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Tytuł:
Crystal Structure and Magnetic Properties of Pyrrhotite-Type Compounds $Fe_{7-y}V_{y}S₈$
Autorzy:
Selezneva, N.
Ibrahim, P.
Toporova, N.
Sherokalova, E.
Baranov, N.
Powiązania:
https://bibliotekanauki.pl/articles/1397027.pdf
Data publikacji:
2018-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Fn
75.30.Kz
75.50.Gg
Opis:
The pyrrhotite-type compounds $Fe_{7-y}V_{y}S₈$ have been synthesized and studied by means of the X-ray diffraction and magnetization measurements in order to reveal how the substitution of V for Fe affects the crystal structure, phase transition and magnetic properties. The growth of the V content in $Fe_{7-y}V_{y}S₈$ results in changes of the crystal structure and leads to a sharp decrease in the resultant magnetization, non-monotonous change of the coercive field and reduction of the magnetic ordering temperature. Unlike ferrimagnetic ordering in pyrrhotite Fe₇S₈ the compound V₇S₈ is observed to exhibit a Pauli-paramagnetic behaviour.
Źródło:
Acta Physica Polonica A; 2018, 133, 3; 450-452
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Interaction of the Components in the $BaO-Tb_2 O_{3+δ}-CuO$ and Related Systems
Autorzy:
Zaremba, O.
Gladyshevskii, R.
Powiązania:
https://bibliotekanauki.pl/articles/1398239.pdf
Data publikacji:
2018-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Fn
Opis:
The isothermal section of the phase diagram of the $BaO-Tb_2 O_{3+δ}-CuO$ system at 1173 K was constructed based on X-ray powder diffraction data. The existence of the compounds BaTbO₃ (SrZrO₃ structure type, I4/mcm, a = 0.6034(1), c = 0.8576(1) nm) and Ba₄₄Cu₄₅O₉₀ (own structure type, Im-3m, a =1.8266(3) nm) was confirmed in the binary BaO-Tb₂O₃ and BaO-CuO systems, respectively, but no ternary oxides were found. The investigation of samples with nominal composition $A_{0.5}Tb_{0.5}TO_3$ (A = Ca, Sr or Ba, T = Ni or Zn) showed the presence of phases from the corresponding binary systems, or unreacted reagents.
Źródło:
Acta Physica Polonica A; 2018, 133, 4; 1024-1026
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
ORR Electrocatalysis on Cr³⁺, Fe²⁺, Co²⁺-Doped Manganese(IV) Oxides
Autorzy:
Sokolsky, G.
Zudina, L.
Boldyrev, E.
Miroshnikov, O.
Gauk, N.
Kiporenko, O.
Powiązania:
https://bibliotekanauki.pl/articles/1030872.pdf
Data publikacji:
2018-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Fn
61.72.-y
85.40.Ry
Opis:
The ionic dopant additives have different mechanisms of their influence upon MnO₂ electrocrystallisation process and depending on dopants added the following polymorphs are stabilised: α -MnO₂ (hollandite, I4/m) - NH₄⁺; γ -MnO₂ (ramsdellite, Pbnm) - Co²⁺, Fe²⁺; layered polymorph δ -MnO₂ (birnessite, C2/m) - Cr³⁺. The defect states of intergrowth method in ramsdellite matrix and twinning, OH groups studied by X-ray diffraction and the Fourier transform infrared mtehod, respectively, indicate their high content in case of Fe²⁺ and Co²⁺-doped manganese dioxide. CVA oxygen reduction reaction peaks were established after experiments in alkaline electrolytes and dioxygen (argon, air) atmosphere. Activity of doped samples studied is comparable with other published data. Both doped with Co²⁺ and Fe²⁺ samples display maximal currents and some distinctive features in oxygen reduction reaction.
Źródło:
Acta Physica Polonica A; 2018, 133, 4; 1097-1102
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Refinement of the Modulated Structures of Pb-Free and Pb-Doped Bi-2223 HTSC
Autorzy:
Shcherban, O.
Akselrud, L.
Giannini, E.
Gladyshevskii, R.
Powiązania:
https://bibliotekanauki.pl/articles/1030916.pdf
Data publikacji:
2018-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Fn
74.72.-h
Opis:
The incommensurate modulated structures of Pb-free and Pb-doped Bi-2223 phases were refined on single-crystal X-ray diffraction data.
Źródło:
Acta Physica Polonica A; 2018, 133, 4; 1027-1029
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Structure Characterisation of Micro-and Nanocrystalline Powders of Dy_{1-x}R_xFeO₃ (R = La, Pr, Nd, Sm, Gd)
Autorzy:
Pavlovska, O.
Lutsyuk, I.
Kondyr, A.
Zhydachevskyy, Ya.
Vakhula, Ya.
Pieniążek, A.
Vasylechko, L.
Powiązania:
https://bibliotekanauki.pl/articles/1029717.pdf
Data publikacji:
2018-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Fn
61.05.cp
Opis:
This work deals with the study of the phase and crystal structure behaviour of new micro- and nanocrystalline ferrites Dy_{1-x}R_xFeO₃ obtained by solid state reactions (R = La, Pr) and sol-gel citrate (R = Nd, Sm, Gd) techniques. It was established that all synthesized samples adopt orthorhombic perovskite structure isotypic with GdFeO₃. Unit cell dimensions and atomic coordinates of the mixed rare earth ferrites derived by full profile Rietveld refinement technique agree well with the data of the "pure" DyFeO₃ and RFeO₃ compounds, thus proving formation of continuous solid solutions Dy_{1-x}R_xFeO₃ in the DyFeO₃-RFeO₃ systems (R = La, Pr, Nd, Sm, Gd). Peculiarity of the Dy_{1-x}La_xFeO₃ series is the lattice parameters crossover and formation of dimensionally tetragonal structure at x ≈0.97.
Źródło:
Acta Physica Polonica A; 2018, 133, 4; 802-805
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Behaviour of PrCo_{1-x}Fe_xO₃ Probed by X-ray Synchrotron Powder Diffraction and Impedance Spectroscopy Measurements
Autorzy:
Pekinchak, O.
Sugak, D.
Ubizskii, S.
Suhak, Yu.
Fritze, H.
Vasylechko, L.
Powiązania:
https://bibliotekanauki.pl/articles/1029711.pdf
Data publikacji:
2018-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Fn
61.05.cp
65.40.De
72.60.+g
Opis:
Crystal structure and transport properties of the mixed praseodymium cobaltites-ferrites PrCo_{1-x}Fe_xO₃ have been studied in the temperature range of 298-1173 K by a combination of in situ X-ray synchrotron powder diffraction and temperature dependent impedance spectroscopy measurements. In situ high temperature powder diffraction examination of PrCo_{1-x}Fe_xO₃ series revealed considerable anomalies in the lattice expansion which are especially pronounced for the cobalt-rich specimens. These anomalies, which are reflected in a sigmoidal dependence of the unit cell dimensions and in the considerable increase of the thermal expansion coefficients, are obviously associated with transitions of Co^{3+} ions from low spin to the higher spin states and the coupled metal-insulator transitions, occurring in in rare earth cobaltites at the elevated temperatures. Indeed, the temperature-dependent impedance measurements clearly prove the change of conductivity type from dielectric to the metallic behaviour in the mixed cobaltite-ferrites PrCo_{1-x}Fe_xO₃ at the elevated temperatures.
Źródło:
Acta Physica Polonica A; 2018, 133, 4; 798-801
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A System of B-C-N-O: Synthesis, Characterization and Determination of Unit Cell Parameters
Autorzy:
Gül, G.
Kurtuluş, F.
Powiązania:
https://bibliotekanauki.pl/articles/1033375.pdf
Data publikacji:
2017-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
33.20.Ea
61.66.-f
61.66.Fn
84.40.-x
Opis:
Boron-rich solids are good candidates to apply instead of diamond. Boron has a unique crystal structure and compounds of it are resistant to heat treatment. These structures have light density, high hardness, and chemically inertness. Also, boron compounds display thermal and electronic properties as a thermoelectric power at high temperatures. A boron, carbon, nitrogen, and oxygen containing compound was synthesized for the first time by classical microwave method using elemental amorphous boron, active carbon, and urea with 1:1:1 molar ratio. The compound is crystallized in monoclinic system with unit cell parameters a=12.9575 Å, b=9.3264 Å, c=9.6529 Å, β =113.277° which are calculated by POWD indexing program. The X-ray diffraction, POWD, the Fourier transform infrared, scanning electron microscopy/energy X-ray diffraction spectroscopy and thermogravimetric/different thermal analysis were achieved.
Źródło:
Acta Physica Polonica A; 2017, 131, 1; 36-38
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Simulation study of topological point defects in graphitic layer - curvature effect and pair correlation function analysis
Autorzy:
Hawelek, L.
Powiązania:
https://bibliotekanauki.pl/articles/1075560.pdf
Data publikacji:
2016-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.ue
61.72.J-
61.43.Bn
61.66.Fn
61.05.C-
Opis:
The effect of three types of topological defects, single vacancy, double vacancy and the Stone-Thrower-Wales defect on the atomic arrangement in a single graphitic layer is studied using computer simulations. The topological defects were positioned on the perfect hexagonal graphitic layer 20 Å in diameter with different distance from the layer edge and then the geometry of the system was independently optimized using the reactive bond order potential, the semi-empirical quantum-chemical PM7 and the density functional theory method. Curvature and the distortion of the graphitic layer caused by the defects are analyzed and their influence on the pair correlation function is discussed.
Źródło:
Acta Physica Polonica A; 2016, 130, 3; 811-816
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetic and Structural Study of $Mn_{1.15}Fe_{0.85}P_{1-x}Ge_{x}$ (0.25 < x < 0.32) Magnetocaloric Compounds Prepared by Arc Melting
Autorzy:
Hawelek, L.
Wlodarczyk, P.
Zackiewicz, P.
Polak, M.
Kaminska, M.
Puźniak, R.
Radelytskyi, I.
Kolano-Burian, A.
Powiązania:
https://bibliotekanauki.pl/articles/1402326.pdf
Data publikacji:
2015-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.30.Sg
75.30.Kz
61.05.C-
61.66.Fn
Opis:
Recently, room temperature magnetocaloric materials increasingly attracted attention in the development of magnetic refrigerators. In this paper, an effect of P/Ge substitution on the magnetic phase transition in the series of $Mn_{1.15}Fe_{0.85}P_{1-x}Ge_{x}$ (0.25 < x < 0.32) magnetocaloric compounds prepared by the arc melting technique and subsequent homogenization process has been studied. Calorimetric and magnetization results show that the temperature of structural phase transition coincide with the Curie temperature and fall within the temperature range 270-355 K. The magnetic entropy change reaches the maximum value for the compound with x=0.28 and equals to 32 J/(kg K) for the magnetic field change of 5 T. The adiabatic temperature change for the same sample, measured using magnetocalorimeter, is equal to 1.2 K for the magnetic field change of 1.7 T. It was found that the increase of Ge content in the sample causes weakening of first order magnetic transition, which is manifested by the lowering difference in transition temperature measured in two zero-field-cooling and field-cooled-cooling regimes.
Źródło:
Acta Physica Polonica A; 2015, 128, 1; 76-80
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nuclear Magnetic Resonance in Hexaferrite/Maghemite Composite Nanoparticles
Autorzy:
Křišťan, P.
Hondlík, O.
Štěpánková, H.
Chlan, V.
Kouřil, K.
Řezníček, R.
Pollert, E.
Veverka, P.
Powiązania:
https://bibliotekanauki.pl/articles/1386884.pdf
Data publikacji:
2015-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.60.-k
75.50.Gg
75.50.Tt
75.47.Lx
61.66.Fn
Opis:
Due to their bio-compatibility and non-toxicity, ferrimagnetic iron oxides are suitable for various medical applications. In the case of hyperthermia, the promising approach how to reach desired magnetic properties is to combine more phases into a composite material. A series of samples containing maghemite and M-hexaferrite was prepared by sol-gel method with subsequent thermal treatment where annealing temperature and time were varied. The samples were characterized by X-ray diffraction. In this paper we focused mainly on application of nuclear magnetic resonance spectroscopy to investigate these strongly inhomogeneous nanoparticle composites. Frequency-swept ⁵⁷Fe NMR spectra of nanoparticle samples were measured in a zero external magnetic field at 4.2 K. Utilizing differences in optimal excitation field strengths and in relaxation times, we were able to resolve NMR signal assigned to hexagonal ferrite of M-phase from signal which showed features attributed to maghemite.
Źródło:
Acta Physica Polonica A; 2015, 127, 2; 514-516
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Photocatalytic Properties of Mechanochemically Synthesized Nanocrystalline $ZnAl_2O_4$ and CdSe
Autorzy:
Kostova, N.
Eliyas, Al.
Fabián, M.
Achimovičová, M.
Baláž, P.
Powiązania:
https://bibliotekanauki.pl/articles/1375494.pdf
Data publikacji:
2014-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.20.-n
61.05.cp
61.46.-w
61.66.Fn
Opis:
Nanocrystalline powders of $ZnAl_2O_4$ and CdSe were prepared via mechanochemical synthesis. Powder slurries were coated as thin films on $SiO_2$ thin layer chromatography (TLC) sheet by capillary method. The photocatalytic activity of the film coating was tested in a self-made gas-phase flat-plate continuous-flow photocatalytic reactor with toluene as model air contaminant. The tested nanocrystalline $ZnAl_2O_4$ turned out to be poor oxidation photocatalyst under UV irradiation. CdSe displays considerable photocatalytic activity under visible light, where $TiO_2$ is inactive. The nonconventional one-step mechanochemical route to $ZnAl_2O_4$ and CdSe synthesis offers several advantages compared to traditional processing routes, including low-temperature solid state reactions at ambient temperature, absence of organic templates contamination and low expenses.
Źródło:
Acta Physica Polonica A; 2014, 126, 4; 967-970
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Promising Synthetic Route Hydrothermal Synthesis of Non-Stoichiometric Cerium and Boron Containing Compounds and Characterization
Autorzy:
Çelik, G.
Kurtuluş, F.
Powiązania:
https://bibliotekanauki.pl/articles/1181838.pdf
Data publikacji:
2014-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.33.Pt
61.66.Fn
61.05.cp
Opis:
Cerium, the most abundant rare earth element, and boron containing mineral (lithium tetraborate pentahydrate) were used for synthesizing rare earth borates. Alternatively, for preparing rare earth borates, hydrothermal technique can be used. The non-stoichiometric cerium and boron containing compounds were synthesized by hydrothermal method using cerium sulphate and lithium tetraborate pentahydrate in appropriate molar ratio. Characterizations were done by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy/energy dispersive X-ray analysis, and thermogravimetric/differential thermal analysis.
Źródło:
Acta Physica Polonica A; 2014, 125, 2; 325-326
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of Secondary Interactions and Structure-Activity-Relationship of Two Benzoic Acids
Autorzy:
Dinesh, J.
Powiązania:
https://bibliotekanauki.pl/articles/1400141.pdf
Data publikacji:
2013-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Fn
Opis:
Two benzoic acids, 2-[3-(o-methylphenoxymethyl)-5-phenyl-[1,2,4]triazol-4-yl]-benzoic acid [I] and 2-[3-(m-methylphenoxymethyl)-5-phenyl-[1,2,4]triazol-4-yl]-benzoic acid [II] were synthesized and their crystal structures have been analyzed to the reliability factor of 4.2% [I] and 4.8% [II]. Different structural motifs (i.e. chains, dimmers, rings, etc.) bonded through C-H...π, ı...ı and hydrogen interactions have been analyzed. Structure-activity-predictions have been identified on the basis of structural fragments and variation in activities has been observed in both the compounds. The detailed analysis of non-covalent interactions illustrates that the shifting of methyl group from ortho-to-para increases the bioactivity-predictions of "Endothelin B receptor antagonist".
Źródło:
Acta Physica Polonica A; 2013, 123, 4; 704-708
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Low Temperature Crystal Structure Behaviour of Complex Yttrium Aluminium Oxides YAlO_3 and Y_3Al_5O_{12}
Autorzy:
Senyshyn, A.
Vasylechko, L.
Powiązania:
https://bibliotekanauki.pl/articles/1399474.pdf
Data publikacji:
2013-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Fn
61.05.F-
65.40.De
65.60.+a
63.70.+h
Opis:
Crystal structures of two yttrium aluminium oxides, namely $YAlO_3$ and $Y_3Al_5O_{12}$, were investigated in the temperature range 3.4-300 K by high-resolution neutron powder diffraction. Neither traces of phase transformations nor discontinuous changes of physical properties were observed. Thermal expansion of yttrium aluminium oxides was evaluated in terms of 1st order Grüneisen approximation, where the Debye temperatures and the Grüneisen parameters have been estimated for both compositions. Anomalies in the thermal expansion of yttrium aluminium perovskite have been observed and modelled using the Einstein oscillator with negative Grüneisen parameter. Extended bond length analysis revealed significant thermally-driven modifications of the aluminium-oxygen framework.
Źródło:
Acta Physica Polonica A; 2013, 124, 2; 329-335
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Experimental and Theoretical Study of Zircon and Scheelite Phases of $DyVO_4$
Autorzy:
Ermakova, O.
Paszkowicz, W.
López-Solano, J.
Muñoz, A.
Dabkowska, H.
Powiązania:
https://bibliotekanauki.pl/articles/1431671.pdf
Data publikacji:
2012-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
42.70.Hj
61.43.Bn
61.66.Fn
Opis:
Polycrystalline zircon-type dysprosium orthovanadate, $DyVO_4,$ prepared from a single crystal grown by slow cooling from $PbO//PbF_2$ flux, was studied by X-ray diffraction. Rietveld refinement provided the following unit cell size and oxygen atom coordinates: a=7.14811(4) Å; c=6.30825(4) Å, V=322.323(3) Å3, y($O^{2-}$)=0.4300(4); z($O^{2-}$)=0.2082(4) which are of a particularly high accuracy and show consistency with earlier reported values. Density functional theory calculations within the generalized gradient approximation for the exchange-correlation energy were also performed, providing values of structure parameters which differ by less than 2% from the experimental ones. The agreement between theory and experiment demonstrates the value of these calculations for understanding the structure of compounds of $RVO_4$ family. In addition, density functional theory calculations were performed for the scheelite-type $DyVO_4$; also for this polymorph the discrepancy with the only known set of lattice parameters is less than 2%. Values of oxygen atom coordinates have not been reported yet for this polymorph; here, the calculated ones are quoted.
Źródło:
Acta Physica Polonica A; 2012, 121, 4; 920-927
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 42

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