- Tytuł:
- Franck-Condon Effects in Resonance Raman Spectra of TCNQ$\text{}^{-}$ and C$\text{}_{10}$H$\text{}_{8}^{+}$ Radicals. A Search for Dushinsky Rotation of Totally Symmetric Modes
- Autorzy:
-
Zborowski, K.
Pawlikowski, M. - Powiązania:
- https://bibliotekanauki.pl/articles/1933604.pdf
- Data publikacji:
- 1995-09
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
- 33.20.Fb
- Opis:
- The resonance Raman spectra of tetracyanoquinodimethane anion (TCNQ$\text{}^{-}$) and naphthalene cation (C$\text{}_{10}$H$\text{}_{8}^{+}$) are analyzed in terms of theoretical model based on the Franck-Condon effects. The model includes also the effect of rotation of totally symmetric normal coordinates upon electronic excitation to the resonant state (Dushinsky effects). It is shown that such a simple model accounts correctly for the available resonance Raman spectra for TCNQ$\text{}^{-}$ and C$\text{}_{10}$H$\text{}_{8}^{+}$ radicals. The possible model refinements such as vibronic coupling effects are also briefly discussed.
- Źródło:
-
Acta Physica Polonica A; 1995, 88, 3; 435-444
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł