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Wyszukujesz frazę "Apollofix dyes" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Effect of gamma-irradiation on aqueous solutions of Apollofix dyes
Autorzy:
Solpan, D.
Torun, M.
Güven, O.
Powiązania:
https://bibliotekanauki.pl/articles/147642.pdf
Data publikacji:
2007
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
gamma irradiation
Apollofix dyes
decoloration
organic pollutants degradation
wastewater treatment
Opis:
Radiation processing has been considered as a promising process for the treatment of textile industry waste effluents. In this study, the possibility of using gamma-rays to degrade and decolorize Apollofix dyes in water has been investigated. Two different Apollofix dyes, Apollofix Red (AR) and Apollofix Yellow (AY) in aqueous solutions were irradiated in air with doses from 1.0 kGy to 8.0 kGy at a 0.14 kGy/h of dose rate. The change in absorption spectra, pH, chemical oxygen demand (COD), biological oxygen demand (BOD) and the degree of decoloration (percent reduction in optical density) were examined in the presence and absence of H2O2. The absorption bands at 534 nm and 420 nm for AR and AY were observed to decrease rapidly with increasing irradiation dose. The degree of decoloration of each dye solution with irradiation dose was estimated as 100 percent for the lower concentration (50 ppm) dye solutions. The complete decoloration was observed after 2.0 kGy and 1.0 kGy doses for AR and AY dyes. The COD and BOD reduction and the change of pH for all dye solutions on irradiation showed similar behavior.
Źródło:
Nukleonika; 2007, 52, 3; 109-113
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Azo dye degradation by high-energy irradiation: kinetics and mechanism of destruction
Autorzy:
Takács, E.
Wojnárovits, L.
Pálfi, T.
Powiązania:
https://bibliotekanauki.pl/articles/146575.pdf
Data publikacji:
2007
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
azo dyes
decolouration
reaction mechanism
kinetics
Apollofix Red
Reactive Black 5
Opis:
The kinetics and mechanism of dye destruction is discussed on the example of Apollofix Red (AR-28) and Reactive Black 5 (RB-5) radiolysis in dilute aqueous solution. The dose dependence of colour disappearance is linear when the reactive intermediate reacts with the colour bearing part of the molecule causing destruction of the conjugation here with nearly 100% efficiency. In this case, spectrophotometry can be used to follow-up dye decomposition. Such a linear dependence was observed when hydrated electrons or hydrogen atoms reacted with the dye. However, in the case of hydroxyl radical reactions some coloured products form with absorption spectra very similar to those of the starting dye molecules. For that reason, spectrophotometric measurements give false results about the concentration of intact dye molecules. Analysis made by the HPLC (high-pressure liquid chromatography) method reveals logarithmic time dependence in agreement with a theoretical model developed.
Źródło:
Nukleonika; 2007, 52, 2; 59-67
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
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