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Wyświetlanie 1-2 z 2
Tytuł:
Development of a Catalyst for Flue Gas Purification from Carbon Monoxide of Multi-Chamber Furnaces for Baking Electrode Blanks
Autorzy:
Ivanenko, Olena
Trypolskyi, Andrii
Gomelya, Nikolai
Karvatskii, Anton
Vahin, Andrii
Didenko, Olga
Konovalova, Viktoria
Strizhak, Peter
Powiązania:
https://bibliotekanauki.pl/articles/1839547.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
carbon monoxide
flue gas
purification
catalyst
oxidation
conversion
multi-chamber furnace
Opis:
The catalysts based on natural zeolite-clinoptilolite of Sokyrnytsia deposit modified with oxides of Mn4+, Fe2+, Fe3+, Cu2+, Cr3+ were synthesized. It was determined that 100% conversion of carbon monoxide was achieved at a temperature of 390°C when using the copper-manganese-oxide catalyst (30% CuO + 70% MnO2). It was shown that although the use of the manganese-oxide catalyst provided 92.8% of CO conversion degree, this catalyst had the most advantages for application compared to the other studied solids. The structural parameters of the manganese-oxide catalyst were determined using XRD, SEM, and nitrogen adsorption. The composition of the main elements of the catalyst samples was determined by micro-X-ray spectral analysis. It was shown that using the catalyst containers in chambers heated by flue gases in the fire channels of a multi-chamber furnace for baking of electrode blanks can be one of the constructive solutions to the problem of flue gas purification from carbon monoxide. The environmental safety of the copper-manganese-oxide catalyst application for the treatment of the flue gases of electrode production is justified by obtaining a catalyst from spent sorbents for purification of the manganese-containing natural water and its non-toxicity in the case of burial or storage in landfills.
Źródło:
Journal of Ecological Engineering; 2021, 22, 1; 174-187
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Assessment of the Effect of Oxygen and Carbon Dioxide Concentrations on Gas Evolution During Heat Treatment of Thermoanthracite Carbon Material
Autorzy:
Panov, Yevgen
Gomelia, Nikolai
Ivanenko, Olena
Vahin, Andrii
Leleka, Serhii
Powiązania:
https://bibliotekanauki.pl/articles/124362.pdf
Data publikacji:
2020
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
carbon monoxide
flue gases
thermoanthracite pouring
graphitization
oxidation
pyrolysis
Opis:
The processes of the interaction of carbon material (thermoanthracite pouring) with a gas-air mixture in a heat chamber were studied while heating to 800–850°C. The influence of temperature, oxygen and carbon dioxide concentration on the formation efficiency of carbon monoxide, carbon dioxide, hydrogen and methane was determined. A pilot plant was created, which provided heating of the carbon material at the indicated temperatures and regulating the supply of air and carbon dioxide. It was found that a noticeable oxidation of the carbon material in the heat chamber in the presence of oxygen or carbon dioxide occurs at the temperatures above 500°C. Significant concentrations of carbon monoxide were formed at temperatures of 600–800°C. It was shown that when using gas mixtures with an oxygen content of 7–21% minimum concentrations of carbon monoxide are formed at an oxygen content of 14%. At temperatures above 500°C, the formation of hydrogen and methane in gas flows was noted. The methane yield increased with the decreasing oxygen content.
Źródło:
Journal of Ecological Engineering; 2020, 21, 2; 139-149
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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