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Wyświetlanie 1-15 z 136
Tytuł:
Wzrost i właściwości optyczne kryształu BaGd2 (MoO4)4 domieszkowanego Er3+
Growth and optical properties of Er3+-doped BaGdcrystal 2 (MoO4)4
Autorzy:
Han, S.
Wang, J.
Zhang, H.
Pan, S.
Xv, H.
Wang, Y.
Shen, C.
Powiązania:
https://bibliotekanauki.pl/articles/142191.pdf
Data publikacji:
2013
Wydawca:
Stowarzyszenie Inżynierów i Techników Przemysłu Chemicznego. Zakład Wydawniczy CHEMPRESS-SITPChem
Tematy:
Wytwarzanie kryształów
ciepło właściwe
widmo
czas trwania fluorescencji
crystal growth
specific heat
spectrum
fluorescence lifetime
Opis:
Pojedynczy kryształ BaGd2(MoO4)4 domieszkowany 1% at. Er3+ wyhodowano metodą Czochralskiego. Omówiono szczegóły procedury otrzymywania i wzrostu kryształu. Kryształ ma doskonałą płaszczyznę poślizgu (010), a jego łupliwość czyni go przydatnym jako ośrodek czynny w mikrolaserach. Zmierzono widmo absorpcyjne w zakresie światła widzialnego i bliskiej podczerwieni (NIR) w temperaturze pokojowej. W zakresie od 380 do 1600 nm występuje kilka intensywnych pików absorpcyjnych. Zmierzono również widmo fluorescencyjne wzbudzane za pomocą lampy ksenonowej. Zaobserwowano intensywny pik emisyjny NIR 1536 nm. Czasy trwania fluorescencji 4I13/2 oraz 4I11/2 wyznaczone za pomocą dopasowania krzywej wykładniczej wyniosły odpowiednio 5,85 ms i 112,62 μs. Ciepło właściw Er3+ BaGd2(MoO4)4 w 25°C wynosi 0,471 J g-1 K-1. Na podstawie zmierzonych widm obliczono parametry optyczne na podstawie teorii Judda-Ofelta (J–O).
A 1 at % Er3+ doped BaGd2(MoO4)4 single crystal was grown by the Czochralski method. Details on the preparation and growth procedures were discussed. The crystal has a perfect (010) cleavage plane, and the cleavage character makes the crystal suitable as a gain medium for microchip lasers. The absorption spectrum in the visible and near-infrared (NIR) regions was measured at room temperature. There are several strong absorption peaks in the range from 380 to 1600 nm. The fluorescence spectrum excited by a Xenon lamp was also measured. A strong NIR emission peak located at 1536 nm was observed. The fluorescence lifetimes of 4I13/2 and 4I11/23+:BaGd2(MoO4)4 at 25°C is 0.471 J g-1 K-1. Using the measured spectra, the optical parameters were calculated using the J–O theory.
Źródło:
Chemik; 2013, 67, 9; 763-770
0009-2886
Pojawia się w:
Chemik
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wave propagation in piezoelectric rings with rectangular cross-sections
Autorzy:
Zhang, X.
Wang, Y.
Chen, H.
Powiązania:
https://bibliotekanauki.pl/articles/279995.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Mechaniki Teoretycznej i Stosowanej
Tematy:
piezoelectric rings
orthogonal polynomial
guided wave
dispersion curves
Opis:
The ring ultrasonic transducers are widely used in the ocean engineering and medical fields. This paper employs an extended orthogonal polynomial approach to solve the guided wave propagation in two-dimensional structures, i.e. piezoelectric rings with rectangular cross- -sections. The extended polynomial approach can overcome the drawbacks of the conven- tional orthogonal polynomial approach which can be used to solve wave propagation in one-dimensional structures. Through numerical comparison with the available results for a rectangular aluminum bar, the validity of the present approach is illustrated. The dispersion curves and displacement and electric potential distributions of various rectangular piezo- electric rings are calculated, and the effects of different radius to thickness ratios, width to height ratios and polarizing directions on the dispersion curves are illustrated.
Źródło:
Journal of Theoretical and Applied Mechanics; 2015, 53, 3; 673-682
1429-2955
Pojawia się w:
Journal of Theoretical and Applied Mechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Utilization of cement and other additives for solidification/stabilization of soil contaminated simultaneously with Cd2+ and Pb2+ ions
Autorzy:
Xi, Y.
Wang, H.
Guo, L.
Zhang, M.
Powiązania:
https://bibliotekanauki.pl/articles/208172.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
cement
soil pollution
X-ray diffraction
dyfrakcja rentgenowska
zanieczyszczenie gleby
Opis:
Various additives, including cement, quicklime, fly ash, montmorillonite, sepiolite and their proportions were employed to stabilize/solidify artificially prepared soils contaminated simultaneously with two kinds of ions such as Cd2+ and Pb2+. The unconfined compressive strength of the stabilized soils was measured to estimate the possibility of recycling. The efficiency of Cd2+ and Pb2+ immobilization in contaminated soils was also evaluated using the US EPA TCLP toxicity test. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to elucidate the mechanisms responsible for the immobilization of heavy metals. The experimental results demonstrate that in terms of soils simultaneously polluted with Cd2+ and Pb2+ ions, the curing effect of fly ash is better than that of montmorillonite and sepiolite. When Cd2+ and Pb2+ coexist in soil specimens, the curing is more difficult than for Cd2+ or Pb2+ alone, which is antagonistic mechanism. Also, the leaching concentration of Cd2+ and Pb2+ gradually decreases upon increasing pH when pH < 8. For pH ≥ 8, the leaching concentration of Cd2+ and Pb2+ reached a minimum. Besides, the results of XRD and SEM are in agreement with those of the strength and leaching tests.
Źródło:
Environment Protection Engineering; 2018, 44, 1; 61-73
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Using chemometrics to identify water quality in Daya Bay, China
Autorzy:
Wu, M.-L.
Wang, Y.-S.
Sun, C.-C.
Wang, H.
Lou, Z.-P.
Dong, J.-D.
Powiązania:
https://bibliotekanauki.pl/articles/49096.pdf
Data publikacji:
2009
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
robust principal component analysis
water quality
chemometrics
China
cluster analysis
Daya Bay
Opis:
In this paper, chemometric approaches based on cluster analysis, classical and robust principal component analysis were employed to identify water quality in Daya Bay (DYB), China. The results show that these approaches divided water quality in DYB into two groups: stations S3, S8, S10 and S11 belong to cluster A, which lie in Dapeng Cove, Aotou Harbor and the north-eastern part of DYB, where water quality is related mainly to anthropogenic activities. The other stations belong to cluster B, which lie in the southern, central and eastern parts of DYB, where the quality is related mainly to water exchange with the South China Sea. Cluster analysis yields good results as a first exploratory method for evaluating spatial difference, but it fails to demonstrate the relationship between variables and environmental quality on the one hand and the untreated data on the other. However, with the aid of suitable chemometric approaches, the relationship between samples or variables can be investigated. Classical and robust principal component analysis can provide a visual aid for identifying the water environment in DYB, and then extracting specific information about relationships between variables and spatial variation trends in water quality.
Źródło:
Oceanologia; 2009, 51, 2; 217-232
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Transcriptomic analysis of different tissues in Korean arborvitae
Autorzy:
Mu, H.
Gao, Y.
Cheng, F.
Lin, L.
Wang, G.
Xia, F.
Powiązania:
https://bibliotekanauki.pl/articles/2077762.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Instytut Dendrologii PAN
Tematy:
Thuja koraiensis
transcriptome
tissue specific
Opis:
Korean arborvitae (Thuja koraiensis) is an evergreen shrub or small tree native to Korea and the extreme Changbai Mountain of China threatened by habitat loss. Due to the limited genomic sources of Ko- rean arborvitae, it is important to explore transcriptome to understand this economically important plant. We used RNA-seq technology to characterize the transcriptome of root, stem and leaf in Korean arborvitae, respectively. Based on the bioinformatics analysis of assembled transcriptome data, transcriptional path- ways and differentially expressed genes (DEGs) were identified. There were 152.26 million reads generated, and 446,568 unigenes with a mean size of 423.51 nt obtained via de novo assembly. Of these, 204,091 unigenes (45.70%) were further annotated by comparison to public protein databases. A total of 63,495 unigenes (14.22%) were associated into 130 pathways by searching against the KEGG database. DEGs analysis identified 11,890, 5,900 and 10,136 DEGs from the comparison of root vs. stem, root vs. leaf and stem vs. leaf, respectively. Besides, photosynthesis, plant hormone signal transduction and metabolism and biosynthesis of sugar and amino acids were changed in different tissues. We obtained 446,568 unigenes in Korean arborvitae and 11,890, 5,900 and 10,136 DEGs from the compar- ison of root vs. stem, root vs. leaf and stem vs. leaf, respectively. These results will aid in understanding and carrying out future studies on the molecular basis of Korean arborvitae and contribute to future artificial production and applications.
Źródło:
Dendrobiology; 2019, 81; 31-39
1641-1307
Pojawia się w:
Dendrobiology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thidiazuron enhanced somatic embryogenes is fromcallus lines of Arabica Coffee and subsequent plant regeneration
Autorzy:
Wang, Y.-C.
Lin, M.-Z.
Huang, B.
Chung, H.-H.
Chen, J.-T.
Powiązania:
https://bibliotekanauki.pl/articles/19649.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Źródło:
Acta Biologica Cracoviensia. Series Botanica; 2018, 60, 2
0001-5296
Pojawia się w:
Acta Biologica Cracoviensia. Series Botanica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermally Induced Polymorphic Transformation of Hexanitrohexaazaisowurtzitane (HNIW) Investigated by in-situ X-ray Powder Diffraction
Autorzy:
Liu, Y.
Li, S.
Wang, Z.
Xu, J.
Sun, J.
Huang, H.
Powiązania:
https://bibliotekanauki.pl/articles/358065.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
HNIW
polymorphism
in situ X-ray diffraction
phase transition
heat stimulation
Opis:
The ε→γ phase transition of HNIW induced by heat was investigated with in situ X-ray powder diffraction (PXRD). The effects of purity, particle size, insensitive additives and the time of isothermal heat treatment on the phase transition were evaluated. It was found that the phase transition is irreversible with changes in temperature, and the two phases can coexist in a certain temperature range. Moreover, the initial phase transition temperature increases with increasing purity and decreasing particle size of HNIW, and thus with the approximate crystal density. The addition of graphite and paraffin wax to HNIW as insensitive additives leads to a decrease in the initial phase transition temperature, but the addition of TATB does not affect the initial phase transition temperature. Thus, TATB is a suitable insensitive additive. Moreover, at the critical temperature, the isothermal time determined the efficiency of the ε- to γ-phase transition. This work lays the foundations for the choice of molding technologies, performance test methods, ammunition storage options, as well as the manufacture of HNIW-based explosive formulations.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 4; 1023-1037
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Reinforcement of the TNT System by a Newly-designed GAP-based Polyurethane-Urea: a Molecular Simulation Investigation
Autorzy:
Qian, W.
Shu, Y.
Ma, Q.
Li, H.
Wang, S.
Chen, X.
Powiązania:
https://bibliotekanauki.pl/articles/358512.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
TNT
GAP
polyurethane-urea
inter-molecular interaction
mechanical properties
Opis:
A glycidyl azide (GAP)-based polyurethane-urea (PUU) modifier used in the 1,3,5-trinitrotoluene (TNT)-based composite explosive was investigated by molecular simulation. Inter-molecular interactions were investigated using quantum chemistry calculation on the dimer of TNT and GAP-PUU, and attractive forces were found between the two molecules. The cohesive energy densities and the solubility parameters were obtained through molecular dynamics simulations combined with thermodynamic calculations on the TNT and GAP-PUU amorphous cell models, and the miscibility of the modifier in molten TNT was predicted to be good. The interaction energies and the mechanical properties were then obtained by molecular simulations and mechanical calculations on the solid-phase models of the GAP-PUU with TNT along three crystalline directions, and an improvement in the mechanical properties was predicted.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 2; 411-426
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of the Energetic Additive Coated MgH2 on the Power of Emulsion Explosives Sensitized by Glass Microballoons
Autorzy:
Cheng, Y.
Wang, Q.
Liu, F.
Ma, H.
Shen, Z.
Guo, Z.
Liu, R.
Powiązania:
https://bibliotekanauki.pl/articles/357940.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
emulsion explosive
power
hydrogen storage material
magnesium hydride
Opis:
Traditional emulsion explosives, in spite of excellent water resistance, safe handling and good storage performance, have low power problems which seriously hinders their use. In order to improve the power of emulsion explosives, a hydrogen based emulsion explosive was devised. Scanning electron microscope pictures and experimental storage results show that the coating effect and stability of coated magnesium hydride (MgH2) are very good. The power of an emulsion explosive sensitized by glass microballoons was significantly increased (24.30 mm compression of lead block) after adding coated MgH2, compared to only 16.10 mm compression when not added. Thus emulsion explosives with coated MgH2 as an energetic additive have many potential applications.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 3; 705-713
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, Characterization and Compatibility Studies of Poly(DFAMO/NIMMO) with Propellant and PBX Ingredients
Autorzy:
Li, H.
Yang, Y.
Pan, J.
Wang, W.
Pan, R.
Zhu, W.
Powiązania:
https://bibliotekanauki.pl/articles/358094.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
energetic binder
synthesis
characterization
compatibility
PDN
Opis:
Oxetane-based polymers substituted with difluoroamino groups can be used as energetic binders in propellants and polymer-bonded explosives (PBXs). As a novel candidate, poly(3-difluoroaminomethyl-3-methyloxetane/3-nitratomethyl-3-methyloxetane) (PDN) was synthesized and its structure was established. Thermogravimetry (TG) and differential scanning calorimetry (DSC) were employed to investigate its thermal decomposition behaviour. The compatibility between PDN and some common ingredients of propellants and PBXs was evaluated by the DSC method. PDN with good thermal stability was synthesized via a cationic solution polymerization process. Additionally, it has improved compatibility with cyclotetramethylenetetranitramine (HMX), carbon black (C.B.) and lead carbonate (PbCO3) compared with homopoly(3-difluoroaminomethyl-3-methyloxetane) (PDFAMO). PDN could be used as a promising difluoroamino energetic binder in the future.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 1; 85-99
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Theoretical Studies of a New Insensitive Explosive, 2’-Methyl-3-nitro-2’H-[1,3’-bi(1,2,4-triazole)]-5,5’-diamine
Autorzy:
Luo, J.
Liu, Y.
Wang, J.
Chai, T.
Yuan, J.
Chang, S.
Yu, Y.
Jing, S.
Ma, H.
Powiązania:
https://bibliotekanauki.pl/articles/358633.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
insensitive explosive
synthesis
theoretical studies
density functional theory
new 1,2,4-triazole derivative
Opis:
A new insensitive energetic material 2’-methyl-3-nitro-2’H-[1,3’-bi(1,2,4-triazole)]-5,5’-diamine (1) was prepared by a three-step synthesis from commercially available chemicals. The energetic title compound was comprehensively characterized by various means, including FT-IR, multinuclear (1H, 13C, 14N) NMR spectroscopy, elemental analysis, HPLC and thermal analysis. The sensitivities of the synthesized material towards various external stimuli (impact, friction) were determined according to the BAM method. The optimized structure and related thermodynamic parameters were obtained at the DFT-B3LYP/6-31+G** theoretical level. The detonation properties of the material were also predicted according to the Kamlet-Jacobs formulae and the Monte-Carlo method. The results show that the density, heat of formation, detonation velocity, detonation pressure, impact sensitivity and purity were 1.83 g/cm3, 369 kJ/mol, 7.52 km/s, 25.4 GPa, 82.3 J and 97.7%, respectively. In addition, the compound was an insensitive high explosive which could meet the requirements of high energetic materials.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 2; 269-280
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Characterization of PolyNIMMO-HTPB-polyNIMMO Triblock Copolymer as a Potential Energetic Binder
Autorzy:
Wang, X.
Shu, Y.
Lu, X.
Mo, H.
Xu, M.
Powiązania:
https://bibliotekanauki.pl/articles/358529.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
triblock copolymer
cationic ring opening polymerization
polymer
DSC
Opis:
Triblock copolymer polyNIMMO-HTPB-polyNIMMO was synthesized by cationic ring opening polymerization of NIMMO (3-nitratomethyl-3-methyloxetane) in the presence of hydroxyl-terminated polybutadiene catalyzed by BF3·OEt2. The polymer was characterized by FT-IR, 1H NMR, 13C NMR spectroscopy, and GPC. DSC was used to investigate the thermal behaviour of the triblock copolymer and its exothermic decomposition peak was found to be at 215 °C. All of the results indicated that the triblock copolymer polyNIMMO-HTPB-polyNIMMO might serve as a potential energetic propellant binder.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 3; 456-467
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Characterization of 1-(1-chlorocyclopropyl)-2-(1,2,4-triazol-1-yl)ethan-1-one
Autorzy:
Ji, H.
Niu, Y.
Liu, D.
Wang, W.
Dai, C.
Powiązania:
https://bibliotekanauki.pl/articles/778677.pdf
Data publikacji:
2017
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
prothioconazole
1,2,4-triazole
N-alkylation reaction
Opis:
A simple and efficient method to prepare 1-(1-chlorocyclopropyl)-2-(1,2,4-triazol-1-yl)ethan-1-one via nucleophilic substitution of 2-chloro-1-(1-chlorocyclopropyl)ethanone and 1,2,4-triazole is described. The title compound is the key intermediate required for the synthesis of prothioconazole, a promising agricultural fungicide. By exploring changes in the reaction time, temperature, ratio of starting reagents, acid binding agent, and the nature of phase transfer catalyst, the reaction conditions could be optimized to afford the desired N-alkylated material in near-quantitative yield. The ultimate yield of the product after recrystallization was 93%, with a purity of 99% based on its characterization by Gas Chromatography-Mass Spectrometer (GC-MS), Fourier Transform infrared spectroscopy (IR), Proton Magnetic Resonance (1H NMR), and Carbon-13 Nuclear Magnetic Resonance (13C NMR). The synthetic process is suitable for industrial application, with the advantages of high yield and facile preparation under mild operating conditions.
Źródło:
Polish Journal of Chemical Technology; 2017, 19, 1; 41-47
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on the rheological properties of CL-20/HTPB casting explosives
Autorzy:
Li, H.-X..
Wang, J-Y.
An, C.-W.
Powiązania:
https://bibliotekanauki.pl/articles/358310.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
casting explosive
particle gradation
rheological properties
plasticizer
Opis:
The rheological properties of ε-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12hexaazaisowurtzitane (CL-20)/hydroxy-terminated polybutadiene (HTPB) casting explosives with different formulations were tested and analyzed. The effects of both the weight percentage (wt.%) of CL-20 and its particle size, as well as the type and content of plasticizers, on the rheological properties of CL-20/HTPB casting explosives were investigated in detail. The results show that the viscosity and pseudoplasticity of CL-20/HTPB casting explosives increase with increasing wt.% of CL-20 and decreasing particle size. The gradation of CL-20 particle size also affects the rheological properties of the casting explosives. When the mixing ratio of 30 μm to 2 μm particles is 3:1, the viscosity reaches its lowest value and the non-Newtonian index reaches the maximum value of 0.5698. The viscosity, non-Newtonian index and impact sensitivity of the samples studied are clearly decreased by the addition of dioctyl adipate (DOA), dioctyl sebacate (DOS) or dibutyl phthalate (DBP). However, the three plasticizers do not appear to affect the thermal decomposition of CL-20/HTPB casting explosives. With respect to the rheological properties, mechanical properties and sensitivity, DOA is the optimum plasticizer to use in CL-20/HTPB casting explosives.
Źródło:
Central European Journal of Energetic Materials; 2014, 11, 2; 237-255
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 136

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