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Tytuł:
Wpływ fluorków i kwasu mlekowego na odporność korozyjną stopów tytanu w symulowanym roztworze sztucznej śliny
Influence of Fluoride and Lactic Acid to Corrosion Resistance of Titanium Alloys in Simulated Artificial Saliva Solution
Autorzy:
Loch, J.
Krawiec, H.
Łukaszczyk, A.
Powiązania:
https://bibliotekanauki.pl/articles/382532.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
stop tytanu
odporność korozyjna
sztuczna ślina
kwas mlekowy
fluorek sodu
titanium alloy
corrosion resistance
artificial saliva
lactic acid
Opis:
Ze względu na powszechne wykorzystanie stopów tytanu w stomatologii, w pracy podjęto badania elektrochemiczne stopów tytanu: Ti-10Mo-4Zr i Ti-6Al-4V, których celem było określenie właściwości korozyjnych podczas ekspozycji w fizjologicznym roztworze sztucznej śliny, w temperaturze 37 °C, pH = 8,0 i swobodnym dostępie tlenu, a następnie modyfikacji roztworu poprzez dodatek kwasu mlekowego oraz fluorku sodu. Odporność korozyjną obu stopów porównano na podstawie badań potencjału korozyjnego i potencjodynamicznych krzywych polaryzacyjnych wykonanych techniką liniowej woltamperometrii (LSV).
Titanium alloys are used in medicine and dentistry due to perfect combination of their high strength, corrosion resistance and biocompatibility. Currently, titanium alloys are among the most attractive metallic materials used to manufacture such implants as artificial hip joints, knee joints, intervertebral discs, screws securing the fracture. Most kinds of screws used in dentistry for basic fixing of ceramic dental prostheses are made from titanium alloys. Widespread use of titanium alloys in dentistry is the reason for electrochemical research on two titanium alloys: Ti-6Al-4V and Ti-10Mo-4Zr. The aim of the research was to determine the corrosion when the alloy is exposed to physiological artificial saliva solution at the temperature of 37 °C, pH = 8.0 and in aerated solution and modification of saliva solution: added lactic acid and sodium fluoride.
Źródło:
Archives of Foundry Engineering; 2015, 15, 4 spec.; 87-90
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Studies of corrosion behaviour in acid environment of binary Mg-Li alloys for plastic forming
Autorzy:
Białobrzeski, A.
Saja, K.
Żmudzińska, M.
Powiązania:
https://bibliotekanauki.pl/articles/380235.pdf
Data publikacji:
2011
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
ultralight Mg-Li alloy
corrosion behaviour
acid media
stop ultralekki Mg-Li
zachowanie korozyjne
środowisko kwaśne
Opis:
The article discusses studies and corrosion tests of binary Mg-Li alloys for plastic forming examined in an acid medium (5% HCl solution) for the time of 0-144 hours. In short it can be stated that corrosion of the examined Mg-Li alloys in 5% HCl solution proceeded in a similar mode in all the studied alloys, regardless of the lithium content.
Źródło:
Archives of Foundry Engineering; 2011, 11, 3 spec.; 25-28
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Selective Corrosion of Al2Cu Intermetallic Phase in Orthophosphoric Acid Aqueous Solutions
Autorzy:
Kwolek, P.
Gradzik, A.
Szeliga, D.
Kościelniak, B.
Powiązania:
https://bibliotekanauki.pl/articles/351947.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
intermetallic phase
selective corrosion
orthophosphoric acid
electrochemical impedance spectroscopy
Opis:
Al2Cu phase has been obtained by melting pure metals in the electric arc furnace. It has been found that the intermetallic phase undergoes selective corrosion in the H3PO4 aqueous solutions. Aluminium is dissolved, the surface becomes porous and enriched with copper. The corrosion rate equals to 371 ±17 g∙m-2∙day-1 (aerated solution) and 284 ± 9 g∙m-2∙day-1 (deaerated solution). The surface of Al2Cu phase after selective corrosion was characterised by using electrochemical impedance spectroscopy. It was found that the surface area of the specimens increases with temperature due to higher corrosion rate and is between 2137 and 3896 cm2.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 4; 1223-1229
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Seed Shells as Active and Nontoxic Corrosion Inhibitors for Aluminum in Aggressive Acid Environment
Autorzy:
Nwanneka, Emembolu Loveth
Okeychukwu, Onukwuli Dominic
Kanwulia, Igbokwe Pilomena
Powiązania:
https://bibliotekanauki.pl/articles/1031576.pdf
Data publikacji:
2020
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Acid inhibition
Afzelia africana
Aluminum corrosion
Brachystegia eurycoma
Derium microcarpum
Mucuna flagellipes
Pentaclethra macrophlla
chemical measurements
seed shell extracts
thermodynamic parameters
Opis:
Chemical (weight loss and thermometric) measurements were used to study the corrosion inhibition characteristics of five seed shells, namely Afzelia africana seed shell (AASS), Brachystegia eurycoma seed shell (BESS), Derium microcarpum seed shell (DMSS), Mucuna flagellipes seed shell (MFSS) and Pentaclethra macrophlla seed shell (PMSS), respectively, on the inhibition of aluminum corrosion in aggressive 2.0 % HCl solutions at 30 and 50 °C for 8 hrs. Weight loss and thermometric measurements demonstrated that the seed shells (AASS, BESS, DMSS, MFSS and PMSS extracts) act as good corrosion inhibitors. Addition of the seed shell extracts decreases the corrosion rate of the process thereby improving inhibition performance. The result also reveals that the five seed shell extracts adsorb on the Aluminum surface through physical adsorption in accordance with Flory-Huggins and Langmuir adsorption isotherms at all temperatures investigated. Kinetic-thermodynamic parameters indicate a spontaneous adsorption process. Results of inhibition efficiency demonstrates that DMSS extract performed better as compared to BESS, AASS, PMSS and MFSS extracts.
Źródło:
World News of Natural Sciences; 2020, 31; 120-137
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Odporność zapraw z udziałem popiołów lotnych z kotłów fluidalnych i konwencjonalnych na korozję kwasową
The resistance of mortars with fluidized beds boiler fly ashes and conventional fly ashes to acid corrosion
Autorzy:
Janowska-Renkas, E.
Kowalska, J.
Kaliciak, A.
Janus, G.
Powiązania:
https://bibliotekanauki.pl/articles/131481.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Komisja Inżynierii Budowlanej PAN Oddział w Katowicach
Tematy:
popioły lotne ze spalania w kotłach fluidalnych
popioły lotne z kotłów konwencjonalnych
korozja kwasowa
trwałość zapraw
fly ashes
fluidized boiler
conventional boiler
acid corrosion
durability of cement mortars
Opis:
This paper presents the results of research undertaken to determine the impact of the aggressive environment of acid corrosion on the durability of cement mortars with the participation of fluidized beds boiler fly ashes and conventional fly ashes used separately and in the form of mixtures. The beneficial effect of fluidized beds boiler fly ashes on the physical properties of cement mortars has been shown, i.e. reduction of the contraction, decrease of weight loss and reduction of the destruction of mortars in acid corrosion. This effect was especially beneficial for mortars containing higher (45% by weight) content of fluidized fly ashes, used separately and in the form of mixtures, regardless of the aggressiveness of the environment (1%, 3% and 5% HCl solution).
Źródło:
Roczniki Inżynierii Budowlanej; 2016, 16; 101-109
1505-8425
Pojawia się w:
Roczniki Inżynierii Budowlanej
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kinetics of Corrosion Process in H2SO4 and HNO3 Aqueous Solutions of Lead Free Sn-Ag-Cu Solder Alloys
Autorzy:
Guśpiel, J.
Wierzbicka-Miernik, A.
Reczyński, W.
Powiązania:
https://bibliotekanauki.pl/articles/352914.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
electronic materials
polarization
acid corrosion
Opis:
This paper presents the results of the corrosion resistance of Sn-Ag-Cu alloys in air-saturated aqueous solutions containing NO3-, SO42- ions, whose concentration was equivalent to their contents in acid rains and in concentrations 10 - 100 times higher. The Ag, Cu and Sn concentrations in the corrosive media were determined using the Atomic Absorption Spectrometry. The specific dissolution rate and corrosion current were derived using the a rotating disc technique. The corrosion rate of Sn- Ag-Cu alloys depends on pH of the examined solutions and on the concentration of oxygen near the phase boundary. In the whole range of concentrations of the applied H2SO4 + HNO3 mixtures of acids, the pure Sn was more corrosion resistant than eutectic alloy as well as the near eutectic one, following the sequence: Sn>Sn3.66Ag0.91Cu>3.8Ag0.7Cu.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 2A; 559-568
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation on Corrosion Inhibition of Hura Crepitans for 2101 Duplex Stainless Steel in an Acidic Environment
Autorzy:
Temitayo, Ogunmodede O.
Vawe, Humwapwa
Johnson, Jonathan
Adewole, Ezekie
Ilesanmi, Osasona
Powiązania:
https://bibliotekanauki.pl/articles/2201784.pdf
Data publikacji:
2022
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
corrosion
steel
Hura crepitans
inhibitor
sulphuric acid
Opis:
Corrosion is a global menace which has imparted the world economy greatly. One of the solutions proffered to these challenges is the use of inhibitors. Several natural inhibitors have been used to protect engineering materials from corroding. This research is focused on investigating the inhibitive properties of Hura crepitans seed (HCS) on Duplex Stainless Steel 2101 (DSS2101) in H2SO4. The selected plant part was subjected to characterization to determine the presence of organic anti-corrosion agents present. From the result, phytochemicals such as saponin, tannins, steroid and flavonoids were observed. The presence of the organic group accounted for the inhibitive efficiency recorded in the environment. The polarization studies revealed that generally the inhibitor produced from seed extract of Hura crepitans, improved the corrosion resistance of DSS2101 in 0.5M H2SO4. The optimum corrosion inhibitor efficiency was observed at 0.2% inhibitors in 0.5M H2SO4 for 2101DSS.
Źródło:
Advances in Science and Technology. Research Journal; 2022, 16, 4; 56--63
2299-8624
Pojawia się w:
Advances in Science and Technology. Research Journal
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Inhibition of Brass Corrosion in Acid Medium Using Thiazoles
Autorzy:
Taha, K. K.
Mohamed, M. E.
Khalil, S. A.
Talab, S. A.
Powiązania:
https://bibliotekanauki.pl/articles/411634.pdf
Data publikacji:
2013
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Benzothiazoles
Brass Corrosion Inhibitors
Perchloric Acid
Opis:
Brass as an alloy composed mainly of copper is great industrial uses such as heat exchangers and similar other facility due to its good thermal properties. Due to the presence of the considerable ratio of zinc the alloy suffers from zinc dissolution or dezincification. Dezincification rate increases with the increase in the ratio of zinc in the alloy. In this study benzothiazole (BTH) and its substituent’s 2-methylbenzothiazole (MeBTH), 2-aminobenzothiazole (ABTH), 2-mercaptobenzothiazole (MBTH) and 2-phenylbenzothiazole (PhBTH) have been used as corrosion inhibitors for α-brass in stirred 0.1 M HClO4. The methods of investigation include weight loss, Tafel and linear polarizations and electrochemical impedance spectroscopy. The order of inhibition efficiency (% E) was calculated and the values obtained has indicated the sequence of inhibition efficiency was found to be BTH < MeBTH < ABTH < PhBTH < MBTH. The calculated values of thermodynamic parameters support this order. The inhibitors were found to suppress the corrosion rate by the formation of films which were identified by IR, SEM and EDAX techniques.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2013, 9, 2; 87-102
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of Nicotiana Tobaccum Extract Additive on the Quality of Electroplating of Zinc on Mild Steel
Autorzy:
Loto, C.A.
Loto, R.T.
Powiązania:
https://bibliotekanauki.pl/articles/779362.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
electrodeposition
tobacco
steel surface
acid chloride solution
corrosion
Opis:
Experimental investigations have been performed to determine the effects of nicotiana tobaccum (tobacco) extract additive on the electrodeposition of zinc on mild steel in acid chloride solution. The experiments were performed under different plating time, different additive concentrations and fixed pH conditions. Zinc electrodeposition on mild steel was performed using a DC - supply at defined operating parameters. The surface of the plated steel was examined using scanning electron microscopy (SEM); and Energy Dispersive Spectroscopy (EDS) for the surface elemental composition analysis. Different surface characteristics were obtained depending upon the concentration of the additive and the plating time. The corrosion resistance of the plated surface was also determined by a gravimetric method. The quality of the electro-deposition of zinc was good as indicated by the microstructural morphology of the plated surface except for the few porosities observed. The electrodeposition process was sensitive to the changes in the additive concentration and plating time. Any variation in the plating parameter produced an entirely new and different surface morphology.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 1; 37-45
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Na3VO4 Inhibitor on the Corrosion Resistance of Al2Cu Intermetallic Phase in H3PO4 Aqueous Solution
Autorzy:
Kwolek, P.
Powiązania:
https://bibliotekanauki.pl/articles/354857.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
intermetallic phase
selective corrosion
orthophosphoric acid
electrochemical impedance spectroscopy
sodium orthovanadate
Opis:
Sodium orthovanadate was tested as a corrosion inhibitor of intermetallic Al2Cu in 1 M H3PO4. The Al2Cu–H3PO4–Na3VO4system was studied using the following methods: inductively coupled plasma optical emission spectrometry, scanning electron microscopy with energy dispersive x-ray spectroscopy, x-ray diffraction, electrochemical impedance spectroscopy, polarisation and open circuit potential. It was found that the corrosion rate decreased as the inhibitor concentration increased. The highest inhibition efficiency 99% was obtained when sodium orthovanadate initial concentration was equal to 100 mM, pH = 1.11, due to precipitation of a protective layer of insoluble salt, containing vanadium, phosphorus, sodium and oxygen, on the surface. At pH = 0.76 the protective layer was not formed and inhibition efficiency decreased to 76%. Selective corrosion of the intermetallic phase caused a significant increase of an electric double layer capacitance and decrease of a charge transfer resistance.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 1; 175-183
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dew point of the flue gas of boilers co-firing biomass with coal
Autorzy:
Ciukaj, S.
Pronobis, M.
Powiązania:
https://bibliotekanauki.pl/articles/185075.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
acid dew point
low-temperature corrosion
biomass
co-firing
korozja
biomasa
współspalanie
Opis:
The paper deals with the impact of co-firing biomass with coal in boilers on the dew point of the flue gas. Co-firing of biomass may have twofold implications on corrosion and fouling, which are the processes that determine the lowest acceptable flue gas outlet temperature and as a result, boiler efficiency. Both phenomena may be reduced by co-firing of usually low sulphur biomasses or enhanced due to increased moisture content of biomass leading to increased water dew point. The present study concerns the problem of low-temperature corrosion in utility boilers. The paper gives (in the form of diagrams and equations) a relationship between water dew point and moisture content of fuel mixture when co-firing coal and various biomasses. The regression analysis shows that despite significant differences in the characteristics of coals and these of additional fuels, which are planned for co-firing in large-scale power boilers, the water dew point can be described by a function given with the accuracy, which shall be satisfactory for engineering purposes. The discussion of the properties of biofuels indicates that the acid dew point surplus over the water dew point ([delta]tr = tr -twr) is not likely to exceed 10 K when co-firing biomass. The concluding remarks give recommendations for the appropriate operation of boilers in order to reduce risks associated with biomass co-combustion.
Źródło:
Chemical and Process Engineering; 2013, 34, 1; 101-108
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Determination of the Effect of Environmental Factors on the Corrosion of Water Distribution System Based on Analysis of On-line Corrosion Monitoring Results
Autorzy:
Jażdżewska, A.
Gruszka, M.
Mazur, R.
Orlikowski, J.
Banaś, J.
Powiązania:
https://bibliotekanauki.pl/articles/355721.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
water distribution system
acid rain
corrosion monitoring
online
linear polarization method
Opis:
Corrosion of water distribution system is a significant issue causing problems with quality, safety and continuity of distribution. The changes of corrosion rates of the water distribution systems in Cracow made of carbon steel were investigated by analysis of online corrosion monitoring system results. Corrosion rates were determined using the linear polarization method. The impactof rain, temperatures, conductivity, dissolved oxygen content on corrosion rate were characterized. The corrosivity of different water sources like mountain water, underground water or river water were indicated. The possible actions for reducing corrosion losses were characterized. Results show that pollution of the environment in the form of acid rain and runoff from agriculture as well as the type of the source water has significant influence on corrosion of water distribution system. Corrosion monitoring system gives possibility of controlling corrosion rate by mixing waters from different sources in the way to obtain less corrosive mixture. (see Fig 8).
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 1; 109-116
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Determination of metal corrosion in wood treated with new-generation water-borne preservatives
Autorzy:
Can, Ahmet
Sivrikaya, Hüseyin
Taşcioğlu, Cihat
Powiązania:
https://bibliotekanauki.pl/articles/342791.pdf
Data publikacji:
2020
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Technologii Drewna
Tematy:
alkaline copper quaternary (ACQ)
boric acid (BA)
micronized copper quaternary (MCQ)
nano boron (NB)
corrosion test
Opis:
In this study, the corrosion performances of ammonium copper quaternary (ACQ) and boric acid (BA) wood preservatives were investigated, with micronized copper quaternary (MCQ) and nano boron (NB) used as reference materials. In the study, Scots pine (Pinus sylvestris L.) wood samples were impregnated according to the full-cell process method with ACQ at 2.4% concentration, BA at 4% and MCQ and NB at 1%. The ACQ- and BA-impregnated samples were then impregnated for a second time using five different water-repellent materials: tall oil, linseed oil, sodium silicate, methyl hydrogen silicone and N'-N-(1,8- naphthalyl)hydroxylamine. Polyethylene glycol (PEG) 600 and aluminum sulfate were introduced as single impregnations in the form of homogeneous mixtures with ACQ and BA. The corrosion properties of the impregnated and control samples, including metal weight loss (MWL) and corrosion depth, were examined. The MWL values of the ACQ-impregnated samples showed an increase compared to the control group. The MWL values of the MCQ-impregnated samples were lower than those of the samples impregnated with ACQ, whilst the MWL values of the BA-impregnated samples were higher than those of the samples impregnated with NB.
Źródło:
Drewno. Prace Naukowe. Doniesienia. Komunikaty; 2020, 62, 205; 59-68
1644-3985
Pojawia się w:
Drewno. Prace Naukowe. Doniesienia. Komunikaty
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Corrosion inhibition of mild steel in HCl solution by Tinidazole
Autorzy:
Reza, I.
Saleemi, A.R.
Naveed, S.
Powiązania:
https://bibliotekanauki.pl/articles/779380.pdf
Data publikacji:
2011
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
korozja kwasowa
stal miękka
polaryzacja
tynidazol
acid corrosion
mild steel
polarization
EIS
tinidazole
Opis:
Tinidazole, a pharmaceutical compound has been investigated with reference to the inhibition of mild steel acidic corrosion in 1 molar HCl by means of weight loss and electrochemical measurements. The outcomes attained at 30°C revealed that the Tinidazole had obtained 90% inhibition efficiency at 400 ppm concentration. These results explain that the inhibition process occurs by means of adsorption. The inhibitor molecules adsorb on the surface of the metal, following Langmuir's adsorption isotherm. Potentiodynamic polarization measurements established that Tinidazole is an inhibitor of a mixed type. An appropriate equivalent electric circuit for modeling and the analysis of impedance data to give a better explanation of the process of corrosion inhibition have been proposed.
Źródło:
Polish Journal of Chemical Technology; 2011, 13, 1; 67-71
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Corrosion behaviour of binary Mg-Li alloys for plastic forming
Autorzy:
Białobrzeski, A.
Saja, K.
Żmudzińska, M.
Powiązania:
https://bibliotekanauki.pl/articles/380767.pdf
Data publikacji:
2011
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
ultralight Mg-Li alloy
alkaline corrosion
acid media
stop ultralekki Mg-Li
korozja alkaliczna
środowisko kwaśne
Opis:
The paper outlines the course of corrosion processes in magnesium and Mg-Li alloys. The methodology of corrosion studies of alloys for plastic forming and their chemical composition as well as micrographs of alloys intended for research are presented.
Źródło:
Archives of Foundry Engineering; 2011, 11, 3 spec.; 15-20
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
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