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Tytuł:
Teledetekcja satelitarna w monitorowaniu lasów tropikalnych
Satellite remote sensing in monitoring of tropical forests
Autorzy:
Zawiła-Niedźwiecki, T.
Koranteng, A.
Ugarte, H. F.
dos Santos, J. R.
Maldonado, F. D.
Powiązania:
https://bibliotekanauki.pl/articles/132247.pdf
Data publikacji:
2008
Wydawca:
Polskie Towarzystwo Geograficzne
Tematy:
las tropikalny
degradacja
teledetekcja satelitarna
monitorowanie
tropical forest
degradation
satellite remote sensing
monitoring
Źródło:
Teledetekcja Środowiska; 2008, 39; 41-47
1644-6380
Pojawia się w:
Teledetekcja Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Serological and molecular evidence of hepadnavirus infection in swine
Autorzy:
Vieira, Y.R.
Silva, M.F.M.
Santos, D.R.L.
Vieira, A.A.
Ciacci-Zanella, J.R.
Barquero, G.
do Lago, B.V.
Gomes, S.A.
Pinto, M.A.
de Paula, V.S.
Powiązania:
https://bibliotekanauki.pl/articles/989989.pdf
Data publikacji:
2015
Wydawca:
Instytut Medycyny Wsi
Tematy:
diagnostic
hepadnavirus
swine
Opis:
Introduction and objective. Recently, investigations in a swine herd identified evidence of the existence of a novel member of the Hepadnavirus family endemic in swine. The aim of this study was to investigate the serological and molecular markers of Hepadnavirus circulation in Brazilian domestic swine and wild boar herds, and to evaluate the identity with HBV and other Hepadnaviruses reported previously. Materials and methods. For the study, 376 swine were screened for hepatitis B virus serological markers. Analyses were performed in serum samples using commercial enzyme-linked immunosorbent assay (ELISA) kits (DiaSorin®) for anti-HBc, HBsAg and anti-HBs. Reactive and undetermined swine serum samples were selected to perform DNA viral extraction (QIAamp DNA Mini Kit, Qiagen®), partial genome amplification and genome sequencing. Results. From 376 swine samples analysed, 28 (7.45%) were reactive to anti-HBc, 3 (0.80%) to HBsAg and 6 (1.6%) to anti-HBs. Besides, more 17 (4.52%) swine samples analyzed were classified in the grey zone of the EIA test to anti-HBc and 2 (0.53%) to HBsAg. From 49 samples molecularly analyzed after serological trial, 4 samples showed a positive result for the qualitative PCR for Hepadnavirus. Phylogenetic reconstruction using partial genome sequencing (360 bp) of 3 samples showed similarity with HBV with 90.8–96.3% of identity. Conclusions. Serological and molecular data showed evidence of the circulation of a virus similar to hepatitis B virus in swine.
Źródło:
Annals of Agricultural and Environmental Medicine; 2015, 22, 1
1232-1966
Pojawia się w:
Annals of Agricultural and Environmental Medicine
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Directional Ordering in Amorphous $Fe_{43}Ni_{43}Zr_7Cu_1B_6$ Ferromagnetic Alloys
Autorzy:
Varga, M.
Varga, R.
Vojtaník, P.
Hernando, B.
Prida, V.
Santos, J.
Pérez, M.
Powiązania:
https://bibliotekanauki.pl/articles/1533987.pdf
Data publikacji:
2010-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.50.Kj
75.60.Nt
Opis:
Development of the atomic directional ordering in the $Fe_{43}Ni_{43}Zr_7Cu_1B_6$ alloy, during its conventional the same as after transverse magnetic field annealing, was experimentally studied by the amplitude dependence of susceptibility and hysteresis loops measurements, respectively. Diffusion processes of the mobile atoms caused perminvar effect, decrease of the initial susceptibility, increase of the critical field, and linear shape of the hysteresis loop. Uniaxial magnetic anisotropy, created during magnetic field annealing of the FeNiZrCuB alloy, was confirmed also by observation of the surface domain structure.
Źródło:
Acta Physica Polonica A; 2010, 118, 5; 804-806
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Collaborative paradigm for single-machine scheduling under just-in-time principles: total holding-tardiness cost problem
Autorzy:
Varela, M. L. R.
Madureira, A. M.
Dantas, J. D.
Santos, A. S.
Putnik, G. D.
Trojanowska, J.
Machado, J.
Powiązania:
https://bibliotekanauki.pl/articles/406794.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
single-machine
scheduling
heuristics
just-in-time
agile manufacturing
holding-tardiness cost problem
Opis:
The problem of sequencing jobs on a single machine to minimize total cost (earliness and tardiness) is nowadays not just important due to traditional concerns but also due to its importance in the context of Collaborative Networked Organizations and Virtual Enterprises, where precision about promptly responses to customers’ requests, along with other important requirements, assume a crucial role. In order to provide a contribution in this direction, in this paper the authors contribute with an applied constructive heuristics that tries to find appropriate solutions for single machine scheduling problems under different processing times and due dates, and without preemption allowed. In this paper, two different approaches for single-machine scheduling problems, based on external and internal performance measures are applied to the problem and a comparative analysis is performed. Computational results are presented for the problem under Just-in-Time and agile conditions on which each job has a due date, and the objective is to minimize the sum of holding costs for jobs completed before their due date and tardiness costs for jobs completed after their due date. Additional computational tests were developed based on different customer and enterprise oriented performance criteria, although preference is given to customer-oriented measures, namely the total number of tardy jobs and the maximum tardiness.
Źródło:
Management and Production Engineering Review; 2018, 9, 1; 90-103
2080-8208
2082-1344
Pojawia się w:
Management and Production Engineering Review
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Monitoring wylesień lasów deszczowych Amazonii na podstawie radiometrycznych przetworzeń zdjęć satelitarnych
The monitoring of the Amazon rainforest deforestation on the basis of a radiometric analysis of satellite images
Autorzy:
Ugarte, H.F.
Zawiła-Niedźwiecki, T.
Dos Santos, J.R.
Maldonado, F.D.
Powiązania:
https://bibliotekanauki.pl/articles/1012565.pdf
Data publikacji:
2008
Wydawca:
Polskie Towarzystwo Leśne
Tematy:
zdjecia satelitarne
satelita CBERS-2
satelita Landsat ETM plus
Amazonia
teledetekcja satelitarna
lesnictwo tropikalne
monitoring
wylesienia
lasy tropikalne
satellite remote sensing
tropical forest
deforestation
bolivia
the amazon
Opis:
The article discusses the results of research on radiometric processing of multitemporal satellite images in order to monitor deforestation in the Amazon region. Images acquired by Landsat ETM+ and CBERS−2 were used. The proposed algorithms enabled an objective analysis of deforestation and regeneration distribution within tropical rainforests. The advantage of the method is its simple algorithm and lack of need for atmospheric correction.
Źródło:
Sylwan; 2008, 152, 07; 3-8
0039-7660
Pojawia się w:
Sylwan
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spatial analysis of vegetal cover and sediment yield in Tapacura river catchment based on remote sensing and GIS
Analiza przestrzenna ilosci sedymentu oraz pokrywy roslinnej w zlewni rzeki Tapacura okreslona na podstawie zdalnych obserwacji oraz analizy GIS
Autorzy:
Silva, R M
Santos, C.A.G.
Gico Lima Montenegro, S.M.
Silva, L.P.
Powiązania:
https://bibliotekanauki.pl/articles/81843.pdf
Data publikacji:
2010
Wydawca:
Szkoła Główna Gospodarstwa Wiejskiego w Warszawie. Wydawnictwo Szkoły Głównej Gospodarstwa Wiejskiego w Warszawie
Tematy:
spatial analysis
vegetation cover
sediment yield
Tapacura River
catchment
remote sensing
GIS analysis
Opis:
Mapping and assessment of erosion risk is an important tool for planning of natural resources management, allowing researchers to propose modifi cation in land-use properly and implement more sustainable management strategies in the long-term. The Tapacurá river catchment, located in Pernambuco State, Northeastern Brazil, is one of the planning units for management of water resources of Recife Metropilitan Region (RMR), and it is divided into 12 sub-basins. The objective of this study is to evaluate the spatial variability of vegetal cover and sediment yield in this basin through remote sensing and GIS techniques. Maps of the erosivity (R), erodibility (K), topographic (LS), cover-management (C) and support practice (P) factors were derived from the digital elevation model (DEM), climate database, and soil and NDVI maps, taking into account information available in the literature. In order to validate the simulation process, Sediment Delivery Ratio (SDR) was estimated. The obtained NDVI map showed vegetation loss during the analyzed period, indicating a distinct contrast between loss and gains of vegetation index. The vegetation and sediment yield mapping showed to be a useful tool for environmental monitoring and management, which can provide satisfactory results when jointly used. The results suggest a mean SDR around 0.9 and estimate the sediment yield as 23.98 ton/ha/month.
Analiza przestrzenna ilości sedymentu oraz pokrywy roślinnej w zlewni rzeki Tapacura określona na podstawie zdalnych obserwacji oraz analizy GIS. Artykuł przedstawia sposób wykorzystania zebranych w terenie danych dotyczących pokrywy roślinnej oraz ilości sedymentu określonego za pomocą zdalnych obserwacji oraz analizy GIS w celu monitorowania środowiska i zarządzania zlewniami. W pracy wykorzystano metodę USLE-SDR, a także cyfrowy model terenu. Badania prowadzono w zlewni rzeki Tapacura w północno-wschodniej Brazylii. Wyniki sugerują przyjęcie wartości parametru SDR = 0,9, a oszacowana wielkość transportu rumowiska wynosi 23,98 t/ha/miesiąc.
Źródło:
Annals of Warsaw University of Life Sciences - SGGW. Land Reclamation; 2010, 42, 1; 5-16
0208-5771
Pojawia się w:
Annals of Warsaw University of Life Sciences - SGGW. Land Reclamation
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Improved single-stage OTAs using differential-folded voltage combiners
Autorzy:
Santos-Tavares, R
Santin, E
Borrego, R
Oliveira, J
Goes, J.
Powiązania:
https://bibliotekanauki.pl/articles/397711.pdf
Data publikacji:
2013
Wydawca:
Politechnika Łódzka. Wydział Mikroelektroniki i Informatyki
Tematy:
voltage-combiners
single-stage
OTA
common-drain
common-source
DTMOS
łącznik napięciowy
wspólny dren
wspólne źródło
Opis:
A new technique to enhance single-stage operational transconductance amplifiers (OTAs) is presented. Enhanced DC gain and reduced input parasitic capacitances are achieved by employing two input fully-differential voltage combiners, i.e. a combination of transistors in common-drain and common-source configurations operating as a preamplifier stage. Simulation results show that the input capacitance can be as small as 195 fF (corresponding to a 46 % reduction) while achieving a GBW of 1982 MHZ (@ CL = 1 pF) with a PM of about 60⁰. The complete amplifier dissipates only 1.78 mW corresponding to a figure-of-merit (FoM) of 1115 MHz-pF/mW.
Źródło:
International Journal of Microelectronics and Computer Science; 2013, 4, 4; 175-179
2080-8755
2353-9607
Pojawia się w:
International Journal of Microelectronics and Computer Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
New sauropod trackways from the Middle Jurassic of Portugal
Autorzy:
Santos, V F
Moratalla, J.J.
Royo-Torres, R.
Powiązania:
https://bibliotekanauki.pl/articles/22749.pdf
Data publikacji:
2009
Wydawca:
Polska Akademia Nauk. Instytut Paleobiologii PAN
Tematy:
new sauropod
sauropod
paleontology
trackway
Middle Jurassic
Jurassic
Portugal
Dinosauria
Sauropoda
morphotype
Opis:
The Galinha tracksite reveals a sequence of Bajocian–Bathonian limestones belonging to the Serra de Aire Formation (West−Central Portugal) and is one of the few sites in the world where Middle Jurassic sauropod dinosaur tracks can be found. This tracksite is characterised by the presence of long, wide gauge sauropod trackways, the Middle Jurassic age of which suggests these dinosaurs were more widely distributed over time than previously thought. Two trackways contain unique pes and manus prints with morphologies that allow a new sauropod ichnotaxon to be described: Polyonyx gomesi igen. et isp. nov. On the basis of different manus/pes prints and trackway features, the proposal is made to subdivide Sauropodomorpha ichno−morphotypes into five groups: Tetrasauropus−like, Otozoum−like, Breviparopus/Parabrontopodus−like; Brontopodus−like, and Polyonyx−like. Polyonyx gomesi igen. et isp. nov. is thought to represent a nonneosauropod eusauropod, with a well developed manus digit I. The posterior orientation of this digit print suggests they were made by a eusauropod dinosaur with a posteriorly rotated pollex. The manus print morphologies observed in two trackways suggest a stage of manus structure intermediate between the primitive non−tubular sauropod manus and the tubular metacarpal arrangement characteristic of more derived sauropods. The low heteropody (manus:pes area ratio 1:2) of the trackway renders it possible they could have been made by eusauropods such as Turiasaurus riodevensis, which has a similar manus:pes area ratio. The Polyonyx igen. nov. trackway was made by non−neosauropod eusauropod, and suggests that wide gauge sauropod trackways were not exclusively made by Titanosauriformes.
Źródło:
Acta Palaeontologica Polonica; 2009, 54, 3; 409-422
0567-7920
Pojawia się w:
Acta Palaeontologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Estimating forest biomass by remote sensing RADAR data in Brazil
Autorzy:
Santos, J.R.
Gama, F.F.
da Conceicao Bispo, P.
Powiązania:
https://bibliotekanauki.pl/articles/52438.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Technologii Drewna
Tematy:
forest biomass
biomass modelling
forest inventory
tropical forest
remote sensing
eucalyptus tree
stand
RADAR data
Brazil
Źródło:
Drewno. Prace Naukowe. Doniesienia. Komunikaty; 2014, 57, 192
1644-3985
Pojawia się w:
Drewno. Prace Naukowe. Doniesienia. Komunikaty
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Portuguese version of the Swedish Occupational Fatigue Inventory (SOFI) among assembly workers: Cultural adaptation, reliability and validity
Autorzy:
Santos, Joana
Carvalhais, Carlos
Ramos, Catarina
Coelho, Tiago
Monteiro, Pedro R.
Vaz, Mário A.
Powiązania:
https://bibliotekanauki.pl/articles/2161877.pdf
Data publikacji:
2017-05-08
Wydawca:
Instytut Medycyny Pracy im. prof. dra Jerzego Nofera w Łodzi
Tematy:
reliability
confirmatory factor analysis
validity
cultural adaptation
perceived fatigue
Swedish Occupational Fatigue Inventory
Opis:
Objectives Reliable and valid instruments are essential for understanding fatigue in occupational settings. This study analyzed the psychometric properties of the Portuguese version of the Swedish Occupational Fatigue Inventory (SOFI). Material and Methods A cross-sectional study was conducted with 218 workers from an automotive industry involved in assembly tasks for fabrication of mechanical cables. Convergent and discriminant validity, internal consistency reliability and confirmatory factor analysis were performed. Results Results showed adequate fit to data, yielding a 20-item, 5-factor structure (all intercorrelated): Chi²/df (ratio Chi² and degrees of freedom) = 2.530, confirmatory fit index (CFI) = 0.919, goodness of fit index (GFI) = 0.845, root mean square error of approximation (RMSEA) = 0.084. The SOFI presented an adequate internal consistency, with the sub-scales and total scale presenting good reliability values (Cronbach’s α values from 0.742 to 0.903 and 0.943 respectively). Conclusions Findings suggest that the Portuguese version of the SOFI may be a useful tool to assess fatigue and prevent work-related injuries. In future research, other instruments should be used as an external criterion to correlate with the SOFI dimensions. Int J Occup Med Environ Health 2017;30(3):407–417
Źródło:
International Journal of Occupational Medicine and Environmental Health; 2017, 30, 3; 407-417
1232-1087
1896-494X
Pojawia się w:
International Journal of Occupational Medicine and Environmental Health
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Parasites community of Astronotus crassipinnis (Cichlidae), a fish from the Brazilian Amazon
Autorzy:
Santos, G.G.
Oliveira, M.S.B.
Neves, L.R.
Tavares-Dias, M.
Powiązania:
https://bibliotekanauki.pl/articles/972319.pdf
Data publikacji:
2018
Wydawca:
Polskie Towarzystwo Parazytologiczne
Tematy:
aggregation
parasites
Amazon
Astronotus crassipinnis
Cichlidae
Opis:
We provide the first study on the diversity and community of parasites in Astronotus crassipinnis from the lower Amazon River, in Brazil. Of 35 hosts examined, 100% were infected with one or more species of parasites, such as Gussevia asota, Gussevia astronoti, Gussevia rogersi, Posthodiplostomum sp., Contracaecum sp., Gorytocephalus sp. and Dolops longicauda. Gussevia asota, G. astronoti and G. rogersi were dominant, and, in total, 9788 parasites were collected. The richness of parasite species (4.9±0.7), Brillouin diversity (0.46±0.28) and evenness (0.29±0.17) were low. Parasites had aggregated dispersion, parasitism did not affect the host condition factor, and host size did not influence abundance, species richness and parasite diversity. The parasitic fauna was characterized by the presence of few species of parasites with high prevalence and low abundance, specifically the endoparasites, besides dominance of ectoparasites. The presence of endoparasites indicates that the diet of A. crassipinnis consists mostly of mollusks and microcrustaceans. This fish species is an intermediate host for Posthodiplostomum sp., Contracaecum sp. and Gorytocephalus sp., parasites found in larval stage. Finally, the behavior and availability of infective stages, which are intermediate hosts for endoparasites, were factors structuring the communities of endoparasites.
Źródło:
Annals of Parasitology; 2018, 64, 2; 121-128
0043-5163
Pojawia się w:
Annals of Parasitology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
An alternative 3D numerical method to study the biomechanical behaviour of the human inner ear semicircular canal
Autorzy:
Santos, C. F.
Belinha, J.
Gentil, F.
Parente, M.
Jorge, R. N.
Powiązania:
https://bibliotekanauki.pl/articles/951835.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
biomechanika
FEM
mechanika płynów
narząd przedsionkowy
ucho wewnętrzne
vertigo
biomechanics
finite element method
human vestibular system
fluid mechanics
inner ear
Opis:
Purpose: The vestibular system is the part of the inner ear responsible for balance. Vertigo and dizziness are generally caused by vestibular disorders and are very common symptoms in people over 60 years old. One of the most efficient treatments at the moment is vestibular rehabilitation, permitting to improve the symptoms. However, this rehabilitation therapy is a highly empirical process, which needs to be enhanced and better understood. Methods: This work studies the vestibular system using an alternative computational approach. Thus, part of the vestibular system is simulated with a three dimensional numerical model. Then, for the first time using a combination of two discretization techniques (the finite element method and the smoothed particle hydrodynamics method), it is possible to simulate the transient behavior of the fluid inside one of the canals of the vestibular system. Results: The obtained numerical results are presented and compared with the available literature. The fluid/solid interaction in the model occurs as expected with the methods applied. The results obtained with the semicircular canal model, with the same boundary conditions, are similar to the solutions obtained by other authors. Conclusions: The numerical technique presented here represents a step forward in the biomechanical study of the vestibular system, which in the future will allow the existing rehabilitation techniques to be improved.
Źródło:
Acta of Bioengineering and Biomechanics; 2017, 19, 1; 3-15
1509-409X
2450-6303
Pojawia się w:
Acta of Bioengineering and Biomechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Determination of the JWL Constants for ANFO and Emulsion Explosives from Cylinder Test Data
Autorzy:
Sanchidrián, J. A.
Castedo, R.
López, L. M.
Segarra, P.
Santos, A. P.
Powiązania:
https://bibliotekanauki.pl/articles/358385.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
cylinder test
JWL equation of state
LS-DYNA
ANFO
emulsion explosives
Opis:
The Jones-Wilkins-Lee (JWL) equation of state parameters for ANFO and emulsion-type explosives have been obtained from cylinder test expansion measurements. The calculation method comprises a new radial expansion function, with a non-zero initial velocity at the onset of the expansion in order to comply with a positive Gurney energy at unit relative volume, as the isentropic expansion from the CJ state predicts. The equations reflecting the CJ state conditions and the measured expansion energy were solved for the JWL parameters by a non-linear least squares scheme. The JWL parameters of thirteen ANFO and emulsion type explosives have been determined in this way from their cylinder test expansion data. The results were evaluated through numerical modelling of the tests with the LS-DYNA hydrocode; the expansion histories from the modelling were compared with the measured ones, and excellent agreement was found.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 2; 177-194
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis and glycosyl composition of the exopolysaccharide isolated from submerged fermentation of Ganoderma lucidum CG144
Autorzy:
Rubel, R.
Freire dos Santos, L.
Stutz Dalla Santa, H.
Porto de Souza Vandenberghe, L.
Wojciechowski, A.L.
de Carvalho, J.C.
Habu, S.
Destefanis Vitola, F.M.
Augur, C.
Soccol, C.R.
Powiązania:
https://bibliotekanauki.pl/articles/56735.pdf
Data publikacji:
2014
Wydawca:
Polskie Towarzystwo Botaniczne
Tematy:
glycosyl composition
exopolysaccharide
isolation
submerged fermentation
Ganoderma lucidum
heteroglycan
herbal medicine
Chinese medicine
Opis:
The evaluation of glycosyl composition is an essential step to guide future research designs applied in bioactivity. In the same way, the unexplored potential bioactivity of exopolysaccharide from Ganoderma lucidum is huge. Therefore, this study investigated the glycosyl composition of the exopolysaccharide isolated from submerged fermentation of G. lucidum to serve as guide for future studies on bioactivity. Glycosyl content and composition were evaluated by combined GC/ MS of the TMS derivatives of the monosaccharide methyl glycosides produced from the sample by acidic methanolysis. Glycosyl composition analysis showed that the dominant carbohydrate component in all samples of exopolysaccharide isolated from submerged fermentation of G. lucidum CG 144 was glucose (58.1%), mannose (26.6%) and galactose (12.5%) which can be referred to as heteroglycan. These results suggest that this Ganoderma exopolysaccharide may be a new immunomodulatory agent.
Źródło:
Acta Societatis Botanicorum Poloniae; 2014, 83, 3
0001-6977
2083-9480
Pojawia się w:
Acta Societatis Botanicorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
4-amine-2-mercaptopyrimidine modified silica gel applied in Cd(II) and Pb(II) extraction from an aqueous medium
Autorzy:
Pereira, A.S.
Ferreira, G.
Caetano, L.
Castro, R.S.D.
dos Santos, A.
Padilha, P.M.
Castro, G.R.
Powiązania:
https://bibliotekanauki.pl/articles/778413.pdf
Data publikacji:
2010
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
4-amino-2-merkaptopirymidyna
krzemionka
ekstrakcja metali
środowisko wodne
4-amine-2-mercaptopyrimidine
silica
metal extraction
aqueous medium
Opis:
This paper discusses silica surface modification by a process involving a two-step reaction: anchoring of a silylating agent, followed by an attachment of a 4-amino-2-mercaptopyrimidine molecule. The modified material (Si-BP) was successfully characterized by the FTIR spectra, which revealed amine absorption bands, and through 13C and 29Si NMR spectra, which confirm the proposed structure of the modified silica (Si-BP). Si-BP was used to extract cadmium and lead from an aqueous medium at 298 K. The Si-BP kinetics towards metal ions was very fast, i.e., about 10 minutes, although extraction was significantly impaired at pH 3. The series of adsorption isotherms were adjusted to a modified Langmuir equation and the maximum extraction capacity was 0.193 and 0.387 mmol g-1 for Cd(II) and Pb(II), respectively. An analysis of the Ř values lead to the inference that the resulting metal ligand complex was type 1:1.
Źródło:
Polish Journal of Chemical Technology; 2010, 12, 1; 7-11
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł

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