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Tytuł:
Potencjał węglowodorowy skał macierzystych i geneza gazu ziemnego akumulowanego w utworach miocenu zapadliska przedkarpackiego w strefie Rzeszowa
Hydrocarbon potential of source rocks and origin of natural gases accumulated in Miocene strata of the Carpathian Foredeep in Rzeszów area
Autorzy:
Kotarba, M. J.
Więcław, D.
Kosakowski, P.
Kowalski, A.
Powiązania:
https://bibliotekanauki.pl/articles/2074398.pdf
Data publikacji:
2005
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
zapadlisko przedkarpackie
miocen autochtoniczny
kopalna substancja organiczna
geochemia
potencjał węglowodorowy
gaz ziemny
izotopy trwałe
Carpathian Foredeep
autochthonous Miocene
organic matter
hydrocarbon potential
methane
gas origin
microbial processes
organic geochemistry
stable isotopes
Opis:
In the autochthonous Upper Badenian and Lower Sarmatian strata of the Carpathian Foredeep in the Rzeszów area the total organic carbon (TOC) contents vary from 0.02 to 1.26 wt. %(average 0.64 wt. %). Geochemical studies on the dispersed organic matter demonstrated the presence of gas-prone type III (humic) kerogen with small admixtures of algal type II kerogen. At depths less than 2,500 metres the organic matter is immature, thus microbial processes predominated. Methane concentration in natural gases accumulated within Miocene strata usually exceeded 94 vol. %and was generated by microbial reduction of carbon dioxide. Microbial methane was generated mainly during deposition of autochthonous Miocene sediments, but it is possible that this process continues today on a small scale. Higher gaseous hydrocarbons (mainly ethane and propane), which are usually minor constituents (concentrations less than 0.4 vol. %), were generated during diagenetic processes and at the initial stage of the low-temperature thermogenic processes. The slight changes in the geochemical indices of dispersed organic matter and isotope ratios of natural gases with depth are evidence of the homogeneity of deposition of humic organic matter in shallow marine basin during the Late Badenian and the Early Sarmatian and the fact that similar gas generation conditions can be found in the Miocene sequence. Generation and accumulation of microbial methane and the formation and charging multiple stacked reservoirs within the autochthonous Miocene strata, e.g., Palikówka, Jasionka, Stobierna and Terliczka deposits, was facilitated by rhythmic and cyclic deposition of clays and sands and their very high sedimentation rate.
Źródło:
Przegląd Geologiczny; 2005, 53, 1; 67--76
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Górnojurajsko-dolnokredowe skały macierzyste w zachodniej części Karpat fliszowych
Upper Jurassic--Lower Cretaceous source rocks in the western part of the Flysch Carpathians
Autorzy:
Golonka, J.
Matyasik, I.
Skupien, P.
Więcław, D.
Waśkowska-Oliwa, A.
Krobicki, M.
Strzeboński, P.
Vasicek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/184046.pdf
Data publikacji:
2008
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
Karpaty zewnętrzne
baseny sedymentacyjne
górna jura
kreda dolna
węglowodory
skały macierzyste
Outer Carpathians
sedimentary basins
Upper Jurassic
Lower Cretaceous
hydrocarbons
source rocks
Opis:
Przedmiotem rozważań przedstawionego artykułu jest analiza możliwości odnalezienia górnojurajsko-dolnokredowych skał macierzystych w zachodniej części Karpat fliszowych, na terenie Polski i Republiki Czeskiej. Górnojurajskie margle mikułowskie stanowią skały macierzyste światowej klasy. Te bogate w substancję organiczną skały z TOC 0.2-10% zasilały ropy naftowe w basenie wiedeńskim i pod nasunięciem karpackim w Czechach i Austrii. Podobne skały macierzyste prawdopodobnie występują w głębokich strefach pod nasunięciem w Polsce. Utwory formacji wędryńskiej i grodziskiej nie zawierają większych ilości węgla organicznego. Większą zawartość TOC stwierdzono natomiast w formacji wierzowskiej i najwyższej części formacji grodziskiej. Utwory te reprezentują globalne anoksyczne wydarzenie oceaniczne OAE 1b. Utwory formacji wierzowskiej mogą stanowić potencjalne skały macierzyste dla systemów obejmujących różnego wieku skały zbiornikowe Karpat zewnętrznych.
The analysis of possibility to find Upper Jurassic--Lower Cretaceous source rocks in the western part of Flysch Carpathians in Poland and Czech Republic was the subject of present paper. The Upper Jurassic organic-rich Mikulov marls represent world-class source rocks. These 1400 m thick organic-rich rocks with TOC value 0.2-10% sourced oils in the Vienna Basin and Carpathian subthrust in Czech Republic and Austria. The similar source rocks perhaps exist in the deeper subthrust areas in Poland. The Vendryne Formation rocks do not contain significant amount of organic carbon. The increased TOC was encountered within the Verovice Formation and uppermost part of Hradiste Formatio. These rocks represent global anoxic event OAE 1b. Verovice Formation contains potential source rocks for the Outer Carpathians systems with reservoirs various in age.
Źródło:
Geologia / Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie; 2008, 34, 3/1; 73-81
0138-0974
Pojawia się w:
Geologia / Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Inkluzje fluidalne w halicie oraz bituminy w solach ewaporatów mioceńskich ukraińskiego Przedkarpacia jako wskaźnik występowania nagromadzeń węglowodorów w niżej leżących utworach
Fluid inclusions in halite and bitumens in rock salt from Miocene evaporites in the Ukrainian Fore-Carpathian region: as indicators of hydrocarbon accumulations in the underlying strata
Autorzy:
Więcław, D.
Lytvyniuk, S. F.
Kovalevych, V. M.
Peryt, T.M.
Powiązania:
https://bibliotekanauki.pl/articles/2074593.pdf
Data publikacji:
2008
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
inkluzje fluidalne
bituminy
trwałe izotopy węgla
miocen
zapadlisko przedkarpackie
ewaporaty
fluid inclusions
bitumens
stable carbon isotopes
biomarkers
Miocene
Carpathian Foredeep
evaporites
Opis:
Fluid inclusions in halite from Miocene rock salt of the Ukrainian Carpathian Foredeep Basin in locations where evaporites overlie oil and gas reservoir rocks are characterized by their high methane content and the presence of oil droplets in some of them. They are thus similar to fluid inclusions reported from geochemical aureoles around oil and gas accumulations in the Zechstein (Upper Permian) of western Poland (Kovalevych et al., 2008). Geochemical analyses of bitumen in bulk samples of rock salt (including content and distribution of n-alkanes and isoprenoids, carbon isotope ratios) suggest a varied origin: hydrocarbon extracted from halite from boreholes located in proximity (proved or assumed) of oil and gas deposits (Lopushna-7, Grynivka-525) are probably related to organic material dispersed within the rock salt itself, and those from the barren areas (Verkhniy Strutyn-29) are most probably cogenetic with oil accumulated in the deposits of the Boryslav-Pokuttya Nappe.
Źródło:
Przegląd Geologiczny; 2008, 56, 9; 837-841
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The red-bed-type precious metal deposit in the Sieroszowice-Polkowice copper mining district, SW Poland
Autorzy:
Pieczonka, J.
Piestrzyński, A.
Mucha, J.
Głuszek, A.
Kotarba, M. J.
Więcław, D.
Powiązania:
https://bibliotekanauki.pl/articles/191385.pdf
Data publikacji:
2008
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
Kupferschiefer - Poland
precious metals
geology
petrology
Opis:
Since 50 years copper-silver ores have been extracted from the Lubin-Sieroszowice deposit located on the border between the Lower and Upper Permian sediments. It is a world class stratoidal type deposit. In the whole world the Kupferschiefer unit is recognized as a black, clayey organic-rich shale. The Cu-Ag deposit is a part of the Fore-Sudetic Monocline, and is located on the border of the Lower and Upper Permian strata The monocline includes three rock complexes. The first is the basement, which comprises Proterozoic crystalline rocks and Carboniferous sediments. It is overlain by monoclinally dipping Permian and Triassic sedimentary rocks. In this work, study on ore mineralisation of the red variety of the Kupferschiefer are presented. Oxidation of the Kupferschiefer as an epigenetic phenomena.The oxidized zones reveal low concentrations of simple copper sulphides with the dominating chalcopyrite accompanied by bornite, pyrite, covellite, galena, clausthalite, chalcocite, digenite, spioncopite, geerite, native Au, electrum, tetraauricupride, naumannite, native Pb, Pd-arsenides and minerals of mixed composition: Au-Ag-Pb-Bi-Se-Te, Au-Ag-Pb-Te, Bi-Cu, Bi-Pd and Pd-As-O. Most important are natural alloys of precious metals, Pd-arsenides and oxidized phases (mostly Pd ones), which strongly influence the effectiveness of froth flotation. Precious metals form several parageneses: i - clausthalite - native Pb - electrum - AuPb2, ii - Pt-native Au - native Pd - sobolevskite - native Pb, iii - native Au - haematite - bornite - minerals of covellite-chalcocite group, iiii - electrum - tetraauricupride - chalcocite, iiiii - electrum - Pd-arsenides - tellurides - selenides - BiPd and CuBi natural alloys - Pd-oxides. The red Kupferschiefer variety is distinctly lower in carbonates and resembles rather a marl. Average Fe2O3 content is about 5 times higher than that in the grey Kupferschiefer. The average TOC content in the red Kupferschiefer is about 10 times lower than that in the black Kupferschiefer and about 5 times lower than that in the grey Kupferschiefer. Average Cu content is 1,070 ppm at variability coefficient 81% . The grey Kupferschiefer contains 3 times higher contents of Cu and its variability coefficient is 2 times higher, which points out to quantitative changes during the leaching of copper when secondary oxidation of deposit proceeded. Thus, low Cu and TOC values can be indicative for oxidizing environment and, consequently, can be good exploration guides to zones enriched in precious metals. Average Au content in the red Kupferschiefer is high 15.419 ppm, is much higher than that for the grey Kupferschiefer. Comparison of metal contents in samples from the oxidized zones reveal high variability of Au values in the red, which may change from a few ppm to over 100 ppm. Negative Cu-Au correlation supports the hypothesis on the introduction of gold into the red Kupferschiefer during the leaching of copper. Au horizon is continuous and located close to the bottom contour of Cu deposit. It includes the top part of the sandstone and extends down, even beneath 1 m from the top of the sandstone. The average thickness of the high-Au zones is 0.2 m, and various from 0 up to 1.4 meters. The Au and PGE deposit described in this paper fit well in the world criteria for economic-grade accumulations.
Źródło:
Annales Societatis Geologorum Poloniae; 2008, 78, No 3; 151-280
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biological markers and stable carbon isotope studies of bitumen impregnating Quaternary sediments at Starunia palaeontological site and vicinity (Carpathian region, Ukraine)
Autorzy:
Kotarba, M. J.
Fabiańska, M.
Więcław, D.
Kowalski, A.
Zych, H.
Powiązania:
https://bibliotekanauki.pl/articles/191516.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
biomarkers
stable carbon isotopes
bitumen content
oil origin
woolly rhinoceros
Starunia palaeontological site
Carpathian region
Ukraine
Opis:
Biological markers and stable carbon isotopic compositions of bitumen impregnating the Pleistocene and Holocene sediments around the Starunia palaeontological site (Carpathian region, Ukraine) near discovered remnants of a mammoth and three woolly rhinoceroses, and one almost completely preserved rhinoceros carcass found in 1907 and 1929, were investigated. The research was carried out to assess genetic connections between the bitumen and oils from the nearby deep accumulations of the Boryslav-Pokuttya and Skyba units of the Carpathians. Another aim of these geochemical studies was to reveal the secondary geochemical processes (oxidation and biodegradation) influencing the bitumen, and to determine which environments have been favourable or unfavourable for the preservation of large Pleistocene vertebrates. Bitumen included within the near-surface rocks are not genetically connected with residual organic matter present in Quaternary sediments. Geochemical features, such as distributions of pentacyclic triterpanes and steranes, biomarker parameters and isotope composition indicate that all bitumens originate from oil-prone, Type II kerogen with insignificant admixture of terrestrial Type III kerogen in the middle stage of catagenesis. The oils occurring in deep accumulations in the Starunia area were the sole source of bitumen found in the near-surface sediments. Input of immature organic matter to bitumen from Pleistocene and Holocene sediments has not been found. The main factors differentiating the bitumen were: biodegradation, water washing and/or weathering. Additional influence of transport of bitumen by brine was found. The most favourable conditions for preservation of large, extinct mammals within the Pleistocene muds exist in the vicinity of Nos 22 and 23 boreholes, where bitumen is best preserved. The worst conditions were found in the vicinity of Nos 1, 4, 4' and 15 boreholes. Intensification of biodegradation and weathering effects were followed by intensive, chaotic changes of the remnants of large Pleistocene mammals.
Źródło:
Annales Societatis Geologorum Poloniae; 2009, 79, No 3; 463-480
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Bitumen and salt contents within the Quaternary sediments at Starunia palaeontological site and vicinity (Carpathian region, Ukraine)
Autorzy:
Kotarba, M. J.
Więcław, D.
Toboła, T.
Zych, H.
Kowalski, A.
Ptak, S.
Powiązania:
https://bibliotekanauki.pl/articles/191512.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
bitumen content
chloride ion content
Pleistocene
Holocene
Starunia palaeontological site
Carpathian region
Ukraine
Opis:
Geochemical studies were conducted on bitumen and salts saturating the Pleistocene and Holocene sediments from an abandoned ozokerite mine in Starunia. This location is noted for the discovery of remnants of a mammoth and three woolly rhinoceroses in 1907, and a nearly completely preserved rhinoceros carcass in 1929. The bitumen (oil) and brines (chloride ions) were preserving agents for the large Pleistocene mammals. The main mass of organic carbon hosted in the Pleistocene muds is related to bitumen originating from oil migrating from deep accumulations within the Boryslav-Pokuttya Unit. The highest analysed bitumen content is 9.26 wt%. The chloride ion content, originating from highly concentrated brines ascending from the salt-bearing Miocene Vorotyshcha beds, vary from 0 to 4.66 wt% but this usually does not exceed 1 wt%. The natural pathways of underground fluids (oil, gas and water) migration within the Quaternary sediments were disturbed by intensive ozokerite mining operations run between the last three decades of the 19th century and 1960. Therefore, the present preservation and conservation conditions of large, extinct mammals' remains can be different from those prevailing during the Pleistocene, when the mammals were buried. Taking into consideration the contents of the remaining preservatives: chloride and bitumen, the most favourable zone for fossils conservation and preservation is located close to boreholes Nos 22, 23, 28 and 36N, where the thickness of Pleistocene muds exceeds 2 metres. Generally, the spatial distributions of bitumen and chloride ion contents within the Holocene sediments and salt-bearing Miocene Vorotyshcha beds are very similar to those in the Pleistocene sediments.
Źródło:
Annales Societatis Geologorum Poloniae; 2009, 79, No 3; 447-461
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Charakterystyka macierzystości wybranych utworów fliszowych w przygranicznej strefie polskich Karpat Zewnętrznych
Source rock characteristic of the selected flysch deposits in the transfrontier area of the Polish Outer Carpathians
Autorzy:
Kosakowski, P.
Więcław, D.
Kotarba, M. J.
Powiązania:
https://bibliotekanauki.pl/articles/183729.pdf
Data publikacji:
2009
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
geochemia naftowa
potencjał węglowodorowy
Karpaty zewnętrzne
warstwy menilitowe
kreda górna
kreda dolna
petroleum geochemistry
hydrocarbon potential
Outer Carpathians
Menilite Beds
Upper Cretaceous
Lower Cretaceous
Opis:
Charakterystykę geochemiczną poziomów potencjalnie macierzystych utworów fliszowych jednostek alochtonicznych wschodniej części polskich Karpat Zewnętrznych wykonano dla dolnokredowych warstw wierzowskich, lgockich i spaskich, górnokredowych warstw istebniańskich i inoceramowych oraz oligoceńskich warstw menilitowych. W analizie wykorzystano wyniki badań geochemicznych 875 próbek skał z profili 11 odwiertów i 48 odsłonięć w polskiej i przygranicznej ukraińskiej części Karpat Zewnętrznych. Wyniki badań geochemicznych potwierdzają, że warstwy menilitowe są najlepszymi skałami macierzystymi. Ropotwórczy kerogen II typu jest generalnie niedojrzały lub dojrzały w fazie wczesnej "okna ropnego". Parametry kinetyczne kerogenu warstw menilitowych są zbliżone w jednostkach śląskiej i skolskiej oraz wyraźnie niższe w jednostce borysławsko-pokuckiej. Pozostałe analizowane kredowe wydzielenia litostratygraficzne lokalnie spełniają ilościowe kryterium macierzystości i mogą uzupełniać bilans węglowodorowy utworów fliszowych Karpat.
Potential source rock horizons of the flysch cover were geochemically characterized in the eastern border area of the Polish flysch Carpathians: Lower Cretaceous Verovice, Lgota and Spas Beds, Upper Cretaceous Istebna and Inoceramian Beds as well as Oligocene Menilite Beds. The results of geochemical analyses of 875 rock samples collected from 11 boreholes and 48 outcrops in the Polish Outer Carpathians as well as from the adjacent Ukrainian were analyzed. The results indicate that Menilite Beds are the best source rocks of the Carpathian flysch cover in all analyzed tectonic units. The oil-prone Type II kerogen, deposited in marine environment of regular salinity, was proved to be usually immature or mature at an early stage of "oil window". Kinetic parameters of organic matter dispersed in the Menilite Beds, calculated based on organic sulphur content, are similar for the Silesian and Skole units and significantly lower in the Boryslav-Pokuttya Unit. The remaining lithostratigraphic divisions: Verovice, Lgota, Spas, Istebna and Inoceramian Beds, locally meet the source-rock requirements and can supplement the hydrocarbon balance of the Carpathians.
Źródło:
Geologia / Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie; 2009, 35, 4/1; 155-190
0138-0974
Pojawia się w:
Geologia / Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Estimation of hydrous-pyrolysis kinetic parameters for oil generation from Baltic Cambrian and Tremadocian source rocks with Type-II kerogen
Autorzy:
Więcław, D.
Kotarba, M. J.
Lewan, M. D.
Powiązania:
https://bibliotekanauki.pl/articles/2059067.pdf
Data publikacji:
2010
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Baltic Region
Cambrian
Ordovician
hydrous pyrolysis
organic sulfur
kinetic parameters
type II kerogen
Opis:
Determining kinetic parameters for oil generation from a source rock by hydrous pyrolysis requires a considerable amount of sample (kilograms) and laboratory time (several weeks). In an effort to circumvent these requirements, hydrous-pyrolysis (HP) kinetic parameters for oil generation from Upper Cambrian and Tremadocian source rocks of the Baltic region are estimated by two methods: (1) organic sulfur content in kerogen and (2) HP experiments conducted at 330 and 355°C for 72 h. Estimates for the Upper Cambrian source rocks based on organic sulfur contents gave activation energies from 47 to 56 kcal/mole and frequency factors from 1.156 ' 1025>/sup> to 1.078 ' 1028 m.y.-1 . Tremadocian source rocks based on organic sulfur content gave estimated activation energies from 60 to 62 kcal/mole and frequency factors from 1.790 ' 1029 to 1.104 ' 1030 m.y.-1 . The estimates for the Tremadocian source rocks were less affected by thermal maturation because their low kerogen S/(S + C) mole fractions (< 0.018) remained essentially constant. Conversely, the higher kerogen S/(S + C) mole fractions (>>gt; 0.018) of the Upper Cambrian source rocks decreased with thermal maturation and resulted in overestimation of the kinetic parameters. The second method was designed to estimate kinetic parameters based on two HP experiments. The assumption that the maximum yield in calculating the rate constant at 330°C (k330°C could be determined by a second hydrous pyrolysis experiment at 355°C for 72 h proved not to be valid. Instead, a previously established relationship between Rock-Eval hydrogen index and maximum HP yield for Type-II kerogen was used to calculate k330°C from oil yields generated by the HP experiment at 330°C for 72 h assuming a first-order reaction. HP kinetic parameters were determined from relationships between k330°C and the HP kinetic parameters previously reported. These estimated HP kinetic parameters were in agreement with those obtained by the first method for immature samples, but underestimated the kinetic parameters for samples at higher thermal maturities. Applying these estimated HP kinetic parameters to geological heating rates of 1 and 10°C/m.y. indicated that the Upper Cambrian source rocks would generate oil notably earlier than the overlying Tremadocian source rocks. This was confirmed in part by available data from two neighboring boreholes in the Polish sector of the Baltic.
Źródło:
Geological Quarterly; 2010, 54, 2; 217-226
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Habitat and hydrocarbon potential of the lower Paleozoic source rocks in the Polish part of the Baltic region
Autorzy:
Kowalski, A.
Więcław, D.
Grotek, I.
Kotarba, M. J.
Kosakowski, P.
Powiązania:
https://bibliotekanauki.pl/articles/2059076.pdf
Data publikacji:
2010
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Baltic Region
northern Poland
source rock
hydrocarbon potential
Lower Paleozoic
Opis:
The quantity, genetic type and maturity of organic matter dispersed in the Lower Cambrian to the uppermost part of the Silurian (Pridoli) sequence of the Polish part of the Baltic region was determined based on the results of geochemical analyses of a total of 1377 rock samples collected from 38 onshore and offshore boreholes. The best source rocks were found in the Upper Cambrian-Tremadocian succession where present and initial total organic carbon (TOC) contents are up to ca. 18 and 20 wt.%, respectively. Caradocian (Ordovician) strata can be considered as an additional source of hydrocarbons. In the individual boreholes median present and initial TOC contents vary from 0.5 to 3.3 wt.% and from 1 to 6 wt.%, respectively. The Llandovery (Silurian) strata reveal moderate and locally high hydrocarbon potential of the source rocks. The present TOC content reaches locally 10 wt.% (usually 1-2 wt.%). Another source of hydrocarbons can be clayey intercalations within the Middle Cambrian strata. Their organic matter content rarely exceeds 1 wt.%, being often a result of advanced organic matter transformation. In all lower Paleozoic strata investigated from the Polish part of the Baltic region oil-prone, low-sulphur Type-II kerogen occurs, deposited in anoxic or sub-oxic conditions. The maturity of all source rocks changes from the initial phase of the low-temperature thermogenic processes in the northeastern part to the overmature stage in the southwestern part of the study area.
Źródło:
Geological Quarterly; 2010, 54, 2; 159-182
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Origin of oils accumulated in the Middle Cambrian reservoirs of the Polish part of the Baltic region
Autorzy:
Kowalski, A.
Więcław, D.
Kotarba, M. J.
Powiązania:
https://bibliotekanauki.pl/articles/2059062.pdf
Data publikacji:
2010
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Baltic Region
Lower Paleozoic
oil origin
biomarkers
stable carbon isotopes
oil-oil correlation
Opis:
We have examined 21 samples of crude oils accumulated in the Middle Cambrian sandstone reservoirs from the Polish part of the Baltic region. All the crude oils have similar parameters and indices, which suggests generation from the same source rock. Evaporative fractionation and biodegradation processes were detected in oil collected from the B4-N1/01 borehole. All crude oils have high gravities and low-sulphur contents, less than 0.3 wt.%, which suggests that their source rock contained low-sulphur kerogen deposited in a clastic environment. A low asphaltenes content (below 0.3 wt.%) and high saturate/aromatic hydrocarbon ratios indicate long migration distances or high thermal maturities. The longest migration distance was probably attained by oils from the arnowiec and B16 deposits. The biomarker data indicate an algal origin for the source organic matter deposited under conditions of clastic sedimentation. The stable carbon isotope data support this observation. The maturity of the oils analysed varies from ca. 0.75 to ca. 1.05% on the vitrinite reflectance scale. Unlike the B6, B16, Dbki and arnowiec accumulations, oils from the B3 and B4 accumulations reveal the lowest maturity.
Źródło:
Geological Quarterly; 2010, 54, 2; 205-216
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wstępna ocena macierzystości wybranych utworów paleozoiku Gór Świętokrzyskich
The preliminary assessment of the selected Paleozoic deposits of the Holy Cross Mountains
Autorzy:
Malec, J.
Więcław, D.
Zbroja, S.
Powiązania:
https://bibliotekanauki.pl/articles/183720.pdf
Data publikacji:
2010
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
Góry Świętokrzyskie
paleozoik
potencjał węglowodorowy
Rock-Eval
Paleozoic
Holy Cross Mountains
hydrocarbon potential
Opis:
Na podstawie wyników badań pirolitycznych Rock-Eval 47 próbek skalnych określono wstępną charakterystykę macierzystości wybranych serii litostratygraficznych paleozoiku Gór Świętokrzyskich. Badaniami objęto skały wieku kambryjskiego, ordowickiego, sylurskiego, karbońskiego i permskiego charakteryzujące się ciemną barwą. Utwory kambru i ordowiku w regionie łysogórskim charakteryzują się bardzo słabymi parametrami macierzystości. W sylurze najbogatsze w materię organiczną są iłowce landoweru warstw bardziańskich (średnio 3% wag. TOC), w karbonie - iłowce wizenu i turneju formacji z Zaręb (przeciętnie 2.8% wag. TOC), a w górnym permie - wapień cechsztyński (średnio 1.6% wag. TOC). W utworach dolnego paleozoiku jest obecna materia organiczna pochodzenia morskiego (kerogen II typu). Dominuje ona również w utworach górnego paleozoiku. Lokalne wtrącenia lądowego kerogenu III typu stwierdza się w karbońskiej formacji z Zaręb. Utwory kambru i ordowiku w rejonie łysogórskim są przejrzałe. Stopień przeobrażenia badanych utworów syluru, karbonu i permu odpowiada początkowej i Środkowej fazie "okna ropnego". Obszarem perspektywicznym dla poszukiwań węglowodorów jest NW obrzeżenie Gór Świętokrzyskich, gdzie bogate w materię organiczną paleozoiczne kompleksy litologiczne występują pod osadami pokrywy mezozoicznej.
The hydrocarbon potential of selected Paleozoic lithostratigraphic complexes of the Holy Cross Mountains was determined based on the results of Rock-Eval pyrolysis of 47 samples. For investigations only rocks in dark colours from Cambrian, Ordovician, Silurian, Carboniferous and Permian strata were selected. The Cambrian and Ordovician strata from the Łysogóry Region have poor source-rock parameters. Among the Silurian strata, the claystones of the Bardo Beds (ca. 3 wt. % TOC) are the richest in total organic carbon (TOC). The claystones of the Zaręby Formation (Carboniferous - Visean and Tournaisian) have mean TOC content ca. 2.8 wt. % and the Zechstein Limestone (Permian) ca. 1.6 wt. % TOC. In the Early Paleozoic strata marine kerogen (Type-II) is present. It dominates also in the Upper Paleozoic strata. Local inputs of the terrigenous Type-III kerogen were confirmed in the Zaręby Formation (Carboniferous). The Cambrian and Ordovician strata in the Łysogóry region are overmature. Maturity of the investigated Silurian, Carboniferous and Permian strata corresponds with the initial and middle phases of the "oil window". The NW margin of the Holy Cross Mountains, where the Paleozoic complexes rich in the organic matter are covered by the Mesozoic complex, is perspective area for hydrocarbon exploration.
Źródło:
Geologia / Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie; 2010, 36, 1; 5-24
0138-0974
Pojawia się w:
Geologia / Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Evaluation of hydrocarbon potential of the autochthonous Miocene strata in the NW part of the Ukrainian Carpathian Foredeep
Autorzy:
Kotarba, M. J.
Więcław, D.
Kosakowski, P.
Koltun, Y. V.
Kowalski, A.
Powiązania:
https://bibliotekanauki.pl/articles/191375.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
source rocks
hydrocarbon potential
organic geochemistry
Miocene
Bilche-Volytsia Unit
Ukrainian Carpathian Foredeep
Opis:
The quantity, genetic type, maturity and hydrocarbon potential of dispersed organic matter were determined for the complete sequence of the autochthonous Miocene ranging from the Lower Badenian Sandy-Calcareous Series to the Lower Sarmatian Upper Dashava Formation of the Bilche-Volytsia Unit. Geochemical analyses were conducted on 78 core samples collected from 11 wells in the Ukrainian Carpathian Foredeep between the Ukrainian-Polish state border and the Stryi River. The most favourable source-rock parameters characterize the Upper Badenian Kosiv Formation where the highest TOC contents, from 0.44 to 2.01 wt% (median 0.76 wt%), were found. Only slightly lower values were obtained for the Lower and the Upper Dashava formations – from 0.01 to 1.45 wt% (median 0.72 wt%) and from 0.62 to 0.77 wt% (median 0.71 wt%), respectively. In the Lower Badenian Sandy-Calcareous Series, the Lower Badenian Baraniv beds, and the Upper Badenian Tyras Formation, the TOC content is lower and varies from 0.00 to 0.77 wt%. Immature type III (terrestrial) kerogen dominates the analysed sections of the Kosiv and Dashava formations. Marine organic matter was detected sporadically, and only in the Upper Badenian Kosiv Formation in the vicinity of Kokhanivka, and in the Upper Badenian Kosiv and Tyras formations.
Źródło:
Annales Societatis Geologorum Poloniae; 2011, 81, No 3; 395-407
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Habitat and hydrocarbon potential of the Palaeozoic source rocks in the Kraków–Rzeszów area (SE Poland)
Autorzy:
Więcław, D.
Kotarba, M. J.
Kowalski, A.
Kosakowski, P.
Powiązania:
https://bibliotekanauki.pl/articles/191373.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
source rock
hydrocarbon potential
Rock-Eval pyrolysis
biomarkers
stable carbon isotopes
Palaeozoic basement
Małopolska Block
Polish Carpathian Foredeep
Opis:
The quantity, genetic type and maturity of organic matter dispersed in Ordovician, Silurian, Devonian and Lower Carboniferous strata in the basement of the Carpathian Foredeep between Kraków and Rzeszów were determined based on the results of organic geochemical analyses of 600 rock samples collected from 44 wells. The best source rocks were found in the Silurian strata where the total organic carbon (TOC) content is up to 6.6 wt% and the median value equals ca. 1.5 wt%. The median values of the initial organic carbon contents in individual wells vary from 1.2 to 3.5 wt%. The Ordovician, Lower Devonian and clastic facies of the Lower Carboniferous strata can be considered as an additional source of hydrocarbons with the median TOC values of 0.27, 0.56 and 0.53 wt%, respectively. The Middle and Upper Devonian strata as well as the carbonate facies of the Lower Carboniferous strata have much lower quantities of organic carbon, although in these strata levels with elevated TOC contents were observed. In the Lower Palaeozoic and Lower Devonian strata, the oil-prone, low-sulphur Type II kerogen is present, whereas in the younger divisions presence of the gas-prone Type III kerogen is visible. In the Lower Carboniferous clastics gas-prone kerogen dominates. The Silurian and clastic facies of the Lower Carboniferous strata have been deposited in the normal marine conditions, whereas the Ordovician, Devonian and carbonate facies of the Lower Carboniferous strata usually experienced reducing conditions. The source rocks are mostly at the initial and middle phase of the low-temperature thermogenic processes. Locally, immature (in the Lower Carboniferous carbonates in the vicinity of Łąkta gas-condensate field) or late-mature (in the Middle and Upper Devonian strata in the area of Grobla–Pławowice oil field) source rocks were observed.
Źródło:
Annales Societatis Geologorum Poloniae; 2011, 81, No 3; 375-394
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Origin of liquid hydrocarbons accumulated in the Miocene strata of the Polish Carpathian Foredeep and its Palaeozoic–Mesozoic basement
Autorzy:
Więcław, D.
Powiązania:
https://bibliotekanauki.pl/articles/191540.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
oil origin
biomarkers
stable carbon isotopes
oil-oil correlation
Palaeozoic–Mesozoic basement
Polish Carpathian Foredeep
Opis:
Petroleum geochemical data of 34 oils and condensates accumulated in the Carpathian Foredeep and its Mesozoic and Palaeozoic basement were used to assess their origin and genetic type. The analysed liquid hydrocarbons are characterized by variable densities and sulphur contents. No relationship between these parameters and the reservoir rock age has been found. Secondary processes of evaporative fractionation and biodegradation are evidenced for some oils. These processes proceeded most intensively on the oil from Góra Ropczycka-1K well. The oils from Opaka-1, Lubaczów-157 and Góra Ropczycka-1K wells were generated from organic matter deposited in the Upper Jurassic carbonates. The oil from the inflow in Załazie-2 well originated from the Cambrian strata, but also contains biomarkers characteristic of Miocene strata. The next family, genetically connected with the Silurian and Ordovician source rocks, consists of oils accumulated in the Lower Carboniferous carbonates in Nosówka deposit and in the Upper Jurassic in the inflow into Łękawica-1 well. The condensates collected from the Miocene (Łękawica-1, Pilzno-37, Tarnów-39 and -45 wells) and Upper Jurassic strata (Łąkta-27 and Tarnów-5 wells) were generated by organic matter dispersed in the Middle Jurassic or Lower Carboniferous clastic facies. The remaining oils, from Grobla-Pławowice, Wierzchosławice, Jastrząbka Stara, Partynia-Podborze, Dąbrowa Tarnowska, Brzezówka and Zagorzyce deposits, and the inflows into Tarnów-47 and Pilzno-12 wells were generated from kerogen enriched in organic sulphur usually dispersed in carbonate rocks. Such a type of sediments occurs in the Devonian and Lower Carboniferous strata. Also, these strata as well as the underlying Silurian rocks have sufficient maturity for generation of the discussed oils. The oleanane in the discussed oils most probably originates from kerogen of the Upper Cretaceous or Miocene strata, through which these oils migrated and eluted this biomarker.
Źródło:
Annales Societatis Geologorum Poloniae; 2011, 81, No 3; 443-458
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Petroleum systems in the Palaeozoic–Mesozoic basement of the Polish and Ukrainian parts of the Carpathian Foredeep
Autorzy:
Kotarba, M. J.
Więcław, D.
Kosakowski, P.
Wróbel, M.
Matyszkiewicz, J.
Buła, Z.
Krajewski, M.
Koltun, Y. V.
Tarkowski, J.
Powiązania:
https://bibliotekanauki.pl/articles/191548.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
source rock oil-gas correlations
petroleum system
generation and expulsion areas
Palaeozoic–Mesozoic basement
Carpathian Foredeep
Polska
Ukraine
Opis:
Comprehensive geochemical analyses (Rock-Eval pyrolysis, stable carbon isotopes, biomarkers and aromatic hydrocarbons and elemental composition of kerogen) provide an explanation of genetic relationships between dispersed organic matter in various source rock horizons of the Palaeozoic–Mesozoic basement in the Carpathian Foredeep and also the liquid (oils and condensates) and gaseous hydrocarbons accumulated in reservoirs in the area between Kraków and Ivano-Frankivs’k. The study region was divided into seven zones around oil, condensate and gas deposits for detailed determination of genetic oil – natural gas – source rock correlation. Based on source, reservoir, seal and overburden rocks, generation, expulsion, migration and accumulation of hydrocarbons and trap formation along with 1-D and 2-D modelling, two separated petroleum systems of the Palaeozoic–Mesozoic strata were established. One petroleum system occurs in the western part of the Małopolska Block, the second one in the eastern part of the Małopolska Block and western part of the Kokhanivka Zone (south-eastern Poland – western Ukraine). In addition, nine generation and expulsion areas were identified. The comparison of the two petroleum systems reveals that the western part of the Małopolska Block has considerably greater prospects for oil and gas exploration than the eastern part of the Małopolska Block and the western part of the Kokhanivka Zone.
Źródło:
Annales Societatis Geologorum Poloniae; 2011, 81, No 3; 487-522
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł

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