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    Wyświetlanie 1-2 z 2
    Tytuł:
    Enhanced biosolubilization of mid-low grade phosphate rock by formation of microbial consortium biofilm from activated sludge
    Autorzy:
    Xiao, Chunqiao
    Wu, Xiaoyan
    Zhu, Lei
    Yu, Tong
    Xu, Zhenghe
    Chi, Ruan
    Powiązania:
    https://bibliotekanauki.pl/articles/110353.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    biosolubilization
    phosphate rock (PR)
    microbial consortium
    activated sludge
    biofilm
    Opis:
    Mid-low grade phosphate rock (PR) is a potential source of free phosphate to facilitate crop growth, but a cost effective and environmentally responsible extraction process is required. In this study, the capacity of a microbial consortium from activated sludge to solubilize PR in a laboratory-scale column reactor was investigated. The microbial consortium proved capable of efficiently releasing soluble phosphate in the reactor effluent over the 90-day trial. The microbial consortium grew well in the column system as evidenced by reduced chemical oxygen demand (COD) in the reaction solution. Biofilm formation was identified as critical for biosolubilization of the mid-low grade PR. Imaging of the biofilm by scanning electron microscopy (SEM) revealed a dense network of microbial cells embedded in extracellular polymeric substances (EPS). The biofilm contained both oxic and anoxic zones. The pH decreased significantly in both the biofilm and the reaction solution during operation, indicating healthy growth of the microbial consortium with corresponding acid generation and subsequent enhancement of phosphate solubilization.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 1; 217-224
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Morphological analysis of organo-montmorillonites via MD simulations
    Autorzy:
    Karataş, Deniz
    Tekin, Adem
    Can, Muhammed F.
    Xu, Zhenghe
    Çelik, Mehmet S.
    Powiązania:
    https://bibliotekanauki.pl/articles/2146936.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    organo-montmorillonite
    tetradecyl dimethyl ethyl benzyl ammonium chloride
    molecular dynamics simulation
    cation exchange capacity
    binding energy
    Opis:
    Adsorption on clay surfaces has been studied intensively in recent years. The most curious subject of these studies, which are generally experimental, is how the surfactants are adsorbed at the atomic level to the surface. In this study, the adsorption of quaternary amine salt (tetradecyl dimethyl ethyl benzyl ammonium chloride–TDEBAC) to sodium montmorillonite (Na-MMT) with various cation exchange capacities (CEC) was investigated by using Molecular Dynamics (MD) simulation. In the simulations, as in the experimental studies, it was revealed that the surfactants were both adsorbed on to basal surfaces and settled between the layers. From the morphological analysis obtained from MD simulations, it was calculated that the inter-molecular interaction between the layers was higher than on the basal surface. For example, for the model with 118 CEC motif, the binding energy of all three surfactants in the models with the hydrophilic heads facing the same direction was calculated as -678.18 kcal/mol at the basal surface, while this value was found to be -688.90 kcal/mol in the interlayer. The more striking result is that in the simulations made by turning the head of the middle one of the three surfactants towards the tails of the right and left ones, only -34.86 kcal/mol binding energy was calculated on the basal surface, while this value was -525.63 kcal/mol in the interlayer. As compared middle reversed surfactant models with the same direction ones, despite increased CEC the intermolecular interaction decreased for the basal surface, but the interaction increased between the layers.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 5; art. no. 152499
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-2 z 2

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