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Tytuł:
Fire properties of electric cables used in buildings
Autorzy:
Kaczorek-Chrobak, Katarzyna
Plichta, Andrzej
Półka, Marzena
Powiązania:
https://bibliotekanauki.pl/books/21150473.pdf
Data publikacji:
2023
Wydawca:
Instytut Techniki Budowlanej
Opis:
A significant number of cables of different materials and construction is used extensively in building objects increasing their fire load and, therefore, strongly influencing safety in the case of fire. Electric cables and electrical installations constructed from them, despite being important elements of fire safety, are not considered in the general analysis of the fire safety of buil-dings and are usually not assessed as potential fire risks. One of the tasks in the field of counteracting fire hazards in buildings should be to reduce the risk of fires caused by short circuits in electrical installations. In the event of fire, the process of fire propagation involving electric cables should be considered, which, due to the way cables are installed in buildings, can transfer fire over long distances from the origin of the fire and across storeys through installation shafts. The scientific problem of the doctoral dissertation is to determine the impact of significant constructional and material parameters of electric cables on their fire properties by establishing the qualitative, and possibly also quan-titative, relationships between these parameters. The aim of the presented work was to investigate the effect of material and constructional parameters on the fire properties of electrical cables, such as heat release, smoke generation, range of flame spread and amount of toxic fire effluents under various ventilation conditions. To the best of the author’s knowledge, such systematic research has not been published so far. The presented study is original and fills the scientific gap regarding the constructional and material parameters of electric wires and cables, which influence their fire properties. In order to investigate the relationship between the constructional–mate-rial parameters of cables and their fire properties, eighty-three cables (eighty-nine cable samples) were examined by means of a standard experi-mental method. The selection of cable samples included the presence of one distinctive parameter. The conclusions drawn from the experiments were as follows: (1) construction, the number of conductors and the presence of armour or concentric metallic conductors improve fire properties by forming a barrier against flame penetration through the cable; (2) the use of copper conductors resulted in decreasing fire parameters compared to cables with aluminium conductors (maximum average heat release rate parameter almost four times lower for copper cables); (3) construction materials based on plasticised poly(vinyl chloride) significantly reduce the fire properties of cables compared to halogen-free materials (maximum average heat release rate parameter more than 17 times higher for fully halogenated cables), which is due to the decomposition process of the material; (4) no clear relationship between the fire parameters and cable parameter χ was found. The χ para-meter was developed to improve the monotonicity of the reaction to the fire test results obtained and has been used in the selection of cable samples for testing within the same cable family so far. As the investigation showed a significant impact of the number of metallic barriers (conductors) on flame penetration into the inner layers of electric cables and the volume of non-metallic materials on the fire properties of cables, a parameter related to the volume of effective non-combustible content Ω was proposed. The new Ω parameter depends on the non-metallic non-combustible components volume to non-metallic combustible components volume ratio and the effective area of heat transfer within the cable. Increasing Spearman’s correlation factors (close to −1) were obtained for total heat release rate and total smoke generation parameters as a function of the Ω parameter rather than the χ parameter. In order to examine the amount of fire/combustion gases under ventilation-controlled fires, a simple poly(vinyl chloride)-based copper electric wire widely used in buildings was studied by means of a Steady State Tube Furnace. A reference pure polymer unplasticised poly(vinyl chloride) and additionally pure low-density polyethylene were also tested. Decreasing carbon dioxide yields at different ventilation conditions for the poly(vinyl chloride) based copper electric wire were obtained in comparison to three times higher yields for pure poly(vinyl chloride) and two times for low-density polyethy-lene than those received for the tested wire at the same ventilation conditions, which confirms the insignificant contribution of the hyperventilation effect to humans during a cable fire. To the contrary, four times higher values of toxic carbon monoxide yields were obtained for the tested wire rather than for the reference polymer and pure low-density polyethylene. The maxi-mum value of carbon monoxide yield (0.57 g/g) was obtained in the case of 5 l/min of primary airflow, which decreased with increasing ventilation. The measured yields of hydrocarbons were similar to the reference values except for the equivalence ratio = 0.27. The corrosive and toxic hydrochloric acid occurring in fire effluents from the studied wire was independent of the ventilation conditions tested. The reaction between copper and the hydrochloric acid compound, inorganic fillers, and hydrochloric acid decreased the hydrochloric acid content in fire effluents. Analysis using Quintiere's theory showed that the cone calorimeter me-thod can be used in numerical modelling of the cable burning process, and its use can significantly facilitate and reduce the number of cable fire tests, without adversely affecting the final results. Summarising, the analysis of the impact of cable construction is an important element from the point of view of the fire safety of buildings. In the course of the study, it was found that factors such as the shape, number and material used for conductor formulation, as well as the types of mate-rials from which the non-metallic elements of the cables are made, and the presence of armour or concentric conductors significantly influence the fire properties of cables, such as heat release, smoke generation, range of fire spread and fire effluent toxicity, largely reducing the fire properties of cables. The experiments enabled the development of a new cable parameter Ω, which is a better predictive indicator of cable flammability than the standard and commonly used parameter χ. In addition, it was found that it is possible to replace large geometric scale fire tests with a simpler cone calorimeter method by applying Quintiere’s theory of electric cables.
Dostawca treści:
Biblioteka Nauki
Książka
Tytuł:
Chemical recycling of polyesters
Recykling chemiczny poliestrów
Autorzy:
Dębowski, Maciej
Iuliano, Anna
Plichta, Andrzej
Kowalczyk, Sebastian
Florjańczyk, Zbigniew
Powiązania:
https://bibliotekanauki.pl/articles/947058.pdf
Data publikacji:
2019
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Chemii Przemysłowej
Tematy:
recycling
solid-state polycondensation
polylactide
poly(ethylene terephthalate)
glycolysis
hydrolysis
aminolysis
ammonolysis
recykling
polikondensacja w ciele stałym
polilaktyd
poli(tereftalan etylenu)
glikoliza
hydroliza
aminoliza
amonoliza
Opis:
In the presented paper, two basic strategies that can be used in the processes of chemical recycling of polyester material were described. The first of them involves increasing the molar mass of recycled materials in the solid-state polycondensation (SSP) process and/or joining their chains with various types of substances easily reacting with the end groups of polyesters (so-called extending agents). The essence of the second strategy is the degradation of the material under the influence of various protogenic agents (such as water, alcohols, glycols and amines) to obtain low-molecular products or oligomers that can be used as raw materials in the synthesis of many classes of polymers. The methods that are already used in PET [poly(ethylene terephthalate)] recycling and the possibility of their extension to other types of polyesters are both shown.
W pracy przedstawiono dwie podstawowe strategie możliwe do wykorzystania w procesach chemicznego recyklingu tworzyw poliestrowych. Pierwsza z nich polega na zwiększeniu masy molowej utylizowanych tworzyw polimerowych w procesie polikondensacji w ciele stałym (SSP) i/lub łączeniu ich łańcuchów za pomocą różnego typu substancji łatwo reagujących z grupami końcowymi poliestrów (tzw. czynników przedłużających). Istotą drugiej strategii jest degradacja tworzywa pod wpływem różnych czynników protogennych (takich jak: woda, alkohole, glikole i aminy) w celu uzyskania produktów małocząsteczkowych lub oligomerów, które można wykorzystać jako surowce w syntezie wielu klas materiałów polimerowych. Omówiono metody stosowane już w recyklingu PET [poli(tereftalanu etylenu)], a także możliwość ich rozszerzenia na inne gatunki poliestrów.
Źródło:
Polimery; 2019, 64, 11-12; 764-776
0032-2725
Pojawia się w:
Polimery
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and characterization of one-component, moisture curing polyurethane adhesive based on Rokopol® D2002
Synteza i charakterystyka jednoskładnikowych klejów poliuretanowych na osnowie polieterodiolu Rokopol® D2002
Autorzy:
Wadas, Jadwiga
Oliwa, Rafał
Pilch-Pitera, Barbara
Byczyński, Łukasz
Heneczkowski, Maciej
Florjańczyk, Zbigniew
Plichta, Andrzej
Rokicki, Gabriel
Powiązania:
https://bibliotekanauki.pl/articles/945761.pdf
Data publikacji:
2020
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Chemii Przemysłowej
Tematy:
PUR
adhesive
moisture-curing
rheometry
DSC
Al/Al bonding
kleje
szczeliwa
utwardzanie wilgocią
reometria
Al/Al
klejenie
Opis:
One-part, moisture curing polyurethane (PUR) adhesives based on poly(oxypropylene)diol Rokopol® and 4,4’-diphenylmethylene diisocyanate (MDI) modified with di-isononyl phthalate and a number of inorganic fillers and additives such as carbon black, thixotropic agent, dispersants and dibutyltin dilaurate as curing catalyst were developed. Adhesive curing was followed using dynamic oscillation rheometry and effect of some components on viscoelastic properties of curing materials was discussed. The cured materials were characterized by means of differential scanning calorimetry (DSC) and water contact angle measurements. The adhesive performance of obtained materials in bonding aluminum was evaluated by tensile shear bond strength tests.
Opracowano jednoskładnikowe kleje na osnowie diizocyjanianu 4,4’-metylenodifenylu (MDI) i polioksypropylenodiolu z środkami pomocniczymi (ftalanem diizononylu jako plastyfikatorem, napełniaczami: talkiem, haloizytem, modyfikowanym bentonitem; dyspergatorami, sadzą pigmentową i katalizatorem utwardzania – dilaurynianem dibutylocyny). Proces sieciowania analizowano za pomocą reometru z dynamiczną oscylacją. Metodą różnicowej kalorymetrii skaningowej wyznaczano temperaturę zeszklenia, ponadto określano kąt zwilżania i właściwości adhezyjne otrzymanych materiałów przeznaczonych do łączenia spoin Al/Al.
Źródło:
Polimery; 2020, 65, 7-8; 568-571
0032-2725
Pojawia się w:
Polimery
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Polycarbonate-based polyurethane – attractive materials for adhesives, binders and sealants production
Poliuretany z segmentami oligowęglanowymi jako atrakcyjne materiały do produkcji klejów, spoiw i uszczelniaczy
Autorzy:
Iuliano, Anna
Dębowski, Maciej
Plichta, Andrzej
Kowalczyk, Sebastian
Florjańczyk, Zbigniew
Rokicki, Gabriel
Parzuchowski, Paweł. G.
Mazurek-Budzyńska, Magdalena
Wołosz, Dominik
Pilch-Pitera, Barbara
Powiązania:
https://bibliotekanauki.pl/articles/945769.pdf
Data publikacji:
2020
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Chemii Przemysłowej
Tematy:
aliphatic oligocarbonate diols
isocyanate
polyurethane
mechanical properties
adhesives
alifatyczne oligowęglanodiole
izocyjaniany
poliuretany
właściwości mechaniczne
kleje
Opis:
In the last few years, a very wide range of oligocarbonate diols, oligomers of carbonic acid esters terminated on both sides with hydroxyl groups, have appeared on the chemical market. They are mainly used for the production of flexible segments in precious grades of polyurethanes used in biomedical engineering. Poly(carbonate-urethane) due to high resistance to oxidizing and hydrolytic agents is also an attractive material for the production of adhesives and coatings with increased resistance to weather conditions. This paper presents the current state of knowledge on the methods of synthesis and main producers of oligomerols with carbonate groups, methods of poly(carbonate-urethane) synthesis and examples of its commercial applications.
W ostatnich latach na rynku chemicznym pojawiła się bardzo bogata gama oligowęglanodioli, czyli oligomerycznych estrów kwasu węglowego, zakończonych z obu stron grupami hydroksylowymi. Są one wykorzystywane głównie do wytwarzania segmentów elastycznych w szlachetnych gatunkach poliuretanów stosowanych w inżynierii biomedycznej. Poli(węglano-uretany), dzięki dużej odporności na czynniki utleniające i hydrolityczne, stanowią także atrakcyjny materiał do produkcji klejów i powłok, trwałych w różnych warunkach atmosferycznych. W niniejszej pracy przedstawiono aktualny stan wiedzy dotyczący metod otrzymywania i głównych producentów oligomeroli z segmentami oligowęglanowymi, metod syntezy poliuretanów zawierających te segmenty oraz przykłady komercyjnych zastosowań poli(węglano-uretanów).
Źródło:
Polimery; 2020, 65, 7-8; 497-508
0032-2725
Pojawia się w:
Polimery
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Profile distribution of metals in Gelic Cambisols of Kaffiöyra, Spitsbergen
Autorzy:
Plichta, Witold
Kuczyńska, Irena
Sapek, Andrzej
Powiązania:
https://bibliotekanauki.pl/articles/2052830.pdf
Data publikacji:
1991
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Arctic
Spitsbergen
Gelic Cambisols
metal elements
Źródło:
Polish Polar Research; 1991, 12, 2; 195-201
0138-0338
2081-8262
Pojawia się w:
Polish Polar Research
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-5 z 5

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