- Tytuł:
- Synthesis, Structure and Energetic Properties of a Catenated N6, Polynitro Compound: 1,1’-Azobis(3,5-dinitropyrazole)
- Autorzy:
-
Li, Y.-N.
Shu, Y.-J.
Wang, Y.-L.
Wang, B.-Z.
Zhang, S.-Y.
Bi, F.-Q. - Powiązania:
- https://bibliotekanauki.pl/articles/358573.pdf
- Data publikacji:
- 2017
- Wydawca:
- Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
- Tematy:
-
energetic compound
1,1’-azobis(3,5-dinitropyrazole)
synthesis
energetic properties - Opis:
- A nitrogen-rich, polynitro energetic compound with an N,N-azo linkage, 1,1’-azobis(3,5-dinitropyrazole) (ABDNP), has been synthesized by an oxidative coupling reaction of 1-amino-3,5-dinitropyrazole with different oxidizing agents. The target compound was characterized by IR spectroscopy, 1H and 13C nuclear magnetic resonance spectroscopy, elemental analysis, mass spectra, X-ray diffraction and differential scanning calorimetry (DSC). The DSC results show that 1,1’-azobis(3,5-dinitropyrazole) decomposes at a relatively high onset temperature (202.9 °C), which indicates that 1,1’-azobis(3,5-dinitropyrazole) has acceptable thermal stability. The energetic properties were obtained, with a measured density and heat of formation matched by theoretically computed values based on the B3LYP method.
- Źródło:
-
Central European Journal of Energetic Materials; 2017, 14, 2; 321-335
1733-7178 - Pojawia się w:
- Central European Journal of Energetic Materials
- Dostawca treści:
- Biblioteka Nauki
Artykuł