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Wyświetlanie 1-5 z 5
Tytuł:
Interaction of Hydrogen with Vanadium Layers Preadsorbed on Tungsten Field Emitter Tip
Autorzy:
Błaszczyszyn, R.
Wachowicz, E.
Błaszczyszynowa, M.
Powiązania:
https://bibliotekanauki.pl/articles/1968928.pdf
Data publikacji:
1998-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
79.70.+q
82.65.My
Opis:
Interaction of hydrogen with vanadium layers preadsorbed on a thermally cleaned tungsten field emitter was studied at room temperature and 78 K through measurements of the total work function changes. An increase in the work function followed by its slight decrease at higher exposure can be understood taking into account the possibility of negatively (β$\text{}^{-}$) and positively (β$\text{}^{+}$) polarized adspecies formation on thin vanadium layer. This process leads to vanadium hydride formation. The work function results suggest that hydrogen diffusion into the vanadium layer is meaningful at room temperature. Thermal desorption of hydrogen adsorbate carried out within the temperature range 409-461 K from thin vanadium layer (Θ$\text{}_{V}$ = 40) provided a value of 127 ± 6 kJ/mol for the activation energy for desorption.
Źródło:
Acta Physica Polonica A; 1998, 93, 5-6; 763-773
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chemisorption Theory at Submonolayer Coverages: Influence of the Dynamic Hopping on the Electronic Characteristics
Autorzy:
Cardenas, R.
Taranko, E.
Taranko, R.
Fedyanin, V.
Powiązania:
https://bibliotekanauki.pl/articles/1891892.pdf
Data publikacji:
1991-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
73.20.-r
82.65.My
Opis:
The influence of the dynamic hopping term included in the Newns-Anderson Hamiltonian on the electronic structure of the chemisorbed layer at different coverages rates is investigated. It is shown that this additional interaction can destroy the initial symmetry of the Newns-Anderson model or restore this symmetry in the initial negative asymmetric case. The coverage dependence of the adatom electron charge is also studied for the case of hydrogen chemisorption on a model transition metal surface.
Źródło:
Acta Physica Polonica A; 1991, 80, 5; 731-743
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Determination of Submonolayer Coverages Using Auger Escape Depths
Autorzy:
Godowski, P. J.
Hardegree, E. L.
Powiązania:
https://bibliotekanauki.pl/articles/1931323.pdf
Data publikacji:
1994-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
79.20.Fv
68.10.Jy
82.65.My
Opis:
A simple method for determining submonolayer adsorbate coverages by means of Auger electron spectroscopy is presented. The procedure is based on the ratio of low to high kinetic energy Auger signals from the substrate alone, therefore it does not require a direct measurement of adsorbate peaks. It may be of special interest in cases where the adsorbate signal is difficult or impossible to measure, as well as when adsorbate and substrate peaks overlap or when peaks are absent (H or He) or of low intensity. The method is tested by quantification of sulphur layer on the Ni(001) and on the polycrystalline iron surface.
Źródło:
Acta Physica Polonica A; 1994, 85, 5; 843-848
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Progress into Understanding of Alkali Metal Interaction with a Silicon Surface
Autorzy:
Soukiassian, P.
Powiązania:
https://bibliotekanauki.pl/articles/1892155.pdf
Data publikacji:
1992-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
68.35.-p
73.20.At
79.60.Eq
82.65.My
Opis:
The atomic and electronic structure and interface formation of alkali metal (Na, K, Rb, Cs) and Si(100)2 × 1 surfaces is investigated by photoemission - XPS, UPS - using synchrotron radiation, scanning tunneling microscopy (STM) and by photoemission extended X-ray absorption fine structure (PEXAFS) experiments. The XPS-UPS results indicate that the alkali metal-silicon bond is a weak and polarized covalent bonding even at low coverages with adsorbate metallization at the monolayer. In contrast to III-V semiconductor surfaces, alkali metals do not induce significant structural changes of the surface: STM images performed with atomic resolution for the representative K/Si(100)2×1 systems demonstrate that, at one mono-layer coverage, the K atoms form one-dimensional linear metallic chains parallel to the Si dimers rows ⟨110⟩ direction and distant by 7.68 Å with a single site of adsorption. Below half a monolayer, the K atoms occupy various coexisting sites with no long range order. An ordering transition occurs around half a monolayer in which the adsorbate-adsorbate interaction, which was so far neglected in theoretical calculations, appears to be the leading driving force. The proposed models and concepts are discussed and compared to the latest state-of-art theoretical calculations.
Źródło:
Acta Physica Polonica A; 1992, 81, 1; 19-32
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chemisorption Isotherms for Ising Anderson Hamiltonian
Autorzy:
Taranko, E.
Cardenas, R.
Taranko, R.
Fedyanin, V. K.
Powiązania:
https://bibliotekanauki.pl/articles/1931807.pdf
Data publikacji:
1994-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
68.45.-v
82.65.My
Opis:
The adsorption isotherms for Ising-Anderson type model Hamiltonian describing the chemisorbed system was calculated. The submonolayer coverage of the substrate surface was considered on the equal footing together with the electronic characteristics of the chemisorbed adatoms in a self-consisting manner. The resulting adsorption isotherms depend in explicit way on the electronic parameters describing the chemisorbed adatoms and substrate metal.
Źródło:
Acta Physica Polonica A; 1994, 86, 6; 917-927
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-5 z 5

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