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    Wyświetlanie 1-7 z 7
    Tytuł:
    Relative Explosive Strength and Detonation Characteristics of Some Explosive Mixtures Containing Urea and Peroxides
    Autorzy:
    Hussein, A. K.
    Zeman, S.
    Suceska, M.
    Jungova, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/403797.pdf
    Data publikacji:
    2017
    Wydawca:
    Wojskowa Akademia Techniczna im. Jarosława Dąbrowskiego
    Tematy:
    urea
    hydrogen peroxide
    perchlorate
    nitrates
    ballistic mortar
    Explo5
    Opis:
    Several mixtures, based on urea, urea hydrogen peroxide complex (UHP), triacetone triperoxide (TATP) with some inorganic oxidants were studied by means of ballistics mortar with TNT as a reference standard. The detonation pressure, P, detonation velocity, D, detonation heat, Q, and volume of gaseous product at standard temperature and pressure conditions (STP condition) were calculated by the mean of Explo5 V6.3. The relatively high explosive strength of some samples relative to the TNT charge, focuses on the positive influence of hydrogen peroxide presence in these mixtures, with advantage in the form of its complex with urea (i.e. as UHP). This influence connects with hydroxi-radical in the mixture under its initiation (as the first intermediate of this initiation reaction).
    Źródło:
    Problemy Mechatroniki : uzbrojenie, lotnictwo, inżynieria bezpieczeństwa; 2017, 8, 3 (29); 23-32
    2081-5891
    Pojawia się w:
    Problemy Mechatroniki : uzbrojenie, lotnictwo, inżynieria bezpieczeństwa
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Dynamic Mechanical Properties of Artifcially Aged Double Base Rocket Propellant and the Possibilities for the Prediction of Their Service Lifetime
    Autorzy:
    Matečić-Mušanić, S.
    Sućeska, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/358886.pdf
    Data publikacji:
    2013
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    ageing
    double base rocket propellants
    dynamic mechanical analysis
    glass transition temperature
    lifetime prediction
    loss modulus
    softening temperature
    storage modulus
    tan δ
    Opis:
    The ageing of double base (DB) rocket propellants, as a consequence of the chemical reactions and physical processes that take place over time, has a signifcant effect on their relevant properties, such as chemical composition and mechanical and ballistic properties. The changes to relevant properties limit the safe and reliable service life of DB rocket propellants. Accordingly, numerous research efforts have been undertaken to fnd reliable methods to measure the changes caused by ageing in order to assess the quality of DB rocket propellants at a given moment of their lifetime, and to predict their remaining service lifetime. In this work we studied the dynamic mechanical properties of DB rocket propellant artifcially aged at temperatures of 80, 85 and 90 °C, in order to detect and quantify changes in the dynamic mechanical properties caused by ageing, and to investigate the possibilities for the prediction of service lifetime. Dynamic mechanical properties were studied using a dynamic mechanical analyser (DMA). The results obtained have shown that ageing causes signifcant changes in the storage modulus (E´), the loss modulus (E˝) and the tan δ curves’ shape and position. These changes are quantifed by following some characteristic points on the E´-T, E˝-T, and tan δ-T curves (e.g. glass transition temperatures; storage modulus, loss modulus and tan δ at characteristic temperatures, etc.). It has been found that the monitored parameters are temperature and time dependent, and that they can be shown to be functions of the so called ‘reduced time of artifcial ageing’. In addition, it has been found that, on the basis of known changes in viscoelastic properties as a function of time and ageing temperature, and the known kinetic parameters of the ageing process, it is possible to calculate (determine) the change in the properties at any ageing temperature provided that the mechanism of the ageing process does not change. Unfortunately, the use of kinetic parameters obtained by artifcial ageing at high temperatures (above 60 °C) for the prediction of the propellant lifetime will not give reliable results, because the mechanisms of ageing at 85 °C and 25 °C are not the same.
    Źródło:
    Central European Journal of Energetic Materials; 2013, 10, 2; 225-244
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The Applicability of Chromatographic Methods in the Investigation of Ageing Processes in Double Base Rocket Propellants
    Autorzy:
    Matečić-Muśanić, S.
    Sućeska, M.
    Čuljak, R.
    Powiązania:
    https://bibliotekanauki.pl/articles/358695.pdf
    Data publikacji:
    2013
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    activation energy
    artifcial ageing
    DB rocket propellants
    decomposition
    Ethyl Centralite (EC)
    Gel Permeation Chromatography (GPC)
    High Performance Liquid Chromatography (HPLC)
    kinetics of degradation
    mean molecular mass of NC
    Opis:
    The ageing of double base (DB) rocket propellants is the result of chemical decomposition reactions and physical processes, causing degradation of a number of relevant propellant properties (such as reduction in stabilizer and nitroglycerine (NG) content, reduction of the mean molecular mass of nitrocellulose (NC) etc.), which is refected in a decrease in the reliable service life time of DB propellants. This is the reason why the study of processes of ageing and their consequences (effects) is so important. In this paper we have studied the kinetics of DB rocket propellant decomposition during their artifcial ageing, i.e. at elevated temperatures. The kinetic parameters were obtained by measurements of the stabilizer/Ethyl Centralite (EC) content and the mean molecular mass reduction of NC, during artifcial ageing at temperatures of 80, 85 and 90 °C. Consumption of the EC was observed using High Performance Liquid Chromatography (HPLC), whilst the reduction in the mean molecular mass of NC was monitored using Gel Permeation Chromatography (GPC). It has been shown that artifcial ageing of DB propellant causes signifcant EC consumption and a reduction in the mean molecular mass of NC, from the very beginning of ageing. EC is entirely consumed after 120 days at 80 °C, and is followed by the intensive reactions of NC decomposition. Signifcant changes in the mean molecular mass of NC starts after 60 days of ageing at 90 °C (or ~250 days at 80 °C). The results obtained from the kinetic data have shown that the activation energy of DB propellant decomposition, determined on the basis of changes in the mean molecular mass of NC is 145.09 kJ•mol-1 , whilst the activation energy of decomposition obtained on the basis of EC consumption is 142.98 kJ•mol-1 , which is consistent with available literature values [1, 2].
    Źródło:
    Central European Journal of Energetic Materials; 2013, 10, 2; 245-262
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Applicability of Non-isothermal DSC and Ozawa Method for Studying Kinetics of Double Base Propellant Decomposition
    Autorzy:
    Matečić Mušanić, S.
    Fiamengo Houra, I.
    Sućeska, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/358012.pdf
    Data publikacji:
    2010
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    double base propellant
    kinetics
    Ozawa method
    nitroglycerine
    evaporation
    Opis:
    In order to determine Arrhenius kinetic constants various experimental techniques and testing conditions have been used. Also, various kinetic approaches and data treatment procedures have been applied, resulting sometimes in considerable disagreement in the values of the kinetic parameters reported in literature. Kinetics of decomposition of DB propellants from non-isothermal DSC experiments using unhermetically closed sample pans, and effect of nitroglycerine (NG) evaporation on the kinetic results and kinetics of NG evaporation has been studied by isothermal thermogravimetry. It has been shown by experiments and numerical simulation that at slower heating rates and smaller sample mass NG may completely evaporate before DSC peak maximum, resulting in a higher values of the activation energy (173 kJ/mol). At faster heating rates and larger sample masses certain amount of NG still exists in the propellant at the peak maximum temperature, resulting in lower values of the activation energy (142 kJ/mol). The discontinuity point on the Ozawa plot is connected with the presence of NG in the propellant at DSC peak maximum temperature. This implies that the activation energy obtained using small samples and slow heating rates (173 kJ/mol) corresponds to the activation energy of decomposition of nitrocellulose from DB propellant.
    Źródło:
    Central European Journal of Energetic Materials; 2010, 7, 3; 233-251
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Determination of Nitroglycerine Content in Double Base Propellants by Isothermal Thermogravimetry
    Autorzy:
    Fiamengo, I.
    Sućeska, M.
    Matečić Mušanić, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/357942.pdf
    Data publikacji:
    2010
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    thermal methods
    thermogravimetry
    identifcation
    homogeneous propellants
    double based propellants
    nitroglycerine content
    Opis:
    Thermal methods play an important role among various measuring techniques used in the analysis of explosive materials. These methods are mostly used for the investigation and determination of thermal properties of energetic materials (e.g. melting process, polymorphic transformations, temperature of initiation, etc.), as well as to estimate thermal stability, and to study thermal decomposition. Furthermore, thermal methods can be also used for analytical purposes, such as identifcation of some commonly used high explosives, determination of their purity, determination of phlegmatiser content, etc. The aim of this work was to study the possibility of application of isothermal and non-isothermal thermogravimetry for determination of nitroglycerine content in double based propellants. It has been found out that thermogravimetry can be used not only to distinguish clearly between nitrocellulose and double based propellants, but also for rough determination of nitroglycerine content in double based propellants. The difference between an actual and experimentally determined content of nitroglycerine in double based propellants (i.e. accuracy of the method) is dependent on composition of propellant and data treatment method.
    Źródło:
    Central European Journal of Energetic Materials; 2010, 7, 1; 3-19
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study of Mechanical Properties of Naturally Aged Double Base Rocket Propellants
    Autorzy:
    Sućeska, M.
    Matečić Mušanić, S.
    Fiamengo, I.
    Bakija, S.
    Bakić, A.
    Kodvanj, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/357946.pdf
    Data publikacji:
    2010
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    mechanical properties
    rocket propellant
    natural ageing
    dynamic mechanical analysis
    tensile test
    Opis:
    Various chemical reactions and physical processes (such as stabilizer consumption, migration and evaporation of nitroglycerine, decomposition of nitroglycerine and nitrocellulose, etc.) take place in double based rocket propellants grains over the time, even under ambient storage conditions. The overall effect of these reactions and processes are changes of physical, chemical, thermal, ballistic and mechanical properties of rocket propellants with storage time, i.e. the reduction of the propellants performances and safe service life. The aim of this work was to evaluate the mechanical changes of rocket propellants – sustainers, built in in-service antitank guided missiles systems, induced by natural ageing at ambient conditions during up to 35 years of storage. The mechanical and viscoelastic properties were tested using a dynamic mechanical analyser, an uniaxial tensile and compression tester, and a notch toughness tester. The results have shown that the changes of the studied mechanical and viscoelastic properties are evident, although the results of the tests are rather scattered (as a consequence of measuring uncertainty, different ageing histories of propellants, etc.) or changes of some properties are not too pronounced. For example, after 15 years of storage at ambient conditions the glass transition temperature increases for about 5 C, the tan δ in the glass transition region decreases for about 5%, the storage and loss modulus at 25 °C increase for about 15%, Young modulus at 23 C increases up to 30%, the notch toughness at -30 C decreases up to 15%, etc. Along with these tests, the stabilizer content determination and proving ground ballistic tests were also done.
    Źródło:
    Central European Journal of Energetic Materials; 2010, 7, 1; 47-60
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Thermal Stability and Detonation Characteristics of Pressed and Elastic Explosives on the Basis of Selected Cyclic Nitramines
    Autorzy:
    Elbeih, A.
    Pachmáň, J.
    Zeman, S.
    Trzciński, W. A.
    Akstein, Z.
    Sućeska, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/358014.pdf
    Data publikacji:
    2010
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    detonation
    C4 matrix
    BCHMX
    HMX
    HNIW
    RDX
    stability
    Viton
    Opis:
    Bicyclo-HM X (cis-1,3,4,6-tetranitro-octahydroimidazo-[4,5-d] imidazole or BCHM X) was studied as a plastic explosive bonded with the C4 matrix and with Viton A. Also a series of nitramines namely RDX (1,3,5-trinitro-1,3,5=triazinane), HM X (1,3,5,7-tetranitro-1,3,5,7-tetrazocane) and HNIW (ĺ-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane, ĺ-CL-20) were studied for comparison with the same types of binders. The detonation velocity, D, of all prepared mixtures was measured. Their thermal stability was determined using non-isothermal differential thermal analysis (DTA). While the C4 matrix lowers the thermal stability of the resulting explosives, Viton A enhances this stability. Approximate relationships between the peaks of exothermic decomposition and the D values were found. The detonation parameters were also calculated by means of Kamlet & Jacobs method, CHEETAH and improved EXPLO5 code for all the mixtures. From the measured D values and the calculated detonation parameters, it is obvious that the detonation parameters of BCHM X-mixtures are very close to HM X-explosives and better than those of RDX-mixtures. It was found that the C4 matrix reduces the difference between the values of energy of detonation in the studied C4 mixtures. As expected, the pressed HNIW-Viton A mixture has the highest detonation parameters of all of the prepared mixtures.
    Źródło:
    Central European Journal of Energetic Materials; 2010, 7, 3; 217-232
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-7 z 7

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