- Tytuł:
- Magnetic recykling of complex catalysts immobilized on thiol-functionalized polymer supports
- Autorzy:
-
Bączek, N
Strzelec, K.
Wąsikowska, K. - Powiązania:
- https://bibliotekanauki.pl/articles/779554.pdf
- Data publikacji:
- 2013
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
encapsulation
magnetic recycling
epoxy resin
supported catalysts
Heck reaction
hydrogenation reaction - Opis:
- In this work, the application of the thiol-functionalized epoxy resin encapsulated on magnetic core as supports for palladium catalysts is reported. The study focuses on obtaining of heterogeneous catalysts which can be separated by magnetic field. Palladium complex catalyst [PdCl2(PhCN)2] has been heterogenized by anchoring to these supports via ligand exchange reaction. The characterization of polymeric supports and heterogenized palladium catalysts has involved research methods like time-of-flight secondary ion mass spectrometry (TOF-SIMS), scanning electron microscopy (SEM) and nitrogen BET surface area measurements. The activity and stability during long-term use of the investigated catalytic systems were tested in a Heck and hydrogenation reaction. The influence of the type of thiols used as epoxy hardeners and the morphology of the supports on the catalytic properties of epoxy-supported palladium catalysts was discussed.
- Źródło:
-
Polish Journal of Chemical Technology; 2013, 15, 3; 65-68
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki
Artykuł