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    Wyświetlanie 1-8 z 8
    Tytuł:
    Quantum Chemical Study of Aminonitrocyclopentanes as Possible High Energy Density Materials (HEDMs)
    Autorzy:
    Bai, J.
    Chi, W. J.
    Li, L. L.
    Yan, T.
    Wen, X. E.
    Li, B. T.
    Wu, H. S.
    Ma, F. L.
    Powiązania:
    https://bibliotekanauki.pl/articles/358101.pdf
    Data publikacji:
    2013
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    cyclopentane derivatives
    high energy density materials
    impact sensitivity
    quantum chemistry
    DFT
    available free space
    Opis:
    Nitro and amine groups were introduced into the cyclopentane skeleton, and the heats of formation, detonation performance, bond dissociation energies, and impact sensitivity for these aminonitrocyclopentanes were calculated in detail at the B3LYP/6-311G** level. The results show that all of the derivatives have negative heats of formation, which are influenced by the position of the substituent groups. Their stabilities were estimated and analyzed according to their bond dissociation energies and calculated characteristic H50 values. Most of the compounds were found to have a lower impact sensitivity than HMX. Furthermore, the detonation velocities and detonation pressures were predicted via the Kamlet-Jacobs equation. Of all these aminonitrocyclopentanes, E has the best detonation properties (ρ = 2.05 g/cm3, D = 9.11 m/s, P = 39.62 GPa) and can be considered as a candidate high energy density material.
    Źródło:
    Central European Journal of Energetic Materials; 2013, 10, 4; 467-480
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Unconditional security by the laws of classical physics
    Autorzy:
    Mingesz, R.
    Kish, L. B.
    Gingl, Z.
    Granqvist, C.-G.
    Wen, H.
    Peper, F.
    Eubanks, T.
    Schmera, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/220876.pdf
    Data publikacji:
    2013
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    information theoretic security
    unconditional security
    secure key exchange
    secure key distribution
    quantum encryption
    Opis:
    There is an ongoing debate about the fundamental security of existing quantum key exchange schemes. This debate indicates not only that there is a problem with security but also that the meanings of perfect, imperfect, conditional and unconditional (information theoretic) security in physically secure key exchange schemes are often misunderstood. It has been shown recently that the use of two pairs of resistors with enhanced Johnsonnoise and a Kirchhoff-loop - i.e., a Kirchhoff-Law-Johnson-Noise (KLJN) protocol . for secure key distribution leads to information theoretic security levels superior to those of today's quantum key distribution. This issue is becoming particularly timely because of the recent full cracks of practical quantum communicators, as shown in numerous peer-reviewed publications. The KLJN system is briefly surveyed here with discussions about the essential questions such as (i) perfect and imperfect security characteristics of the key distribution, and (ii) how these two types of securities can be unconditional (or information theoretical).
    Źródło:
    Metrology and Measurement Systems; 2013, 20, 1; 3-16
    0860-8229
    Pojawia się w:
    Metrology and Measurement Systems
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Ship Route Design for Avoiding Heavy Weather and Sea Conditions
    Autorzy:
    Cai, Y.
    Wen, Y.
    Wu, L.
    Powiązania:
    https://bibliotekanauki.pl/articles/116290.pdf
    Data publikacji:
    2014
    Wydawca:
    Uniwersytet Morski w Gdyni. Wydział Nawigacyjny
    Tematy:
    Ship Route
    Ship Route Design
    green energy policy
    Heavy Weather
    Avoiding Heavy Weather
    Avoiding Sea Conditions
    Baltic Sea
    Gulf of Finland
    Opis:
    This paper covers the current state of maritime oil transportation in the Baltic Sea and the development of oil transportation in the 2000s, as well as estimations of transported oil volumes in 2020 and 2030 in the Gulf of Finland. The scenarios were formulated on the basis of a current state analysis, energy and transportation strategies and scenarios and expert assessments. The study showed that the volumes of oil transportation in the Gulf of Finland will increase only moderately compared to the current status: 9.5-33.8 %, depending on the scenario. Green energy policy favours renewable energy sources, which can be seen in the smaller volumes of transported oil in the 2030 scenarios compared to the 2020 scenarios. In the Slow development 2020 scenario, oil transport volumes for 2020 are expected to be 170.6 Mt (million tonnes), in the Average development 2020 187.1 Mt and in the Strong development 2020 201.5 Mt. The corresponding oil volumes for the 2030 scenarios were 165 Mt for the Stagnating development 2030 scenario, 177.5 Mt for the Towards a greener society 2030 scenario and 169.5 Mt in the Decarbonising society 2030 scenario.
    Źródło:
    TransNav : International Journal on Marine Navigation and Safety of Sea Transportation; 2014, 8 no. 4; 551-556
    2083-6473
    2083-6481
    Pojawia się w:
    TransNav : International Journal on Marine Navigation and Safety of Sea Transportation
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Direct synthesis of dimethyl carbonate and propylene glycol using potassium bicarbonate as catalyst in supercritical CO2
    Autorzy:
    Wen, Y.
    Zhang, R.
    Cang, Y.
    Zhang, J.
    Liu, L.
    Guo, X.
    Fan, B.
    Powiązania:
    https://bibliotekanauki.pl/articles/778066.pdf
    Data publikacji:
    2015
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    direct synthesis
    dimethyl carbonate
    carbon dioxide
    potassium bicarbonate
    supercritical fluids
    Opis:
    The improved one-pot synthesis of dimethyl carbonate and propylene glycol from propylene oxide, supercritical carbon dioxide, and methanol with potassium bicarbonate as the catalyst has been reported in this paper. As far as we know, it is the first time to use potassium bicarbonate only as the catalyst in the production process which is simple and cheap. Satisfactory conversion rate of propylene oxide and yield of the products could be achieved at the optimized conditions with quite a small amount of by-products. Our new method offers an attractive choice for the production of dimethyl carbonate in large-scale industry efficiently and environmental friendly.
    Źródło:
    Polish Journal of Chemical Technology; 2015, 17, 1; 62-65
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Copper adsorption reaction rate and ion exchange ratio during the copper activation of sphalerite
    Autorzy:
    Liu, J.
    Luo, D.
    Huang, L.
    Wang, Y.
    Wen, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/110651.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    sphalerite
    copper activation
    solution chemistry
    ion exchange ratio
    reaction rate
    Opis:
    A theoretical analysis method of the solution chemistry characteristic of Cu(II) at various pH values was developed. Using such method, the existence form of Cu species and their proportions in aqueous solution can be clearly determined. After that, the copper adsorption and ion exchange ratio (E) during the copper activation of sphalerite were investigated. The results indicated that the copper activation of sphalerite can be divided into two stages, i.e., the fast activation stage (t ≤4 min) and slow activation stage (t >4 min). The general form of the copper adsorption rate was determined as ΓCu=K1ln(t) +Γ1, which is confirmed by the data fitting of the fast activation stage. The lower activation pH results in higher ion exchange efficiency for Cu substituting Zn. For a strong acid pH of 4.1, the E maintains about 1:1 in the entire activation time range and is not dependent on the activation time. However, the value of E is greater than 1 under weak acidic (pH=6.2) and alkaline (pH=9.1) pH conditions and it significantly depends on the activation time. For such conditions, E decreases with increase in the activation time, which supports the ion exchange mechanism, but within short activation time, it is not a 1:1 ion exchange process.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 2; 377-385
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Efficient sulfidization of lead oxide at high temperature using pyrite as vulcanizing reagent
    Autorzy:
    Zheng, Y.-X.
    Lv, J.-F.
    Wang, H.
    Wen, S.-M.
    Huang, L.
    Powiązania:
    https://bibliotekanauki.pl/articles/110351.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    lead oxide
    sulfidization roasting
    pyrite
    reaction mechanism
    TG
    Opis:
    A sulfidization roasting-flotation process was usually viewed to be effective in treating the refractory oxide ore. In this paper, pyrite was proposed to be applied as a potential vulcanizing reagent to transform PbO or its surface to PbS based on feasibilities of technology and economy. The evolution process, phase and characteristics of crystal growth were investigated by TG, XRD and SEM-EDS, respectively, to interpret the interaction mechanism of lead oxide and pyrite at high temperature. It was found that the decomposition process of pyrite under argon atmosphere was a slow process of sulfur released from FeS2 to FexS, which made the process easier to be controlled. When PbO was introduced into the system, the initial solid-solid (PbO-FeS2) reaction and prevailing solid-gas (PbO-S2(g)) reaction occurred at about 500 °C and 700 °C, respectively. Combined with the SEM-EDS analyses results, the optimal temperature for the sulfidization of PbO should be in the range of 700-750 °C.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 2; 270-277
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on mine ventilation resistance coefficient inversion based on genetic algorithm
    Badanie inwersji współczynników oporu wentylacji kopalnianej na podstawie algorytmu genetycznego
    Autorzy:
    Gao, K.
    Deng, L.
    Liu, J.
    Wen, L.
    Wong, D.
    Liu, Z.
    Powiązania:
    https://bibliotekanauki.pl/articles/219844.pdf
    Data publikacji:
    2018
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    wentylacja kopalni węgla
    współczynnik wentylacji
    odwrócenie
    algorytm genetyczny
    coal mine ventilation
    ventilation coefficient
    inversion
    genetic algorithm
    Opis:
    The frictional resistance coefficient of ventilation of a roadway in a coal mine is a very important technical parameter in the design and renovation of mine ventilation. Calculations based on empirical formulae and field tests to calculate the resistance coefficient have limitations. An inversion method to calculate the mine ventilation resistance coefficient by using a few representative data of air flows and node pressures is proposed in this study. The mathematical model of the inversion method is developed based on the principle of least squares. The measured pressure and the calculated pressure deviation along with the measured flow and the calculated flow deviation are considered while defining the objective function, which also includes the node pressure, the air flow, and the ventilation resistance coefficient range constraints. The ventilation resistance coefficient inversion problem was converted to a nonlinear optimisation problem through the development of the model. A genetic algorithm (GA) was adopted to solve the ventilation resistance coefficient inversion problem. The GA was improved to enhance the global and the local search abilities of the algorithm for the ventilation resistance coefficient inversion problem.
    Współczynnik oporu oporu wentylacji jezdni w kopalni węgla jest bardzo ważnym parametrem technicznym w projektowaniu i renowacji wentylacji kopalnianej. Obliczenia oparte na wzorach empirycznych i badaniach terenowych w celu obliczenia współczynnika oporu mają ograniczenia. W niniejszym badaniu proponuje się inwertowaną metodę obliczania współczynnika oporu wentylacji kopalni za pomocą kilku reprezentatywnych danych dotyczących przepływu powietrza i ciśnienia w węzłach. Model matematyczny metody inwersji jest opracowywany na zasadzie najmniejszych kwadratów. Zmierzone ciśnienie i obliczone odchylenie ciśnienia wraz z zmierzonym przepływem i obliczonym odchyleniem przepływu są uwzględniane przy określaniu obiektywnej funkcji, która obejmuje również ciśnienie w węźle, przepływ powietrza i ograniczenia współczynników oporu wentylacji. Problem odwrotności współczynnika oporu wentylacji został przekształcony w nieliniowy problem optymalizacji poprzez opracowanie modelu. Zastosowano algorytm genetyczny (GA) w celu rozwiązania problemu inwersji współczynnika oporu wentylacji. GA został ulepszony w celu zwiększenia globalnych i lokalnych możliwości wyszukiwania algorytmu problemu odwrotności współczynnika oporu wentylacji.
    Źródło:
    Archives of Mining Sciences; 2018, 63, 4; 813-826
    0860-7001
    Pojawia się w:
    Archives of Mining Sciences
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Genetic diversity and relationship of Hunan province of China local tree peonies based on SSR markers
    Autorzy:
    Zhang, M.-H.
    Jin, X.-L.
    Wen, Y.-F.
    Shen, S.
    Wen-Xing
    Wu, S.
    Lu, J.-H.
    Ye-Ye
    Powiązania:
    https://bibliotekanauki.pl/articles/12665369.pdf
    Data publikacji:
    2019
    Wydawca:
    Uniwersytet Przyrodniczy w Lublinie. Wydawnictwo Uniwersytetu Przyrodniczego w Lublinie
    Tematy:
    China
    Hunan Province
    plant cultivation
    tree peony
    Paeonia suffruticosa
    ornamental plant
    genetic diversity
    genetic relationship
    SSR marker
    Opis:
    Paeonia sect. Moutan is a wide known ornamental plant in the world. The objective of this study was to provide the theoretical basis for scientific preservation and utilization of tree peony resources of Hunan province of China. Simple sequence repeat (SSR) markers were applied to reveal the genetic diversity and relationship of 21 tree peony resources and 45 domestic and foreign tree peony cultivars. Clear bands, the size of which ranged from 115 bp to 379 bp, were detected with 14 primers. In total, 90 alleles were detected and the number of alleles detected with one primer varied between 5 and 13; the number of effective alleles ranged from 1.183 to 2.070; the polymorphism ratio of each locus was 100%. The observed heterozygosity, which ranged from 0.120 to 0.851 with an average of 0.532, was larger than the expected one, which ranged from 0.090 to 0.470 with an average of 0.300. Shannon index ranged from 0.137 to 0.695 and fixation index ranged from −0.332 to −0.869. The results show abundant genetic diversity in tree peony of Hunan province and SSR markers distinguishing homonymous tree peony resources successfully.
    Źródło:
    Acta Scientiarum Polonorum. Hortorum Cultus; 2019, 18, 4; 213-223
    1644-0692
    Pojawia się w:
    Acta Scientiarum Polonorum. Hortorum Cultus
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-8 z 8

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