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Tytuł:
‘Aegean’ – kolisty obszar w południowej Europie – jego geologia a największe kratery na Ziemi
’Aegean’ – a circular structure in southern Europe – its geology versus the largest craters on Earth
Autorzy:
Walesiak, Tomasz
Powiązania:
https://bibliotekanauki.pl/articles/30146482.pdf
Data publikacji:
2024-04
Wydawca:
Polskie Towarzystwo Meteorytowe
Tematy:
impact structures
multi-ring
central uplift
gravity anomaly
Fe-Ni ore
mantle deformation
pseudotachylite
mass extinction
Opis:
Analysis of online available references suggests that circular characteristics observed around Aegean Sea in southern Europe may represent protobasin class of impact craters, which small central peak and surrounded peak ring appear to be formed by the Cyclades. Thinner crust, upper mantle deformation (uplift), recognition of basin in upper mantle re-filled with rocks having lower density than surrounding mantle, central Aegean Sea area free of sediments and almost perfect circular anomaly of density with diameter over 500 km are only few arguments which may indicate its real origin. The strongest fact standing for hypothesis of impact is presence of deep, lithospheric fracture zones with both circular and radial character, detected up to the distance of ~516 km from common geometric point of all rings (providing estimated diameter of the largest circle over 1000 km). Existence of pseudotachylite veins and breccias in central Cyclades are contributory evidence. Mélange covered by Fe-Ni rich ores in Jurassic/Cretaceous boundary, if related to impact, may give clue to explanation of localized in Europe Tithonian mass extinction event 145 Ma. However, pseudotachylites and breccias can be produced by endogenic processes (e.g., plate tectonics). A further research is required to find evidence of passage of shock wave through target rocks.
Źródło:
Acta Societatis Metheoriticae Polonorum; 2024, 15; 154-177
2080-5497
Pojawia się w:
Acta Societatis Metheoriticae Polonorum
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Abrasive wear resistance of Fe3Al and Satellite 6 coatings for the protection of valve seats surfaces
Autorzy:
Szczucka-Lasota, Bożena
Tarasiuk, Wojciech
Cybulko, Piotr
Węgrzyn, Tomasz
Powiązania:
https://bibliotekanauki.pl/articles/27311342.pdf
Data publikacji:
2023
Wydawca:
Politechnika Śląska. Wydawnictwo Politechniki Śląskiej
Tematy:
valve seat
abrasive wear
intermetal Fe3Al
Stellite 6
gniazdo zaworu
zużycie ścierne
Opis:
The development of a technology that increases the service life of valve seats in CNG/LNG-powered vehicles requires the appropriate selection of material and the technology of its application. Commercially used valve seat materials show accelerated wear under operating conditions, especially in natural gas vehicle engines. The authors developed a new material concept and a new technological concept for the protection of the valve seat in CNG/LNG-powered vehicles. This article aims to present the first stage of tribological research. Two materials were used in the research: Stellite 6 alloy and Fe3Al intermetal. A commonly used material for valve seats of combustion engines is Stellite 6. The Fe3Al is the new proposed material coating for the protection of the valve seats of internal combustion engines. This article compares the abrasive wear resistance of these materials. The abrasion tests were performed on a T-11 pin-on-disc tester, and the counter-sample was steel S235JR. The test conditions were similar to those prevailing during the operation of the valves in the head of the internal combustion engine, without the influence of temperature. The obtained results indicate that the Fe3Al intermetal is characterized by a lower coefficient of friction and lower wear intensity than Stellite 6. The results confirm that the Fe3Al phase is a prospective material to be used as a protective material on the valve seat of vehicles.
Źródło:
Zeszyty Naukowe. Transport / Politechnika Śląska; 2023, 118; 219--228
0209-3324
2450-1549
Pojawia się w:
Zeszyty Naukowe. Transport / Politechnika Śląska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption of hydrated Fe(OH)2+ on the kaolinite surface: A density functional theory study
Autorzy:
Wu, Hongqiang
Miao, Yuqi
Long, Qibang
Yan, Huashan
Li, Yong
Qiu, Sen
Wu, Hao
Zhao, Guanfei
Qiu, Tingsheng
Powiązania:
https://bibliotekanauki.pl/articles/27323639.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
kaolinite
adsorption
Fe
density functional theory
Opis:
The present study employed density functional theory (DFT) to analyze the adsorption configuration and mechanism of Fe(OH)2+ on the kaolinite (001) surface. The findings demonstrated that Fe(OH)2(H2O)4+ is the main type in which hydrated Fe(OH)2+ can be found in aqueous solution. On the surface of kaolinite, Fe(OH)2(H2O)4+ will be adsorbed. There are two forms of adsorption: outer-sphere and inner-sphere coordination (monodentate/bidentate) adsorption. Fe(OH)2(H2O)4+ has a moderate propensity to adsorb on the alumina octahedral sheet of kaolinite when the outer-sphere coordination adsorption takes place. In cases of inner-sphere coordination adsorption, Fe exhibits a tendency to form monodentate adsorption compounds in conjunction with Ou atoms. Additionally, it prefers to create bidentate adsorption compounds through coordination with both Ot and Ou atoms. The adsorption mechanism analysis results show that the ionic property of Fe atom decreases after outer-sphere coordination adsorption. After inner-sphere coordination adsorption, some electrons of Fe atom are transferred to the surface O atom. The presence of electrons between the Fe and O atoms enhances the formation of bonds, hence enhancing the covalent nature of the Fe-O bond. Theoretical FT-IR (Fourier transform infrared spectroscopy) calculations show that the formation of Fe-O chemical bonds. Because of the lower adsorption energy and more chemical bonds, hydrate Fe(OH)2+ is more likely to be bidentate adsorbed on the kaolinite surface.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 174415
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Densification and Magnetic Properties of Fe Powder Compacts According to Heat-Treatment Conditions
Autorzy:
Yoo, Hyo-Sang
Kim, Yong-Ho
Kim, Cheol-Woo
Son, Hyeon-Taek
Powiązania:
https://bibliotekanauki.pl/articles/2203721.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Fe powder
heat-treatment
microstructure
density
Opis:
In this study, the effects of heat-treatment conditions of Fe powder compacts on densification, microstructure, strength and magnetic properties were investigated. The prepared Fe powder was compressed in a mold of diameter 20 mm at a pressure of 800 MPa for 30 sec. This Fe powder compact was heat-treated under different atmospheres (air and 90% Ar + 10% H2 and heat-treatment temperatures (300 and 700℃). The Fe powder compacts heat-treated in an Ar+H2 mixed gas atmosphere showed a denser microstructure and higher density than the Fe powder compacts heat-treated in an air atmosphere. Oxygen content in the heat-treatment conditions played a significant role in the improvement of the densification and magnetic properties.
Źródło:
Archives of Metallurgy and Materials; 2023, 68, 1; 47--50
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Magnetite Oxide Nanoparticles and Tungsten Oxide Nanoparticles on Phosphate Removal from Aqueous Solutions
Autorzy:
EL-Baz, Amro
Mokhtar, Mona
Abdo, Ahmed
Powiązania:
https://bibliotekanauki.pl/articles/24201790.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
phosphate removal
nanoparticles
Fe3O4 NPs
WO3 NPs
adsorption
desorption
Opis:
Phosphate (P) removal from aqueous solutions were studied by a new mineral adsorbent, tungsten (VI) oxide (WO3) nanoparticles (NPs), which has not been the subject of much research in the field of removing P contaminants from agricultural wastewater. In this paper, P was removed from aqueous solutions by a new mineral adsorbent, WO3 NPs and it was compared with magnetite (iron IV) oxide (Fe3O4) nanoparticles (NPs) under the same ambient operating conditions i.e., The influence of the dosage of adsorbents, initial P concentration, contact time, pH and temperature. The values that achieved the best removal were recorded. It was concluded that the best limits for pH were at 2–3, contact time at 40 minutes, temperature at 45 °C and adsorbent dose at 1.0 g/L. Best results of the variables were applied on samples of real agricultural wastewater, which achieved removal ratio of 77.3% and 75.42% for Fe3O4 and WO3 NPs, respectively. SEM, EDX and FTIR images and analyses were conducted to describe the characteristics of nano-adsorbents used before and after P adsorption in aqueous solutions. The P adsorption kinetics for aqueous solutions were examined by fitting results of the experiment to both the first & second pseudo-kinetically models. The outcome indicated that kinematic data fit better with pseudo-second-order kinetic models. Moreover, the information captured from equilibrium adsorption was analyzed using isothermal methods (by Langmuir & Freundlich Forms). Their results showed that the Freundlich form is considered more suitable than Langmuir form in analyzing the biosorption of P ions. The thermodynamic demeanor of P adsorption by Fe3O4 and WO3 NPs was analyzed and evaluated, and the thermodynamic data analyses confirmed the process of P adsorption was spontaneous. The ΔG° value was negative, while ΔH° and ΔS° values found to be positive, which means that the adsorption of P was a spontaneous, random and endothermic operation. In general, Fe3O4 and WO3 nanoparticles had a high efficiency in removing phosphate from water. In addition, WO3 NPs has been identified as one of the most promising adsorbents due to its rapid and effective adsorption of pollutants.
Źródło:
Journal of Ecological Engineering; 2023, 24, 3; 287--303
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Evaluation of the Wear of an Fe-Al Alloy Turbocharger Rotor Seal Ring under Selected Operating Conditions
Ocena zużycia pierścienia uszczelniającego wirnika turbosprężarki wykonanego ze stopu Fe-Al w wybranych warunkach eksploatacji
Autorzy:
Bąkowski, Henryk
Cebulski, Janusz
Ćwiek, Janusz
Powiązania:
https://bibliotekanauki.pl/articles/27310172.pdf
Data publikacji:
2023
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
wear abrasive
turbocharger rotor seal ring
Fe-Al alloy
zużywanie ścierne
pierścień uszczelniający wirnika turbosprężarki
stop Fe-Al
Opis:
This publication presents the possibility of extending the service life of the rotor shaft seal ring in an automotive turbocharger by using an intermetallic Al-Fe alloy. Comprehensive results of tribological, metallographic and profilometric tests of this alloy (vacuum cast) operating in a sliding association on a T-05 bench allowed the representation of a real friction node. Based on empirical tests, it will be possible to determine which alloy (Al-Fe alloy or the one currently used for sealing rings of a car turbocharger rotor shaft) has better tribological properties. For this purpose, the research was based on an experiment that assumes three main factors determining the wear of the tested association. The result of the experimental plan was to obtain threedimensional diagrams showing the influence of the wear factors on the friction force and surface topography.
W publikacji przedstawiono możliwość wydłużenia czasu eksploatacji pierścienia uszczelniającego wałka wirnika w turbosprężarce samochodowej poprzez zastosowanie międzymetalicznego stopu Al-Fe. Kompleksowe wyniki badań tribologicznych, metalograficznych oraz profilometrycznych tego stopu (odlewanego próżniowo) pracującego w skojarzeniu ślizgowym na stanowisku T-05 pozwoliły na odzwierciedlenie rzeczywistego węzła tarcia. Na podstawie przeprowadzonych badań empirycznych będzie można stwierdzić, który ze stopów (stop Al-Fe czy obecnie stosowany na pierścienie uszczelniające wałka wirnika turbosprężarki samochodowej) posiada lepsze właściwości tribologiczne. W tym celu badania oparto na eksperymencie, który zakłada trzy główne czynniki decydujące o zużyciu badanego skojarzenia. W wyniku przeprowadzonego planu eksperymentu możliwe było uzyskanie wykresów trójwymiarowych ujmujących wpływ czynników eksploatacyjnych na siłę tarcia oraz topografię powierzchni.
Źródło:
Tribologia; 2023, 1; 19--26
0208-7774
Pojawia się w:
Tribologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of annealing conditions on changes of the structure and selected properties of Al88Y7Fe5 and Al88Y6Fe6 alloys
Autorzy:
Babilas, Rafał
Spilka, Monika
Łoński, Wojciech
Radoń, Adrian
Kądziołka-Gaweł, Mariola
Gębara, Piotr
Powiązania:
https://bibliotekanauki.pl/articles/2204524.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Al-Y-Fe metallic glasses
heat treatment
structural tests
corrosion resistance
magnetic properties
szkło metaliczne Al-Y-Fe
obróbka cieplna
test strukturalny
odporność na korozję
właściwości magnetyczne
Opis:
Al-Y-Fe amorphous and nanocrystalline alloys are characterized by a unique collection of diverse properties that are influenced by various factors, including heat treatment. In this paper, the effect of heat treatment on the structural changes and selected properties of Al-Y-Fe metallic glasses in the as-spun state is investigated. The structure of the Al88Y7Fe5 and Al88Y6Fe6 alloys was examined by X-ray diffraction (XRD) and Mössbauer spectroscopy (MS). The corrosion resistance of the samples was characterized using polarization tests in a 3.5% NaCl solution at 25 °C. The effect of sodium chloride on the surface was studied with scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS). The magnetic properties of Al-based alloys were explored using a vibrating sample magnetometer (VSM). It was revealed that the tested alloys show better properties after annealing than in the as-spun state. The annealing of the Al88Y7Fe5 and Al88Y6Fe6 alloys in the temperature range of 200 to 300 °C improved the magnetic properties and corrosion resistance of these materials. After 3,600 s, the better EOCP values were recorded for the Al88Y6Fe6 and Al88Y7Fe5 alloys after annealing at 300 °C and 200 °C, adequately. On the basis of the polarization tests, it was concluded that the electrochemical properties are better for Al88Y6Fe6 alloys after annealing at 300 °C.
Źródło:
Bulletin of the Polish Academy of Sciences. Technical Sciences; 2023, 71, 2; art. no. e144614
0239-7528
Pojawia się w:
Bulletin of the Polish Academy of Sciences. Technical Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructures and Tensile Properties of Fe-Cr-Al Oxide Dispersion Strengthened Ferritic Alloys for High Temperature Service Components
Autorzy:
Park, Minha
Bae, Jaeyoon
Kim, Byung-Jun
Kim, Bu-Ahn
Noh, Sanghoon
Powiązania:
https://bibliotekanauki.pl/articles/2203715.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Fe-Cr-Al
ferritic alloy
oxide dispersion strengthening
complex oxide
tensile strength
Opis:
In present study, Fe-22Cr-4.5Al oxide dispersion strengthened ferritic alloys were fabricated using a pre-alloyed powder with different minor alloying elements, and their microstructures and tensile properties were investigated to develop the advanced structural materials for high temperature service components. Planetary-typed mechanical alloying and uniaxial hot pressing processes were employed to fabricate the Fe-Cr-Al oxide dispersion strengthened ferritic alloys. Microstructural observation revealed that oxide dispersion strengthened ferritic alloys with Ti, Zr additions presented extremely fine micro-grains with a high number density of nano-scaled oxide particles which uniformly distributed in micro-grains and on the grain boundaries. These oxide particles were confirmed as a fine complex oxide, Y2Zr2O7. These favorable microstructures led to superior tensile properties than commercial ferritic stainless steel and oxide dispersion strengthened ferritic alloy with only Ti addition at elevated temperature.
Źródło:
Archives of Metallurgy and Materials; 2023, 68, 1; 85--88
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Numerical Modelling and Experimental Testing on Polyurethane Adhesively Bonded Joints Behaviour in Wood-Wood and Wood-Carbon Fibre Reinforced Polymer Layouts
Autorzy:
Kawecki, Bartosz
Powiązania:
https://bibliotekanauki.pl/articles/2201917.pdf
Data publikacji:
2023
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
FE analysis
adhesively bonded joints
wood-wood joints
Wood-CFRP joints
double-lap connection
cohesive stiffness
cohesive strength
delamination
Opis:
Scientists do a variety of laboratory tests on timber and wood-containing composites. An example is adhesively bonded joints in such materials. Despite a wide range of empirical research, consideration of adhesive layers or surfaces in a structure is commonly done in a very simplified manner - they are often modelled as a perfect connection between adherends. It means the cohesive stiffness and opportunity of progressive delamination are neglected. This may lead to an overestimation of the structural load-bearing capacity. The article presents wood-wood and wood-CFRP adhesively bonded joints’ investigations, based on own experimental testing technique (covering a current one as a Digital Image Correlation), analytical double-lap model for adhesives and advanced numerical Finite Element approach. The aim of the paper is to give the guidelines for complex, non-linear modelling of connections in glue laminated timber and wood-CFRP composites that can be utilised for many purposes.
Źródło:
Advances in Science and Technology. Research Journal; 2023, 17, 2; 36--52
2299-8624
Pojawia się w:
Advances in Science and Technology. Research Journal
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Properties and Morphology of Fly Ash Based Alkali Activated Material (AAM) Paste Under Steam Curing Condition
Autorzy:
Razak, Rafiza Abd
Izman, Sharifah Nur Syamimi Syed
Abdullah, Mohd Mustafa Al Bakri
Yahya, Zarina
Abdullah, Alida
Mohamed, Rosnita
Powiązania:
https://bibliotekanauki.pl/articles/28099518.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
alkali activated material
AAM
geopolymer
fly ash
steam-cured
high-Fe
Opis:
This paper details the properties, microstructures, and morphologies of the fly ash-based alkali-activated material (AAM), also known as geopolymers, under various steam curing temperatures. The steam curing temperature result in subsequent high strengths relative to average curing temperatures. However, detailed studies involving the use of steam curing for AAM remain scarce. The AAM paste was prepared by mixing fly ash with an alkali activator consisting of sodium silicate (Na2SiO3) and sodium hydroxide (NaOH). The sample was steam cured at 50°C, 60°C, 70°C, and 80°C, and the fresh paste was tested for its setting time. The sample also prepared for compressive strength, density, and water absorption testings. It was observed that the fastest time for the fly ash geopolymer to start hardening was at 80°C at only 10 minutes due to the elevated temperature quickening the hydration of the paste. The compressive strength of the AAM increased with increasing curing time from 3 days to 28 days. The AAM’s highest compressive strength was 61 MPa when the sample was steam cured at 50°C for 28 days. The density of AAM was determined to be ~2122 2187 kg/m3, while its water absorption was ~6.72-8.82%. The phase analyses showed the presence of quartz, srebrodolskite, fayalite, and hematite, which indirectly confirms Fe and Ca’s role in the hydration of AAM. The morphology of AAM steam-cured at 50°C showed small amounts of unreacted fly ash and a denser matrix, which resulted in high compressive strength.
Źródło:
Archives of Metallurgy and Materials; 2023, 68, 2; 785--789
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structural Characterization and Properties of Al/Fe Multi-Layer Composites Produced by Hot Pressing
Autorzy:
Kowalski, Wojciech
Paul, Henryk
Mania, Izabela
Petrzak, Paweł
Czaja, Paweł
Chulist, Robert
Góral, Anna
Szlezynger, Maciej
Powiązania:
https://bibliotekanauki.pl/articles/2203732.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Fe/Al multilayered composite
intermetallic phase
electron microscopy
microhardness test
Opis:
This study aimed to develop Fe/Al multilayered metallic/intermetallic composites produced by hot pressing under an air atmosphere. Analyses were carried out on the composite plates made up of alternatively situated sheets of AA1050 aluminum alloy and DN04 low carbon steel, which were annealed at 903 K for 2, 5, and 10 h. Annealing was performed to obtain reaction layers of distinct thickness. The samples were examined using X-Ray diffraction and scanning and transmission electron microscope equipped with an energy-dispersive X-Ray spectrometer. To correlate the structural changes with mechanical properties, microhardness measurements in near-the-interface layers were performed. All the reaction layers grew with parabolic kinetics with η-Al5Fe2 intermetallic phase as the dominant component. After annealing for 5 and 10 hours, a thin sublayer of θ-Al13Fe4 phase was also detected.
Źródło:
Archives of Metallurgy and Materials; 2023, 68, 1; 137--144
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Characterization of ZnO/MnFe2O4 Nanocomposites for Degrading Cationic Dyes
Autorzy:
Yuniar
Agustina, Tuty Emilia
Faizal, Muhammad
Hariani, Poedji Loekitowati
Powiązania:
https://bibliotekanauki.pl/articles/24201760.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
nanocomposite
ZnO/Fe2O4
cationic dyestuff
photocatalysis
Opis:
By breaking down harmful dye waste into harmless components under the right irradiation sources, photocatalysis is an unorthodox but promising technique that can reduce industrial wastewater pollution, particularly in the textile industry. Synthetic textile dyes called cationic dyes must be handled carefully because they are poisonous and challenging to breakdown. Photocatalytic oxidation is a useful technique for eliminating hazardous organic pigments. This investigation aims to synthesize and characterize ZnO/MnFe2O4 nanocomposites as well as investigate the effects of varying ZnO:MnFe2O4 ratios, pH levels, doses, and irradiation times on band gap reduction and photocatalytic applications tested with cationic dyes, specifically methylene blue, under the illumination of sunlight. the co-precipitation approach for the manufacture of nanocomposites with different mole ratios of ZnO:MnFe2O4 (1:0.1; 2:0.1; 3:0.1). The component comprising the nanocomposite is ZnO/MnFe2O4, according to the results of the characterisation using XRD, SEM-EDX, FTIR, and BET. UV-DRS measurements of the band gap revealed that as ZnO was reduced, the band gap of the nanocomposite likewise decreased, from 3.35 eV to 2.78 eV. The greatest degradation of 93.2% was achieved for the degradation of 50 mg/L methylene blue (MB) dye with a catalyst dosage of 20 mg at a ratio of 1:0.2 for 50 minutes of irradiation. Since the point of zero charges (pzc) was reached at a pH of 7.8, a photodegradation adsorption-friendly solution pH of 8 was created.
Źródło:
Journal of Ecological Engineering; 2023, 24, 4; 252--263
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A multi-analytical approach for the analysis of cation distribution in a aluminoceladonite structure
Autorzy:
Kądziołka-Gaweł, Mariola
Dulski, Mateusz
Czaja, Maria
Krzykawski, Tomasz
Szubka, Magdalena
Powiązania:
https://bibliotekanauki.pl/articles/2172615.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
aluminoceladonite
ions position characterization isomorphic substitutions
Fe bearing phyllosilicates
X-ray photoelectron spectroscopy
Mössbauer spectroscopy
Raman spectroscopy
glinokrzemiany
krzemiany warstwowe
rentgenowska spektrometria fotoelektronów
XPS
spektroskopia mössabuerowska
spektroskopia Ramana
Opis:
In this paper cation arrangement in two samples of aluminoceladonite, emerald green and dark-green were studied by Mössbauer, Raman and X-ray photoelectron spectroscopies. The X-ray photoelectron spectroscopy (XPS) spectra obtained in the region of the Si2p, Al2p, Fe2p, K2p, and O1s core levels provided information, for the first time highlighting a route to identify the position of Si, Al, K, and Fe cations in a structure of layered silicates. The XPS analysis showed the presence of Al in tetrahedral and octahedral coordination while the K2p line indicated the possibility of K+ substitution by other cations in interlayer sites. Mössbauer spectroscopy provided information about crystal chemistry with respect to the local electronic and geometric environment around the Fe atom and to distortions of the polyhedra. It turned out that iron was located mostly in the cis-octahedra position wherein about 75% of iron appeared in the form of Fe3+. The most preferred cation combinations around Fe corresponded to 3Fe3+ ions and MgFe2+Fe3+/2MgFe3+. Raman spectroscopy illustrated aluminium substitution in silicon and iron positions wherein the concentration of the aluminium determined the degree of structural distortion within the layered system. These isomorphic substitutions implied a typical band arrangement in the hydroxyl region, which has not been observed in celadonites so far.
Źródło:
Acta Geologica Polonica; 2022, 72, 3; 353--368
0001-5709
Pojawia się w:
Acta Geologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A Study on the Optimization of Metalloid Contents of Fe-Si-B-C Based Amorphous Soft Magnetic Materials Using Artificial Intelligence Method
Autorzy:
Choi, Young-Sin
Kwon, Do-Hun
Lee, Min_Woo
Cha, Eun-Ji
Jeon, Junhyub
Lee, Seok-Jae
Kim, Jongryoul
Kim, Hwi-Jun
Powiązania:
https://bibliotekanauki.pl/articles/2174571.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Fe-based amorphous
soft magnetic properties
artificial intelligence
machine learning
random forest regression
Opis:
The soft magnetic properties of Fe-based amorphous alloys can be controlled by their compositions through alloy design. Experimental data on these alloys show some discrepancy, however, with predicted values. For further improvement of the soft magnetic properties, machine learning processes such as random forest regression, k-nearest neighbors regression and support vector regression can be helpful to optimize the composition. In this study, the random forest regression method was used to find the optimum compositions of Fe-Si-B-C alloys. As a result, the lowest coercivity was observed in Fe80.5Si3.63B13.54C2.33 at.% and the highest saturation magnetization was obtained Fe81.83Si3.63B12.63C1.91at.% with R2 values of 0.74 and 0.878, respectively.
Źródło:
Archives of Metallurgy and Materials; 2022, 67, 4; 1459--1463
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of the Corrosion Rate of FeMn-Si Biodegradable Material
Autorzy:
Roman, Ana-Maria
Chelariu, Romeu
Cimpoesu, Ramona
Stirbu, Ioan
Ionita, Iulian
Cazacu, Marius Mihai
Prisecariu, Bogdan Anton
Cimpoesu, Nicanor
Pietrusiewicz, Paweł
Sodor, Alina
Powiązania:
https://bibliotekanauki.pl/articles/2174554.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
biodegradable
Fe-Mn alloy
degradation rate
Opis:
The Fe-based alloy with manganese led to the appearance of new austenitic alloys, with the antiferromagnetic property pursued, resulting in compatibility with the magnetic field as that of magnetic resonance imaging. The corrosion resistance behavior of the biodegradable Fe-Mn-Si alloy was analyzed in a thermostatic chamber at 37±1°C for 24, 48 and 72 hours by immersing in Ringer solution. Also, the cast and laminated samples were subjected to electro-corrosion tests using a potentiostat equipment. Linear and cyclic potentiometry is presented for characterize the corrosion behavior of the experimental samples in electrolyte. Due to the interaction between the alloy and the liquid medium a change in the solution pH was observed. Structure analysis and chemical composition details of the surfaces were obtained using electron scanning microscopy (SEM) and X-ray energy dispersive spectroscopy (EDS).
Źródło:
Archives of Metallurgy and Materials; 2022, 67, 4; 1243--1250
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 426

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