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Wyświetlanie 1-15 z 44
Tytuł:
Observation of Antioxidants Activity using NMR Relaxation Measurements
Autorzy:
Wierzuchowska, D.
Witek, M.
Blicharska, B.
Powiązania:
https://bibliotekanauki.pl/articles/1030645.pdf
Data publikacji:
2018-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.60.-k
76.90.+d
76.30.Rn
Opis:
Formation of free radicals in biological solutions leads to the changes in water protons relaxation times. Therefore, NMR relaxation measurements were used to investigate kinetics of oxidation processes induced by the addition, in low amounts, of hydrogen peroxide (H_2O_2) to aqueous protein solution and to blood serum. The measured relaxation times were not stable over time because of the progressive formation of free radicals and their damaging action to the protein structure. The addition of antioxidants (ascorbic acid, gallic acid etc.) changed the relaxation time courses due to free radical scavenging. Similar time courses, thus anti-oxidant actions, were observed in various blood serum without antioxidant additive. Moreover, the observed kinetics of spin-lattice relaxation time (T_1) depended on several factors, such as: structure and concentration of protein solutions and activity and concentration of the added antioxidants.
Źródło:
Acta Physica Polonica A; 2018, 133, 2; 289-291
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
SWR Studies of Higher-Order Surface Anisotropy Terms in (Ga,Mn)As Thin Films
Autorzy:
Puszkarski, H.
Tomczak, P.
Diep, H.
Powiązania:
https://bibliotekanauki.pl/articles/1030424.pdf
Data publikacji:
2018-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.50.Pp
76.50.+g
75.70.-i
75.30.Ds
76.60.-k
Opis:
We extend the theory of spin-wave resonance (SWR) by introducing a new formula representing the surface pinning parameter as a series of contributions from different anisotropies existing in (Ga,Mn)As thin films. Comparing our theory with the reported experimental studies of SWR in thin films of the ferromagnetic semiconductor (Ga,Mn)As, we find that besides the first-order cubic anisotropy, higher-order cubic anisotropies (in the second and third orders) as well as uniaxial anisotropies (perpendicular in the first and second orders, and in-plane diagonal) occur on the surface of this material. To our best knowledge this is the first report of the existence of higher-order surface anisotropy fields in (Ga,Mn)As thin films.
Źródło:
Acta Physica Polonica A; 2018, 133, 3; 635-638
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Stochastic Dynamics on the Nuclear Magnetic Resonance in a Field Gradient
Autorzy:
Tóthová, J.
Lisý, V.
Powiązania:
https://bibliotekanauki.pl/articles/1032635.pdf
Data publikacji:
2017-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.60.-k
76.60.Lz
05.40.-a
05.10.Gg
Opis:
In the present contribution, the attenuation function S(t) for an ensemble of spins in a magnetic-field gradient is calculated through an accumulation of the phase shifts in the rotating frame resulting from the changes of the particle displacements. The found S(t) is applicable for any kind of the stochastic motion of spins, including their non-Markovian dynamics with memory. Depending on the considered system, both the classical expressions valid for normal diffusion at long times and new formulae for the short-time Brownian motion can be obtained. Our method is also applicable to the NMR pulse sequences based on the refocusing principle. This is demonstrated by describing the spin echo experiment developed by Hahn.
Źródło:
Acta Physica Polonica A; 2017, 131, 4; 1111-1113
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Solid State ¹³C Nuclear Magnetic Resonance Study of Morphology and Molecular Mobility in Quenched Poly(3-hydroxybutyrate)
Autorzy:
Baran, A.
Vrábel, P.
Olčák, D.
Powiązania:
https://bibliotekanauki.pl/articles/1032243.pdf
Data publikacji:
2017-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.41.+e
81.05.Lg
76.60.-k
74.25.nj
Opis:
Single pulse magic angle spinning ¹³C NMR spectra and the carbon spin-lattice relaxation times T₁(¹³C) were used for the study of morphology and molecular mobility in poly(3-hydroxybutyrate) quenched in cold water after melting in a twin-screw extruder. The crystallinity of the quenched sample was found to be comparable with that of virgin material, and the decrease in dimensions of the crystallites grown after quenching was deduced from the single pulse magic angle spinning ¹³C NMR spectra. The spin-lattice relaxation curves for the carbons of the CO, CH, CH₂ and CH₃ groups were found to be bi-exponential, which enables the molecular mobility within crystalline and amorphous domains to be studied. The spin-lattice relaxation times T₁(¹³C) estimated for the carbons of the CO, CH, CH₂ groups show the chain mobility enhancement within crystalline domains of the quenched sample, but the influence of the quenching on the CH₃ group rotation and on the main chain motion within amorphous regions was not observed.
Źródło:
Acta Physica Polonica A; 2017, 131, 4; 1144-1146
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
NMR Relaxation Measurements as a Tool for Observation of Oxidative Processes
Autorzy:
Wierzuchowska, D.
Skórski, L.
Blicharska, B.
Powiązania:
https://bibliotekanauki.pl/articles/1398821.pdf
Data publikacji:
2016-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.60.-k
76.90.+d
76.30.Rn
Opis:
Water proton relaxation times, T₁ and T₂, were measured to assess the kinetics of the oxidative processes in biological samples. The oxidation in aqueous solutions of albumins was promoted by an addition of 3% hydrogen peroxide (H₂O₂). Immediately following this addition a sharp exponential decrease of both relaxation times was observed. As we confirmed experimentally, the time course of relaxation depended on several essential factors like structure and the concentration of proteins and also the presence of antioxidants added to solution. In experiments with protein solutions containing a small amount of ascorbic acid, after reaching a minimum, relaxation time increased towards the initial (pre-addition H₂O₂) values. We conclude that this T₁ and T₂ recovery is a consequence of the presence of antioxidants and may be used to evaluate its action. This study demonstrates that nuclear magnetic resonance (NMR) relaxation measurements may be useful in evaluating free radicals reactions and antioxidants capacity.
Źródło:
Acta Physica Polonica A; 2016, 129, 2; 226-228
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
NMR Study of Multiferroic Iron Niobate Perovskites
Autorzy:
Kouřil, K.
Chlan, V.
Štěpánková, H.
Řezníček, R.
Laguta, V.
Raevski, I.
Powiązania:
https://bibliotekanauki.pl/articles/1384854.pdf
Data publikacji:
2015-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.60.-k
76.60.Jx
75.10.Nr
75.85.+t
Opis:
We present $\text{}^{93}Nb$, $\text{}^{207}Pb$ and $\text{}^{135,137}Ba$ NMR study of multiferroic lead iron niobate and barium iron niobate ceramics. We ascribe development of NMR spectra on cooling below room temperature to magnetism of ferric ions close to resonating nuclei and introduce a framework capable of describing key features of the observed temperature induced changes. We show that the ferric ions have much stronger influence on hyperfine fields at nuclei of large cations in lead compound and estimate strength of interaction of superantiferromagnetic clusters.
Źródło:
Acta Physica Polonica A; 2015, 127, 2; 234-236
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nuclear Magnetic Resonance in Hexaferrite/Maghemite Composite Nanoparticles
Autorzy:
Křišťan, P.
Hondlík, O.
Štěpánková, H.
Chlan, V.
Kouřil, K.
Řezníček, R.
Pollert, E.
Veverka, P.
Powiązania:
https://bibliotekanauki.pl/articles/1386884.pdf
Data publikacji:
2015-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.60.-k
75.50.Gg
75.50.Tt
75.47.Lx
61.66.Fn
Opis:
Due to their bio-compatibility and non-toxicity, ferrimagnetic iron oxides are suitable for various medical applications. In the case of hyperthermia, the promising approach how to reach desired magnetic properties is to combine more phases into a composite material. A series of samples containing maghemite and M-hexaferrite was prepared by sol-gel method with subsequent thermal treatment where annealing temperature and time were varied. The samples were characterized by X-ray diffraction. In this paper we focused mainly on application of nuclear magnetic resonance spectroscopy to investigate these strongly inhomogeneous nanoparticle composites. Frequency-swept ⁵⁷Fe NMR spectra of nanoparticle samples were measured in a zero external magnetic field at 4.2 K. Utilizing differences in optimal excitation field strengths and in relaxation times, we were able to resolve NMR signal assigned to hexagonal ferrite of M-phase from signal which showed features attributed to maghemite.
Źródło:
Acta Physica Polonica A; 2015, 127, 2; 514-516
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Estimation of the Degree of Crystallinity of Partially Crystalline Polypropylenes Using $\text{}^{13}C$ NMR
Autorzy:
Hronský, V.
Koval'aková, M.
Vrábel, P.
Uhrínová, M.
Olčák, D.
Powiązania:
https://bibliotekanauki.pl/articles/1378162.pdf
Data publikacji:
2014-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.41.+e
76.60.-k
81.05.Lg
Opis:
The paper deals with a method for the estimation of the degree of crystallinity for partially-crystalline isotactic-polypropylenes (i-PP) using high-resolution solid-state $\text{}^{13}C$ NMR. For this purpose direct polarization $\text{}^{13}C$ MAS NMR spectra were measured for i-PP samples with different degrees of crystallinity at 98°C. The areas beneath the resonance lines in these spectra correspond to the number of carbons in particular functional groups, while the widths and shapes of the lines reflect the degree of crystallinity, crystalline modifications, distribution of chain conformations and the chain mobility. The $\text{}^{13}C$ MAS NMR spectra, measured using appropriate combination of delay time and high proton decoupling field, made it possible to detect only amorphous domains in the sample. This enabled identification of the lines associated with the amorphous domains in the complete $\text{}^{13}C$ MAS NMR spectra and provided sufficient information for reliable estimation of the degree of crystallinity. The heteronuclear Overhauser enhancement of the $\text{}^{13}C$ NMR signals due to short delay time was taken into account in our calculations.
Źródło:
Acta Physica Polonica A; 2014, 126, 1; 409-410
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Molecular Dynamics of Proteins Investigated by NMR Relaxation Methods
Autorzy:
Wierzuchowska, D.
Blicharska, B.
Powiązania:
https://bibliotekanauki.pl/articles/1360657.pdf
Data publikacji:
2014-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.60.-k
76.90.+d
Opis:
The nuclear magnetic resonance relaxation times of solvent water nuclei are known to decrease upon addition of diamagnetic solute protein. For this reason NMR relaxation methods are able to provide information on molecular dynamics changes of water protons and their interaction with macromolecules' surfaces. We present results of measurements of relaxation rates $R_1$ = 1/$T_1$, $R_2$ = 1/$T_2$ and $R_{1ρ}$ = 1/$T_{1ρ}$ in the rotating frame for three proteins: chicken egg white lysozyme, egg white albumin, and bovine serum albumin, obtained at proton resonant frequency of 60 MHz. Besides the relaxation rates dependences on concentration in the 4-23% (g/100 g solution) range, the analysis of the Carr-Purcell-Meiboom-Gill CPMG multi-echo $T_2$ experiments with variable pulse rate τ was performed. The dependences of relaxation rates on protein concentration are linear at low concentration. When protein concentration increases the slope of the straight line rapidly changes at so-called "critical" concentration which depends on MW of the diluted protein. Investigated dispersion of $T_2$, obtained using the CPMG method with a variable pulse rate, for concentrations higher and lower than the "critical" one, exhibits unequal behavior. At high concentration one-exponential curves and at low concentration two-exponential curves correspond closely with experimental data. The obtained parameters of exponents allow an estimation of the ratio of the amount of water with the determined motion freedom, that is free and bounded water, in solution. We showed that the CPMG dispersion method applied to aqueous protein solutions may widen the current understanding of the nature of molecular dynamics of hydrated water protons in non-perturbed environment.
Źródło:
Acta Physica Polonica A; 2014, 125, 4; 907-910
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Solid State $\text{}^{13}C$ NMR Study of Modified Polyhydroxybutyrate
Autorzy:
Vrábel, P.
Hronský, V.
Fričová, O.
Koval'aková, M.
Chodák, I.
Alexy, P.
Powiązania:
https://bibliotekanauki.pl/articles/1382700.pdf
Data publikacji:
2014-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.41.+e
76.60.-k
81.05.Lg
Opis:
Structural changes in polyhydroxybutyrate (PHB) brought about by addition of chain extender and/or plasticizer were studied using $\text{}^{13}C$ MAS NMR spectra, which were measured using the direct polarization technique at 30 and 98°C. Four resonances associated with the CO, CH, $CH_{2}$ and $CH_{3}$ groups of PHB were observed in the spectra. The $CH_{3}$ resonance appearing at 98°C shows splitting into two lines related to the crystalline and amorphous regions. Analysis of the $CH_{3}$ resonances made it possible to estimate the influence of applied modifications on crystallinity and distribution of conformations in amorphous and crystalline domains of PHB samples.
Źródło:
Acta Physica Polonica A; 2014, 126, 1; 419-420
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structure of Iron Oxide Nanoparticles Studied by $\text{}^{57}Fe$ NMR
Autorzy:
Křišťan, P.
Chlan, V.
Štěpánková, H.
Řezníček, R.
Görnert, P.
Payer, P.
Powiązania:
https://bibliotekanauki.pl/articles/1378149.pdf
Data publikacji:
2014-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.60.-k
75.50.Gg
75.50.Tt
Opis:
In this work we apply nuclear magnetic resonance (NMR) spectroscopy of $\text{}^{57}Fe$ nuclei for investigation of submicron and nanocrystalline iron oxide systems. The studied iron oxide particles are obtained from ferrous hydroxide gels (prepared from $FeCl_{2}$ and KOH) by aging at elevated temperatures (90 °C) with $KNO_{3}$ as oxidant. The $\text{}^{57}Fe$ NMR spectra of the samples are measured in temperature range 4.2-370 K in a zero external magnetic field. Signals of $\text{}^{57}Fe$ nuclei assigned to tetrahedral and octahedral iron sites are well resolved. The NMR spectra and their temperature dependences are compared with those of stoichiometric and nonstoichiometric magnetite single crystals, as well as with samples of maghemite.
Źródło:
Acta Physica Polonica A; 2014, 126, 1; 138-139
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Free Volume of Condensed Phases Confined in a Nanopore as Seen by Computer Simulations and Compared to PALS
Autorzy:
Račko, D.
Powiązania:
https://bibliotekanauki.pl/articles/1196175.pdf
Data publikacji:
2014-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.70.Bj
61.20.Ja
76.60.-k
64.70.pm
Opis:
In this contribution the free volume of glycerol phase confined in a nanopore in a wide temperature range is computed. The computed free volume is compared to the previously computed values in the glycerol bulk. The mean cavity volumes are also discussed with the experimental measurements by positronium annihilation lifetime spectroscopy. The computer simulations show that in the case of the confined glycerol phase the mean cavity volumes are larger than in the simulated bulk, and also the temperature dependence has a different qualitative behavior; the computed data are in agreement with experimental measurements performed for glycerol in a pore of comparable size with diameter 6 nm. The simulations also indicate that an aspect of filling a pore is important for experimentalists. In the case of a perfectly sealed pore the cavity volume is observed to rise with decreasing temperature.
Źródło:
Acta Physica Polonica A; 2014, 125, 3; 785-788
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetic Hyperfine Fields of Nanoperm Alloys
Autorzy:
Miglierini, M.
Kohout, J.
Lančok, A.
Šafářová, K.
Powiązania:
https://bibliotekanauki.pl/articles/1428957.pdf
Data publikacji:
2012-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.50.Tt
75.75.-c
76.80.+y
76.60.-k
68.37.Rt
Opis:
Magnetic hyperfine fields of $Fe_{90}Zr_7B_3$ Nanoperm nanocrystalline alloy are characterized by $\text{}^{57}Fe$ Mössbauer spectrometry and $P^{57}Fe$ NMR as well as by magnetic force microscopy. $\text{}^{57}Fe$ NMR enables to distinguish a broad signal of iron atoms located in a residual amorphous matrix from a narrow one which belongs to Fe in nanograins. The former coincides with the distribution of hyperfine fields obtained from $\text{}^{57}Fe$ Mössbauer spectroscopy. In addition, it is possible to make a distinction between NMR signals of the Fe nanograins located in magnetic domains from that of the nanograins positioned in domain walls. This is confirmed by magnetic force microscopy where appearance of maze-domains is observed.
Źródło:
Acta Physica Polonica A; 2012, 121, 5-6; 1263-1265
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Molecular Dynamics in Biological Systems Observed by NMR Relaxation in a Rotating Frame
Autorzy:
Wierzuchowska, D.
Skórski, L.
Blicharska, B.
Powiązania:
https://bibliotekanauki.pl/articles/1490095.pdf
Data publikacji:
2012-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.60.-k
76.90.+d
Opis:
NMR relaxation provides powerful tools for obtaining information on three-dimensional structures, dynamic properties and intermolecular interactions of biological macromolecules. One of these methods, called dispersion profile, is based on measuring the field dependence of spin-relaxation rates in the rotating frame, $R_{1ρ} = 1//T_{1ρ}$, in the presence of a low magnetic field $B_1$. In the presented study we use this method for investigation of molecular dynamics in protein samples. Dispersion profiles can be predicted theoretically and using two models, assuming either dipolar interaction between protons or power law dispersion, we have evaluated some molecular dynamic parameters of water adsorbed on protein surface. Our researches are focused on the connections of obtained parameters of molecular dynamics with conformation changes of protein. We have calculated the correlation times and power parameters for samples of lyophilized powder of albumins (egg white and bovine and rabbit blood serum) and lysozyme, as well as its aqueous solutions. Analysis of these parameters yields valuable information on the molecular nature of investigated biological systems. We also used this method to analyze experimental data of $T_{1ρ}$ obtained by other authors for bovine serum albumin and we have found good accordance with their conclusions concerning molecular dynamics of proteins.
Źródło:
Acta Physica Polonica A; 2012, 121, 2; 434-438
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
$\text{}^{11}$B-NMR Study of $SmB_6$ under Pressure
Autorzy:
Pristáš, G.
Mito, T.
Kohara, T.
Gabáni, S.
Reiffers, M.
Flachbart, K.
Takeshita, N.
Shitsevalova, N.
Powiązania:
https://bibliotekanauki.pl/articles/1534330.pdf
Data publikacji:
2010-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.60.-k
62.50.-p
71.28.+d
Opis:
We present first experimental results of $\text{}^{11}$B-NMR of SmB_6 under applied pressure. From measurement of nuclear spin-lattice relaxation time $(T_1)$ we find that with applied pressure the value of activation gap $E_{g}$ is decreasing. This decrease is larger than in case of other experimental techniques. We suppose that the enhancement of $1//T_1$ in temperature range 20-100 K with applied pressure reflects not only a suppression of hybridization gap, but also changes in spin correlations.
Źródło:
Acta Physica Polonica A; 2010, 118, 5; 895-896
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 44

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