Informacja

Drogi użytkowniku, aplikacja do prawidłowego działania wymaga obsługi JavaScript. Proszę włącz obsługę JavaScript w Twojej przeglądarce.

English (EN)·Polski (PL)·Yкраїнський (UK)
Przejdź do strony domowej biblioteki Centralna Biblioteka Wojskowa Link otwiera się w nowym oknie Logo biblioteki Prolib Integro - strona głównaCentralna Biblioteka Wojskowa

Wyszukujesz frazę "Anilines" wg kryterium: Temat

  Lista filtrów
Wyrównaj
    Wyświetlanie 1-3 z 3
    Tytuł:
    Ultrasonic Assisted Synthesis, Acoustical Property and Antibacterial Activity of Some Schiff Bases
    Autorzy:
    Premalatha, R.
    Santhi, N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412100.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    substituted anilines
    3-bromo-4-fluorobenzaldehyde
    Schiff bases
    ultrasonication
    acoustical parameters and antimicrobial activity
    Opis:
    An efficient, simple clean synthesis of Schiff bases of some 4-nitroaniline/ 2,4-dinitroaniline/ 3,4-dichloroaniline / 4-methoxy-3-nitro aniline with 3-bromo-4-fluorobenzaldehyde were done by an ultrasound irradiation method. The major advantages of ultra-sonication are short reaction time, operational simplicity, high yield, easy workup and environment friendly procedure. The isolated compounds obtained by ultrasound irradiation method were characterized by UV, IR and NMR spectral data. These acoustical parameters were determined. Furthermore their antibacterial activities are screened against certain strains of bacteria and showed significant anti-microbial activity.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 14, 1; 53-64
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Spectral LFER studies in some N-(substituted phenyl) formamides
    Autorzy:
    Thirunarayanan, Ganesamoorthy
    Muthuvel, Inasekaran
    Sathiyendiran, Vasudevan
    Powiązania:
    https://bibliotekanauki.pl/articles/764126.pdf
    Data publikacji:
    2015
    Wydawca:
    Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
    Tematy:
    N-(Substituted phenyl)formamides
    Sulphated titania(TiO2-SO4–-)
    IR and NMR spectra
    Anilines
    Hammett correlations.
    Opis:
    A series of N-(substituted phenyl) formamides were synthesised by sulphated titania (TiO2-SO4 2-) catalyzed formylation of substituted anilines and formic acid in acetonitrile medium at room temperature. The synthesised formamide derivatives are characterized by their spectral data. The infrared νNH, CO (cm-1) stretches, chemical shifts(δ, ppm) of NH, COH and ipso carbons(Ar-C-NH) were assigned and correlated with Hammett substituent constants using single and multi-regression analysis. From the results of statistical analyses, the effect of substituents on the spectral data have been studied.
    Źródło:
    Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2015, 70, 2
    2083-358X
    Pojawia się w:
    Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Strukturalne konsekwencje wiązania wodorowego
    Strustural consequences of the h-bonding
    Autorzy:
    Krygowski, T.M.
    Szatyłowicz, H.
    Powiązania:
    https://bibliotekanauki.pl/articles/171995.pdf
    Data publikacji:
    2011
    Wydawca:
    Polskie Towarzystwo Chemiczne
    Tematy:
    wiązanie wodorowe
    podstawione fenole
    podstawione aniliny
    aromatyczność
    AIM
    NBO
    H-bond
    substituted phenols
    substituted anilines
    aromaticity
    atoms in molecules
    natural bond orbital
    NBO analysis
    Opis:
    Hydrogen bonding belongs to the most important chemical interactions in life and geochemical processes as well as in technologies, that is documented in many review articles [1-10], monographs [11-17] and numerous publications. Figure 1 presents how "popular" are studies concerning hydrogen bonds (the term H-bond/bonding/bonded in a title, key-words or in abstract) in the last decade. First information about H-bond formation appeared at the end of XIX and a few other at beginning of XX centuries [19-24]. Most common definition of H-bonding stems from Pauling [27], whereas the newest IUPAC definition was published very recently [26]. Most frequently H-bonding is experimentally described by geometry parameters [28, 32] - results of X-ray and neutron diffraction measurements, but NMR and IR/Raman spectroscopies are also in frequent use. Characteristic of interactions by H-bonding is usually discussed in terms of energies [29-31], with use of various quantum chemical theories [54-57] and applications of various models as AIM [35, 41, 42, 45-48] and NBO [43, 44] which allowed to formulate detailed criteria for H-bond characteristics [35, 48]. H-bonds are classified as strong, mostly covalent in nature [7, 29, 34], partly covalent of medium strength [35] and weak ones, usually non-covalent [7, 29, 34, 35]. Theoretical studies of H-bonding mainly concern equilibrium systems, however simulation of H-bonded complexes with controlled and gradually changing strength of interactions [61-71] are also performed. The latter is main source of data referring to effect of H-bonding on structural properties: changes in the region of interactions, short and long-distance consequences of H-bonding. Application of the model [61] based on approaching hydrofluoric acid to the basic center of a molecule and fluoride to the acidic one, (Schemes 2 and 3) allows to study changes in molecular structure of para-substituted derivatives of phenol and phenolate [62, 64] in function of dB…H, or other geometric parameter of H-bond strength (Fig. 2). It is also shown that CO bond lengths in these complexes is monotonically related to H-bond formation energy and deformation energy due to H-bond formation [65]. Alike studies carried out for para-substituted derivatives of aniline and its protonated and deprotonated forms [77, 78, 81] give similar picture (Fig. 3). AIM studies of anilines [77, 78] lead to an excellent dependence of logarithm of electron density in the bond critical point and geometric parameter of H-bond strength, dB…H presented in Figure 4. Substituents and H-bond formation affect dramatically geometry of amine group [66] in H-bonded complexes of aniline as shown by changes of pyramidalization of bonds in amine group (Fig. 5). Some short- and long-distance structural consequences of H-bonding are shown by means of changes in ipso angle (for amine group) in the ring and ipso-ortho CC bond lengths (Fig. 6). Moreover, the mutual interrelations are in line with the Bent-Walsh rule [84, 86]. Changes of the strength of H-bonds in complexes of p-substituted aniline and its protonated and deprotonated derivative are dramatically reflected by aromaticity of the ring66 estimated by use of HOMA index [87, 88] (Fig. 7), where strength of H-bonding is approximated by CN bond lengths. Scheme 4 presents application of the SESE [91] (Substituent Effect Stabilization Energy) for description in an energetic scale joint substituent and H-bond formation effects.
    Źródło:
    Wiadomości Chemiczne; 2011, 65, 11-12; 953-974
    0043-5104
    2300-0295
    Pojawia się w:
    Wiadomości Chemiczne
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-3 z 3

      Ta witryna wykorzystuje pliki cookies do przechowywania informacji na Twoim komputerze. Pliki cookies stosujemy w celu świadczenia usług na najwyższym poziomie, w tym w sposób dostosowany do indywidualnych potrzeb. Korzystanie z witryny bez zmiany ustawień dotyczących cookies oznacza, że będą one zamieszczane w Twoim komputerze. W każdym momencie możesz dokonać zmiany ustawień dotyczących cookies