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Wyświetlanie 1-2 z 2
Tytuł:
Effect of Mg and Ca on the Characteristics of Inclusions in Sulphur Steel
Autorzy:
Tian, J.
Qu, T.
Wang, D.
Wang, H.
Xu, Z.
Xinrui, E.
Powiązania:
https://bibliotekanauki.pl/articles/355348.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Mg treatment
Ca treatment
MnS
complex sulfide
inclusions
Opis:
The effects of Mg and Ca on sulfide modification of sulphur steel were studied to elucidate the difference between micromagnesium treatment and micro-calcium treatment for the inclusion of sulphur steel. The results show that the inclusions in the steel appeared with an oxide core of Al2O3 and MnS wrapped. After the addition of Mg, the core was changed to spinel, and the MnS coating was changed to Mn-Mg-S. After Ca was added, the core was changed to Ca-Al-O, and the MnS coating was changed to Mn-Ca-S. The Mg content was higher than Ca content in the sulfides of the steel. Therefore, Mg was more effective than Ca in terms of sulfide modification with the same content of Mg and Ca in steel, but the yielding rate of Mg was lower than that of Ca. The Mg content in the oxide core was higher than Mg of the coating of the inclusions in the steel treated with Mg or Mg-Ca. In contrast, the Ca content in the oxide core was lower than Ca of the coating of the inclusions in the steel treated with Ca or Mg-Ca. MnS formed and precipitated during the melt solidification process. The complex sulfide (Mg-Mn-S) was precipitated around MgO·Al2O3 in the Mg treated steel during the cooling process. CaS inclusion was precipitated on the CaO·Al2O3 inclusions in the liquid Ca-treated steel. Thus, CaS was formed first, whereas MnS was formed during the cooling process, followed by the formation of complex sulfide (CaS+MnS), which finally precipitated around CaO·Al2O3 in the Ca-treated steel.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 4; 1599-1607
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optimization and evaluation of alkali-pretreated Paeonia ostii seed coats as adsorbent for the removal of MB from aqueous solution
Autorzy:
Liu, Q.
Li, T.
Zhang, S.
Qu, L.
Ren, B.
Powiązania:
https://bibliotekanauki.pl/articles/779066.pdf
Data publikacji:
2018
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Alkali-pretreated Paeonia ostii seed coats
Adsorption
Methylene blue
Mechanism
Opis:
A novel efficient adsorbent, alkali-pretreated Paeonia ostii seed coats (AP-PSC), was investigated for the removal of methylene blue (MB) dye from solution. Orthogonal array design was applied to optimize the process parameters viz. alkali concentration, liquid-solid ratio (LSR) and pretreatment time. The results revealed that the optimal pretreatment conditions were at 0.8% (w/w) NaOH with LSR of 0.35 L g–1  treating for 50 min. Equilibrium and kinetic studies indicated that Langmuir isotherm and Pseudo-second-order models described the experimental data well. The maximum adsorption capability was of 368.2 mg g–1  for MB at 25°C. Thermodynamic parameters suggested that the AP-PSC adsorption process was physical, endothermic and spontaneous. Furthermore, the adsorption process was influenced by several interactive mechanisms, including ion-exchange, as well as Van der Waals forces and hydrogen bonds that occur concomitantly. It was concluded that AP-PSC may be potential as an efficient adsorbent to remove MB from solution.
Źródło:
Polish Journal of Chemical Technology; 2018, 20, 3; 29-36
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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