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Wyświetlanie 1-4 z 4
Tytuł:
Efficient method for Knoevenagel condensation in aqueous solution of amino acid ionic liquids (AAILs)
Autorzy:
Ossowicz, P.
Rozwadowski, Z.
Gano, M.
Janus, E.
Powiązania:
https://bibliotekanauki.pl/articles/779648.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
recycling
catalysis in water
amino acid ionic liquids
Knoevenagel reaction
Opis:
This work reports on the use of the amino acid ionic liquids (AAILs) which have been used as catalysts in Knoevenagel condensation of various aldehydes with malononitrile. For research we use tetrabutylammonium ionic liquids based on eight natural amino acids. The reaction was carried out in an aqueous medium. Using water as solvent provided efficient and simple method of isolation of pure product with high yield. Moreover, amino acid ionic liquid dissolved in water could be reused many times without any loss of its catalytic activity. The influence of the anion was studied. Moreover the effect of technological parameters such as: the temperature, the catalyst content, and the reaction time on yield of reaction were investigated.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 4; 90-95
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation, properties and potential applications of a photocurable varnish with pleasant limonene smell
Autorzy:
Bednarczyk, P.
Wróblewska, A.
Czech, Z.
Malko, M.W.
Rozwadowski, Z.
Markowska-Szczupak, A.
Powiązania:
https://bibliotekanauki.pl/articles/778106.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
varnishes with limonene
smelling varnishes
urethane acrylate
UV-curing coating
Opis:
Photocurable materials which are obtained on the basis of urethane acrylate resins are often used in the industry for the production varnishes or protective coatings. The main disadvantage which is connected with the utilization of these varnishes is their unpleasant smell during the process of production and curing. This work presents the photocurable varnish which was obtained on the basis of aliphatic urethane acrylate and R-(+)-limonene. The utilization of this raw materials allows to obtain the smelling coatings. The aim of this work were the studies on the influence of limonene molecules on the mechanical properties of the UV-cured coatings. These studies showed that the coatings with limonene molecules retain their properties, and are characterized by the very good adhesion, cohesion and high gloss. These kinds of varnishes can be applied for preparation of appropriate protective coatings on the surface of wood, metals, and nail plates. These protective coatings have not only pleasure smell but also can have the bactericidal and fungicidal properties. The studies performed with Escherichia coli ATCC29425 and Candida albicans confirmed these properties.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 2; 13-19
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dielectric Spectroscopy Studies of 4-Cyano-3-fluorophenyl 4-Butylbenzoate Liquid Crystal at High Pressure
Autorzy:
Rozwadowski, T.
Massalska-Arodź, M.
Juszyńska, E.
Krawczyk, J.
Wojnarowska, Ż.
Paluch, M.
Powiązania:
https://bibliotekanauki.pl/articles/1419574.pdf
Data publikacji:
2012-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
64.70.M-
77.22.Gm
Opis:
For 4-cyano-3-fluorophenyl 4-butylbenzoate, nematic glassformer at ambient pressure, dielectric relaxation studies were performed under elevated pressure. In the isobaric experiment, on cooling the nematic phase two superarrhenius α-relaxations, ascribed to the reorientations of molecules around short axes and precession of long molecular axes were found and the Arrhenius β-relaxation related to intramolecular motions. Complexity of dynamics at elevated and ambient pressure is similar. Shift towards lower frequencies was found for both α-relaxations.
Źródło:
Acta Physica Polonica A; 2012, 122, 2; 378-381
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-4 z 4

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