectively. Here study the thermodynamics of property of system such as Gibbs free energy and reaction kinetics of system respectively. The Vibrating Sample magnetometer (VSM) is used to study the magnetic properties of alloy such as cocerviety, saturation magnetization and retentivity.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 4; 1593-1596
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Solubility of butylated hydroxytoluene (BHT) in aqueous and alcohol sulutions from 293.15 to 313.15 K
Autorzy:
Baluja, S.
Bhesaniya, K.
Bhalodia, R.
Chanda, S.
Powiązania:
https://bibliotekanauki.pl/articles/412163.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
butylated hydroxytoluene (BHT)
average deviation
relative deviation
gibbs energy
Opis:
The solubility of Butylated hydroxyl toluene in aqueous and alcohol solutions were determined at different temperatures (293.15 to 313.15) K. Using Van’t Hoff and Gibb’s equations, some thermodynamic functions such as Gibbs energy, enthalpy and entropy of dissolution, and of mixing of Butylated hydroxyl toluene in aqueous and alcohol solutions, were evaluated from solubility data. The solubility was greater in butanol and minimum in water. The enthalpies, entropy and Gibb’s energy of dissolution were positive for all solvents.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 9; 48-58
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of oxygen binding by hemoglobin on the basis of mean intrinsic thermodynamic quantities
Autorzy:
Bordbar, Abdol-Khalegh
Mousavi, Sayed
Dazhampanah, Hamid
Powiązania:
https://bibliotekanauki.pl/articles/1041216.pdf
Data publikacji:
2006
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
cooperativity
mean intrinsic Gibbs free energy
linkage phenomena
hemoglobin
Opis:
The binding data for oxygenation of human hemoglobin, Hb, at various temperatures and in the absence and presence of 2,3-diphosphoglycerate, DPG, and inositol hexakis phosphate, IHP, were analyzed for extraction of mean intrinsic Gibbs free energy, ΔGo, enthalpy, ΔHo, and entropy, ΔSo, of binding at various partial oxygen pressures. This method of analysis considers all the protein species present such as dimer and tetramer forms which were not considered by Imai et al. (Imai K et al., 1970, Biochim Biophys Acta 200: 189 - 196) , in their analysis which was based on Adair equation. In this regard, the values of Hill equation parameters were estimated with high precision at all points of the binding curve and used for calculation of ΔGo, ΔHo and ΔSo were also calculated by analysis of ΔGo values at various temperatures using van't Hoff equation. The results represent the enthalpic nature of the cooperativity in Hb oxygenation and the compensation effect of intrinsic entropy. The interpretation of results also to be, into account the decrease of the binding affinity of sites for oxygen in the presence of DPG and IHP without any considerable changes in the site - site interaction (extent of cooperativity). In other words, the interactions between bound ligands, organic phosphates and oxygen, are more due to a decreasing binding affinity and not to the reduction of the cooperative interaction between sites. The results also document the more heterotropic effect of IHP compared to DPG.
Źródło:
Acta Biochimica Polonica; 2006, 53, 3; 563-568
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Bayesian Inference for State Space Model with Panel Data
Autorzy:
Pandey, Ranjita
Chaturvedi, Anoop
Powiązania:
https://bibliotekanauki.pl/articles/466044.pdf
Data publikacji:
2016
Wydawca:
Główny Urząd Statystyczny
Tematy:
Bayesian analysis
Gibbs sampler
conditional posterior densities
predictive distribution
Opis:
The present work explores panel data set-up in a Bayesian state space model. The conditional posterior densities of parameters are utilized to determine the marginal posterior densities using the Gibbs sampler. An efficient one step ahead predictive density mechanism is developed to further the state of art in prediction-based decision making.
Źródło:
Statistics in Transition new series; 2016, 17, 2; 211-220
1234-7655
Pojawia się w:
Statistics in Transition new series
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A fundamental study of monovalent and divalent ions on froth properties in the presence of terpenic oil
Autorzy:
Li, Yubiao
Wang, Hongduo
Li, Wanqing
Song, Shaoxian
Powiązania:
https://bibliotekanauki.pl/articles/110301.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
surface tension
froth stability
dynamic foamability index
Gibbs adsorption isotherm
Opis:
In order to minimize fresh water usage, much attention has been paid to the flotation using saline or sea water. However, the effects of various ions in these waters on froth properties in flotation are not fully understood. In this study, the effects of electrolyte solutions containing NaCl, KCl, CaCl2, and MgCl2 at different concentrations in the presence of terpenic oil as a frother were investigated on froth performance, dynamic froth stability (DFS). It was found that KCl had the best synergistic effects with terpenic oil in reducing the solution surface tension. In the presence of terpenic oil, the DFS and half-life time were reduced with the increased ion concentration. Dynamics foamability index measurements (DFI) confirmed that the increased ion concentration increased the foamability, as frother did. In addition, Gibbs adsorption isotherm suggested that the amount of terpenic oil adsorbed at the gas-liquid interface was increased with the increased ion concentration. This study therefore indicated that the presence of ions can reduce the froth stability but not decline foamability due to terpenic oil, enlighting the application of saline or sea water in defoaming process in flotation.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 3; 643-654
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Innovative Method of Forecasting the Generator Gas Composition after the Process of Pyrolysis and Gasification
Autorzy:
Slowak, Anna Maria
Powiązania:
https://bibliotekanauki.pl/articles/2174900.pdf
Data publikacji:
2022
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
gasification
pyrolysis
biomass
regenerative energy
synthetic gas
mathematical modeling
Gibbs energy
Opis:
The article presents a new approach to forecasting producer gas composition. Thermochemical treatment of biomass was presented as an effective method of producing flammable gas. The methods of predicting the gas composition of the generator are described, and then its efficiency depends on the device’s parameters. In order to create a method for forecasting gas composition, the authors’ works were used as the basis on which the energy characteristics of the gases obtained were assessed. It was assumed in this paper that it is essential to understand the influence of each parameter on the energy characteristics of the gas. It made it possible to optimize the composition and predict thermal characteristics. This article presents the results of experimental studies on biomass gasification and a mathematical model based on Gibbs free energy.
Źródło:
Rocznik Ochrona Środowiska; 2022, 24; 97--109
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A Bayesian significance test of change for correlated observations
Autorzy:
Slama, Abdeldjalil
Powiązania:
https://bibliotekanauki.pl/articles/729738.pdf
Data publikacji:
2014
Wydawca:
Uniwersytet Zielonogórski. Wydział Matematyki, Informatyki i Ekonometrii
Tematy:
autoregressive model
change point
HPD region sets
p-value
Gibbs sampler
Opis:
This paper presents a Bayesian significance test for a change in mean when observations are not independent. Using a noninformative prior, a unconditional test based on the highest posterior density credible set is determined. From a Gibbs sampler simulation study the effect of correlation on the performance of the Bayesian significance test derived under the assumption of no correlation is examined. This paper is a generalization of earlier studies by KIM (1991) to not independent observations.
Źródło:
Discussiones Mathematicae Probability and Statistics; 2014, 34, 1-2; 51-62
1509-9423
Pojawia się w:
Discussiones Mathematicae Probability and Statistics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of the Mining Industry Wastes as Raw Material for Melting of the Complex Fesial Ferroalloys
Autorzy:
Machulec, B.
Bialik, W.
Gil, S.
Powiązania:
https://bibliotekanauki.pl/articles/355998.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
FeSiAl
FeSi75
model
submerged arc furnace
Gibbs energy minimization method
Opis:
An economical alternative for the steel industry which uses a separate ferrosilicon and aluminum for the deoxidization of steel is a complex deoxidizer in the form of FeSiAl alloys. The effectiveness of complex deoxidizers is higher and they have a positive effect on quality improvement and also for mechanical properties of the finished steel. It is associated with a smaller number of non-metallic inclusions and a more favorable its distribution in the structure of steel. Noteworthy are the waste from the mining industry simultaneously contains SiO2 and Al2 O3 oxides with a few of dopants in the form of CaO, MgO, FeO, TiO2 oxides. These wastes are present in large quantities and can be a cheap raw material for obtaining complex FeSiAl ferroalloys by an electrothermal method. “Poor” hard coal grades which so far did not apply as a reducing agent in the ferroalloy industry because of the high ash content can also be a raw material for the electrothermal FeSiAl process. The electrothermal FeSiAl melting process is similar to the ferrosilicon process in the submerged arc furnace. For this reason, a model based on Gibbs’ free enthalpy minimization algorithm was used to analyze the simultaneous reduction of SiO2 and Al2 O3 oxides, which was originally elaborated for the ferrosilicon smelting process. This is a system of two closed reactors: the upper one with the lower temperature and the lower one with the higher temperature. Between the reaction system and the environment, and between the reactors inside the system, there is a cyclical mass transfer in moments when the state of equilibrium is reached in the reactors. Based on the model, the basic parameters of the electrothermal reduction process of SiO2 and Al2 O3 oxides were determined and a comparative analysis was made towards the ferrosilicon process.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 2; 975-979
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chalcones: A Solubility study at different temperatures
Autorzy:
Bhalu, A. A.
Bhesaniya, K. D.
Vekariya, N. J.
Baluja, S. H.
Powiązania:
https://bibliotekanauki.pl/articles/412118.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Chloroform
dichloromethane
thermodynamic parameters
dissolution enthalpy
Gibb’s energy and en tropy
Opis:
Some new chalcones are synthesized by the condensation of aryl ketones with aromatic aldehydes and solubility of these synthesized chalcones is determined in chloroform and dichloromethane at temperatures ranging between 293.15 K and 313.15 K by gravimetric method. The experimental data was correlated well with modified Apelblat equation. Further, from the experimental solubility data, some thermodynamic parameters such as dissolution enthalpy, Gibb’s energy and entropy etc. were evaluated using van’t Hoff equation. The positive Gibb’s energy and negative entropy suggests spontaneous dissolution and more ordered structure in solution.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 12; 7-19
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Canonical distributions and phase transitions
Autorzy:
Athreya, K
Smith, J
Powiązania:
https://bibliotekanauki.pl/articles/729916.pdf
Data publikacji:
2000
Wydawca:
Uniwersytet Zielonogórski. Wydział Matematyki, Informatyki i Ekonometrii
Tematy:
canonical distribution
canonical ensemble
Gibbs state
phase transition
entropy maximization
Rényi entropy
Opis:
Entropy maximization subject to known expected values is extended to the case where the random variables involved may take on positive infinite values. As a result, an arbitrary probability distribution on a finite set may be realized as a canonical distribution. The Rényi entropy of the distribution arises as a natural by-product of this realization. Starting with the uniform distributionon a proper subset of a set, the canonical distribution of equilibriumstatistical mechanics may be used to exhibit an elementary phase transition, characterized by discontinuity of the partition function.
Źródło:
Discussiones Mathematicae Probability and Statistics; 2000, 20, 2; 167-176
1509-9423
Pojawia się w:
Discussiones Mathematicae Probability and Statistics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Bayesian Analysis for Hybrid MSF-SBEKK Models of Multivariate Volatility
Autorzy:
Osiewalski, Jacek
Pajor, Anna
Powiązania:
https://bibliotekanauki.pl/articles/483307.pdf
Data publikacji:
2009
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Bayesian econometrics
Gibbs sampling
time-varying volatility
multivariate GARCH processes
multivariate SV processes
Opis:
The aim of this paper is to examine the empirical usefulness of two new MSF - Scalar BEKK(1,1) models of n-variate volatility. These models formally belong to the MSV class, but in fact are some hybrids of the simplest MGARCH and MSV specifications. Such hybrid structures have been proposed as feasible (yet non-trivial) tools for analyzing highly dimensional financial data (large n). This research shows Bayesian model comparison for two data sets with n = 2, since in bivariate cases we can obtain Bayes factors against many (even unparsimonious) MGARCH and MSV specifications. Also, for bivariate data, approximate posterior results (based on preliminary estimates of nuisance matrix parameters) are compared to the exact ones in both MSF-SBEKK models. Finally, approximate results are obtained for a large set of returns on equities (n = 34).
Źródło:
Central European Journal of Economic Modelling and Econometrics; 2009, 1, 2; 179-202
2080-0886
2080-119X
Pojawia się w:
Central European Journal of Economic Modelling and Econometrics
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 29

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