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    Tytuł:
    Cechy litologiczne i geochemiczne turońskich osadów węglanowych ze stylolitami Karpat pokucko-bukowińskich
    Lithological and geochemical features of Turonian carbonates with stylolites in Pokuttya–Bukovyna (Ukrainian Carpathians)
    Autorzy:
    Radkovets, N.
    Manzhar, N.
    Powiązania:
    https://bibliotekanauki.pl/articles/2062203.pdf
    Data publikacji:
    2012
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    Turonian limestones
    stylolites
    material compositions
    Carpathian autochthon
    wapienie turonu
    stylolity
    skład mineralny
    autochton karpacki
    Opis:
    Badania składu materialnego węglanów ze stylolitami w Karpatach pokucko-bukowińskich wykazały, że zawartość CaCO3 w skałach waha się od 68 do 92%, a pozostałości nierozpuszczalnej od 8 do 32. Szczątki organiczne wielkości od 0,02 do 1 mm (otwornice, ślimaki, ramienionogi i inoceramy) stanowią 40–55% skały, a reszta to kalcyt pelitomorficzny. Części nierozpuszczalne materiału stylolitów to na ogół minerał hydromikowy – illit oraz materia organiczna, cechująca się zwiększoną zawartością żelaza i strontu (>10 razy). Spektoskopia infraczerwona bituminu chloroformowego zawartego w stylolitach wykazała, że materia organiczna powstała głównie z mikroskładników planktonicznych (autochtonicznych) i uległa istotnym zmianom postsedymentacyjnym: polimeryzacji oraz utleniania.
    Chemical analysis of carbonates with stylolites from the autochthon of the Pokuttya–Bukovyna Carpathians showed that the СаСО3 content in the rocks ranges between 68 and 92%, insoluble residue makes 8–32%. Investigation of clayey limestones using the polarizing microscopy allowed to establish that the 0.02–1 mm sized organic debris (foraminifera, gastropods, brachiopods and inocerams) makes 40–55% of the rock. The rest is the matrix represented by pelitomorphic calcite. X-ray diffractometry showed that insoluble residue of the organic-rich clay from stylolites is represented by the hydromicaceous mineral – illite with admixture of organic matter. Results of quantitative spectral analysis revealed the increased iron and strontium (>10 times) content in both limestones and organic-rich clays. Infrared spectrometry of chloroform bitumen extracted from the organic-rich clay from stylolites showed that the dispersed organic matter by its origin consists mainly of planktonogenic (autochthonous) microcomponents and underwent significant postsedimentary transformations: polymerization and oxidation.
    Źródło:
    Biuletyn Państwowego Instytutu Geologicznego; 2012, 449; 131--136
    0867-6143
    Pojawia się w:
    Biuletyn Państwowego Instytutu Geologicznego
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Ediacaran-Paleozoic subsidence history of the Volyn-Podillya-Moldavia Basin (W and SW Ukraine, Moldova, NE Romania)
    Autorzy:
    Poprawa, P.
    Radkovets, N.
    Rauball, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/2060431.pdf
    Data publikacji:
    2018
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    Ediacaran-Early Paleozoic
    Volyn-Podillya-Moldavia basin
    tectonic subsidence
    backstripping
    Opis:
    Tectonic subsidence history was analysed for the Ediacaran-Paleozoic Volyn-Podillya-Moldavia Basin, by performing 1D backstripping for 21 boreholes located in western and SW Ukraine, Moldova and NE Romania. Tectonic subsidence history is coherent across the area studied. Development of the basin commenced with an Ediacaran phase of extension, initiated with the emplacement of rift-related volcanic rocks and associated with rapid syn-rift tectonic subsidence. During this event, tectonic subsidence increased towards the SW, i.e. towards the edge of the East European Craton, where the Ediacaran rift zone was located. At that time, a rift developed along the whole SW margin of the East European Craton from Scandinavia to the Black Sea. Development of this large extensional basin was related to the latest stages of break-up of the Precambrian supercontinent Rodinia/Pannotia and ultimately the formation of the Tornquist Ocean. The latest Ediacaran to Late Ordovician tectonic subsidence pattern was characteristic of the post-rift thermal sag stage of extensional basins. The SW margin of the newly formed Baltica, including the area studied, became a passive continental margin. The late Cambrian uplift and erosion was presumably related to a far-field effect of contractional events or intra-plate stresses. Since the Late Ordovician, a gradual change to a collisional tectonic setting is observed across the SW margin of Baltica. In the study area, this is indicated by a systematic increase in subsidence rate from Wenlock to Early Devonian time, creating subsidence curves with convex shapes typical of foreland basin development. The Silurian to Early Devonian Volyn-Podillya-Moldavia Basin is interpreted here as a flexural foredeep related to a Caledonian collision zone located further to the SW. The prominent diachroneity in the initiation of the foredeep basin development at a scale of the whole SW margin of Baltica is coherent with a model of oblique collision of Avalonia and Baltica. During the Pragian-Emsian, the basin was part of a system of post-collisional Old Red basins, with subsidence driven presumably by lithospheric isostatic imbalance resulting from the Caledonian collision and development of an accretionary wedge. Middle to Late Devonian short-term phases of rapid subsidence in small depocentres might be regarded as an indication of a transtensional tectonic regime.
    Źródło:
    Geological Quarterly; 2018, 62, 3; 459--486
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Origin and migration of oil from the Ukrainian Outer Carpathians to their Mesozoic basement: a case of Lopushna traps
    Autorzy:
    Radkovets, N. Y.
    Kotarba, M.
    Koltun, Y.
    Kowalski, A.
    Kosakowski, P.
    Więclaw, D.
    Powiązania:
    https://bibliotekanauki.pl/articles/2060167.pdf
    Data publikacji:
    2016
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    Ukrainian Carpathians
    Lopushna oil field
    oil origin
    biomarkers
    stable carbon isotopes
    migration pathways
    Opis:
    Lopushna oil field has been discovered in Mesozoic-Paleogene strata of the platform basement under the Ukrainian Outer (Flysch) Carpathians. Oils from two main accumulations, occurring in the Upper Cretaceous sandstone and Upper Jurassic limestone reservoirs, have been analysed in order to identify their origin and relation to the known petroleum systems in the region of the Outer Carpathians and the basement of the Carpathian Foredeep. Results of geochemical investigations of oils, including biomarker and isotopic data, show a good correlation with oils, accumulated in the Carpathian flysch strata. Oils are low-sulphur and did not undergo significant degradation. They were generated from Type II or II/III kerogen, deposited in anoxic environments in clastic sediments. Generation occurred at the peak of “oil window”, probably in the temperature range of 122 to 126oC. The presence of oleanane indicates the Cretaceous or younger source rocks. Good correlation on biomarker and isotopic data with the organic matter dispersed in Oligocene Menilite Beds, occurring at the top of the Carpathian flysch succession, allowed authors to identify them as source rocks for oils of the Lopushna field, which thus can be regarded as an oil family of the Outer Carpathians. The migration distance for both Lopushna oils and oils accumulated in the Carpathian flysch strata was similar. A number of sub-vertical dislocations, on which the subsided flysch strata occur at the same depth level with the Jurassic and Cretaceous rocks of the platform, can be assumed as possible migration pathways from the mature source rocks of the Oligocene Menilite Beds of Boryslav-Pokuttya, Skyba or Krosno units to the Lopushna type traps, which suggests the possibility of existence of other hydrocarbon accumulations of this type. The Lopushna field so far is unique containing this type of oil found in the basement of the Ukrainian Carpathian Foredeep.
    Źródło:
    Geological Quarterly; 2016, 60, 1; 133--148
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Source rock geochemistry, petrography of reservoir horizons and origin of natural gas in the Devonian of the Lublin and Lviv basins (SE Poland and western Ukraine)
    Autorzy:
    Radkovets, N. Y.
    Kotarba, M. J.
    Wójcik, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/2060597.pdf
    Data publikacji:
    2017
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    Devonian
    Lublin Basin
    Lviv Basin
    Rock-Eval pyrolysis
    petrography
    isotope geochemistry
    Opis:
    The Rock-Eval source rock characteristics, mineral composition and type-porosity of reservoir horizons, and origin of natural gas in the Devonian of the Lublin and Lviv basins are described. In the Lower Devonian, the TOC content ranges from 0.01 to 1.82 wt.% in the Lublin Basin, and from 0.01 to 0.45 wt.% in the Lviv Basin. Transformation of organic matter varies from immature in the Lochkovian (Lviv Basin) to mature and overmature in the Emsian (Lublin Basin). The organic matter contains mainly Type-II kerogen, and underwent primary and/or secondary oxidation processes. In the Middle Devonian, the TOC content varies from 0.00 to 1.63 wt.% in the Lublin Basin, and from 0.02 to 0.64 to 2.35 wt.% in the Lviv Basin. The organic matter contains mainly Type-II kerogen and is immature in the Givetian of the Lviv Basin and mature in the Eifelian of the Lviv Basin and in the Eifelian and Givetian in the Lublin Basin. In the Upper Devonian, the TOC content is from 0.02 to 2.62 wt.% in the Lublin Basin, and from 0.04 to 1.43 wt.% in the Lviv Basin. Type-II kerogen dominates in both basins. Organic matter is mature in the Upper Devonian in the Lublin Basin and in the Famennian of the Lviv Basin and overmature in the Frasnian of the Lviv Basin. The reservoir horizons in the Devonian of the Lublin and Lviv basins are developed in clastic, carbonate and sulphate rocks. Terrigenous rocks form several separate horizons in the Lower and Middle Devonian of the Lviv Basin, and in the Upper Devonian (Famennian) of the Lublin Basin. Their filtration properties relate to intergranular porosity, while the fracture space has subordinate significance. Carbonate rocks form thick saturated horizons in the Givetian in the Lviv Basin, and in the Eifelian, Givetian and Frasnian in the Lublin Basin. Their filtration properties are produced by fracture porosity. Sulphates and carbonate-sulphate rocks with fracture and cavern porosity play a role as reservoir horizons in the Middle Devonian of the Lublin Basin. The natural gas collected from the Upper Devonian of the Lublin Basin was generated mainly during low-temperature thermogenic processes, from Ordovician–Silurian Type-II kerogen. The gas from the Middle Devonian reservoirs of the Lviv Basin was produced from Ordovician–Silurian Type-II kerogen and partly from the Middle and Upper Devonian mixed Type-III/II kerogen with maturity from about 0.9 to 1.4%. Carbon dioxide was formed by both thermogenic and microbial processes. Molecular nitrogen was generated mainly through thermal transformation of organic matter and also from destruction of NH4-rich illite of the clayey facies of the Ordovician–Silurian strata.
    Źródło:
    Geological Quarterly; 2017, 61, 3; 569--589
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The Silurian of southwestern margin of the East European Platform (Ukraine, Moldova and Romania) : lithofacies and palaeoenvironments
    Autorzy:
    Radkovets, N.
    Powiązania:
    https://bibliotekanauki.pl/articles/2059822.pdf
    Data publikacji:
    2015
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    East European Platform
    Silurian
    lithofacies
    reef
    shelf of Baltica
    palaeoenvironments
    Opis:
    Silurian strata, stretching along the western margin of the East European Platform from the Baltic to the Black Sea, represent a potential target for both conventional and unconventional hydrocarbon exploration. Distribution of the black shale facies, prospective for shale gas, and the reef facies, prospective for oil, has been studied in respect of palaeoenvironments. The Silurian sequence has been investigated in the territory of Ukraine (Volyn-Podillyan Plate, Dobrogean Foredeep) and correlated with the data on Moldova and Romania (Moldovian Platform). The occurrence of Silurian strata, their thickness, and petrographic and lithological characteristics allowed reconstructing the distribution of open-shelf, reef and lagoonal facies. The reef facies migrated during the Wenlock–Middle Pridoli, shifting towards the open sea and back towards the shore, and therefore has been termed a migrating reef facies. Correspondingly, the boundary between the open-shelf and reef facies was shifting. The facies distribution was controlled by the transgressive-regressive cycles, which caused the fluctuations of the shelf water depth in different time intervals of the Silurian. The shelf water depth of about 100 m, where the top of the oxygen-minimum layer impinged on the sea bottom, was the boundary between the open-shelf facies, represented by organic-rich sediments, and the reef buildups.
    Źródło:
    Geological Quarterly; 2015, 59, 1; 105--118
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
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