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Wyświetlanie 1-10 z 10
Tytuł:
Effects of $TiO_2$ Source on the Electrochemical Performance of $Li_4Ti_5O_{12}$
Autorzy:
Kiliç Dokan, F.
Şahan, H.
Özdemır, N.
Özdemır, B.
Patat, Ş.
Powiązania:
https://bibliotekanauki.pl/articles/1311661.pdf
Data publikacji:
2014-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
88.80.ff
Opis:
This study examined the formation mechanism of $Li_4Ti_5O_{12}$ by a ball mill assisted solid-state reaction between $Li_2CO_3$ and $TiO_2$ for applications in lithium ion batteries, also effects of $TiO_2$ source such as rutile type and anatase type on the electrochemical performance of $Li_{4}Ti_5O_{12}$. However, it is believed that the particle properties may depend significantly on the synthesis process and starting materials, which lead to final products with a range of sizes, morphologies, and even phases.
Źródło:
Acta Physica Polonica A; 2014, 125, 2; 650-651
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Characterization of Spinel $Li_4Ti_5O_{12}$ Anode Material by CTAB Assisted Sol-Gel Method
Autorzy:
Kiliç Dokan, F.
Şahan, H.
Özdemır, B.
Özdemır, N.
Patat, Ş.
Powiązania:
https://bibliotekanauki.pl/articles/1293936.pdf
Data publikacji:
2014-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
88.80.ff
Opis:
Recently, there has been considerable interest in $Li_4Ti_5O_{12}$ as a potential anode for use in lithium ion batteries. It has many advantages compared to the currently used graphite. It has a good reversibility but no structural change. The material has a theoretical specific capacity of 175 mAh $g^{-1}$. $Li_4Ti_5O_{12}$ powders are usually synthesized by a solid-state reaction of lithium and titanium salts. This method was generally preferred because the synthesis procedures are simple. But there are some disadvantages of solid-state methods such as larger particle size of the products, inhomogeneous distribution, lack of stoichiometry control, etc. These disadvantages can be overcome by sol-gel method. Using surfactant in sol-gel method is easy control on crystal growth and size of the desired products.
Źródło:
Acta Physica Polonica A; 2014, 125, 2; 648-649
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of Multiple Cation (Al, Si, Ti, Co) Doping on Electrochemical Performance οf $LiMn_2O_4$ Cathode Active Material
Autorzy:
Kılıç Dokan, F.
Şahan, H.
Veziroğlu, S.
Akkuş Taş, N.
Aydın, A.
Patat, Ş.
Powiązania:
https://bibliotekanauki.pl/articles/1399894.pdf
Data publikacji:
2013-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
88.80.ff
Opis:
In order to improve the cycling performance of $LiMn_2O_4$, the spinel phases base and multiple cation doped $LiMn_{1.95}Al_{0.0125}Si_{0.0125}Ti_{0.0125}Co_{0.0125}O_4$, $LiMn_{1.9}Al_{0.025}Si_{0.025}Ti_{0.025}Co_{0.025}O_4$ spinels were synthesized by the glycine-nitrate combustion process. The structures of the products were investigated by X-ray diffraction, scanning electron microscopy and electrochemical tests.
Źródło:
Acta Physica Polonica A; 2013, 123, 2; 365-367
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Improvement of Cycling Stability of $LiMn_2O_4$ Cathode by $Al_2O_3$ Surface Coating for Li-Ion Batteries
Autorzy:
Şahan, H.
Göktepe, H.
Kılıç Dokan, F.
Aydın, A.
Veziroğlu, S.
Patat, Ş.
Powiązania:
https://bibliotekanauki.pl/articles/1399895.pdf
Data publikacji:
2013-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
88.80.ff
Opis:
The effect of the $Al_2O_3$ coating on the charge-discharge cycling performance of spinel powder ($LiMn_2O_4$) was investigated in the range of 3.5-4.5 V at 1C. The $Al_2O_3$ coating on the surface of the spinel powder was carried out using the solution method, followed by 500C for 6 h in air. Powder X-ray diffraction pattern of the $Al_2O_3$-coated spinel $LiMn_2O_4$ showed that the $Al_2O_3$ coating medium was not incorporated in the spinel bulk structure. Scanning electron microscopy results showed that the $Al_2O_3$ coating particles were homogeneously distributed on the surface of $LiMn_2O_4$ powder particles. The $Al_2O_3$-coated $LiMn_2O_4$ retained 92.3% of its original capacity after 30 cycles, showing much better cycle ability than the bare lithium manganese oxide. The improvement of electrochemical performance is attributed to suppression of $Mn^{2+}$ dissolution into electrolyte via $Al_2O_3$ layer.
Źródło:
Acta Physica Polonica A; 2013, 123, 2; 368-370
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sol-Gel Synthesis of Nanocomposite $Cu-Li_4Ti_5O_{12}$ Structures for Ultrahigh Rate Li-Ion Batteries
Autorzy:
Erdas, A.
Ozcan, S.
Guler, M.
Akbulut, H.
Powiązania:
https://bibliotekanauki.pl/articles/1401274.pdf
Data publikacji:
2015-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.47.Aa
88.80.ff
Opis:
In this study, spinel $Li_4Ti_5O_{12}$ materials were successfully synthesized by a simple and facile sol-gel process and electroless copper deposition techniques. The characteristics of the as-prepared $Li_4Ti_5O_{12}$ and $Cu-Li_4Ti_5O_{12}$ were examined by X-ray diffraction and scanning electronic microscopy, while the electrochemical performances including charge/discharge and rate performance tests were also investigated. $Cu-Li_4Ti_5O_{12}$ electrode demonstrated the superior initial discharge capacity and rate capability to $Li_4Ti_5O_{12}$ electrode, cycled between 1.0 and 2.5 V. The enhanced rate capability can be attributed to the higher $Li^{+}$ diffusivity and lower charge-transfer resistance due to the electroless deposition of copper. Moreover, when both electrodes discharged with 80 C state of discharge conditions, the reversible capacities were further increased ım70 mAh $g^{-1}$ with excellent cycling stability and almost no irreversible capability was observed during cycling.
Źródło:
Acta Physica Polonica A; 2015, 127, 4; 1026-1028
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Evaluation of Li-Air Batteries With EC-DEC Based Nanocomposite Electrolytes
Autorzy:
Akbulut, A.
Guler, M.
Cetinkaya, T.
Uysal, M.
Akbulut, H.
Powiązania:
https://bibliotekanauki.pl/articles/1401250.pdf
Data publikacji:
2015-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.45.Gj
88.80.ff
82.45.Xy
Opis:
Electrolytes based on organic carbonate solvents of ethylene carbonate (EC) and diethyl carbonate (DEC) were prepared by using LiPF₆ as the Li-source. Nano sized Al₂O₃ (50 nm) was used as a reinforcing component in order to control corrosion and Li₂CO₃ formation. Corrosion of the Li foil anode and electrochemical tests were performed by using EC/DEC/LiPF₆ and nanocomposite EC/DEC/LiPF₆/5wt.% Al₂O₃ electrolytes. Electrochemical tests were performed in the swagelok cells by using Li foil anode and carbon air cathode electrodes. Structural tests were carried out by using scanning electron microscopy (SEM), x-ray diffraction (XRD) and Raman spectroscopy. Results revealed that incorporation of nano Al₂O₃ leads to a decrease of corrosion rate of Li anode and a small decrease in the capacity of the air cells.
Źródło:
Acta Physica Polonica A; 2015, 127, 4; 1023-1025
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Electrochemical Properties of Cu Coated $LiCr_{0.2}V_{0.2}Mn_{0.6}O_2$ Nanocomposites for High Rate Li-Ion Batteries
Autorzy:
Algul, H.
Erdas, A.
Tokur, M.
Guler, M.
Akbulut, H.
Alp, A.
Powiązania:
https://bibliotekanauki.pl/articles/1401278.pdf
Data publikacji:
2015-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.47.Aa
81.15.-z
88.80.ff
Opis:
Several reported problems of commercial LiCoO₂ electrode materials such as high cost, toxicity, limited rate capability and safety concerns are still remain to be problematic to develop the lithium ion consumer electronics such as mobile phones, tablets and notebook computers. In this study, an alternative nanocomposite electrode material based on $LiCr_{0.2}V_{0.2}Mn_{0.6}O_2$ and copper coated one were produced via a facile sol-gel method and electroless Cu deposition techniques. The resulting samples were characterized by X-ray diffraction (Rigaku DMax 2200 diffractometer) using a monochromatized Cu-Kα source (λ=1.5406 Å) and 2θ scan range from 10° to 80° with a speed of 1° $\text{min}^{-1}$. The scanning electron microscope (SEM) was used in order to characterize the morphology of the active materials. The as-synthesized $Cu//LiCr_{0.2}V_{0.2}Mn_{0.6}O_2$ composite cathode exhibits a stable capacity on cycling and good rate capability after 50 cycles and total capacity retention of 93% is obtained. The unique 2D structure of the composite cathode material, its good electrochemical performances and its relatively low cost comparing to LiCoO₂, make this material very promising for applications.
Źródło:
Acta Physica Polonica A; 2015, 127, 4; 1038-1041
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electrical Conductivity, Viscosity and Thermal Properties of TEGDME-Based Composite Electrolytes for Lithium-Air Batteries
Autorzy:
Kartal, M.
Alp, A.
Akbulut, H.
Powiązania:
https://bibliotekanauki.pl/articles/1398791.pdf
Data publikacji:
2016-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
88.80.F-
88.80.ff
82.45.Gj
82.45.Wx
81.07.-b
Opis:
Some important properties of the electrolytes used in Li-air batteries were investigated. Electrolyte composed of a solution of 1 M LiPF₆ in tetra ethylene glycol dimethyl ether (TEGDME) was reinforced with SiO₂, Al₂O₃, poly(ethylene) oxide (PEO) and tris (pentafluorophenyl) borane (TPFPB) additives. The effects of these reinforcements on conductivity, viscosity and thermal stability were investigated. Electrical conductivity tests were carried out using a multiparameter meter. Viscosity tests were performed in a viscometer using tuning-fork vibration method. Thermal stability of the electrolytes was tested by both TG and DSC.
Źródło:
Acta Physica Polonica A; 2016, 129, 4; 816-818
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of Inorganic Nano Powder Additives in TEGDME for Lithium Air Batteries
Autorzy:
Kartal, M.
Uysal, M.
Cetinkaya, T.
Alp, A.
Akbulut, H.
Powiązania:
https://bibliotekanauki.pl/articles/1401233.pdf
Data publikacji:
2015-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
88.80.F-
88.80.ff
82.45.Gj
82.45.Wx
81.07.-b
Opis:
SiO₂ and Al₂O₃ nano fillers were added to an electrolyte composed of a solution 1 M LiPF₆ in tetra ethylene glycol dimethyl ether (TEGDME) and the effects of these nano powders on capacity and cycling performances were investigated. Galvanostatic charge/discharge (GC) measurements were performed in the assembled Li-air cells by using the nanocomposite electrolytes. The discharge capacities of these cells were cyclically tested by a battery tester at a constant current in the voltage range between 2.15 V and 4.25 V. Discharge products of nanocomposite electrolytes were characterized by SEM and XRD spectroscopies. The electrochemical results demonstrated that Al₂O₃ reinforced electrolyte showed higher discharge capacity and cyclability than those of SiO₂ reinforced electrolyte.
Źródło:
Acta Physica Polonica A; 2015, 127, 4; 1016-1018
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ion Beam Formation of Electrocatalysts for Direct Methanol and Ethanol Fuel Cells on the Basis of Carbon Catalyst Supports
Autorzy:
Poplavsky, V.
Dorozhko, A.
Luhin, V.
Matys, V.
Zukowski, P.
Czarnacka, K.
Powiązania:
https://bibliotekanauki.pl/articles/1033764.pdf
Data publikacji:
2017-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
68.37.Hk
81.15.Jj
81.05.U-
82.45.Jn
82.80.Fk
82.80.Yc
88.20.ff
88.30.pd
88.30.pf
Opis:
Ion-beam modification of materials whose service properties are mainly controlled by the surface composition is of especial interest, in particular, for electrocatalysts, namely electrodes of fuel cells - perspective chemical current sources. A catalyst is needed for effective operation of fuel cell. In this paper active layers of the electrocatalysts were prepared by ion beam assisted deposition of catalytic (platinum) and activating (cerium) metals onto carbon (AVCarb® Carbon Fiber Paper P50 and Toray Carbon Fiber Paper TGP-H-060 T) catalyst supports. Formation of layers by ion beam assisted deposition by means of the deposition of metal and mixing of precipitating layer with the substrate by accelerated ions of the same metal, was carried out. Metal deposition and mixing between the precipitable layer and surface of the substrate by accelerated (U=10 kV) ions of the same metal were conducted from a neutral vapor fraction and plasma of vacuum arc discharge of a pulsed electric arc ion source. Study of the morphology and composition of layers was carried out by the scanning electron microscopy, energy dispersive X-ray microanalysis, X-ray fluorescence analysis, and the Rutherford backscattering spectrometry methods. According to the investigations with the use of cyclic voltammetry, the electrocatalysts with the prepared layers exhibited catalytic activity in the reactions of electrochemical oxidation of methanol and ethanol, which form the basis for the principle of operation of low temperature direct methanol and direct ethanol fuel cells.
Źródło:
Acta Physica Polonica A; 2017, 132, 2; 278-282
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-10 z 10

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