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Tytuł:
Synthesis and Characterization of Metal Derivatives of 1,1,2,2-Tetranitraminoethane (TNAE)
Autorzy:
Zhu, C.
Meng, Z.
Xu, Z.
Liu, W.
Liu, Y.
Shi, X.
Xie, T.
Powiązania:
https://bibliotekanauki.pl/articles/358571.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
Ionic compound
1,1,2,2-tetranitraminoethane
thermal property
safety performance
thermal decomposition kinetics
Opis:
The introduction of anions and cations into energetic materials can significantly improve their physicochemical and energetic properties. The K, Zn, Ba, Cu and Pb salts of 1,1,2,2-tetranitraminoethane (TNAE) were synthesized using TNAE as the starting material, and were characterized by IR spectroscopy, NMR spectroscopy and elemental analysis. All of the energetic salts exhibited relatively high thermal stabilities (decomposition temperatures ranging from 195.1 °C to 279.3 °C) and high densities (ranging from 2.1 g·cm–3 to 3.7 g·cm–3). It was demonstrated that the introduction of metal ions conveys better thermal stability than covalent TNAE itself. More importantly, the Zn, Ba and Cu salts exhibited good thermal stability, high density, low sensitivity, and therefore have the potential to be a new class of insensitive, highly energetic explosives for practical applications.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 3; 435-444
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Identification of Ephedra species by phylogenetic analyses using matK and ITS1 sequences
Autorzy:
Zhao, Y.S.
Xie, L.X.
Mao, F.Y.
Cao, Z.
Wang, W.P.
Zhao, Q.P.
Zhang, X.H.
Powiązania:
https://bibliotekanauki.pl/articles/56673.pdf
Data publikacji:
2016
Wydawca:
Polskie Towarzystwo Botaniczne
Opis:
In this study, the species identifications of seven Ephedra plants, including three medicinal plants from the Pharmacopoeia of the People’s Republic of China, were conducted using phylogenetic analyses, and the method’s validity was verified. The phylogenetic trees constructed from the maturase-coding gene (matK) and internal transcribed spacer 1 (ITS1) sequences showed that the former could be used for identifying five Ephedra plants, Ephedra intermedia, E. equisetina, E. antisyphilitica, E. major, and E. aphylla, but it had less power to discriminate E. sinica and E. przewalskii, while the latter could distinguish five Ephedra plants, E. przewalskii, E. equisetina, E. antisyphilitica, E. major, and E. aphylla, but it had less power to discriminate E. sinica and E. intermedia. However, when the two genes were combined, the seven species could be completely distinguished from each other, especially the medicinal plants from the others, which is significant in developing their pharmaceutical uses and in performing quality control assessments of herbal medicines. The method presented here could be applied to the analysis of processed Ephedra plants and to the identification of the botanical origins of crude drugs. Additionally, we discovered that E. equisetina and E. major were probably closely related to each other, and that E. sinica, E. intermedia, and E. przewalskii also had a close genetic relationship.
Źródło:
Acta Societatis Botanicorum Poloniae; 2016, 85, 2
0001-6977
2083-9480
Pojawia się w:
Acta Societatis Botanicorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Depth-resolved measurement of the compression displacement fields on the front and rear surfaces of an epoxy sample
Autorzy:
Zhang, W.
Dong, B.
He, Z.
Xie, S.
Zhou, Y.
Powiązania:
https://bibliotekanauki.pl/articles/174399.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
depth-resolved measurement
compression displacement field
wavenumber-scanning interferometry
epoxy
Opis:
Compression is one of the typical parameters measured in material mechanics. In this research, the compression displacement fields on the front and rear surfaces of an epoxy sample are measured by using a tilt depth-resolved wavenumber-scanning Michelson interferometer. The light source is a distributed feedback laser diode, the wavenumber of which can be modulated to about 1.017 × 104 m–1 by the temperature without mode hopping. A random-sampling Fourier transform is designed to evaluate the phase differences before and after the applied loads. Experimental results show that the depth-resolved measurement of the compression displacement field is of high accuracy. It can be used to analyze force propagation inside resin-based composites.
Źródło:
Optica Applicata; 2018, 48, 2; 311-323
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biomass partition and carbon storage of Cunninghamia lanceolata chronosequence plantations in Dabie Mountains in East China
Autorzy:
Xie, X.
Cui, J.
Shi, W.
Liu, X.
Tao, X.
Wang, Q.
Xu, X.N.
Powiązania:
https://bibliotekanauki.pl/articles/41359.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Instytut Dendrologii PAN
Tematy:
biomass
carbon storage
Cunninghamia lanceolata
Chinese fir
chronosequence
plantation forest
Dabie Mountains
China
Opis:
The quantification of biomass carbon pools is important for understanding carbon cycling in forest ecosystems. This study was designed to reveal the effects of stand age on biomass partitioning and carbon storage of Chinese fir plantation stands in Dabie Mountains of Anhui, East China. A total of six even-aged Chinese fir plantation stands along an age-sequence from 10 to 50 years were selected. To quantify the biomass of different tree components, 18 trees with diameter at breast height (D1.3) from 6.5 to 35.2 cm were harvested from the different aged stands. Biomasses of understory vegetation, forest floor and standing dead trees were also investigated. Total biomass carbon storages ranged from 57.6 to 211.4 Mg ha–1 in the different aged stands. Tree layer comprised from 93.7% to 96.4% of the total biomass C pools in the different aged stands. The C pools of the necromass were from 1.8 to 6.2 Mg ha–1. Stand age had a significant effect on tree biomass partitioning, with an increase in proportion of root biomass. The root/shoot ratios were from 0.187 to 0.312, which was significantly positively correlated to stand age. The existing plantation stands are still developing and have somewhat high rate of biomass and carbon accumulations beyond the normal rotation period (usually 25–30 years) even over an age of 50 years. Appropriate prolongation of the rotation period of Chinese fir plantation will be effective in maintaining long-term productivity and providing large carbon sink. The measurements provide valuable data for modelling productivity of Chinese fir plantation forest.
Źródło:
Dendrobiology; 2016, 76
1641-1307
Pojawia się w:
Dendrobiology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of float-sink and progressive release flotation of ground products of coal middlings
Autorzy:
Xie, W.
He, Y.
Luo, C.
Zhang, X.
Li, H.
Yu, J.
Wang, H.
Shi, F.
Powiązania:
https://bibliotekanauki.pl/articles/109500.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
coal middlings
float-sink
progressive release flotation
XPS
EDX
Opis:
An additional recovery of coking coal middlings can be utilized for increasing of the concentrate yield of coking coal. A combined flow sheet of comminution and flotation can realize this target. To investigate the effect of grinding process on further flotation of ground products, progressive release flotation tests were used to compare with the float-sink tests, which were regarded as a criterion. Coal middlings were ground by wet-milling with iron balls to <0.5 mm. Curves of ash vs. cumulative yields of sized products indicated that the concentrate yield of coal separated by progressive release flotation was lower than that of coal benefited by the float-sink test, with the same ash for four size fractions (0.5-0.25 mm, 0.25-0.125 mm, 0.125-0.074 mm and <0.074 mm). Distributions of elements conducted by energy disperse spectroscopy (EDX) showed that associated kaolinite was liberated and exposed on the surface. It led to the shift of local surface property from hydrophobicity to hydrophilicity. Meanwhile, analyses of chemical property performed by an X-Ray photoelectron spectrometer (XPS) depicted that the hydrophilic mineral FeOOH, which generated in the grinding process, was adsorbed on the coal surface. Flotation of the ground products were worsened due to the increase of hydrophilicity of the coal surface.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 2; 675-684
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
An enclosed dust removal system with ducting
Zamknięty system odpylania z kanalizacją
Autorzy:
Xie, J.
Xue, S.
Chen, W. M.
Zhou, G.
Powiązania:
https://bibliotekanauki.pl/articles/348688.pdf
Data publikacji:
2012
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
chodnik
pyły
modelowanie numeryczne
zamknięty system odpylania
roadways
dusts
enclosed dust removal system
numerical modeling
Opis:
A numerical modeling study is undertaken to understand gas-solid particle flows at the face of a mechanically developing roadway of an underground coal mine which employs a force-exhaust auxiliary ventilation system and uses mist spray for dust suppression. The FLUENT, a commercial computational fluid dynamics (CFD) package is used with Semi Implicit Method for Pressure Linked Equations (SIMPLE) algorithm for simulation. The results of the modeling show that dust control should focus on the middle area of the face. Based on the results, an enclosed dust removal system with ducting was developed. The system was successfully trialed at an underground coal mine with a satisfactory result.
Aby uzyskać przebieg przepływu cząstek gazu na przodku mechanicznie kształtowanego chodnika przewozowego w kopalni podziemnej wykorzystującej system wentylacji kombinowanej i system natrysku rozpylającego do tłumienia pylenia przeprowadzono badania z wykorzystaniem modeli numerycznych. Dla celów symulacji użyto pakietu FLUENT - ogólnodostępnego systemu pomiaru dynamiki płynów w połączeniu z algorytmem SIMPLE. Wyniki modelu pokazują, że odpylanie winno koncentrować się na środkowej powierzchni przodka. Na podstawie uzyskanych wyników opracowano zamknięty system odpylania z kanalizacją. System przetestowano w kopalni z zadowalającym efektem.
Źródło:
AGH Journal of Mining and Geoengineering; 2012, 36, 3; 423-433
1732-6702
Pojawia się w:
AGH Journal of Mining and Geoengineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Changes in the flotation kinetic of bituminous coal before and after natural weathering processes
Autorzy:
Xia, W.
Peng, Y.
Ren, C.
Xie, G.
Liang, C.
Powiązania:
https://bibliotekanauki.pl/articles/951864.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation kinetic
classical first-order rate constant
natural weathering processes
XPS
contact angle
Opis:
Natural weathering processes can make coal surface more hydrophilic due to the increase of content of hydrophilic functional groups (C-O, C=O, and COOH) and the decrease of content of hydrophobic functional groups (C-C and C-H) on coal surface, and hence the flotation recovery of fine coal is reduced. In this paper, a series of flotation tests were conducted in order to investigate the changes in the flotation kinetic of bituminous coal before and after natural weathering processes. Additionally, XPS was used to indicate the changes in surface properties of bituminous coal. In the investigations the flotation kinetic was changing. The classical first-order rate constant (k) of bituminous coal flotation was reduced after the natural weathering processes. A relationship between the classical first-order rate constant (k) and the hydrophilicity ability (HA) was given.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 2; 401-410
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of surface properties of anthracite coals before and after high temperature heating process
Autorzy:
Xia, W.
Xie, G.
Powiązania:
https://bibliotekanauki.pl/articles/951846.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
heating
coal hydrophobicity
XPS
SEM
BET
contact angle
Opis:
Surface property plays a very important role on coal hydrophobicity which determines flotation behavior of fine coals. However, coal spontaneous combustion makes coal suffer both oxidation and high temperature heating processes. Coals from the outside of coal piles primarily suffer oxidation (or combustion process) while coals from the inside of coal piles primarily suffer high temperature heating process. It is necessary to investigate the changes in surface properties of coal before and after high temperature heating process. In this investigation, X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), surface area (BET) and contact angle measurements were used to indicate the changes in surface properties of anthracite coal before and after high temperature heating process. Throughout this study, surface properties of coal changed significantly after high temperature heating process. Meanwhile, coal hydrophobicity can be also reduced after high temperature heating.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 1; 205-212
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Bionic shape design of electric locomotive and aerodynamic drag reduction
Autorzy:
Wu, Z.
Huo, Y.
Ding, W.
Xie, Z.
Powiązania:
https://bibliotekanauki.pl/articles/224333.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
electric locomotive
bionic shape design
aerodynamic drag
numerical simulation
crocodile bionic electric locomotive
lokomotywa elektryczna
bioniczny design
opór aerodynamiczny
symulacja numeryczna
Opis:
Bionics has been widely used in many fields. Previous studies on the application of bionics in locomotives and vehicles mainly focused on shape optimisation of high-speed trains, but the research on bionic shape design in the electric locomotive field is rare. This study investigated a design method for streamlined electric locomotives according to the principles of bionics. The crocodiles were chosen as the bionic object because of their powerful and streamlined head shape. Firstly, geometric characteristic lines were extracted from the head of a crocodile by analysing the head features. Secondly, according to the actual size requirements of the electric locomotive head, a free-hand sketch of the bionic electric locomotive head was completed by adjusting the position and scale of the geometric characteristic lines. Finally, the non-uniform rational B-splines method was used to establish a 3D digital model of the crocodile bionic electric locomotive, and the main and auxiliary control lines were created. To verify the drag reduction effect of the crocodile bionic electric locomotive, numerical simulations of aerodynamic drag were performed for the crocodile bionic and bluff body electric locomotives at different speeds in open air by using the CFD software, ANSYS FLUENT16.0. The geometric models of crocodile bionic and bluff body electric locomotives were both marshalled with three cars, namely, locomotive + middle car + locomotive, and the size of the two geometric models was uniform. Dimensions and grids of the flow field were defined. And then, according to the principle of motion relativity, boundary conditions of flow field were defined. The results indicated that the crocodile bionic electric locomotive demonstrated a good aerodynamic performance. At the six sampling speeds in the range of 40–240 km/h, the aerodynamic drag coefficient of the crocodile bionic electric locomotive decreased by 7.7% on the average compared with that of the bluff body electric locomotive.
Źródło:
Archives of Transport; 2018, 48, 4; 99-109
0866-9546
2300-8830
Pojawia się w:
Archives of Transport
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A new basal actinopterygian fish from the Anisian (Middle Triassic) of Luoping, Yunnan Province, Southwest China
Autorzy:
Wen, W.
Zhang, Q.-Y.
Hu, S.-X.
Zhou, C.-Y.
Xie, T.
Huang, J.-Y.
Chen, Z.Q.
Benton, M.J.
Powiązania:
https://bibliotekanauki.pl/articles/21811.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Instytut Paleobiologii PAN
Tematy:
actinopterygian fish
fish
Anisian
Middle Triassic
Luoping
Yunnan Province
China
Actinopterygii
Halecomorphi
Triassic
Opis:
The new neopterygian fish taxon Luoxiongichthys hyperdorsalis gen. et sp. nov. is established on the basis of five specimens from the second member of the Guanling Formation (Anisian, Middle Triassic) from Daaozi Quarry, Luoping, Yunnan Province, Southwest China. The new taxon is characterized by the following characters: triangular body outline with a distinct apex located between skull and dorsal fin; free maxilla; slender preopercular almost vertical; three suborbitals; at least eight strong branchiostegals with tubercles and comb−like ornamentation on the anterior margin; clavicles present; two postcleithra; ganoid scales covered by tubercles and pectinate ornamentation on the posterior margin with peg−and−socket structure; hemiheterocercal tail slightly forked. Comparison with basal actinopterygians reveals that the new taxon has parasemionotid−like triangular symplectics, but a semionotid opercular system. Cladistic analysis suggests that this new genus is a holostean, and either a basal halecomorph or basal semionotiform.
Źródło:
Acta Palaeontologica Polonica; 2012, 57, 1
0567-7920
Pojawia się w:
Acta Palaeontologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Review of the Characteristic Curves of Silkworm Cocoon Hot air Drying and its Technological Configuration
Przegląd charakterystycznych krzywych suszenia gorącym powietrzem kokonu jedwabnika
Autorzy:
Wei, P.
Tuo, W.
Chen, J.
Chen, X.
Xie, J.
Powiązania:
https://bibliotekanauki.pl/articles/233083.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Biopolimerów i Włókien Chemicznych
Tematy:
cocoon
hot air
drying
characteristic curve
drying technology
kokon
gorące powietrze
suszenie
charakterystyczne krzywe
technologia suszenia
Opis:
To pass on Chinese cocoon-drying technology to developing countries, this paper reviews characteristic curves of silkworm cocoon hot air drying and its recent research advances in cocoon-drying technology in China based on the epochal and regional characters of cocoon drying technology development. (1) Three characteristic curves of cocoon drying are systematically explained, each of which can be divided into preheating, constant speed, and deceleration stages. The temperature susceptibility (i.e., the characteristics of response to temperature conditions) curve of the pupa successively shows heating, constant temperature, and heating processes. (2) Changes in the drying speed and temperature susceptibility of a fresh cocoon layer and naked pupae were examined in detail before and after pupae were killed in the preheating stage. It is proposed that heating the cocoons as soon as possible during the preheating stage of cocoon drying improves the work efficiency and cocoon quality. (3) The effects of the temperature and humidity of the hot air on the cocoon drying speed (i.e., speed coefficients) are obtained using the enthalpy psychrometric chart. The parameter configuration of cocoon drying technology is elaborated according to the speed coefficients in combination with the characteristic curves of cocoon drying and the influence of the laws of cocoon drying technology on cocoon quality. Furthermore, problems in the technological configuration and the direction of future development are noted.
Aby przekazać chińską technologię suszenia kokonów krajom rozwijającym się, w artykule przedstawiono charakterystyczne krzywe suszenia gorącym powietrzem kokonu jedwabnika oraz najnowsze osiągnięcia w dziedzinie technologii suszenia kokonów w Chinach w oparciu o epokowe i regionalne cechy technologii suszenia kokonów. Przedstawiono trzy charakterystyczne krzywe suszenia kokonów, które można podzielić na etapy podgrzewania wstępnego, stałej prędkości i spowalniania. Zbadano szczegółowo zmiany w szybkości i prędkości suszenia świeżej warstwy kokonu i nagich poczwarek przed i po zabiciu poczwarek na etapie wstępnego podgrzewania. Zaproponowano jak najszybsze podgrzewanie kokonów podczas etapu wstępnego suszenia kokonu, co wpływa na poprawę wydajność pracy i jakość kokonu. Wpływ temperatury i wilgotności gorącego powietrza na prędkość suszenia kokonu (tj. współczynniki prędkości) oceniono stosując wykres psychrometryczny entalpii. Konfigurację parametrów technologii suszenia kokonów opracowywano na podstawie analizy uzyskanych współczynników prędkości, charakterystyk krzywych suszenia kokonu i wpływu technologii suszenia na jakość kokonu.
Źródło:
Fibres & Textiles in Eastern Europe; 2018, 4 (130); 20-28
1230-3666
2300-7354
Pojawia się w:
Fibres & Textiles in Eastern Europe
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Development of a blocking immunoperoxidase monolayer assay for differentiation between pseudorabies virus-infected and vaccinated animals
Autorzy:
Wang, Y.B.
Li, Y.H.
Li, Q.M.
Xie, W.T.
Guo, C.L.
Guo, J.Q.
Deng, R.G.
Zhang, G.P.
Powiązania:
https://bibliotekanauki.pl/articles/2087396.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
pseudorabies virus variant strains
anti-pseudorabies virus monoclonal antibody
blocking immunoperoxidase monolayer assay
differentiation between pseudorabies virus-infected and vaccinated animals
Źródło:
Polish Journal of Veterinary Sciences; 2019, 4; 717-723
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption efficiency of pentafluorobenzene on ionic liquids-based silicas
Autorzy:
Wang, X.
Lin, L.
Xie, J.
Yan, X.
Xiao, W.
Tian, P.
Powiązania:
https://bibliotekanauki.pl/articles/778559.pdf
Data publikacji:
2018
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
ionic liquids based silica
pentafl uorobenzene
adsorption
solid-phase extraction
Opis:
The adsorption of pentafl uorobenzene on nine ionic liquid-based silicas was investigated using solid phase extraction. The effects of several variables such as the type of ionic liquid groups, adsorption time, temperatures and water ratio in the solution system were experimentally evaluated. The imidazole-chloride ionic liquid group based silica exhibited the highest adsorption efficiency under the optimized conditions of 5 min adsorption at 30°C in water/methanol (30:70, vol%) solution. In addition, the effects of pH, as well as type and concentrations of chloride salts were investigated. At pH values other than neutral and high salt concentration, the adsorption efficiency was reduced. Finally, the relative standard deviation of less than 5.8% over a 5-day period showed a high precision for the nine tested sorbents.
Źródło:
Polish Journal of Chemical Technology; 2018, 20, 3; 47-52
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption behavior of surfactants on lignite particles with different densities in aqueous medium
Autorzy:
Wang, J.
He, Y.
Wen, B.
Ling, X.
Xie, W.
Wang, S.
Powiązania:
https://bibliotekanauki.pl/articles/110538.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
interfacial surface free energy
adsorption
lignite
surfactant
Washburn equation
Opis:
Lignite is well known for its strong hydrophilicity and hard-to-float properties. However, the surface free energy of the solid is made up of two components, that is the Lifshitz-van der Waals and acid-base interaction energy. Differences in these two components between the low ash (lower density) and high ash fraction (higher density) provide a benefit for improving the separation efficiency through introducing surfactants in flotation. In this paper, thermodynamic characterization of three density lignite fractions was measured by a Washburn dynamic method. Combining the Washburn equation and Van Oss-Chaudhury-Good theory, the surface free energy components of three samples were calculated according to the wetting process by n-hexane, diiodomethane, deionized water and ethylene glycol. The Lifshitz-van der Waals part of surface free energy reduced with the coal density increase, especially between fractions of -1.45 g/cm3 and 1.45-1.80 g/cm3, while the Lewis base part increased slightly. The interfacial interaction free energies between the surfactant and lignite in aqueous medium indicated that the low hydrophilic index benefited for the stronger adsorption intensity. Increase of the surfactant Lifshitz-van der Waals component increases the adsorptive intensity on lower density lignite and the repulsive intensity on higher density lignite, which is beneficial for separation.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 2; 996-1008
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Research on quantifying the hydrophilicity of leached coals by FTIR spectroscopy
Autorzy:
Wang, J.
He, Y.
Yang, Y.
Xie, W.
Ling, X.
Powiązania:
https://bibliotekanauki.pl/articles/110191.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
chemical-structural properties
macerals
hydrophilicity
functional group
Opis:
Surface properties play important roles in characterization of structural parameters and the hydrophilicity index. Accurate analysis of the macerals rather than the average properties of the macerals and minerals are crucial for these parameters and indexes. In order to improve the accuracy of analyzing coal surface property, HF/HCl acid leaching was applied to eliminate the interference of minerals. FTIR was used to characterize the differences in surface chemical composition between raw and processed coal. Moreover, each functional group was analyzed quantitatively. Based on these quantitative data, the structural parameters and hydrophilicity indexes were calculated. From the results of FTIR, the peaks of mineral cover up the types of the organic peaks, such as -COOH and aromatic CH stretching. In addition, they decrease the intensity of the peak such as C=C and aromatics CHx out-of-plane deformation in the spectra of raw coals. However, it provided the accurate types and contents of organic functional groups of the macerals after acid leaching. The structural parameter results indicate that the values cannot reflect the coal ranks through the surface properties of raw coals while they show a good relationship with the degree of coalification in the analysis of processed coals. Besides, the hydrophilicity indexes are verified by the natural floatability of coal macerals of the processed coals. It is also found that the processed lignite coal cannot be floated despite elimination of the hydrophilic minerals. The main reason of hard-to-float property of lignite coal lies in a strong hydrophilicity of macerals.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 1; 227-239
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 29

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