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Tytuł:
Phosphorus recovery from waste - methods review
Autorzy:
Wzorek, Z.
Gorazda, K.
Powiązania:
https://bibliotekanauki.pl/articles/779805.pdf
Data publikacji:
2007
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
odzysk fosforu
ścieki
pomioty
osad ściekowy
mączka mięsno-kostna
phosphorus recovery
waste
manure
sewage sludge
meat-bone meal
Opis:
According to sustainable development principles, searching for alternative phosphorus sources, especially possible ways of its recycling from waste, should be treated as a preferential problem of the phosphorus industry. The ways admitted as most important are: - phosphorus recovery from municipal and industrial sewage and from sewage sludge, - utilization of phosphorus from manure, - management of waste from meat industry. The forecasts elaborated at the end of the last century, indicate that over 50% of the world phosphorus resources in use today will be depleted during the next 60 - 70 years. That fact contributes to increase of market prices of phosphorus products. This work presents possible directions for the recovery and management of sewage sludge, meat meal and manure as a phosphorus source for chemical industry.
Źródło:
Polish Journal of Chemical Technology; 2007, 9, 2; 57-60
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Waste release from meat processing
Autorzy:
Wzorek, Z.
Konopka, M.
Cholewa, J.
Klamecki, G.
Bajcer, T.
Powiązania:
https://bibliotekanauki.pl/articles/777877.pdf
Data publikacji:
2007
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
odpady przemysłu mięsnego
mączka mięsno-kostna
tłuszcz
kości
meat
meat-bone meal
fat
bones
Opis:
The aim of our work is model solution management of waste from meat industry, which would lead to zero waste production with the use of cleaner technology. The process will allow to obtain semi-finished products to be then reused for both meat industry and energy recovery. The model will include thermal utilization of meat, meat-bone and other meat industry waste. The ashes with strictly specified properties containing phosphorus components will be used as a potential raw material for the production of phosphoric acid and salts used in meat production. The new technology is going to be developed in one of the biggest meat factories in Poland - DUDA-BIS in Sosnowiec. The strategic aim of the factory is meat processing with zero waste. That would help to avoid problems with meat waste transport and the expensive utilization of waste to meat-bone meal. The reuse of suitably processed meat waste in meat production will permit to lower production costs. This model will satisfy the requirements of BATNEEC - Best Available Technology No Entailing Excessive Costs. This procedure is advantageous also because in the EU market there are 18 million tons of meat by-products per year. Regardless of how the utilization problems could be solved, suitably processed meat industry waste can be treated as a potential substitute for phosphoric raw materials. According to the forecast, 50% of phosphoric raw material deposits used at the moment will be exhausted in the next 60 - 70 years. As a result a necessity for a new source of the raw materials has arisen.
Źródło:
Polish Journal of Chemical Technology; 2007, 9, 3; 91-94
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal utilization of mixtures of bone waste
Autorzy:
Staroń, P.
Kowalski, Z.
Krupa-Żuczek, K.
Wzorek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/778069.pdf
Data publikacji:
2010
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
odpady-kości
fosfor
wapń
kalorymetr
ciepło spalania
bone-waste
phosphorous
calcium
calorimeter
heat of combustion
Opis:
The results of a research related to the physico – chemical properties of the mixture of bone – waste and their ingredients have been presented. The mixtures was made up from waste: bovine bones, pork bones, bone sludge and bone meal. The content of the individual waste in the mixtures was selected on the basis of the heat of the combustion of the mixture and the amount of the waste produced in a meat processing plant. The heat of the combustion has been determined by the calorimeter, the content of phosphorus by spectrophotometric method, calcium by titration and phase composition by X – ray diffraction. The investigations confirmed that pork bones have the highest heat of the combustion 17 MJ/kg because of a big amount of fats. The analyzed waste has contained on average 16.5 wt % phosphorus and above 30 wt % calcium. X – ray diffraction method has proved that in bone waste one phase – hydroxyapatite occurs.
Źródło:
Polish Journal of Chemical Technology; 2010, 12, 4; 26-30
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Gold Nanoparticles as a Modifying Agent of Ceramic-Polymer Composites
Nanocząsteczkowe złoto jako modyfikator kompozytów polimerowo-ceramicznych
Autorzy:
Sobczak-Kupiec, A.
Tyliszczak, B.
Krupa-Żuczek, K.
Malina, D.
Piątkowski, M.
Wzorek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/353222.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
gold nanoparticles
ceramic-polymer composites
biomaterials
złoto nanocząsteczkowe
kompozyty polimerowo-ceramiczne
biomateriały
Opis:
Much effort has been invested in the development of biomaterials for the repair or replacement of hard tissue. The synthesis of composites based on mineral and organic constituents is nowadays extremely important for the development of materials for biomedical applications. In this paper we report the preparation and characterization of ceramic-polymer composites doped with gold nanoparticles. Properties and applications in medicine and dentistry of colloidal gold nanoparticles depends upon their size and shape. The influence of the presence of the metallic nanoparticles on the degradation process was investigated by pH and conductivity analyses of water filtrates. The nanocomposites were characterized with the use of X-ray Diffaction (XRD) and Fourier Transformed Infrared Spectroscopy (FT-IR) methods. The results of in vitro tests confirmed that it is possible to produce hydroxyapatite/polymer (HA/polymer) composites doped with gold nanoparticles (AuNPs) for medical applications. Tests proved that content of gold nanoparticles in composites had influence on degradation behaviour of HA/Polymer/AuNPs in water environment.
Obecnie wiele starań jest wkładanych w badania dotyczące rozwoju biomateriałów do naprawy i wymiany tkanki kostnej. Otrzymywanie kompozytów opartych na składnikach mineralnych i organicznych jest niezwykle istotne dla rozwoju materiałów do zastosowań biomedycznych. Właściwości i zastosowanie nanocząstek złota w medycynie i stomatologii zależy przede wszystkim od ich wielkości i kształtu. W pracy opisano metodykę otrzymywania oraz charakterystykę kompozytów ceramiczno-polimerowych domieszkowanych nanocząstkami złota. Badano wpływ obecności nanocząstek metalicznych na proces degradacji w środowisku wodnym z wykorzystaniem analiz pH i przewodnictwa. Charakterystykę nanokompozytów wykonano z zastosowaniem dyfrakcji promieni rentgenowskich (XRD) i spektroskopii w podczerwieni z transformacją Fouriera (FT-IR). Na podstawie badań in vitro stwierdzono, że możliwe jest otrzymanie kompozytów polimerowo-ceramicznych modyfikowanych nanocząstkami złota do zastosowań biomedycznych. Badania wykazały, że zawartość nanocząstek złota wpływa na degradację kompozytów HA/Polymer/AuNPs w środowisku wodnym.
Źródło:
Archives of Metallurgy and Materials; 2014, 59, 3; 1005-1009
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Evaluation of the biomedical properties of hydroxyapatite obtained from bone waste
Autorzy:
Sobczak, A.
Kida, A.
Kowalski, Z.
Wzorek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/779210.pdf
Data publikacji:
2009
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
szlam kostny
hydroksyapatyt
kalcynacja
inkubacja
bone sludge
hydroxyapatite
calcining
incubation
SBF
Ringer liquid
Opis:
The method of obtaining hydroxyapatite by thermal treatment of deproteinised and defatted bone pulp called bone sludge was presented. The products of the calcining process were characterized with X-ray diffraction (XRD) and Fourier transformed infrared spectroscopy (FT-IR). The calcium content was determined with titration, whereas the contents of total phosphorus - with a spectrophotomertric method. X-ray investigations confirmed that hydroxyapatite was the main component of the calcining products in the calcining process. The FT-IR spectra confirmed that all organic substances were removed during the calcining process. On the basis of the research into physiological liquids the propensity to resorption of hydroxyapatite bioceramic was evaluated.
Źródło:
Polish Journal of Chemical Technology; 2009, 11, 1; 37-43
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
In vitro tests of dense hydroxyapatite materials
Autorzy:
Sobczak, A.
Kida, A.
Kowalski, Z.
Wzorek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/779248.pdf
Data publikacji:
2009
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
hydroksyapatyt
testy in vitro
inkubacja
hydroxyapatite
dense materials
in vitro tests
incubation
Opis:
The paper presents the results of the calcining process of deproteinised and defatted bone pulp called bone sludge. The calcining process was performed in two stages. The first step of the calcining process was realized at the temperature of 600°C in a rotary kiln. In the second stage the obtained bone ashes were calcined at five different temperatures from 650°C to 950°C for 2 hours in a chamber kiln and in air atmosphere. The products of the calcining process were characterized by the XRD method. Calcium content was determined by titration whereas the contents of total phosphorus and acid-soluble phosphorus - by the spectrophotometric method. The X-ray analysis confirmed that hydroxyapatite is the main component of the calcining products. Calcium and phosphorus contents were kept at the level of 40% and 17.5%, respectively, which corresponded to the Ca/P ratio of not stechiometric hydroxyapatite. In vitro studies, in the simulated body fluid, Ringer liquid and distilled water were realised. The measurements of pH value of SBF and Ringer fluid were realized. Additionally electrical conductivity as well as pH for distilled water where conducted. The goal of these tests was to evaluate chemical durability of dense hydroxyapatite materials.
Źródło:
Polish Journal of Chemical Technology; 2009, 11, 1; 44-49
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of the physicochemical properties of pellets on the germination of pelleted sugar beet seeds
Autorzy:
Podlaski, S.Z.
Wzorek, H.
Chomontowski, C.M.
Powiązania:
https://bibliotekanauki.pl/articles/2082498.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
swelling ability
total porosity
water potential
water content
Opis:
The effects of the physicochemical characteristics of pellets, when applied to sugar beet seeds originating from ten seed companies, on the germination of pelleted seeds were assessed. The most significant factor was the force necessary to break the pellet, which was found to positively correlate with pellet’s abrasion resistance, and negatively with pellet’s water resistance. Pellets dissolved in water, characterized by low water resistance, negatively affected germination under the conditions of excess water in the filter paper. A low water potential of pellets inhibited seed germination, particularly with the shortfall of water in the germination medium. The water flow between the pellet and the pericarp was of much importance for germination. Under the conditions of the shortfall and excess of water in the germination medium, the physicochemical properties pellets had a greater effect on the drawing of water, and on the water flow between the pellet and the seeds, than under the optimum moisture conditions. Organic pellets were characterized by a greater ability to absorb water than mineral or organic-mineral pellets. The pellets varied in their chemical composition, with the greatest variation (over ninety-fold) relating to pellet’s copper content. The following values exhibited low variety: Zn, Mn, and Pb. It can be concluded that pellet’s cracking force and water resistance are the basic parameters of pellet quality, and the swelling ability of pellets is determined by their organic or monaural composition.
Źródło:
International Agrophysics; 2019, 33, 2; 175-183
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Potencial management of waste phosphogypsum with particular focus on recovery of rare earth metals
Autorzy:
Podbiera-Matysik, K.
Gorazda, K.
Wzorek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/778042.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
phosphogypsum waste
phosphogypsum conversion
rare earth elements (REE)
environmental threats
Opis:
Phosphogypsum is a noxious industrial waste contributing to global environmental and economic problems. This publication focuses above all on phosphogypsum resulting from the processing of apatite as a phosphorus bearing compound, since it contains considerable amounts of lanthanides due to its magma origin. The possibilities of its waste-free processing are large, however they require the application of suitable technologies, frequently expensive ones, and allowing for the individual characteristics of the given waste. The research works conducted so far confirm the possibility of applying phosphogypsum for the recovery of lanthanides, and the process enhances the removal of remaining impurities, thanks to which the purified calcium sulphate (gypsum) may find application for the production of construction materials.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 1; 55-61
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nanobiotechnologia - dziś i jutro
Nanobiotechnology - today and tomorrow
Autorzy:
Malina, D.
Sobczak-Kupiec, A.
Wzorek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/1220034.pdf
Data publikacji:
2011
Wydawca:
Stowarzyszenie Inżynierów i Techników Przemysłu Chemicznego. Zakład Wydawniczy CHEMPRESS-SITPChem
Tematy:
nanotechnologia
biotechnologia
zastosowanie w przemyśle
nanotechnology
biotechnology
application in industry
Opis:
Nanotechnologia, to ogólna nazwa zestawu technik i sposobów tworzenia struktur wykazujących wyjątkowe właściwości, które posiadają, w co najmniej jednym wymiarze od 0,1 do 100 nanometrów. Nanobiotechnologia obejmuje wykorzystanie nanomateriałów w medycynie, przemyśle chemicznym i kosmetycznym, czy przemyśle spożywczym. Jednocześnie daje ogromne możliwości w ochronie środowiska. Jednakże nanobiotechnologia jest nauką stosunkowo młodą, nie do końca przebadaną, dlatego też, już teraz należy zastanowić się nad ewentualnymi zagrożeniami, i starać się znaleźć dla nich jak najlepsze rozwiązania.
The nanotechnology is a general name of the set of techniques of creating structures exhibiting unique properties that have at least one dimension between 0.1 to 100 nanometers. The nanobiotechnology includes the use of nanomaterials in fields of science such as medicine, chemical, cosmetic and food industry. Additionally, nanobiotechnology provides huge opportunities in the environmental protection. Although research in nanotechnology continues apace, relatively little is known about the subsequent health effects of exposure, therefore risk assessment of utilizing nanomaterials is needed.
Źródło:
Chemik; 2011, 65, 10; 1027-1034
0009-2886
Pojawia się w:
Chemik
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Manufacturing of phosphoric acid from hydroxyapatite, contained in the ashes of the incinerated meat-bone wastes
Autorzy:
Krupa-Żuczek, K.
Kowalski, Z.
Wzorek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/779039.pdf
Data publikacji:
2008
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
odpady mięsne
hydroksyapatyt
kwas fosforowy
meat waste
hydroxyapatite
phosphoric acid
Opis:
The results of the investigations concerning phosphoric acid manufacturing, by the extraction method, from the ashes containing hydroxyapatite, obtained through the thermal treatment of bone sludge have been presented. The incinerated bone sludge with ~ 16% P content and the minimal amount of impurities can be an alternative source for phosphoric acid production. The process consists in two stages. In the 1st stage, reaction of hydroxyapatite with phosphoric acid resulting in monocalcium phosphate formation in the solution obtained is carried out. The tests revealed that overall hydroxyapatite dissolution in phosphoric acid takes place when the concentration is 37% H3PO4. In the 2nd stage monocalcium phosphate is converted into calcium sulphate using concentrated sulphuric acid at the recommended temperature of 95°C. The principles of the technological idea of the process of phosphoric acid manufacturing from HA-containing ashes, obtained by bone wastes incineration, as well as a preliminary economic analysis for the production of 10 000 t/year of food-grade phosphoric acid have been developed.
Źródło:
Polish Journal of Chemical Technology; 2008, 10, 3; 13-20
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of sodium tripolyphosphate production processes with a cumulative calculation method
Autorzy:
Kowalski, Z.
Kijkowska, R.
Gorazda, K.
Wzorek, Z.
Nowak, A. K.
Powiązania:
https://bibliotekanauki.pl/articles/778020.pdf
Data publikacji:
2010
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
polifosforan sodu
kalkulacja łączna
analiza ekologiczna
sodium tripolyphosphate
cumulative calculation
ecological analysis
Opis:
Sodium tripolyphosphate – one of the condensed phosphates is an important ingredient in various types of cleaning substances and a food additive. The paper presents a comparison of different variants of STPP production with the application of the cumulative calculation method. The material balances of the processes were taken as the basis of the analysis. The method of the process analysis as shown in the cumulative calculation determines the influence of the emissions of dust and gas pollutions originating from a particular production process, as well as wastewater and solid wastes resulting from it, upon the natural environment. It was proved that the solution of the production STPP with the dry one-step method has the lowest impact on the environment among the three assessed solutions.
Źródło:
Polish Journal of Chemical Technology; 2010, 12, 4; 22-25
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Uwarunkowania gospodarki osadami ściekowymi w Polsce i Niemczech
Conditions of sewage sludge management in Poland and Germany
Autorzy:
Henclik, A.
Kulczycka, J.
Gorazda, K.
Wzorek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/296709.pdf
Data publikacji:
2014
Wydawca:
Politechnika Częstochowska. Wydawnictwo Politechniki Częstochowskiej
Tematy:
osady ściekowe
popioły lotne
fosfor
odzysk
sewage sludge
sewage sludge ash
phosphorous
recovery
Opis:
W Polsce dominującym sposobem zagospodarowania osadów ściekowych jest ich składowanie oraz przyrodnicze wykorzystanie. Zgodnie z przepisami prawa taki sposób zagospodarowania musi ulec zmianie, gdyż od 2016 r. będzie obowiązywał zakaz składowania osadów ściekowych. W Niemczech w latach 80. XX w. około 50% osadów ściekowych było składowanych, ale po wprowadzeniu zakazu składowania nieprzetworzonych osadów ściekowych od 2005 r. ilość ta znacznie spadła. Obecnie ponad 50% osadów ściekowych jest spalanych, około 30% jest suszonych i stosowanych w rolnictwie czy do kształtowania terenów, a pozostałe są kompostowane i znajdują różne zastosowania w gospodarce. W artykule porównano sposoby gospodarowania osadami ściekowymi w Polsce i Niemczech, uwzględniając uwarunkowania technologiczne, prawne i ekonomiczne. Zwrócono szczególną uwagę na możliwości zastosowania przetworzonych osadów ściekowych, w tym pozyskiwania cennych surowców, np. fosforu, z popiołów powstałych po ich spaleniu.
In Poland, annually there is produced about 535 000 Mg of dry matter of municipal sewage sludge, and according to forecasts, this amount in 2022 can reach 746 000 Mg of dry matter. In Germany, for several years the annual amount of the sludge produced is at a level about 2 000 000 Mg of dry matter. The produced sludge should be disposed in an environmentally safe manner. In the case of sewage sludge disposal mainly three basic methods are used: agricultural and biological utilization, landfilling and combustion. In Poland, the dominant methods of sewage sludge management is landfilling and agro-biological utilization. According to the current law, this method of management must be changed, because from 2016 the landfilling of sewage sludge will be restricted. In Germany, in the 80s of the 20th century, about 50% of sewage sludge was landfilled, but after the ban for landfilling of unprocessed sewage sludge since 2005, this number dropped significantly. Currently over 50% of sewage sludge is incinerated, about 30% is dried and used in agriculture or for forming land areas, and the rest is composted and used for different purposes in the economy. The article compares methods of sewage sludge management in Poland and Germany, taking into account the conditions of technological, legal and economic issues. Particular attention was paid to the possibility of using processed sewage sludge, including the acquisition of valuable raw materials such as phosphorus from the ash formed after thermal treatment of these sludge. Deadline for introduction in Poland and Germany restriction for landfilling of unprocessed sewage sludge results in the advancement of both the sludge management method in accordance with the requirements of environmental protection and technological advancement and amount of installations for treatment. In an ongoing study in recent years, new methods of obtaining phosphorus are analysed. Such an alternative source can be sewage sludge or ash after its combustion. Initiatives that are aimed directly at the efficient use of phosphorus and its recovery remain scattered and are rarely taken into account in creating policies. Available form of financing research programs are funded by the national resources of individual countries or EU funds.
Źródło:
Inżynieria i Ochrona Środowiska; 2014, 17, 2; 185-198
1505-3695
2391-7253
Pojawia się w:
Inżynieria i Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dry single-stage method of sodium tripolyphosphate production – technological and economic assessment
Autorzy:
Gorazda, K.
Kowalski, Z.
Kijkowska, R.
Pawłowska-Kozińska, D.
Wzorek, Z.
Banach, M.
Nowak, A. K.
Powiązania:
https://bibliotekanauki.pl/articles/778549.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
sodium tripolyphosphate production
dry method
classic method
technical and economic analysis
Opis:
The study presents a technology of sodium tripolyphosphate (STPP) production with the use of a dry, single-stage method. The reacting substrates (concentrated wet-process phosphoric acid - WPPA and solid Na2CO3 ) are mixed with a recycled final product (STPP) in a mixer, then a „quasi-dry” mixture is calcined in a rotary kiln. Thanks to that, some stages of a classic method of STPP production are eliminated: one of the two-stage neutralization of the phosphoric acid with sodium carbonate at temperature ~80°C, filtration of the neutralised solution and its evaporation, as well as the stage of drying a solution of mono- and di-sodium orthophosphate in a spray dryer. According to the presented technical and economical analysis, the costs of STPP production using a single-stage dry method can be 10% lower compared to the classic method.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 1; 41-44
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
From sewage sludge ash to calcium phosphate fertilizers
Autorzy:
Gorazda, K.
Kowalski, Z.
Wzorek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/779127.pdf
Data publikacji:
2012
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
phosphorus recovery
sewage sludge
sewage sludge combustion
ash extraction
fertilizers production
waste
Opis:
Our work presents the results of the research on the utilization of ashes after sewage sludge combustion comprising phosphorus recovery in the form of useful products. The investigations were divided into three parts: selecting the combustion parameters of sewage sludge, examining ash leaching with mineral acids (nitric and phosphoric) to high phosphorus selectivity assuring a low content of iron and heavy metals in the extracted solutions and precipitation of CaHPO4 .2H2O. Suitable temperature of a sewage sludge combustion enables selective extraction of phosphorus compounds from ash because of hematite phase forming, insoluble in mineral acids. The extracts from phosphoric acid leaching, where the extraction of phosphorus compounds was 96.1%, have very good properties for its further use as the initial solution for CaHPO4 .2H2O with 6% lime milk. The obtained product is characterized by high purity and phosphorus availability compatible even with the feed phosphate standard.
Źródło:
Polish Journal of Chemical Technology; 2012, 14, 3; 54-58
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Increasing the bulk density of STPP - influence of the process parameters
Autorzy:
Gorazda, K.
Banach, M.
Makara, A.
Wzorek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/779274.pdf
Data publikacji:
2011
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
tripolifosforan sodu
STPP
gęstość nasypowa
sodium tripolyphosphate
high bulk density
Opis:
The new requirements that were placed on STPP, like high bulk density, the proper relation of Form I and Form II and suitable physicochemical properties, resulted in the development of the present production methods. The paper presents the research results on increasing the bulk density of STPP by a chemical method. In the introduced method the solid sodium phosphate from spray drying and sodium orthophosphate solution, after acid neutralization, were rubbed together. Such an operation changes the physicochemical properties of the dried sodium phosphate before calcining, which results in increasing the bulk density of STPP to a level of 0.80 kg/dm3. The dependence of STPP bulk density on process parameters such as: sodium orthophosphate solution to solid sodium phosphate mass ratio, temperature of dosed sodium orthophosphate solution, as well as the calcining temperature of mixtures were analysed.
Źródło:
Polish Journal of Chemical Technology; 2011, 13, 2; 40-45
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł

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