- Tytuł:
- Effect of Molecular Orientation on Photovoltaic Efficiency and Carrier Transport in a New Semiconducting Polymer
- Autorzy:
-
Kažukauskas, V.
Pranaitis, M.
Sentein, C.
Rocha, L.
Raimond, P.
Duyssens, I.
Van Severen, I.
Lutsen, L.
Cleij, T.
Vanderzande, D. - Powiązania:
- https://bibliotekanauki.pl/articles/1813394.pdf
- Data publikacji:
- 2008-03
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
73.50.-h
81.40.Rs
81.40.Tv
73.61.Ph - Opis:
- New functionalized soluble poly(p-phenylene vinylene) derivative bearing polar molecules was designed and synthesized in order to investigate effects of molecular orientation in polymer photovoltaic devices. The active polar molecule is the 4-(N-butyl-N-2-hydroxyethyl)-1- nitro-benzene group. The grafting of the push-pull molecule with a donor/transmitter/acceptor structure, possessing a large ground state dipole moment, enables the molecular orientation by a dc electric field. An internal electric field stored in such system facilitates exciton dissociation and improves charge transport in single-layer devices. In our systems an increase in the external quantum efficiency by a factor of about 1.5 to 2 is estimated. The associated effects of orientation on the carrier injection and transport properties were evidenced.
- Źródło:
-
Acta Physica Polonica A; 2008, 113, 3; 1009-1012
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł