- Tytuł:
-
Porfiryny zamknięte w żelu krzemionkowym
Porphyrins closed in sol-gel matrix - Autorzy:
- Wiglusz, R. J.
- Powiązania:
- https://bibliotekanauki.pl/articles/172034.pdf
- Data publikacji:
- 2011
- Wydawca:
- Polskie Towarzystwo Chemiczne
- Tematy:
-
porfiryny
pochodne porfiryn
jony lantanowców
spektroskopia UV-VIS
luminescencja
zol-żel
porphyrins
porphyrin derivatives
lanthanide(III) ions
UV-Vis spectroscopy
luminescence
sol-gel - Opis:
- The need for new, chemically and physically stable luminescent materials operating with UV excitations has stimulated research on luminescence properties of doped sol–gel material. In this work, it has been presented a technology of production of silica gels doped with organic molecules, lanthanide compounds and organic/inorganic composites. Optical properties of these materials as functions of temperature, concentration and excitation wavelength are presented. Dynamics of excited states has been discussed based on the decay times and emission efficiencies data. Mechanisms of ligand-to-metal energy transfer as well as other processes affecting emission efficiency are considered. Silica sol–gels doped with di-aminoacid derivatives of porphyrins: PP(Ser)2(Arg)2, PP(Ala)2(Arg)2, PP(Met)2(Arg)2, where Met, Arg and Ser denote methionine, serine and arginine aminoacids, respectively, and H2TTMePP {tetrakis[4-(trimethylammonio)phenyl]-21H,23H-porphine} have been obtained and spectroscopically studied. These materials can find applications as phosphors or sensors of UV irradiation.
- Źródło:
-
Wiadomości Chemiczne; 2011, 65, 7-8; 675-703
0043-5104
2300-0295 - Pojawia się w:
- Wiadomości Chemiczne
- Dostawca treści:
- Biblioteka Nauki
Artykuł