- Tytuł:
- Attachment of 2,2-bipyridine onto a silica gel for application as a sequestering agent for copper, cadmium and lead ions from an aqueous medium
- Autorzy:
-
Souza, E. J.
Cristante, V. M.
Padilha, P. M.
Jorge, S. M. A.
Martines, M. A. U.
Silva, R. I. V.
Carmo, D. R.
Castro, G. R. - Powiązania:
- https://bibliotekanauki.pl/articles/779827.pdf
- Data publikacji:
- 2011
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
2,2-bipirydyna
żel krzemionkowy
adsorpcja
jony metali
2,2'-bipyridine
silica gel
adsorption
metal ions - Opis:
- A method was developed to attach 2,2-bipyridine (BP) onto a silica gel surface by a two-step reaction. The fi rst step consisted of a reaction between the matrix and a silylating agent, 3-chloropropyltrimethoxysilane. In the second step of the reaction, a ligand molecule was attached onto Si-CPTS, yielding the product Si-BP. The modified material contained 0.431±0.01 mmol of 2,2-bipyridine per gram of modified silica, as confirmed by FT-IR spectra of the proposed structure. The surface modification was characterized by the BET technique, which revealed a decrease in the surface area from 614 to 450 m2 g-1. The series of adsorption isotherms for the metal ions were adjusted to fit a modified Langmuir equation. The maximum number of moles of copper, cadmium and lead ions adsorbed was 0.64, 0.53, and 0.54 mmol g-1, respectively. The surface saturation was calculated as ¢ fraction and the values obtained, Cu(II) =1.160, Cd(II) = 1.044 and Pb(II) = 0.997, suggest a type 1:1 metal-ligand complex.
- Źródło:
-
Polish Journal of Chemical Technology; 2011, 13, 4; 28-33
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki
Artykuł