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    Wyświetlanie 1-13 z 13
    Tytuł:
    The Oxygen Reduction Activity of Nitrogen-doped Graphene
    Autorzy:
    Jian-feng, Liu
    Ge, Sun
    Ting, Wang
    Kai, Ning
    Bin-xia, Yuan
    Wei-guo, Pan
    Powiązania:
    https://bibliotekanauki.pl/articles/2174819.pdf
    Data publikacji:
    2022
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    Nitrogen Doping
    Graphene
    Oxygen Reduction Activity
    Molecular Simulation
    Opis:
    Graphite nitrogen, pyridine nitrogen and pyrrole nitrogen are the main nitrogen types in nitrogen-doped graphene materials. In order to investigate the mechanism of the oxygen reduction activity of nitrogen-doped graphene, several models of nitrogen-doped graphene with different nitrogen contents and different nitrogen types are developed. The nitrogen content is varied from 1.3 at% to 7.8 at%, and the adsorption energy is calculated according to the established models, then the band gaps are analyzed through the optimization results, so as to compare the mag-nitude of the conductivity. Finally, the oxygen reduction activity of graphite nitrogen-doped graphene (GNG) is found to be better than pyridine nitrogen-doped graphene (PDNG) and pyrrole nitrogen-doped graphene (PLNG) when the nitrogen content is lower than 2.6 at%, and the oxygen reduction activity of PDNG is the best when the nitrogen content was higher than 2.6 at%.
    Źródło:
    Polish Journal of Chemical Technology; 2022, 24, 3; 29--34
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study of flocculation performance and mechanism of ultrafine montmorillonite particles with NPAM
    Autorzy:
    Wang, Lujun
    Min, Fanfei
    Chen, Jun
    Wang, Ting
    Zhou, Zhuang
    Powiązania:
    https://bibliotekanauki.pl/articles/2146901.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    montmorillonite
    flocculant
    nonionic polyacrylamide
    density functional theory
    Opis:
    Ultrafine montmorillonite particles are the main clay minerals in industrial wastewater. In order to explore the flocculation performance and mechanism of flocculant with montmorillonite, the effects of nonionic polyacrylamide (NPAM) dosage and molecular weight on flocculation effect were studied using a flocculation sedimentation experiment. The morphology of flocs was observed by metallographic microscope and scanning electron microscope, and the microscopic adsorption mechanism was studied utilizing density functional theory (DFT). The results show that the best reagent system for the montmorillonite sample is that the molecular weight of NPAM is 14 million and the added amount is 100 g/t. The floc size increases with rising NPAM dosage, forming a unique multi-level compact space network structure through polymer bridging. The adsorption energy of acrylamide on the Na-(001) surface of montmorillonite is -108.81 kJ/mol, which is significantly higher than -50.66 kJ/mol on the None-(001) surface. Hydrogen bonding is not the main reason for the adsorption of acrylamide on the montmorillonite surface. NPAM mainly causes the flocculation and sedimentation of montmorillonite through the processes of polymer bridging and electrostatic attraction. This study can provide a theoretical basis for the design and synthesis of new flocculants.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 3; art. no. 147790
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synergistic Effects of Plasma Treatment and Fabric Structure on Stab-Resistance Performances of STF/Aramid Composite Fabrics
    Synergistyczny wpływ obróbki plazmowej i struktury tkaniny na parametry odporności na przebicie tkanin kompozytowych STF/aramid
    Autorzy:
    Zhang, Xiayun
    Li, Ting-Ting
    Wang, Yunlong
    Li, Mengxuan
    Lin, Jia-Horng
    Powiązania:
    https://bibliotekanauki.pl/articles/234167.pdf
    Data publikacji:
    2020
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Biopolimerów i Włókien Chemicznych
    Tematy:
    aramid fibre
    weaving
    stab resistance
    shear thickening fluid
    plasma treatment
    włókno aramidowe
    tkanie
    odporność na przebicie
    ciecz zagęszczana ścinaniem
    obróbka plazmowa
    Opis:
    In order to improve the contribution of STF and fabric to the stab resistance of STF-impregnated aramid soft armour materials, the plasma treatment of various fabric structures was conducted. This study explored the interactive effects of plasma treatment, fabric structure and particle size on the spike and knife resistance properties of plasma-treated STF/Aramid fabrics. Fumed silica and polyethylene glycol (PEG) based STFs were prepared with various particle sizes (15 nm, 75 nm) at a solid content of 15%. Various weave structures of fabrics (plain, 2/2 twill, 5/3 satin, 2/2 basket) were impregnated with STF and then plasma-treatment conducted. The rheological behaviour of STF in various silica sizes as well as the spike and knife quasi-static stab resistances of the resultant plasma-treated STF/aramid fabrics in various weave structures were both explored. The results show that the various weave structures of STF/Aramid fabrics treated with plasma exhibited a significant enhancement of quasi-static spike resistance. Furthermor, 2/2 twill, 5/3 satin and basket weaving plasma-treated STF/Aramid with a coarser silica particle in STF showed a higher improvement in quasi-static spike resistance. Interactive effect results show that the plasma treatment of fabric and the silica size in STF affected spike resistance more significantly, while knife resistance was only significantly affected by the fabric structure.
    Aby poprawić odporność na przebicie tkaniny kompozytowych STF/aramid przeprowadzono ich obróbkę plazmową. Zbadano interaktywny wpływ obróbki plazmowej, struktury tkaniny i wielkości cząstek na właściwości odporności na przebicie kolcami i nożem tkanin kompozytowych STF/aramid poddanych działaniu plazmy. Przygotowano STF na bazie zmatowionej krzemionki koloidalnej i glikolu polietylenowego (PEG) o różnych wielkościach cząstek (15 i 75 nm) o zawartości substancji stałych wynoszącej 15%. Różne struktury splotu tkanin (m.in. gładkie, 2/2 diagonalne i 5/3 satynowe) zostały zaimpregnowane STF, a następnie przeprowadzono obróbkę plazmą. Badano zarówno zachowanie reologiczne w przypadku różnych rozmiarów krzemionki, jak i quasi-statyczne odporności na przebicie kolcami i nożem otrzymanych tkanin STF/aramid poddanych obróbce plazmowej i wykonanych z zastosowaniem różnych struktur splotu. Wyniki pokazały, że różne struktury splotu tkanin STF aramid poddanych obróbce plazmą wykazały znaczne zwiększenie quasi-statycznej odporności na przebicie kolcami. Ponadto tkany z grubszą cząstką krzemionki w STF wykazały poprawę w quasi-statycznej odporności na przebicie kolcami. Wyniki pokazały, że obróbka plazmowa tkaniny i rozmiar krzemionki w STF wpłynęły bardziej na odporność na przebicie kolcami, podczas gdy na wytrzymałość na przebicie nożem istotny wpływ miała tylko struktura tkaniny.
    Źródło:
    Fibres & Textiles in Eastern Europe; 2020, 2 (140); 67-75
    1230-3666
    2300-7354
    Pojawia się w:
    Fibres & Textiles in Eastern Europe
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Optimization of soft-sensing model for ash content prediction of flotation tailings by image features tailings based on GA-SVMR
    Autorzy:
    Wang, Guanghui
    He, Ting
    Kuang, Yali
    Lin, Zhe
    Powiązania:
    https://bibliotekanauki.pl/articles/1449310.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    GA-SVMR
    image features
    flotation
    ash content
    Opis:
    Ash content is one of the most important properties of coal quality and the ash prediction of coal slurry in floatation is urgent and important for automation of the floatation process. The aim of this paper is to propose a method of ash content prediction for flotation tailings by the use of image analysis. The mean gray value, energy, skewness and coal slurry concentration are highly correlated with coal slurry ash content by correlation analysis based on experiments while the particles’ size has little effect on the ash. Single variable linear prediction model between coal ash content and mean gray value was developed by the LS and its prediction errors were below 7%. For improving the prediction results, an ash prediction model based on GA-SVMR was established with additional three input parameters: energy, skewness, coal slurry concentration. This model has a higher accuracy with predictive errors all below 5% and 80% of them less than 3%. Results indicate that GA-SVMR model has a higher precision compared with LS model and PSO-SVMR model and soft-sensing model based on image features of the slurry can be used as a new method for ash detection of floatation tailings in automatic control process of coal flotation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 4; 590-598
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Purification and characterization of a novel laccase from the mushroom Pleurotus nebrodensis
    Autorzy:
    Tian, Guo-Ting
    Zhang, Guo-Qing
    Wang, He-Xiang
    Ng, Tzi
    Powiązania:
    https://bibliotekanauki.pl/articles/1039721.pdf
    Data publikacji:
    2012
    Wydawca:
    Polskie Towarzystwo Biochemiczne
    Tematy:
    Pleurotus nebrodensis
    Laccase
    purification
    characterization
    Opis:
    A novel laccase with a molecular mass of 64 kDa and the N-terminal sequence AIGPDDTINF was isolated from fresh fruiting bodies of the mushroom Pleurotus nebrodensis. The purification protocol comprised ion exchange chromatography on DEAE-cellulose, CM-cellulose, and Q-Sepharose, and gel filtration on Superdex 75. The laccase was adsorbed on DEAE-cellulose and Q-Sepharose, but not on CM-cellulose. It demonstrated an optimal temperature of 70°C. The enzyme activity increased steadily over the temperature range 20°C-70°C. There was only a slight reduction in activity at 80°C. However, all activity disappeared following exposure to 100°C for 10 minutes. The enzyme activity changed only slightly over the pH range 3-5, with the optimum at pH 5, but underwent a precipitous decline when the pH was elevated to 6, and was undetectable at pH 8 and pH 9.
    Źródło:
    Acta Biochimica Polonica; 2012, 59, 3; 407-412
    0001-527X
    Pojawia się w:
    Acta Biochimica Polonica
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Application of MoO3 as an efficient catalyst for wet air oxidation treatment of pharmaceutical wastewater (Experimental and DFT study)
    Autorzy:
    Chen, Chen
    Cheng, Ting
    Wang, Lei
    Tian, Yuan
    Deng, Qin
    Shi, Yisu
    Powiązania:
    https://bibliotekanauki.pl/articles/1845416.pdf
    Data publikacji:
    2021
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    wet air oxidation
    catalytic wet air oxidation
    pharmaceutical wastewater
    DFT
    Opis:
    In this work, a highly effective catalyst (MoO3) is synthesized and applied for catalytic wet air oxidation (CWAO) treatment of pharmaceutical wastewater. The catalyst is systematically characterized to investigate the morphology, crystal structure and chemical composition, and the findings demostrated that MoO3 catalyst is successfully synthesized. The degradation mechanism is also illustrated by the density functional theory (DFT) calculation. The degradation experiments confirm that MoO3 catalyst exhibits excellent catalytic performance in CWAO, and the removal rate of TOC (Total Organic Carbon) and COD (Chemical Oxygen Demand) is achieved to more than 93%. The catalyst doses, reaction temperature and reaction time have a significant impact on the removal of pollutants. The degradation process of pollutants in CWAO could be satisfactorily fitted by the second-order kinetics. Besides, MoO3 displays a favorable stability as CWAO catalyst. DFT calculation illustrates that MoO3 catalyst is a typical indirect band gap semiconductor. Moreover, the high temperature environment provides the thermal excitation energy, which favors to the free electrons nearing Fermi level to escape the material surface, and excites them to the conduction band, then directly reduces the pollutants in CWAO. These findings demonstrate that MoO3 can be used as an efficient and excellent catalyst for CWAO of pharmaceutical wastewater.
    Źródło:
    Archives of Environmental Protection; 2021, 47, 2; 47-60
    2083-4772
    2083-4810
    Pojawia się w:
    Archives of Environmental Protection
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Nitrogen-doped Carbon Catalyst by Ultrasonic for Electrocatalytic CO2 Reduction
    Autorzy:
    Liu, Jianfeng
    Wang, Ting
    Zhang, Zhenhai
    Ning, Kai
    Yin, Shibin
    Yuan, Binxia
    Powiązania:
    https://bibliotekanauki.pl/articles/780079.pdf
    Data publikacji:
    2020
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    Nitrogen-doped
    Catalyst
    Ultrasonic
    CO2 Reduction
    Opis:
    The electrocatalytic reduction of carbon dioxide into valued chemicals such as formic acid has the most promising potential in applying renewable energy for useful materials and mitigating the greenhouse effect. However, the studies still focus on developing catalysts with low price and high catalytic properties. In this study, nitrogen atoms were decorated into carbon structure by a unique ultrasonic method, then the nitrogen-doped carbon material was applied as catalyst in CO2 reduction, it exhibited excellent electrochemical activity, 4 times higher than the normal method. The improved activity should be attributed to the interaction between nitrogen and carbon atoms through analysis.
    Źródło:
    Polish Journal of Chemical Technology; 2020, 22, 3; 24-28
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Evaluating measurement accuracy and repeatability with a new device that records spatial knee movement
    Autorzy:
    Tian, Fei
    Huang, Qiuyue
    Zheng, Zhi
    Li, Ningwei
    Zhu, Ting
    Dai, Wei
    Wang, Shaobai
    Powiązania:
    https://bibliotekanauki.pl/articles/27324129.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    gait analysis
    repeatability
    motion analysis
    three-dimensional
    knee joint
    analiza chodu
    powtarzalność
    analiza ruchu
    trójwymiarowy
    staw kolanowy
    Opis:
    Purpose: A novel portable system has been used to evaluate spatial knee movement, but its accuracy and repeatability is not known. The aim of this study was to investigate the accuracy and repeatability of the measurement. Methods: Ten healthy participants were included, and the knee motion trajectory during walking were assessed. Six evaluations were conducted (three days by two raters) for each participant. The motion parameters at the key points and the range of motion were statistically analyzed. Intraclass correlation coefficients (ICC), standard error of the measurement (SEM), and the Bland–Altman method were used. Results: For intra-rater repeatability, 1) the ICC values range from 0.75 to 0.9 for rotations; and 0.64 to 0.96 for translations. Among the ICC values, 100% of rotations and 90% of translations were not less than 0.70; 2) among the SEM values, 100% of rotations were not more than 5°, while 73.3% of translations were less than 3 mm. For inter-rater repeatability, 1) the ICC values range from 0.68 to 0.99 for rotations; and 0.57 to 0.93 for translations. Among the ICC values, 95.6% of rotations and 82.2% of translations were not less than 0.70; 2) among the SEM values, 100% of rotations were not more than 5°, and 48.9% of translations were less than 3 mm. The Bland–Altman plots showed good agreement for intra- and inter-repeatability. Conclusions: The results indicated that the accuracy and repeatability of the measurement were acceptable, except for the inter-rater repeatability for translation. This may help researchers and physicians better interpret the measurement data.
    Źródło:
    Acta of Bioengineering and Biomechanics; 2020, 22, 3; 55--67
    1509-409X
    2450-6303
    Pojawia się w:
    Acta of Bioengineering and Biomechanics
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Hsa-miR-331-3p inhibits VHL expression by directly targeting its mRNA 3-UTR in HCC cell lines
    Autorzy:
    Cao, Yiyi
    Zhang, Jinnan
    Xiong, Dongmei
    Wang, Dan
    Wu, Ting
    Huang, Ailong
    Tang, Hua
    Powiązania:
    https://bibliotekanauki.pl/articles/1039137.pdf
    Data publikacji:
    2015
    Wydawca:
    Polskie Towarzystwo Biochemiczne
    Tematy:
    HCC
    HBV
    miRNA
    Hsa-miR-331-3p and VHL
    Opis:
    Dysregulation of miRNA is widely involved in human cancers, including hepatocellular carcinoma (HCC). Array data for miRNAs indicated that miR-331-3p might be one of the disorderly expressed miRNAs in HCC cell lines, but the function of miR-331-3p in HCC remains unclear. In this study, quantitative real time polymerase chain reaction (qRT-PCR) results indicated that miR-331-3p was up-regulated in HepG2.2.15 cells, Ad-HBV-HepG2 cells and pCH9/3091transfected SMMC7721 cells compared with their control group, respectively. miRNA target prediction software was used, and VHL was found to be one of the target genes of miR-331-3p. qRT-PCR and western blot analysis indicated VHL expression was decreased when miR-331-3p was over-expressed and increased when miR-331-3p was inhibited in SMMC7721 cells. The luciferase reporter activity was inhibited in SMMC7721 cells when co-transfected with miR-331-3p expression vector and VHL 3'-UTR wild type vector and increased in HepG2.2.15 transfected with miR-331-3p inhibitor compared to its control group respectively. When co-transfected with miR-331-3p expression vector and VHL 3'-UTR mutated type vector in SMMC7721 cells the luciferase reporter activity was recovered. All of these results show that HBV up-regulated miR-331-3p expression in HCC cell lines and miR-331-3p could inhibit VHL expression by directly targeting its 3'-UTR. This provided useful information in exploring the mechanism of HCC induced by HBV infection.
    Źródło:
    Acta Biochimica Polonica; 2015, 62, 1; 77-82
    0001-527X
    Pojawia się w:
    Acta Biochimica Polonica
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Optimization of optical uniformity factors of backlight module using robust design method
    Autorzy:
    Wang, Ju-Chi
    Fan, Yu-Cheng
    Fang, Te-Hua
    Tran, Anh-Son
    Cheng, Yu-Ting
    Powiązania:
    https://bibliotekanauki.pl/articles/2060680.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    backlight module
    uniformity
    Taguchi method
    LightTools
    Opis:
    In order to meet the advent of the high-definition liquid crystal display (LCD) era, in addition to the high-quality panel manufacturing technology, how the backlight module can provide a uniform backlight with higher uniformity for a better experience in viewing, is a very important and urgent issue. In this study, the 15.6-inch side-in backlight module was used as the benchmark, and the Taguchi method was applied to find the high uniformity. The matching of the fishbone diagram affects the optical uniformity factor of the backlight module, such as the size of the light guide plate dot, the color of the plastic frame, the color of the fixed gel of the light guide plate, and the difference of the reflection surface. The optical analog software LightTools is used according to the orthogonal table. The signal-to-noise (S/N) ratio of the average uniformity characteristics is obtained, then it is converted into the best response factor of the factor response table and the factor reaction diagram. The homogeneity at 13 points is as high as 90.12%, which is 4.72% higher than the original design factor. The contribution of the four factors to the uniformity can be obtained by using the variance analysis. Finally, the influence of each factor level on the uniformity is discussed.
    Źródło:
    Optica Applicata; 2022, 52, 1; 5--20
    0078-5466
    1899-7015
    Pojawia się w:
    Optica Applicata
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Factors influencing the mental health status of support nurses and their workload during the COVID-19 epidemic
    Autorzy:
    Dai, Zhen-Juan
    Xu, Shen-Ting
    Xue, Fang-Ying
    Zhou, Jian-Ying
    Chen, Jian-Qin
    Wang, Xue-Min
    Powiązania:
    https://bibliotekanauki.pl/articles/23369109.pdf
    Data publikacji:
    2023-12-15
    Wydawca:
    Instytut Medycyny Pracy im. prof. dra Jerzego Nofera w Łodzi
    Tematy:
    COVID-19
    mental health
    epidemic prevention and control
    general mental health questionnaire
    NASA-TLX
    support nurse
    Opis:
    Objectives The authors used the National Aeronautics and Space Administration Task Load Index (NASA-TLX) and general health questionnaire to analyze the factors influencing the mental health status and the workload of support nurses during the COVID-19 epidemic. Material and Methods The authors conducted a cross-sectional survey of 349 support nurses in April–October 2022. Using QuestionStar, a powerful online survey tool, the authors administered surveys to the participants, collected data on the mental health status and workload of support nurses, and analyzed the influencing factors based on the collected data. Results A total of 316 questionnaires were successfully collected, with an effective rate of 98.75%. The proportion of support nurses with mental health problems was 25% and the value of the NASA-TLX questionnaire was: M±SD 68.91±7.28 pts. Multi-factor analysis revealed that the number of children, family support, and nursing support location were the influencing factors of mental health status, while the multivariate analysis revealed that the presence of symptoms, nursing support location, support work type, and total 12-item General Health Questionnaire (GHQ-12) score were the influencing factors of the workload of support nurses. Conclusions Compared to their counterparts in the plains, nurses working in isolated plateau regions who were caring for children and lacked family support, were more likely to have mental health issues. There was a positive correlation between the changes in GHQ-12 and NASA-TLX scores of the study participants. Compared to their counterparts in the plains and the tropical regions, nurses working in plateau regions had a heavier workload. As part of the follow-up measures to prevent and treat patients impacted by the COVID-19 epidemic, it is important to improve the mental health evaluation, consultation, and treatment of the support nurses to guarantee the high quality of the first-line support work.
    Źródło:
    International Journal of Occupational Medicine and Environmental Health; 2023, 36, 6; 761-772
    1232-1087
    1896-494X
    Pojawia się w:
    International Journal of Occupational Medicine and Environmental Health
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Experimental Insight into the Catalytic Mechanism of MFe2O4 (M = Ni, Zn and Co) on the Thermal Decomposition of TKX-50
    Autorzy:
    Hou, Xiaoting
    Zhang, Ming
    Zhao, Fengqi
    Yang, Yanjing
    An, Ting
    Li, Hui
    Pan, Qing
    Wang, Xiaohong
    Zhang, Kun
    Powiązania:
    https://bibliotekanauki.pl/articles/27788010.pdf
    Data publikacji:
    2021
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    bimetallic iron oxide
    thermal decomposition
    TKX-50
    catalysis
    mechanism
    Opis:
    Synthesized dihydroxylammonium 5,5’-bistetrazole-1,1’-diolate (TKX-50) owes its outstanding application prospects in the field of insensitive solid propellants not only to its high energetic performance but also to its low mechanical sensitivity. Based on the excellent catalytic activity of bimetallic iron oxides for the thermal decomposition of TKX-50, the catalytic mechanism of bimetallic iron oxides (NiFe2O4, ZnFe2O4 and CoFe2O4) for TKX-50 pyrolysis has been explored. For this study, the decomposition process of TKX-50, before and after mixing with the bimetallic iron oxides NiFe2O4, ZnFe2O4 and CoFe2O4 was monitored by in-situ FTIR and gas-phase MS-FTIR instruments. Of the different catalysts, ZnFe2O4 gave the best result for reducing the initial decomposition temperature of TKX-50. Additionally, the activation energy of functional group cleavage of TKX-50, before and after mixing with ZnFe2O4, was also calculated for mechanism analysis from the results of the in-situ FTIR measurements. The results showed that the condensate and the gas-phase decomposition products of TKX-50 remained unchanged after mixing with different catalysts, while the activation energy of tetrazole ring cleavage was significantly reduced. The results of this study will be helpful for the rational design of insensitive solid propellant formulations containing TKX-50, and for understanding the pyrolysis mechanisms of TKX-50 before and after mixing with the efficient catalyst ZnFe2O4.
    Źródło:
    Central European Journal of Energetic Materials; 2021, 18, 2; 223--244
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Preparation of magnesium hydroxide by modifier-directed hydration and its effect on flame retardancy and mechanical properties of polypropylene
    Autorzy:
    Wang, Mei Jia
    Bai, Li Mei
    Zhang, Meng Ting
    Ma, Yu Xin
    Zhao, Liu Cheng
    Li, Shao Ying
    Powiązania:
    https://bibliotekanauki.pl/articles/27323651.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    modifier
    hydration preparation
    magnesium hydroxide
    polypropylene
    Opis:
    With the rapid development of the polymer materials industry and the improvement of people's environmental awareness, magnesium hydroxide has been widely used in polymer materials due to its high decomposition temperature, non-toxic smoke suppression, and the advantages of neutralizing harmful gases produced by polymer combustion. However, the conventional preparation methods of magnesium hydroxide exhibit several issues, including high hydrophilicity, elevated polarity, and limited compatibility with polymers. This research proposes an improved method by adding sodium stearate and KH560 modifier, controlling the rate of magnesium oxide and preparing magnesium hydroxide flame retardants using a modifier-directed hydration method. Various characterizations confirmed its morphology, particle size and structure. The magnesium hydroxide exhibits low polarity, small particle size, stable structure and excellent hydrophobicity (with a contact angle of 120.32°, and a free energy of 1.34mN/m). In parallel, the magnesium hydroxide/polypropylene composites demonstrate excellent flame retardancy (LOI of 25%, V-1 grade) and simultaneously enhance the dispersion of magnesium hydroxide within the polypropylene matrix, improving the material's toughness and strength.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 175706
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-13 z 13

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