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Tytuł:
Zmienność składu chemicznego kwaśnych wód spływu powierzchniowego z czynnej hałdy odpadów górniczych reprezentujących osady krakowskiej serii piaskowcowej Górnośląskiego Zagłębia Węglowego
Variability of chemical composition of acidic runoff waters from anactive spoil heap of mining wastes representing sediments of the Cracow Sandstone Series of the Upper Silesian Coal Basin
Autorzy:
Bauerek, A.
Bebek, M.
Frączek, R.
Paw, K.
Kasperkiewicz, W.
Powiązania:
https://bibliotekanauki.pl/articles/2075663.pdf
Data publikacji:
2017
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
kwaśne wody kopalniane
AMD
odpady górnicze
Górnośląskie Zagłębie Węglowe
metale ciężkie
siarczany
acid mine drainage
coal mining waste
Upper Silesian Coal Basin
heavy metals
sulphates
Opis:
Analysis of physical and chemical properties of water runoff samples collected in the vicinity of a spoil heap near the coal mine in Libiąż showed that they represented a classic example of acid mine drainage. For the first time in the Upper Silesian Coal Basin, it has been documented that rainwater in contact with a surface layer of waste containing pyrite (FeS2) and scarce carbonate phases, produces strongly acidified wastewater. This process is accompanied by a dramatic increase in the concentration of dissolved ions (eg. Cl-, SO , Fe, Al, Mn). Further geochemical changes occur in the ditch collecting water runoff at the base of the heap. At this stage, oxidation of pyrite catalyzed by bacteria, followed by hydrolysis of iron Fe3+ to form goethite (FeO(OH)) leads to conversion of the less acidic (pH 2.6-3.5), short-time retention runoff water into the aggressive stagnant runoff water (pH 2.1-2.8). Further disintegration of Carboniferous claystones occurs in the acidic stagnant water environment, leading to the decomposition of mineral phases containing heavy metals dispersed in the rock matrix and to mobilization of Zn, Ni, Cu, Cd, Co, and Cr.
Źródło:
Przegląd Geologiczny; 2017, 65, 7; 450--458
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zmiany geochemiczne kwaśnych odcieków z kopalni Smolnik (Karpaty Zachodnie, Słowacja
Geochemical evolution of acid mine drainage quality at the locality of Smolnik (Western Carpathians, Slovakia)
Autorzy:
Slesarova, A.
Zeman, J.
Kusnierova, M.
Powiązania:
https://bibliotekanauki.pl/articles/319429.pdf
Data publikacji:
2006
Wydawca:
Polskie Towarzystwo Przeróbki Kopalin
Tematy:
kwaśny odciek z kopalni
metale ciężkie
trendy zmian
procesy geochemiczne
acid mine drainage
heavy metals
evolution trend
geochemical processes
Opis:
Kwaśne odcieki z kopalń (AMD) są zaliczane do największych zagrożeń środowiskowych. Powstają one w wyniku naturalnego utleniania minerałów siarczkowych - głównie pirytu - narażonych na równoczesne działanie wody i tlenu, i negatywnie wpływają na ekologię środowiska wodnego. Artykuł przedstawia wyniki monitoringu odwadniania kopalni Smolnik od roku 1986 do 2004 oraz analizę zjawisk geochemicznych występujących w trakcie odwadniania.
Acid mine drainage is considered among the worst environmental problems associated with mining activity. AMD originates as a result of the natural oxidation of sulphide minerals, mainly pyrite when exposed to the combined action of water and oxygen and negative affects the whole ecology of aquatic environment. The article presents the results of the monitoring of acid mine drainage quality's evolution at the locality of Smolnik from year 1986 till 2004 and the assumed geochemical processes occurred within the generation of acid mine drainage.
Źródło:
Inżynieria Mineralna; 2006, R. 7, nr 2, 2; 37-41
1640-4920
Pojawia się w:
Inżynieria Mineralna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Treatment of Acid Mine Drainage in a Bioelectrochemical System, Based on an Anodic Microbial Sulfate Reduction
Autorzy:
Angelov, Anatoliy
Bratkova, Svetlana
Ivanov, Rosen
Velichkova, Polina
Powiązania:
https://bibliotekanauki.pl/articles/27323817.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
BES
bioelectrochemical system
MFC
microbial fuel cell
MEC
microbial electrolysis cell
ethanol stillage
microbial sulfate reduction
acid mine drainage
heavy metals
sulphate
Opis:
The possibilities of simultaneous removal of sulfates and heavy metals (Cu, Ni, Zn) from acid mine drainage have been investigated in two-section bioelectrochemical system (BES). The used BES is based on the microbial sulfate reduction (MSR) process in the anode zone and abiotic reduction processes in the cathodic zone. In the present study, the model acid mine drainage with high sulfate (around 4.5 g/l) and heavy metals (Cu2+, Ni2+ and Zn2+) content was performed. As a separator in the laboratory, BES used an anionic exchange membrane (AEM), and for electron donor in the process of microbial sulfate reduction in the bioanode zone – waste ethanol stillage from the distillery industry was employed. In this study, the possibility of sulfates removal from the cathodic zone was established by their forced migration through AEM to the anode zone. Simultaneously, as a result of the MSR process, the sulfate ions passed through AEM are reduced to H2S in the anode zone. The produced H2S, having its role as a mediator in electron transfer, is oxidized on the anode surface to S0 and other forms of sulfur. The applicability of waste ethanol stillage as a cheap and affordable organic substrate for the MSR process has also been established. Heavy metals (Cu2+, Ni2+ and Zn2+) occur in the cathode chamber of BES in different degrees of the removal. As a microbial fuel cell (MFC) operating for 120 hours, the reduction rate of Cu2+ reaches 94.6% (in waste ethanol stillage) and 98.6% (in the case of Postgate culture medium). On the other hand, in terms of Ni2+ and Zn2+, no significant decrease in their concentrations in the liquid phase is found. In the case of microbial electrolysis cell (MEC) mode reduction of Cu2+– 99.9%, Ni2+– 65.9% and Zn2+– 64.0% was achieved. For 96 hours, the removal of sulfates in MEC mode reached 69.9% in comparison with MFC mode – 35.2%.
Źródło:
Journal of Ecological Engineering; 2023, 24, 7; 175--186
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Treatment of acid drainage in a uranium deposit by means of a natural wetland
Autorzy:
Groudeva, V.
Groudev, S.
Stoyanova, A.
Powiązania:
https://bibliotekanauki.pl/articles/147283.pdf
Data publikacji:
2004
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
acid mine drainage
bioremediation
natural wetland
uranium
water cleanup
Opis:
Abstract Acid drainage waters generated in the uranium deposit G-1, Western Bulgaria, were treated by means of a natural wetland located in the deposit. The waters had a pH in the range of about 2.4 3.9 and contained uranium and radium radionuclides, heavy metals (copper, zinc, cadmium, iron, manganese), arsenic and sulphates in concentrations usually much higher than the relevant permissible levels for waters intended for use in the agriculture and/or industry. The wetland was characterized by abundant and emergent vegetation and a diverse microflora. Typha latifolia, Typha angustifolia and Phragmites australis were the main plant species in the wetland but representatives of the genera Scirpus, Juncus, Eleocharis, Potamogeton, Carex and Poa as well as different algae were also present. The water flow through the wetland varied in the range at about 0.2 1.2 l/s reflecting water residence times in the wetland of about 10 50 hours. An efficient water cleanup took place in the wetland, even during the cold winter months at ambient temperatures close to 0°C. The removal of pollutants was due to different processes but the microbial dissimilatory sulphate reduction and the sorption of pollutants on organic matter (living and dead plant and microbial biomass) and clays present in the wetland played the main role.
Źródło:
Nukleonika; 2004, 49,suppl.1; 17-20
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Forming of Acid Mine Drainage Based on Characteristics of Coal Mining, East Kalimantan, Indonesia
Autorzy:
Widayati Amy, Sri
Dani, Umar
Nu'man, Harits
Muslim, Dicky
Nasruddin, Dudi
Nuryahya, Himawan
Nurhasan, Rully
Agustin, Daryl Sarah
Powiązania:
https://bibliotekanauki.pl/articles/27323828.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
coal
sulfur
acid mine drainage
NAPP
net acid production potential
Opis:
As one of the world’s coal producers, Indonesia continues to increase its coal production. The purpose of this study is to identify and analyze the characteristics of coal that has the potential to produce acid mine drainage. The research method is coal mapping and zoning based on formation, observation, and description of coal characteristics, coal sampling, ultimate and proximate testing, and analysis. The results of the study describe the characteristics of coal related to distribution in the early stages of evaluating the potential for acid mine formation, besides that it can be used as a basis for classifying the potential for acid mine drainage which has a high enough total sulfur based on the results of testing on 15 samples. To prevent the reaction to acid mine drainage, it can be based on the geochemical characteristics of coal by constructing a mine reservoir or making water drainage in a mine that is not close to the stockpile, because there is a possibility that water has the potential to form acid mine drainage (AMD) when it comes in contact with coal potential. So that coal does not have the potential to be a source of acid mine drainage.
Źródło:
Journal of Ecological Engineering; 2023, 24, 7; 301--310
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of electro-activation and eggshell powder on the neutralization of acid mine drainage
Autorzy:
Kastyuchik, A.
Karam, A.
Aïder, M.
Powiązania:
https://bibliotekanauki.pl/articles/91971.pdf
Data publikacji:
2017
Wydawca:
Główny Instytut Górnictwa
Tematy:
acid mine drainage
electro-activation
neutralization
effectiveness
kwaśny odciek kopalniany
elektroaktywacja
neutralizacja
skuteczność
Opis:
Acid mine drainage (AMD) production by sulfide mine tailing (SMT) is a major environmental preoccupation because it can degrade water surface quality on account of its strong acidity and advanced content of sulfide, iron (Fe) and other metals and metalloids. Acid neutralization and the precipitation of metals present in AMD were carried out by electro-activation with ion-exchange membranes, which is based on the self-generation of necessary conditions for acid neutralization and metal precipitation. The treatment of SMT was carried out by using an electro-activation cell generated alkaline solution in the cathode compartment. After 60 min of electro-activation, a pHcatholyte of 7.9-9.6, depending on the experimental conditions, was obtained. The absence of Fe and other trace metal ions in the catholyte provide evidence that the electro-activation of SMT promotes the precipitation of insoluble trace metals in the cathode compartment. This approach can be applied to real conditions in combination with a pretreatment of SMT neutralization, inwhich biological calcareous amendments are available. Finally, the electro-activation technology of acid mine drainage may be a feasible, cost-effective approach for SMT neutralization because it focuses on sustainable development.
Źródło:
Journal of Sustainable Mining; 2017, 16, 3; 73-82
2300-1364
2300-3960
Pojawia się w:
Journal of Sustainable Mining
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The 1st Conference on Contemporary Problems of Geochemistry
Autorzy:
Migaszewski, Zdzisław M.
Gałuszka, Agnieszka
Powiązania:
https://bibliotekanauki.pl/articles/2086497.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
acid mine drainage
pollution sources
acid precipitation
natural disasters
Opis:
This issue of “Mineralogy” includes selected papers based on some oral and poster presentations of the 1st Geochemical Conference on “Contemporary Problems of Geochemistry” organized by the Geochemical Group of the Mineralogical Society of Poland and Jan Kochanowski University in Kielce. The conference was held at the Institute of Chemistry of Jan Kochanowski University in Kielce on 27–30 September 2010.
Źródło:
Mineralogia; 2011, 42, 1; 3--5
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The 1st Conference on Contemporary Problems of Geochemistry
Autorzy:
Migaszewski, Z. M.
Gałuszka, A.
Powiązania:
https://bibliotekanauki.pl/articles/2086533.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
acid mine drainage
pollution sources
acid precipitation
natural disasters
Opis:
This issue of “Mineralogy” includes selected papers based on some oral and poster presentations of the 1st Geochemical Conference on “Contemporary Problems of Geochemistry” organized by the Geochemical Group of the Mineralogical Society of Poland and Jan Kochanowski University in Kielce. The conference was held at the Institute of Chemistry of Jan Kochanowski University in Kielce on 27–30 September 2010.
Źródło:
Mineralogia; 2011, 42, 1; 3--5
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Technogenic Impact of Sulphide-Containing Wastes Produced by Ore Mining and Processing at the Ozernoe Deposit: Investigation and Forecast
Autorzy:
Pashkevich, M. A.
Petrova, T. A.
Powiązania:
https://bibliotekanauki.pl/articles/124645.pdf
Data publikacji:
2017
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
dumps of sulphide-containing wastes
adverse impact
environmental hazard
acid mine drainage
express-method of acid indication
Opis:
The paper provides an assessment of the potential technogenic impact of sulphide-containing wastes produced by ore extraction and processing at the Ozernoe deposit, which is currently at the initial stage of mining. The analysed averaged samples of ore and wastes of mining and processing were obtained in the course of semi-industrial experimental preproduction. The results of monitoring studies in the area of sulphide-containing dumps formed at an exploring mine in the 1960s were used for assessing a potential hazard of the wastes. The origin of acid mine drainage is described. Advantages and shortcomings of tests assessing acid mine drainage are considered. The used express-method of acid indication allows to reliably determine the risk of acid mine drainage by the values of acidic and neutralising potentials formed by rocks. An estimation of acid mine drainage formation and heavy metal migration is carried out at dumps of the exploring mine. The forecast of environmental impact is given for the future wastes of mining and processing at the Ozernoe deposit.
Źródło:
Journal of Ecological Engineering; 2017, 18, 6; 127-133
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of Manganese Removal in the Process of Mine Water Remediation
Badanie usuwania manganu w procesie rekultywacji wód kopalnianych
Autorzy:
Macingova, E.
Ubaldini, S.
Luptakova, A.
Powiązania:
https://bibliotekanauki.pl/articles/317987.pdf
Data publikacji:
2016
Wydawca:
Polskie Towarzystwo Przeróbki Kopalin
Tematy:
drenaż kwaśnych wód kopalnianych
usuwanie manganu
strącanie tlenowe
elektroliza
acid mine drainage
manganese removal
oxidative precipitation
electrowinning
Opis:
In this work a comparative study of manganese removal from pre-treated acid mine drainage is described. Manganese removal by three ways was realized. At the first method sodium hydroxide was added to raise pH of processed AMD to the 9.5 to promote the abiotic oxidation of soluble divalent species to insoluble form of manganese. Potassium permanganate was used at pH near neutrality for elimination of manganese from AMD by oxidative precipitation in the second process. A third method, as electrowinning, was applied, finalized to the anodic Mn recovery under MnO2 form. The results showed that the three methods are effective and manganese were removed from acid mine drainage for values that comply with environmental requirements. However, when sodium hydroxide was used as reagent, coprecipitation of manganese and magnesium present in AMD was observed. In the second experiment enhanced selectivity of the process and purity of obtained precipitates were achieved. In the process of electrowinning – over 95% of Mn removal under MnO2 form, with a high degree of purity (about 99%) was attained.
W pracy tej opisano porównawcze badanie usuwania manganu z przygotowanego drenażu kwaśnych wód kopalnianych. Usuwanie manganu odbyło się na trzy sposoby. Po pierwsze, dodano wodorotlenek sodu aby podnieść pH przerabianego AMD do 9.5 aby spowodować abiotyczne utlenianie rozpuszczalnych dwuwartościowych gatunków do nierozpuszczalnej formy manganu. Nadmanganian potasu zastosowano przy pH bliskim poziomu neutralnego aby wyeliminować mangan z kwaśnych wód kopalnianych poprzez tlenowe strącanie w drugiej metodzie. Trzecia metoda, jako elektrolityczna, została zastosowana do anodowego odzysku Mn w formie MnO2. Wyniki wskazały, że trzy metody są efektywne i mangan został usunięty z drenażu kwaśnych wód kopalnianych w ilościach porównywalnych z wymaganiami środowiskowymi. Jednakże, przy zastosowaniu wodorotlenku sodu zaobserwowano wzajemne strącanie manganu i magnezu obecnego w kwaśnych wodach kopalnianych. W drugim eksperymencie zwiększona została selektywność procesu i czystość otrzymanych substancji. W procesie elektrolitycznym – ponad 95% Mn zostało usuniętych w postaci MnO2, przy dużym stopniu czystości (około 99%).
Źródło:
Inżynieria Mineralna; 2016, R. 17, nr 1, 1; 121-127
1640-4920
Pojawia się w:
Inżynieria Mineralna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Schwertmannite precipitated from acid mine drainage in theWestern Sudetes (SW Poland) and its arsenate sorption capacity
Autorzy:
Parafiniuk, J.
Siuda, R.
Powiązania:
https://bibliotekanauki.pl/articles/2059129.pdf
Data publikacji:
2006
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Western Sudetes
schwertmannite
ochre
acid mine drainage
arsenate sorption
Opis:
This paper contains XRD, Mössbauer and IR spectroscopy, chemical composition and thermal analysis results for the mineral schwertmannite present in the weathering zone developed in two abandoned sulphide mines in the Sudetes (SW Poland). In Wieściszowice a pyrite deposit was exploited, and in Radzimowice the deposit consisted of polymetallic mineralization with predominant arsenopyrite. In both localizations schwertmannite is developed as dripstones in underground workings and loose sediments precipitating from the acid mine drainage (AMD) waters. Schwertmannite forms tiny, needle-like crystals 2–3 m in size, usually grouped in botryoidal aggregations. The chemical composition of schwertmannite from Wieściszowice is typical for this mineral, and in Radzimowice the mineral contains up to 5.20 wt. % of As2O5. Due to highly developed specific surface and structural features, schwertmannite has the strongest sorption capabilities among the components of ochres, and takes up the largest amounts of arsenate oxyanion fromAMD, as well as considerable amounts of phosphates and heavymetals. About 71-87% of arsenate is sorbed on to the surface of the schwertmannite crystals and may readily be released into solution, 12–30% is bound into the structure of the mineral, and about 1% is an admixture of insoluble ferric arsenates.
Źródło:
Geological Quarterly; 2006, 50, 4; 475-486
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Removal of lead ions from acid aqueous solutions and acid mine drainage using zeolite bearing tuff
Autorzy:
Zendelska, A.
Golomeova, M.
Golomeov, B.
Krstev, B.
Powiązania:
https://bibliotekanauki.pl/articles/204844.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
adsorption
acid mine drainage
zeolite bearing tuff
lead ions
equilibrium studies
Sasa mine
Opis:
The adsorption of lead ions onto a zeolite bearing tuff (stilbite) from synthetic acid aqueous solution and acid mine drainage taken from Sasa mine, Macedonia, is elaborated in this paper. The results present that adsorption occurs efficiently in both of cases. The physical and chemical properties of the used natural material, zeolite bearing tuff, are characterized by X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy. The concentration of metal ions in solution before and after treatment is obtained by AES-ICP. The effectivity of zeolite bearing tuff is determined through a series of experiments under batch conditions from single ion solutions, whereby the main parameters are the effects of initial pH of solution, mass of adsorbent, initial metal concentration in solution, contacting time and competing cations. The maximum capacity of zeolite bearing tuff for removal of lead ions from solution is determined by equilibrium studies. The experimental obtained data are fitted with Freundlich and Langmuir adsorption models. The experimental data are better fitted with Langmuir adsorption isotherm. Zeolite bearing tuff is effective adsorbent for treating acid mine drainage. The results showed that 99% of lead ions are removed from acid mine drainage, i.e. the concentration of lead ions from 0.329 mg/dm3 decrease to 0.002 mg/dm3. The pH value of acid mine drainage from 3.90 after treatment with zeolite bearing tuff increases to 5.36.
Źródło:
Archives of Environmental Protection; 2018, 44, 1; 87-96
2083-4772
2083-4810
Pojawia się w:
Archives of Environmental Protection
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Removal of heavy metals from groundwater affected by acid mine drainage
Autorzy:
Suponik, T.
Blanco, M.
Powiązania:
https://bibliotekanauki.pl/articles/110087.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
coal mine waste dumps
acid mine drainage
groundwater
PRB technology
metals
zero-valent iron
Opis:
Batch tests have been used to assess the level of the removal of metals (copper, nickel, cobalt, zinc, and chromium, in cationic and in anionic forms) from water at low pH values affected by acid mine drainage. The predominant processes which result in the removal with the use of zero-valent iron (Fe0) in Permeable Reactive Barrier Technology were evaluated. The most probable processes for each metal have been presented in drawings. There are: reductive precipitation leading to the metallic form, co-precipitation mainly with iron in the form of oxides and/or hydroxides and adsorption on the surface of iron corrosion products or on the surface of zero-valent iron.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 1; 359-372
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Recovery of Iron from Acid Mine Drainage in the Form of Oxides
Odzyskiwanie żelaza w formie tlenków z kwaśnego drenowania kopalni
Autorzy:
Macingova, E.
Luptakova, A.
Powiązania:
https://bibliotekanauki.pl/articles/318248.pdf
Data publikacji:
2014
Wydawca:
Polskie Towarzystwo Przeróbki Kopalin
Tematy:
acid mine drainage
iron oxide recovery
structural and mineralogical analysis
kwaśny odciek kopalniany
odzysk tlenku żelaza
analiza strukturalna i mineralogiczna
Opis:
Acid mine drainage (AMD) typical by low pH, high concentration of sulphates and different heavy metals is one of the major sources of environmental damage in mining industry. Treatment methods to address AMD are focused on neutralizing, stabilizing and removing pollutants through various physical, chemical and biological processes. However this type of mining influenced water should be considered not only as serious environmental problem, but also as an important resource due to the universal high metal demand and ambition of potential reuse of metals recovered from AMD. The aim of this work was to recovery of iron in the form of oxides from AMD drained from enclosed and flooded Smolnik sulphidic deposit (Slovakia). The iron was removed from AMD in two steps to very low levels that meet required water quality criteria. The ferrous iron present in AMD was oxidized using hydrogen peroxide. In this stage decreasing of pH value and partial iron precipitation were observed. The follow neutralization using sodium hydroxide resulted in total iron removing by precipitation. The obtained solids were identified as a schwetmannite. The iron oxides were produced by thermal decomposition of precipitates. The morphology of acquired intermediates was studied by cryo-scanning electron microscopy (cryo-SEM) and the Fourier transform infrared spectroscopy (FTIR) was applied to characterization of their composition. Energy dispersive X-ray spectroscopy (EDX) was used for qualitative and quantitative analysis of intermediates and products. The X-ray powder diffraction (XRPD) was performed for the mineralogical analysis of the iron precipitates before and after the differential (DTA) and thermogravimetric (DTG) experiment.
Kwaśne drenowanie kopalni (AMD – Acid Mine Drainage) typowe dla niskiego pH, wysokiego stężenia siarczanów i innych metali ciężkich jest jednym z głównych źródeł szkód środowiskowych w przemyśle wydobywczym. Metody obróbki adresowane dla AMD są skupione na neutralizowaniu, stabilizacji i usuwaniu zanieczyszczeń za pomocą różnych procesów fizycznych, chemicznych i biologicznych. Jednakże ten typ wydobycia, który wpływa niekorzystnie na wodę powinien być uważany nie tylko za poważny problem środowiskowy, a także za ważne źródło zasobów, w związku z powszechnym zapotrzebowaniem na metale i ambicję do potencjalnego powtórnego użycia metali odzyskanych z AMD. Celem tej pracy jest odzysk żelaza w formie tlenków z AMD z zamkniętego i zalanego depozytu Smolniksulphidic (Słowacja). Żelazo zostało usunięte z AMD w dwóch krokach, aż do uzyskania bardzo niskiego poziomu aby zaspokoić kryteria jakości wody. Żelazo (II) obecne w AMD zostało utlenione z użyciem nadtlenku wodoru. Na tym etapie zaobserwowano malejącą wartość pH i częściowe wytrącanie się żelaza. Następująca później neutralizacja z użyciem wodorotlenku sodu skutkowała całkowitym usunięciem żelaza w skutek wytrącania. Uzyskane ciała stałe zostały zidentyfikowane jako schwetmannit. Tlenki żelaza zostały wytworzone w procesie rozkładu termicznego wytrąconego osadu. Morfologia uzyskanych półproduktów została zbadania za pomocą krio-skaningowego mikroskopu elektronowego (krio-SEM) oraz w celu zbadania ich składu zastosowana została spektroskopia w podczerwieni z transformatą Fouriera (FTIR). Spektroskopia z dyspersją energii promieniowania rentgenowskiego (EDX) została zastosowana w analizie jakościowej i ilościowej półproduktów i produktów. Dyfrakcja proszkowa promieniowania rentgenowskiego została użyta do analizy mineralogicznej osadów żelaza przed i po eksperymentach różnicowych (DTA) i termo grawimetrycznych (DTG).
Źródło:
Inżynieria Mineralna; 2014, R. 15, nr 2, 2; 193-198
1640-4920
Pojawia się w:
Inżynieria Mineralna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pyrite oxidation inhibition by hydrophobic films for acid mine drainage control at the source
Autorzy:
Wang, Shuncai
Zhao, Yue
Li, Shuang
Powiązania:
https://bibliotekanauki.pl/articles/110200.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
hydrophobic film
pyrite
suppression
linoleic acid
acid mine drainage
Opis:
Acid mine drainage (AMD), which is also known as acid rock drainage (ARD), can cause serious environmental pollution, especially for surrounding aquatic and terrestrial ecosystems due toits low pH, high metal and sulfate concentration. Acid mine drainage is an urgent environmental problem for the worldwide ore mining industry. In this paper, we demonstrated that hydrophobic films can inhibit the oxidation of pyrite-bearing tailings to achieve the control of at-source AMD. The results of chemical leaching testing showed that the hydrophobic films formed by linoleic acid can suppress the oxidation of pyrite-bearing tailings and reduce the AMD production. In addition, the presence of hydrophobic films of linoleic acid on the surface of pyrite-bearing tailings was confirmed by the results from Fourier transform infrared (FTIR) analyses and scanning electron microscopy with energy dispersive spectrometry (SEM / EDS).
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 5; 1132-1140
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 40

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