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Tytuł:
Tight focusing of radially polarized beams by a devil’s vortex lens
Autorzy:
Chen, Z.
Hu, X.
Chen, X.
Wang, X.
Pu, J.
Powiązania:
https://bibliotekanauki.pl/articles/173576.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
devil’s vortex lens
radially polarized beam
tight focusing
high numerical aperture
Opis:
Tight focusing of radially polarized beams with a devil’s vortex lens is numerically investigated. Multiple focal spots can be generated in the geometric focus when a radially polarized beam is focused by a high numerical aperture objective in the presence of a devil’s vortex lens. The position of the major focal spot shifts from the geometric focus when a devil’s vortex lens with S = 1 is employed, and the position of the focal spot can be controlled by the numerical aperture of the objective. The intensity components of the major focal spot are influenced by the vortex phase of the devil’s vortex lens. A strong longitudinal component near the optical axis is produced by a devil’s vortex lens without vortex phase, and a nearly pure transversal field is produced by a devil’s vortex lens with vortex phase.
Źródło:
Optica Applicata; 2018, 48, 3; 389-398
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal stability and mechanical properties of hybrid materials based on nitrocellulose grafted by aminopropylisobutyl polyhedral oligomeric silsesquioxane
Stabilność termiczna i właściwości mechaniczne materiałów hybrydowych na bazie nitrocelulozy szczepionej oligomerycznym wielofunkcyjnym aminopropyloizobutylosilseskwioksanem
Autorzy:
Yang, X.
Wang, Y.
Li, Y.
Li, Z.
Song, T.
Liu, X.
Hao, J.
Powiązania:
https://bibliotekanauki.pl/articles/945783.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Chemii Przemysłowej
Tematy:
nitrocellulose
hybrid material
aminopropylisobutyl polyhedral oligomeric silsesquioxane
thermal stability
mechanical properties
nitroceluloza
materiał hybrydowy
oligomeryczny wielofunkcyjny aminopropyloizobutylosilseskwioksan
stabilność termiczna
właściwości mechaniczne
Opis:
The need for improvement in nitrocellulose (NC) storage safety and convenience of application requires an increase in NC thermal stability and enhancement of its mechanical properties. To this aim, hybrid materials were synthesized by grafting NC with aminopropylisobutyl polyhedral oligomeric silsesquioxane (amino-POSS) using isophorone diisocyanate (IPDI) as a crosslinking agent. The structure and elemental composition of the resulting products were confirmed by Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (1H NMR and 29Si NMR), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). It was found, based on the silicon mapping using energy dispersive X-ray spectroscopy (EDS), that amino-POSS was well dispersed in NC matrix. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) studies showed that hybrid amino-POSS-NC materials have higher thermal decomposition activation energy (Ea) compared to NC control sample. According to TGA results, the temperatures of 5 % weight loss (T5 %) and 50 % weight loss (T50 %) as well as the residual masses at 240 °C (CR240 °C), were increased as a result of NC modification with amino-POSS. As can be seen from the digital and scanning electron microscopy (SEM) images, the char layers of amino-POSS-NC hybrid materials after burning in air became more compact with increasing amino-POSS content. XPS studies have shown an increased content of the graphitized carbon in the char residues of the modified samples. The results of DSC, TGA, SEM and XPS studies have directly proved the enhancement of the thermal stability of amino-POSS-NC hybrid materials. In addition, tensile strengths and Young's moduli of amino-POSS-NC hybrid materials were increased gradually with the amino-POSS content in the uniaxial tensile tests. All these results show that the proposed modification of nitrocellulose improves the safety of manufacture and use of this material.
Poprawa bezpieczeństwa przechowywania nitrocelulozy (NC) wymaga zwiększenia jej stabilności termicznej, a wygoda używania poprawy właściwości mechanicznych. W tym celu zsyntetyzowano materiały hybrydowe, w których NC szczepiono oligomerycznym wielofunkcyjnym aminopropyloizobutylosilseskwioksanem (amino-POSS) stosując jako środek sieciujący izoforonodiizocyjanian (IPDI). Strukturę i skład otrzymanych materiałów potwierdzono za pomocą spektroskopii w podczerwieni z transformatą Fouriera (FT-IR), jądrowego rezonansu magnetycznego (1H NMR i 29SiNMR), dyfraktometrii rentgenowskiej (XRD) oraz spektroskopii fotoelektronów rentgenowskich (XPS). Na podstawie wyników badań mapowania Si, otrzymanych metodą spektroskopii dyspersji energii promieniowania rentgenowskiego (EDS), stwierdzono, że amino-POSS został dobrze zdyspergowany w matrycy NC. Badania stabilności termicznej przeprowadzone za pomocą różnicowej kalorymetrii skaningowej (DSC) wykazały, że materiały hybrydowe typu amino-POSS-NC charakteryzują się większymi wartościami energii aktywacji rozkładu termicznego (Ea) niż próbka kontrolna NC. Zgodnie z wynikami analizy termograwimetrycznej (TGA) wartości temperatury ubytku 5 % (T5 %) i 50% (T50 %) masy próbki oraz pozostałości masy w temperaturze 240 °C (CR240 °C) zwiększały się na skutek modyfikacji NC za pomocą amino-POSS. Według fotografii cyfrowych i fotografii wykonanych metodą skaningowej mikroskopii elektronowej (SEM) warstwy węglowe powstałe po spaleniu materiałów hybrydowych w powietrzu wraz ze zwiększeniem zawartości amino-POSS stawały się coraz bardziej zwarte, a wyniki badań XPS wykazały, że tworzyło się coraz więcej węgla w postaci grafitu. Wszystkie wyniki DSC, TGA, SEM i XPS dowodzą poprawy stabilności termicznej materiałów hybrydowych amino-POSS-NC. Stwierdzono także, że wytrzymałość na rozciąganie i moduł Young'a podczas prób jednoosiowego rozciągania materiałów hybrydowych rosną ze zwiększaniem się zawartości amino-POSS. Wyniki wszystkich przeprowadzonych badań dowodzą, że zaproponowana modyfikacja NC poprawia bezpieczeństwo wytwarzania i użytkowania tych materiałów w porównaniu z niemodyfikowanym NC.
Źródło:
Polimery; 2017, 62, 7-8; 576-587
0032-2725
Pojawia się w:
Polimery
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Decomposition Characteristics of Ammonium Nitrate(V) in the Presence of Mn2O3/Graphene Oxides
Autorzy:
Xu, Z.
Xu, G.
Fu, X.
Wang, Q.
Powiązania:
https://bibliotekanauki.pl/articles/358837.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
ammonium nitrate(V)
nano-oxides
graphene oxide
thermal decomposition
RSFTIR
Opis:
Nano-composites (Mn2O3, Mn2O3/graphene oxides (GO)) were prepared by a new method. The nano-composites were characterized by XRD and HRTEM. The catalytic performance of the nano-composites on the thermal decomposition of ammonium nitrate(V) (AN) was investigated by TG-DSC and TG-MS. The reaction of AN with the nano-composites in the condensed phase was investigated by RSFTIR. The results of TG-DSC experiments indicated that the nano-composites significantly catalyze the thermal decomposition of AN, especial Mn2O3/GO. The exothermic reaction of AN with Mn2O3/GO commenced at about 185 °C. Based on the TG-MS results, it was ascribed to N2O formation. In the RSFTIR experiments, the dissociation reaction and ionization reaction of AN were both detected. NOx formation at low temperature was also found. NH2 was directly oxidized by HNO3/NO3− at low temperature. The interaction between Mn2O3 and NH3 was detected according to DRIFT experiments. At elevated temperature, the functional groups of GO are destroyed, which had an influence on the interaction between Mn2O3 and GO. A probable mechanism for the exothermic reaction and then its disappearance is proposed. HNO3 gas was absorbed on the surface of solid AN, which can markedly catalyze the thermal decomposition of AN. Perhaps the HNO3 plays a key role in the exothermic reaction and then the reaction of AN disappears at very low temperatures.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 3; 636-659
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Microstructural Evolution in HMX Based Plastic-bonded Explosive During Heating and Cooling Process: an in situ Small-angle Scattering Study
Autorzy:
Yan, G.
Tian, Q.
Liu, J.
Fan, Z.
Sun, G.
Zhang, C.
Wang, Y.
Chen, B.
Gong, J.
Zhou, X.
Yang, Z.
Nie, F.
Li, J.
Li, X.
Powiązania:
https://bibliotekanauki.pl/articles/358618.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
SANS
SAXS
HMX-PBX
thermal damages
phase transition
Opis:
The thermal damage in octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) based plastic-bonded explosive (PBX) was investigated using in situ small-angle neutron and X-ray scattering techniques. The microstructural evolution was quantitatively characterized by the model fitting parameters of total interfacial surface area (Sv) and void volume distribution. The Sv of HMX-PBX decreased markedly above 100 °C, indicating the movement of binder into the voids. After subsequent cooling to room temperature, the scattering intensity increased significantly with increasing storage time, and a new population of voids with average diameter of 20 nm was observed, accompanied by the gradual phase transition of HMX from δ- to β-phase. The experimental results implied that serious damage within the HMX-PBX was developed during storage after heating.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 4; 916-926
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The endomycorrhizal fungal species and their effects on the growth and nutrient characteristics of Eucalyptus maidenii seedlings in China
Autorzy:
Wang, X.
Kong, X.
Zhao, Y.
Cao, Y.
Cao, Z.
Powiązania:
https://bibliotekanauki.pl/articles/2077654.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Instytut Dendrologii PAN
Tematy:
Eucalyptus maidenii
endomycorrhizal fungi
major species
Opis:
Eucalyptus maidenii plantations are typically fertilized to increase the yields of eucalyptus oil and timber. However, the application of chemical fertilizers is costly and can cause environmental pollution and soil erosion. Mycorrhiza fungi can facilitate the cultivation of optimal seedlings while promoting the growth of trees. To date, investigations into the inoculation of endomycorrhizal fungi to enhance the productivity of E. maidenii in Yunnan, China have not been undertaken. The species/dominant species of endomycorrhizal fungi on E. maidenii in Yunnan were isolated and iden- tified. The effect of endomycorrhizal fungi on E. maidenii was elucidated. The major species of endomycor- rhizal fungi that affect E. maidenii were ascertained. Bulk soil was collected from an E. maidenii plantation, and the species of endomycorrhizal fungi were inves- tigated. The effect of the endomycorrhizal fungi on E. maidenii were analyzed via a single factor experimental design, where the number of spores of endomycorrhizal fungi in the seedling substrate were controlled. The major endomycorrhizal fungi species that affected E. maidenii were ascertained via stepwise regression analysis. Five endomycorrhizal fungal species were isolated from the bulk soil, with the dominant being Glomus ag- gregatum and Glomus mosseae. With higher counts of endomycorrhizal fungal spores in the seedling substrate, the infection rate and intensity of seedlings were observed to increase, as well as the NPK concentrations of the bulk soil. With the increased nitrogen concentration in the bulk soil, the nitrogen concentration of the aerial components of the seedlings also increased. The NPK concentrations in the bulk soil and seedlings, the second order lateral roots, the root activity, and the seedling height were significantly promoted by the presence of endomycorrhizal fungi (the third experimental treatment). The NPK concentrations of the bulk soil and seedlings, as well as the growth indices of seedlings increased through endomycorrhizal fungi inoculation. The major species of the endomycorrhizal fungi on E. maidenii were G. aggregatum, Glomus multicaule, and Claroideoglomus etunicatum.
Źródło:
Dendrobiology; 2020, 83; 68-74
1641-1307
Pojawia się w:
Dendrobiology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of Nb Content on the Thermal, Structural, and Magnetic Properties of FeNbB Ribbons
Autorzy:
Hua, Z.
Zuo, B.
Li, M.
Wang, X.
Wang, L.
Liu, J.
Wang, D.
Dong, L.
Powiązania:
https://bibliotekanauki.pl/articles/1365063.pdf
Data publikacji:
2014-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
65.60.+a
61.43.Dq
Opis:
Amorphous $Fe_{80-x}Nb_{x}B_{20}$ (x = 5, 10, 15) ribbons were prepared by single-roller melt spinning method. The thermal, structural and magnetic properties of $Fe_{80-x}Nb_{x}B_{20}$ (x = 5, 10, 15) ribbons were investigated using differential thermal analysis, X-ray diffraction, and vibrating sample magnetometer. The thermal stability is the lowest for $Fe_{70}Nb_{10}B_{20}$ ribbon and the highest for $Fe_{65}Nb_{15}B_{20}$ ribbon. Along with the increase of Nb content, the supercooled liquid region Δ $T_{x}$ increases, indicating that the amorphous formation ability improves. The primary stages of crystallization of the three ribbons are different. The primary devitrification phases are $Fe_{23}B_6$ type for $Fe_{70}Nb_{10}B_{20}$ and $Fe_{75}Nb_5B_{20}$ ribbons, and α-Fe type for $Fe_{65}Nb_{15}B_{20}$ ribbon. $Fe_{80-x}Nb_{x}B_{20}$ (x = 5, 10) ribbons are ferromagnetic and the $Fe_{65}Nb_{15}B_{20}$ ribbon is paramagnetic. The saturation magnetization ($M_{s}$) decreases with increasing Nb content.
Źródło:
Acta Physica Polonica A; 2014, 125, 5; 1149-1151
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Telomerase enhances osteogenic ifferentiation of sheep bone marrow mesenchymal stem cells (BMSCs) by up-regulating PI3K/Akt pathway in vitro
Autorzy:
Zhu, X.
Zhou, L.
Liu, Z.
Chen, X.
Wei, L.
Zhang, Z.
Liu, Y.
Zhu, Y.
Wang, Y.
Yang, X.
Han, Y.
Powiązania:
https://bibliotekanauki.pl/articles/2087304.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
bone marrow mesenchymal stem cells
telomerase
proliferation
osteogenic differentiation
PI3K/Akt signalling pathway
Źródło:
Polish Journal of Veterinary Sciences; 2020, 23, 3; 359-372
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
SYBR Green-based real-time polymerase chain reaction assay for detection of porcine parvovirus 6 in pigs
Autorzy:
Sun, P.
Bai, C.X.
Zhang, D.
Wang, J.
Yang, K.K.
Cheng, B.Z.
Li, Y.D.
Wang, Y.
Powiązania:
https://bibliotekanauki.pl/articles/2087328.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
porcine parvovirus 6
real-time polymerase chain reaction
SYBR Green
Źródło:
Polish Journal of Veterinary Sciences; 2020, 23, 2; 197-202
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on Ships Safety Control System
Autorzy:
Han, X. J.
Meng, X. Y.
Wang, Z. W.
Powiązania:
https://bibliotekanauki.pl/articles/117442.pdf
Data publikacji:
2009
Wydawca:
Uniwersytet Morski w Gdyni. Wydział Nawigacyjny
Tematy:
Safety of Navigation
ships safety
Control System
Ships Safety Control System
Ship Accidents
Human Factor
Control Strategy
Accident Precaution
Opis:
The proportion of main reasons of ships accidents to the whole reasons is discussed in the paper. Among these reasons, human factors are in the majority. So a method to prevent wrong orders sent by a navigator is laid emphasis on. On the basis of this, a ships safety control system is studied. The construction and control principle of the ships safety control system, as well as control strategy, implementation method and key technology are elaborated in the paper.
Źródło:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation; 2009, 3, 1; 19-22
2083-6473
2083-6481
Pojawia się w:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Specific Heat of RBa$\text{}_{2}$Cu$\text{}_{3}$O$\text{}_{7-x}$ and RBaSrCu$\text{}_{3}$O$\text{}_{7-x}$ Compounds (R = Sm, Dy, Er)
Autorzy:
Tarnawski, Z.
Kim-Ngan, N.-T. H.
Wang, X. Z.
Duijn, V. H. M.
Franse, J. J. M.
Powiązania:
https://bibliotekanauki.pl/articles/1968860.pdf
Data publikacji:
1998-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
74.70.-b
75.40.-s
Opis:
The low-temperature specific-heat C(T) data of high-T$\text{}_{c}$ superconductors RBa$\text{}_{2}$Cu$\text{}_{3}$O$\text{}_{7-x}$(R123O$\text{}_{7-x}$) were reviewed. A discussion of the C(T) data obtained on single-crystalline samples of Er123O$\text{}_{7-x}$ and Sm123O$\text{}_{7-x}$ compounds in applied magnetic fields for better evaluation of the crystal-electric-field parameters is given. The C(T) measurements of Sr-substituted compounds RBaSrCu$\text{}_{3}$O$\text{}_{7}$ revealed the λ-type of peak related to the antiferromagnetic order at 1.2 K and 0.6 K respectively for Dy- and Er-compounds. The magnetic singlet ground state in these compounds is produced by weak exchange interactions of -0.05 T/μ$\text{}_{B}$ and -0.035 T/μ$\text{}_{B}$, respectively. For Nd- and Sm-compounds, only a broad anomaly around 0.6 K was observed which is well fitted with a Schottky-type anomaly with an energy splitting of 1.4 K.
Źródło:
Acta Physica Polonica A; 1998, 93, 3; 513-522
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ship recognition and tracking system for intelligent ship based on deep learning framework
Autorzy:
Liu, B.
Wang, S. Z.
Xie, Z. X.
Zhao, J. S.
Li, M. F.
Powiązania:
https://bibliotekanauki.pl/articles/117419.pdf
Data publikacji:
2019
Wydawca:
Uniwersytet Morski w Gdyni. Wydział Nawigacyjny
Tematy:
intelligent ship
deep learning framework
ship recognition system
ship tracking system
ship recognition and tracking system
intelligent navigation
autonomous ship
maritime safety
Opis:
Automatically recognizing and tracking dynamic targets on the sea is an important task for intelligent navigation, which is the prerequisite and foundation of the realization of autonomous ships. Nowadays, the radar is a typical perception system which is used to detect targets, but the radar echo cannot depict the target’s shape and appearance, which affects the decision-making ability of the ship collision avoidance. Therefore, visual perception system based on camera video is very useful for further supporting the autonomous ship navigational system. However, ship’s recognition and tracking has been a challenge task in the navigational application field due to the long distance detection and the ship itself motion. An effective and stable approach is required to resolve this problem. In this paper, a novel ship recognition and tracking system is proposed by using the deep learning framework. In this framework, the deep residual network and cross-layer jump connection policy are employed to extract the advanced ship features which help enhance the classification accuracy, thus improves the performance of the object recognition. Experimentally, the superiority of the proposed ship recognition and tracking system was confirmed by comparing it with state of-the-art algorithms on a large number of ship video datasets.
Źródło:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation; 2019, 13, 4; 699-705
2083-6473
2083-6481
Pojawia się w:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Shear properties of a honeycomb structure with zero Poisson’s ratio
Autorzy:
Song, L.
Sun, Y.
Han, Z.
Wang, T.
Wang, H.
Yin, C.
Shen, X.
Powiązania:
https://bibliotekanauki.pl/articles/38697109.pdf
Data publikacji:
2023
Wydawca:
Instytut Podstawowych Problemów Techniki PAN
Tematy:
honeycomb structure
zero Poisson’s ratio
shear properties
small deformation
large deformation
Opis:
Honeycomb structures with zero Poisson’s ratio show promising potential for application in variable-sweep wing aircraft. The shear properties of these honeycomb structures serve as a crucial indicator of their morphing capacity. This paper derives the linear and non-linear shear properties of a honeycomb structure with zero Poisson’s ratio. A modified factor is introduced to establish a relationship between the linear and non-linear shear modulus of the honeycomb structure, simplifying the calculation method of the non-linear shear modulus. The validity of theoretical predictions is then confirmed using the finite element method Furthermore, the influences of the geometric parameters on the shear properties of the honeycomb structure with zero Poisson’s ratio are investigated, highlighting the varying contributions of these cell geometric parameters to the shear properties.
Źródło:
Archives of Mechanics; 2023, 75, 5; 521-541
0373-2029
Pojawia się w:
Archives of Mechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Self-extinguishing low-nitrogen nitrocellulose based on synergistic effect of dimethyl methylphosphonate and long-chain chlorinated paraffin
Samogasnąca nitroceluloza o małej zawartości azotu z dodatkiem synergicznie działających dimetylofosfonianu metylu i długołańcuchowej chlorowanej parafiny
Autorzy:
Yang, X.
Wang, J.
Song, T.
Li, Z.
Hao, J.
Powiązania:
https://bibliotekanauki.pl/articles/947543.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Chemii Przemysłowej
Tematy:
nitrocellulose
dimethyl methylphosphonate
chlorinated paraffin
multi-flame retardancy mechanism
nitroceluloza
dimetylofosfonian metylu
chlorowana parafina
wielofazowy mechanizm uniepalniania
Opis:
A series of flame retardant low-nitrogen nitrocelluloses (FR/NCs) containing different weight ratios of dimethyl methylphosphonate (DMMP) and long-chain chlorinated paraffin (CP) were directly prepared by blending method, and the burning behaviors, thermal and mechanical properties, pyrolysis process and char residues were investigated.The results showed that (DMMP/CP = 8/2)/NC at a total flame retardant loading of 17 wt % displayed the self-extinguishing behavior following a multi-flame retardancy mechanism with synergistic effect that includes gas-phase effects, endothermic effectsand slightly condensed-phase effects of flame retardancy. In addition, the tensile properties of the (DMMP/CP = 8/2)/NC revealed a synergistic plasticization effect, which could enhance the flexibility of NC. This new system provided a reference for improving a safety storage and widely application of NC in the future.
Metodą bezpośredniego mieszania składników otrzymano serię trudnopalnej nitrocelulozy o małym udziale azotu (NC) zawierającej dimetylofosfonian metylu (DMMP) zmieszany w różnych stosunkach masowych z długołańcuchową chlorowaną parafiną (CP). Oceniano właściwości palne, termiczne i mechaniczne wytworzonych mieszanin, badano również proces ich pirolizy, a także zwęgloną pozostałość po spaleniu. Stwierdzono, że mieszanina (DMMP/CP = 8/2)/NC z udziałem 17 % mas. uniepalniaczy charakteryzowała się zdolnością do samogaśnięcia w wyniku synergicznego wielofazowego mechanizmu uniepalniającego, obejmującego fazy gazową i częściowo skondensowaną, a także efekt endotermiczny. Dodatkowo właściwości wytrzymałościowe przy rozciąganiu wspomnianej mieszaniny wskazywały na synergiczne działanie plastyfikujące zastosowanych związków uniepalniających. Opracowana mieszanina pozwala na zwiększenie bezpieczeństwa przechowywania i użytkowania nitrocelulozy.
Źródło:
Polimery; 2018, 63, 6; 424-435
0032-2725
Pojawia się w:
Polimery
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Review of the Photodecomposition of Some Important Energetic Materials
Autorzy:
Sun, Y.
Shu, Y.
Xu, T.
Shui, M.
Zhao, Z.
Gu, Y.
Wang, X.
Powiązania:
https://bibliotekanauki.pl/articles/358397.pdf
Data publikacji:
2012
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
photodecomposition mechanisms
energetic materials
Opis:
The photodecomposition mechanisms of energetic materials vary with molecular structure, photodissociation wavelength, the phase of the material, experimental pressure and temperature etc. In this paper, the significant progress on photodecomposition studies of some important energetic materials achieved in recent years is introduced in detail, including nitromethane, DMNA (dimethylnitramine), TATB (1,3,5-triamino-2,4,6-trinitrobenzene), RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine), HMX (1,3,5,7-tetranitro-1,3,5,7- tetrazacycloctane) and CL-20 (2,4,6,8,10,12-hexanitrohexaazaisowurtzitane). The difficulties and prospects of photodecomposition research of energetic materials are also indicated.
Źródło:
Central European Journal of Energetic Materials; 2012, 9, 4; 411-423
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Research on the Mechanism and Kinetics of Polymorphic Transitions of ε CL-20 in Composite Systems
Autorzy:
Guo, X.-Y.
Zhang, P.
Xu, J.-J.
Wang, Z.-H.
Jiao, Q.-J.
Powiązania:
https://bibliotekanauki.pl/articles/358032.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
polymorphic transition
kinetics
activation energy
transition temperature
Opis:
In order to explore the polymorphic transition law for ε-CL-20 in composite systems, the polymorphic transition process of pure ε-CL-20 crystals stimulated by heat was investigated by the X-ray Diffraction (XRD) method, and the kinetic parameters of the polymorphic transition process were calculated (including the apparent activation energy Ea and the pre-exponential factor lnA). Meanwhile the effects of different additives on the polymorphic transition process and kinetics of ε-CL-20 were explored in detail. The experimental results showed that the ε-form tends to transform into the γ- form on heating and that the Ea and lnA for the transition process were 209.97 kJ/mol and 57.47, respectively. The first group of additives clearly promoted the polymorphic transition of ε-CL-20 and lowered the initial transition temperature and the activation energy. The second and third groups of additives inhibited the polymorphic transition of ε-CL-20 and raised the initial transition temperature and the activation energy.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 4; 689-702
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 71

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