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Tytuł:
Danger zone of spontaneous combustion in the gob with lower entry retained along the gob
Strefa zagrożenia spontanicznym spalaniem w zrobach z podścianowym chodnikiem utrzymywanym wzdłuż zrobów
Autorzy:
Shu-jie, Y.
Powiązania:
https://bibliotekanauki.pl/articles/164957.pdf
Data publikacji:
2017
Wydawca:
Stowarzyszenie Inżynierów i Techników Górnictwa
Tematy:
pożary podziemne
spontaniczne spalanie
pożary w zrobach
mine fires
spontaneous combustion
fires in gob
Opis:
In recent years, with the increase in mining depth and the change of mining methods (such as: mining with entry retained along the gob, using Y- type ventilation system), the risk of spontaneous combustion has increased, threatening the safety in coal mine. In order to determine the danger zone of spontaneous combustion in the gob, so as to provide the basis for fire prevention, temperature probes and gas exhausting pipes were embedded in the gob along the upper entry and behind supports. Temperature and oxygen concentration at different sites were obtained. Based on the rate of temperature rise and oxygen concentration changes, the risk zone of spontaneous combustion and the features of the “three zones” in the gob were obtained. The heat dissipation zone is very narrow, the widest position of the heat dissipation zone and the oxidation zone are in the triangle strip formed by hydraulic supports and the wall of gangue bags along the lower entry retained along the gob.
W ostatnich latach, wraz ze wzrostem głębokości oraz zmianą sposobów wybierania pokładów węgla (np. wybieranie z chodnikiem przyścianowym utrzymywanym wzdłuż zrobów, używanie systemu wentylacji ścianowej typu Y), zwiększone ryzyko samozapłonu zagraża bezpieczeństwu w kopalniach węgla kamiennego. W celu określenia strefy zagrożenia spontanicznym spalaniem w zrobach i zapewnieniu podstaw zapobiegania pożarom, osadzono sondy temperatury i czujniki tlenu w zrobach wzdłuż chodnika nadścianowego, za obudową zmechanizowaną. Następnie przebadano temperaturę oraz stężenie tlenu w różnych miejscach pomiaru. Na podstawie tempa wzrostu temperatury i zmian stężenia tlenu wyznaczono strefę zagrożenia samozapaleniem. W ten sposób wyznaczono «trzy strefy» w zrobach. Strefę rozpraszania ciepła, która jest bardzo wąska, szersze są strefy rozpraszania ciepła i utleniania, które znajdują się w trójkącie utworzonym przez obudowy hydrauliczne i ścianę.
Źródło:
Przegląd Górniczy; 2017, 73, 9; 1-5
0033-216X
Pojawia się w:
Przegląd Górniczy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Operational model for vessel traffic using optimal control and calibration
Autorzy:
Shu, Y.
Daamen, W.
Ligteringen, H.
Hoogendoorn, S.
Powiązania:
https://bibliotekanauki.pl/articles/135144.pdf
Data publikacji:
2015
Wydawca:
Akademia Morska w Szczecinie. Wydawnictwo AMSz
Tematy:
vessel operation
operational model
optimal control
calibration
waterways
ports
Opis:
Due to the ever-increasing economic globalization, the scale of transportation through ports and waterways has increased sharply. As the capacity of maritime infrastructure in ports and inland waterways is limited, it is important to simulate vessel behavior to balance safety and capacity in restricted waterways. Currently many existing vessel simulation models focus mainly on vessel dynamics and maritime traffic in the open ocean. These models are, however, inapplicable to simulating vessel behavior in ports and inland waterways, because behavior in such areas can be influenced by many factors, such as waterway geometry, external conditions and human factors. To better simulate vessel behavior in ports and waterways, we developed a new maritime traffic model by adapting the theory of pedestrian models. This new model comprises two parts: the Route Choice Model and the Operational Model. The Route Choice Model has been demonstrated and calibrated in our recent study, in which the desired speed is generated. This paper presents the second part of the model, the Operational Model, which describes vessel behavior based on optimal control by using the output of the Route Choice Model. The calibration of the Operational Model is carried out as well. In the Operational Model, the main behavioral assumption is that all actions of the bridge team, such as accelerating and turning, are executed to force the vessel to sail with the desired speed and course. In the proposed theory, deviating from the desired speed and course, accelerating, decelerating and turning will provide disutility (cost) to the vessel. By predicting and minimizing this disutility, longitudinal acceleration and angular acceleration can be optimized. This way, the Operational Model can be used to predict the vessel speed and course. Automatic Identification System (AIS) data of unhindered vessel behavior in the Port of Rotterdam, the Netherlands, were used to calibrate the Operational Model. The calibration results produced plausible parameter values that minimized the objective function. The paths generated with these optimal parameters corresponded reasonably well to the actual paths.
Źródło:
Zeszyty Naukowe Akademii Morskiej w Szczecinie; 2015, 42 (114); 70-77
1733-8670
2392-0378
Pojawia się w:
Zeszyty Naukowe Akademii Morskiej w Szczecinie
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Characterization of PolyNIMMO-HTPB-polyNIMMO Triblock Copolymer as a Potential Energetic Binder
Autorzy:
Wang, X.
Shu, Y.
Lu, X.
Mo, H.
Xu, M.
Powiązania:
https://bibliotekanauki.pl/articles/358529.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
triblock copolymer
cationic ring opening polymerization
polymer
DSC
Opis:
Triblock copolymer polyNIMMO-HTPB-polyNIMMO was synthesized by cationic ring opening polymerization of NIMMO (3-nitratomethyl-3-methyloxetane) in the presence of hydroxyl-terminated polybutadiene catalyzed by BF3·OEt2. The polymer was characterized by FT-IR, 1H NMR, 13C NMR spectroscopy, and GPC. DSC was used to investigate the thermal behaviour of the triblock copolymer and its exothermic decomposition peak was found to be at 215 °C. All of the results indicated that the triblock copolymer polyNIMMO-HTPB-polyNIMMO might serve as a potential energetic propellant binder.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 3; 456-467
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Computational Investigation on the Structure and Performance of Novel 4,7-dinitro-furazano-[3,4-d]-pyridazine Derivatives
Autorzy:
Wang, K.
Shu, Y.
Liu, N.
Ding, X.
Wu, Z.
Lu, Y.
Powiązania:
https://bibliotekanauki.pl/articles/358090.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
4,7-dinitro-furazano-[3,4-d]-pyridazine
heat of formation
density
detonation performance
bond dissociation energy
Opis:
Seven novel energetic 4,7-dinitro-furazano-[3,4-d]-pyridazine derivatives were designed, and their optimized structures and performances were studied by density functional theory (DFT) at B3LYP/6-311g(d,p) level. The detonation performances were estimated by the Kamlet-Jacobs equations. The results show that these compounds have high crystal densities (1.818-1.925 g·cm−3), detonation velocities (8.51-9.56 km·s−1) and detonation pressures (32.28-41.70 GPa). The bond dissociation energies (BDEs) of the weakest bond (N–O bond) vary from 70.889 kJ·mol−1 to 173.283 kJ·mol−1, and some of them exhibit higher BDEs than that of RDX (N–NO2 bond, 149.654 kJ·mol−1) and HMX (N–NO2 bond, 154.905 kJ·mol−1). M4 and M5 exhibit similar and higher detonation performance than RDX (8.81 km·s−1, 34.47 GPa). The detonation performance of M7 (9.56 km·s−1, 41.70 GPa) even surpasses that of HMX (9.10 km·s−1, 39.00 GPa). Otherwise, the specific impulse values of M1-M7 (266-279 s) outperform HMX (266 s) by 0-13 s, which indicates that M1-M7 may show better performance as monopropellants. It is concluded that density, heat of formation, stability, detonation performance and specific impulse of the designed compounds depend on the position and number of the N→O oxidation bonds.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 1; 26-46
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Expansion of Explosive Molecular Crystals: Anisotropy and Molecular Stacking
Autorzy:
Qian, W.
Zhang, C.
Xiong, Y.
Zong, H.
Zhang, W.
Shu, Y.
Powiązania:
https://bibliotekanauki.pl/articles/358262.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
energetic material
anisotropic thermal expansion
molecular stacking
molecular dynamics simulation
density functional theory method
Opis:
Molecular dynamics simulations of three typical explosive crystals, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), 1,1-diamino-2,2- dinitroethene (FOX-7) and 1,3,5-triamino-2,4,6-trinitrobenzene (TATB), were carried out under NPT ensemble and selected force field. The equilibrium structures at elevated temperatures were obtained, which show that the stacking behaviour of the molecules does not change with temperature. The coefficient of thermal expansion (CTE) values were calculated by linear fitting methods, and the results show that the CTE values are close to the experimental results and are anisotropic. The total energies of the cells expanding along each single crystallographic axis were calculated by the periodic density functional theory method, indicating that the energy change rates are anisotropic, and correlation equations of the energy change vs. CTE values were established. The essence of the anisotropy of the explosive crystal’s thermal expansion was compared and elucidated.
Źródło:
Central European Journal of Energetic Materials; 2014, 11, 1; 59-81
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative Theoretical Investigation on Energetic Substituted Furazanyl Ethers
Autorzy:
Liu, N.
Wang, K.
Shu, Y.
Zeman, S.
Wang, B.
Wang, W.
Powiązania:
https://bibliotekanauki.pl/articles/358622.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
furazanyl ethers
heats of formation
bond dissociation energy
detonation performance
melting point
Opis:
Furazanyl ether has great potential to be an important candidate as a casting explosive and energetic plasticizer. The density functional theory (DFT) method was used to investigate the heats of formation (HOFs), molecular stability, detonation performance and melting point of a series of substituted furazanyl ethers at B3LYP/6-311G(d,p) level. The results show that the introduction of –N3 or –N(O)=N– groups significantly improves the HOFs values of the derivatives. The bond dissociation energies (BDEs) were analyzed, showing that the N–O bond in the furazan ring is the weakest for most compounds and the ring is vulnerable to cleavage in thermal decomposition. The calculation of density, detonation velocities and detonation pressures suggests that the substitution of –NF2, –CF(NO2)2, furoxan or –N(O)=N– group is an effective method for enhancing their detonation performance. The melting points were determined according to the variation of specific heat capacity, and good estimates were obtained in comparison with the available experimental data. Taking into account the detonation performance and melting point, four compounds are favoured for application in melt cast explosive or energetic plasticizers.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 1; 47-71
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Reinforcement of the TNT System by a Newly-designed GAP-based Polyurethane-Urea: a Molecular Simulation Investigation
Autorzy:
Qian, W.
Shu, Y.
Ma, Q.
Li, H.
Wang, S.
Chen, X.
Powiązania:
https://bibliotekanauki.pl/articles/358512.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
TNT
GAP
polyurethane-urea
inter-molecular interaction
mechanical properties
Opis:
A glycidyl azide (GAP)-based polyurethane-urea (PUU) modifier used in the 1,3,5-trinitrotoluene (TNT)-based composite explosive was investigated by molecular simulation. Inter-molecular interactions were investigated using quantum chemistry calculation on the dimer of TNT and GAP-PUU, and attractive forces were found between the two molecules. The cohesive energy densities and the solubility parameters were obtained through molecular dynamics simulations combined with thermodynamic calculations on the TNT and GAP-PUU amorphous cell models, and the miscibility of the modifier in molten TNT was predicted to be good. The interaction energies and the mechanical properties were then obtained by molecular simulations and mechanical calculations on the solid-phase models of the GAP-PUU with TNT along three crystalline directions, and an improvement in the mechanical properties was predicted.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 2; 411-426
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Phase Diagrams of the MeNQ/HN and HN/NQ Binary Systems
Autorzy:
Tian, M.-M.
Li, H.-R.
Chen, L.
Ju, X.
Shu, Y.-J.
Powiązania:
https://bibliotekanauki.pl/articles/358436.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
phase diagram
binary system
eutectic
DSC
XRD
Opis:
An equation for a binary phase diagram with two eutectic points was deduced from the Van’t Hoff equation. The melting points of hydrazinium nitrate/ nitroguanidine (HN/NQ) samples with different ratios, ranging from 0 to 1 mole fraction, were explored by differential scanning calorimetry (DSC). The results revealed the presence of two eutectic points in the phase diagram of the HN/NQ binary system. The dependence of temperature on the composition (T-X phase diagram) of HN/NQ was depicted based on the equation described by the DSC data. The phase diagram of MeNQ/HN, with only one eutectic point was constructed by substituting experimental data of the compositions and their corresponding temperatures into the Van’t Hoff equation. The phase diagram with two or more eutectic points indicated the formation of new stable compounds with appropriate ratios of the two components; no new substance appeared in the system with only one eutectic point. Thus, the HN/NQ binary system showed the presence of a new substance, which is probably the HN/NQ co-crystal. No new substance was detected in the MeNQ/HN binary system. The results of the X-ray diffraction patterns agree with the findings from the phase diagrams.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 2; 271-286
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fluorescence Analysis as an Effective Method Used in Micro/Trace Explosive Detection
Autorzy:
Liu, Y.
Shu, Y.
Liu, Xue-yong.
Xiong, Y.
Zhong, Fa-chun.
Sun, Y.
Powiązania:
https://bibliotekanauki.pl/articles/358808.pdf
Data publikacji:
2009
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
micro/trace explosive detection
fluorescence analysis
conjugated polymer
sensing materials
Opis:
There are many kinds of explosives, and their detection methods vary. Nitroaromatic compound is one of the composition of the explosives commonly used. The fuorescence will be quenched when they touch the fuorescent conjugated polymers. General methods for explosives detection have been summarized in this paper, in addition the application of novel fuorescence analysis technique in explosives detection has been introduced. Fluorescent conjugated polymer as chemical sensing material for explosive detection has been reviewed in detail, also a novel fuorescent sensing flm self-assembled by fuorescent small molecule pyrene and homogeneous fuoroimmunoassay have been presented briefy. The development of fuorescence analysis used in the area of determining explosives has been prospected.
Źródło:
Central European Journal of Energetic Materials; 2009, 6, 3-4; 303-311
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Review of the Photodecomposition of Some Important Energetic Materials
Autorzy:
Sun, Y.
Shu, Y.
Xu, T.
Shui, M.
Zhao, Z.
Gu, Y.
Wang, X.
Powiązania:
https://bibliotekanauki.pl/articles/358397.pdf
Data publikacji:
2012
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
photodecomposition mechanisms
energetic materials
Opis:
The photodecomposition mechanisms of energetic materials vary with molecular structure, photodissociation wavelength, the phase of the material, experimental pressure and temperature etc. In this paper, the significant progress on photodecomposition studies of some important energetic materials achieved in recent years is introduced in detail, including nitromethane, DMNA (dimethylnitramine), TATB (1,3,5-triamino-2,4,6-trinitrobenzene), RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine), HMX (1,3,5,7-tetranitro-1,3,5,7- tetrazacycloctane) and CL-20 (2,4,6,8,10,12-hexanitrohexaazaisowurtzitane). The difficulties and prospects of photodecomposition research of energetic materials are also indicated.
Źródło:
Central European Journal of Energetic Materials; 2012, 9, 4; 411-423
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-10 z 17

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