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Wyszukujesz frazę "Otremba, Z." wg kryterium: Autor


Tytuł:
Wpływ dodatku pyłu z węgla brunatnego na podstawowe właściwości fizyczne i wodne poziomu uprawnego gleby powstającej z gruntów pogórniczych PWB Konin
Impact of addition of silt from brown coal on basic physical and water properties of the topsoil developed from post-mining land of Konin brown coal mine
Autorzy:
Otremba, K.
Kaczmarek, Z.
Gajewski, P.
Powiązania:
https://bibliotekanauki.pl/articles/1819302.pdf
Data publikacji:
2012
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
grunty pogórnicze
KWB Konin
węgiel brunatny
pył węglowy
Opis:
Post-mining land created as a result of the deposition of the strippings from Konin Brown Coal Mine (Konin BCM) is being rehabilitated in accordance with principles of the target species concept developed by Bender. The rehabilitation technology realised in accordance with this concept is based on the enhancement of soil chemism and improvement of physical properties supporting the development of vegetation cover and stimulating biogeochemical processes. The basic soil-forming factor in this concept is the anthropogenic factor integrating the action of biotic and abiotic factors into a consistent, mutually supporting system of rehabilitation actions and activities whose aim is to transform, within the period of 10 years, this specific maternal material into soil. One of the forms of integration of the anthropogenic factor into the composition of the solid phase of the developing soils was the addition of brown coal dust - a by-product created in the production of briquettes. The usefulness of brow coal for fertilisation purposes stems from the composition of its organic matter as well as specific physical, physico-chemical and chemical properties. The objective of the research project was to determine the effect of the addition of brown coal on major physical and water properties of anthropogenic topsoil 18 years after application. The research object was situated on the experimental plot of the Department of Soil Science and Restoration established in 1978 on post-mining land of Patnow Mine internal dumping ground. The experiment comprised two variants. Variant A control comprised the area on which, from 1978, the applied treatments were consistent with Bender's concept of target species. In the case of variant B, on an experimental area subjected to restoration treatments for 14 years, fertilisation with brown coal dust in the amount of 1000 t.ha(-1) was applied in 1992. The following four fertiliser combinations were employed in this variant: 0 NPK (1); 100 kg N, 80 kg K2O, 40 kg P2O5 (2); 200 kg N, 80 kg K2O, 40 kg P2O5 (3); 300 kg N, 80 kg K2O, 40 kg P2O5 (4). In both experimental variants, winter cereals were cultivated. Straw and other plant residues were ploughed under every year. In 2010, soil samples of intact and broken structure (V=100 cm3) were collected from the topsoil of individual plots for laboratory exanimations. The following parameters were determined: total carbon and nitrogen, texture composition, solid phase density, soil density, total, drainage and differential porosity, hygroscopic moisture content, maximal hygroscopic capacity, filtration, soil water binding potentials, potential and effective useful retention. It was concluded, among others, that the selected major physical, chemical and water properties of the arable layer of the agriculturally rehabilitated soils in accordance with principles of the concept of target plants were at the typical level characteristic for cultivated soils of similar texture and total carbon content. The addition of brown coal to the top layer of soil developing from post-mining land caused: a decrease in the soil density as well as the density of its solid phase, increase of total porosity, increase in proportions of mezo- and micropores, enhancement in the value of hygroscopic moisture content as well as maximal hygroscopic capacity. In the examined soils, together with the increase of the applied nitrogen fertilizer doses, the content of total carbon as well as C:N ratio narrowed. This was probably due to a faster rate of organic matter mineralisation. Long-term nitrogen fertilisation comprising four combinations failed to affect diversification of the total nitrogen content. In the case of soils with the addition of brown coal, the availability of production water was extremely low. On the other hand, the content of water available for plants but bonded with strong forces was high.
Źródło:
Rocznik Ochrona Środowiska; 2012, Tom 14; 741-751
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ultraviolet-induced fluorescence of lubricate oils
Fluorescencja oleju smarnego wzbudzana światłem ultrafioletowym
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/134176.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Naukowe Silników Spalinowych
Tematy:
lubricate oil
fluorescence
optical fiber
olej smarny
fluorescencja
sensor optyczny
Opis:
The paper describes the study on relationship between the engine lubricate oil quality and fluorescence phenomenon. In order to determine the Excitation-Emission spectra (EEMs) of oil samples, a spectrofluorometer combined with an optical fiber system were applied. Two methods of fluorescence measurement: when oil diluted in non-fluorescent solvent (n-hexane) is placed in the quartz-cuvette inside the spectrofluorometer, and when oil sample is placed outside the spectrofluorometer (then EEMs is measured through the optical fiber sensor) were utilized to analyze the shape of EEMs of lubricate oil. Moreover in the second case of measurement, the optical fiber sensor was placed at an angle of 45 degrees to the oil surface, similarly above the oil surface and beneath the oil surface directly submerged in oil. Preliminary measurement results presented in this paper – on one hand – indicate diversity in the shape of EEMs depending on the method of fluorescence measurement, on the other hand – indicate possibility to measure fluorescence of oil directly in engine lubricate oil circuit.
W artykule przedstawiono wyniki badań związku pomiędzy jakością oleju smarnego a zjawiskiem fluorescencji. W celu wyznaczenia widm zupełnych fluorescencji próbek oleju wykorzystano spektrofluorymetr połączony ze światłowodowym systemem pomiarowym. Zanalizowano kształt widm odnoszących się do oleju smarnego w dwóch sytuacjach, gdy: olej jest rozpuszczony w niefluoryzującym medium (n-hexan) i umieszczony jest w przyrządzie w kwarcowej kuwecie oraz gdy próbka oleju znajduje się na zewnątrz przyrządu, sygnał jest przenoszony światłowodem. Ponadto przy pomiarach z zastosowaniem światłowodu ustawiona pod kątem 45° głowica pomiarowa zestawu światłowodowego znajduje się, odpowiednio: w powietrzu nad powierzchnią oleju albo pod powierzchnię oleju. Przedstawione w niniejszym artykule wstępne wyniki badań z jednej strony wskazują na zróżnicowanie kształtów widm zupełnych fluorescencji względem metody pomiarowej, z drugiej strony – wskazują na możliwość wyznaczania fluorescencji bez wstępnej obróbki laboratoryjnej, bezpośrednio w silnikowym obiegu oleju smarnego.
Źródło:
Combustion Engines; 2015, 54, 4; 21-25
2300-9896
2658-1442
Pojawia się w:
Combustion Engines
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The influence of a static, homogeneous magnetic field on the sorption properties of soybean meal during maritime transport
Autorzy:
Ocieczek, A.
Kaizer, A.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/2063955.pdf
Data publikacji:
2021
Wydawca:
Uniwersytet Morski w Gdyni. Wydział Nawigacyjny
Tematy:
cargo transportation
magnetic field
soyabean meal
maritime transport
sea transportation
sorption properties
brunauer
bulk cargo
Opis:
Providing safety and maintaining high quality of dry cargo, transported by sea, is associated with the necessity of taking into consideration their specific property, which is hygroscopicity. Susceptibility to the impact of water, which also occurs in vapour state, concerns mainly dry cargo, which are organic matter, containing carbohydrates and protein in their composition. This is because these substances have strong connection with water. The example of a bulk cargo often transported by sea is soybean meal, which is mainly produced in the USA, Brazil and Argentina. Due to its economic importance, the quality of soybean meal, which is globally used in the animal nutrition (poultry and swine), remains an important research issue. This product is obtained by subjecting the soybeans to cracking and dehulling processes, in order to facilitate the extraction of the oil. Water absorption of soybean meal causes reactions taking place in it, which leads to the changes in its chemical composition and, consequently, also in its nutritional values. Moreover, increasing the water content, leading to the increase of water activity, may significantly deteriorate the microbiological safety of the meal. Therefore, the research was undertaken to determine whether the sorption properties of soybean meal will change due to the influence of a static, homogeneous magnetic field. This aim has been achieved by determining and comparing the water vapour adsorption isotherms. The comparison of the isotherms determined under normal conditions and under the influence of a static, homogeneous magnetic field with an induction of 10 mT has been made on the basis of empirical data. Furthermore, using the Brunauer, Emett and Teller equation (BET), the monolayer and the energy constant of the sorption process have been estimated. The isotherms were determined at 20°C. The study lasted 9 days. Desiccators with aqueous supersaturated solutions of substances and a generator of a static magnetic field were used in the research. The obtained results have indicated that the influence of the magnetic field is a factor that causes the differentiation between the sorption properties of soybean meal expressed in the volume of the monolayer and the energy associated with the sorption phenomenon. The inferred findings show, that the magnetic field has an impact on the course of the sorption phenomenon in organic samples, and may determine the stability of the cargo during long-term maritime transport.
Źródło:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation; 2021, 15, 3; 649--657
2083-6473
2083-6481
Pojawia się w:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The European controlling system to reduce oil discharges in the sea
Autorzy:
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/246642.pdf
Data publikacji:
2012
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
marine transport
oil pollution detection
satellite surveillance
CleanSeaNet
Opis:
Shiporigin operational discharges of oil mainly include the discharge of bilge water from motor rooms, fuel oil sludge and oily ballast water from fuel tanks. Also, various tankers can illegally discharge of tank-washing residues. Accidental discharges can appear when ship collide or come in distress at sea (e.g. engine breakdown, fire, explosion, pipeline breaks). There is necessity of continuous inspection of marine shipping routes, especially in environmentally sensitive areas (e.g. whole Baltic Sea). If protection against oil pollution is considered - the coastal nations of the North Sea are formed in the Bonn Agreement, whereas coastal nations of the Baltic Sea are formed in the HELCOM convention. Both organizations carrying out the international aerial surveillances and manage international oil-combat systems. Unfortunately, air surveillance can operate mainly in good weather, good visibility and in daylight. The surface of the whole world is observed independently on the time of day and weather by antennas of Synthetic Aperture Radars (SAR) of dozen military satellites with resolution of several meters. Some civil satellites equipped with SAR, supply every few days a set of signals which in ground-based centres are transformed to image of a define area of the sea surface. In these images, the shapes of places, which can be interpreted as polluted by an oil film, are shown. The system is introduced after EU directive and managed by European Maritime Safety Agency (EMSA). EMSA has developed the CleanSeaNet service - a satellite based monitoring system for marine oil spill detection. Advantages and limitations of the SAR-methods are discussed in this study. Physical, meteorological and hydrological as well as organizational conditions for effective use of this system are considered.
Źródło:
Journal of KONES; 2012, 19, 2; 375-381
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The different uses of sea space in Polish Marine Areas: is conflict inevitable?
Autorzy:
Weslawski, J.M.
Urbanski, J.
Kryla-Staszewska, L.
Andrulewicz, E.
Linkowski, T.
Kuzebski, E.
Meissner, W.
Otremba, Z.
Piwowarczyk, J.
Powiązania:
https://bibliotekanauki.pl/articles/48238.pdf
Data publikacji:
2010
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
Polish marine area
spatial planning
sea space
fishery exploitation
nature protection
recreation
global exploitation
infrastructure
Opis:
Seven major types of sea space use (Nature Protection Measures, Fisheries Ex- ploitation, Geological Exploitation, Recreation, Large Infrastructures, Navigation, Military uses) in the Polish Marine Areas are presented in terms of how much space is used (km2) for each use and the degree of overlap among the different uses. The greatest degree of conflict is noted with regard to Nature Protection (which overlaps with 60% of the areas used for Recreation and Geological Exploitation), and Fisheries Exploitation (which overlaps with 60% of the areas used for Nature Protection, Recreation, Infrastructure and Navigation). On the other hand, Fisheries Exploitation areas are the least disturbed by other users, and its major competitor is Nature Protection, which claims 20% of the areas used by fisheries. A GIS–based map that illustrates the degree of conflict is included, and the authors suggest participatory management as the proper way to minimize conflicts over sea space use and to promote the effective protection of natural resources.
Źródło:
Oceanologia; 2010, 52, 3; 513-530
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Testing of the synchronous fluorescence in application to used lubricate oil characterisation
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/243560.pdf
Data publikacji:
2016
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
marine fleet exploitation
lubricate oil
fluorescence spectroscopy
synchronous fluorescence spectra
Opis:
Reliability of the ship propulsion system depends, inter alia, on the quality of lubricate oils. Research indicates that exploitive features of oil are reduced with it runtime in the ship engine circuit. At the present the basic parameters representing exploitive features of oil are: water content, total acid number and total base number or viscosity vs. temperature, anti-wear performance, further: content of additives and their concentrations, reaction products, and other contaminating substances, also magnetically separated large ferromagnetic particles, the size, the shape, the composition and concentration of the abnormal wear particles. Additional properties of oil are described based on atomic emission spectroscopy, granulometry of separated from the lubricant sample by magnets and gravity, permeability changes, as well as rheometric and tribometric characteristics. Complexity of composition of lubricate oil raises the idea to use changes of relative content of any compounds for characterization of oil exploitive features. Fluorescence method is possible to use for oil properties characterisation due to the presence mono and polycyclic compounds in oil that induces fluorescence phenomenon. Therefore identification the fluorescence spectra when exploitation time of oil increases could be novel indicator to monitor of lubricate oil exploitive quality. In this study we present changes of oil fluorescence expressed by synchronous spectra, taking into account working time of exemplary lubricate oil in the ship engine.
Źródło:
Journal of KONES; 2016, 23, 2; 39-44
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Test of the suitability of chosen materials in terms of their use for removing oil spillage from the water environment
Autorzy:
Guźlińska, E.
Kończewicz, W.
Otremba, Z.
Trojnar, D.
Powiązania:
https://bibliotekanauki.pl/articles/241568.pdf
Data publikacji:
2016
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
sorbents
fuel
seawater
maritime engineering
environmental protection
Opis:
The paper presents the study about impregnability of various loose materials dedicated as the fillers of oil absorbent socks and booms. Purpose of the survey was finding the material, which is characterized with the smallest hygroscopicity and the highest absorptivity towards typical fuels used in the marine techniques. The cause of take up the topic is the fact, that the contamination of sea areas with petroleum substances are unfortunately very often, are dangerous for natural environment and first of all are so hard to remove from the sea surface. The natural, mineral and synthetic sorbents were studied under laboratory conditions. Samples of the ten kinds of sorbent, each of 2 grams, were treated with the same amount of the diesel fuel, heavy fuel oil and the sea water also, each time in the same period-time (5 minutes). In order to determine the reliability of the results the authors carried out the test fivefold for the one of searched sorbents (recognized as the most hydrophobic-oleophilic substance). The results are presented in graphical form, based on which we are able to select sorbent that fulfils the greatest extent of required expectations. The results of performed tests show that the method that was described in the paper could be used to test the suitability of various materials for the production of devices for collecting the oil film from the surface of the water.
Źródło:
Journal of KONES; 2016, 23, 3; 171-176
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on oil sorbents effectiveness
Autorzy:
Kończewicz, W.
Grabowska, O.
Lachowicz, D.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/246596.pdf
Data publikacji:
2013
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
fuels
lubricant oil
maritime engineering
environmental protection
Opis:
The paper presents search for objective and quantitative method of determination usefulness of various loose sorbents destined for cleaning surfaces polluted with oil. The motivation to take up the topic is that oil pollution emergence in marine areas remains still as the environmental problem. During the ship exploitation there is possibility of appearing of the fuel oil, lubricating oil, hydraulic oil or even transformer oil leaks on the board which might be erased by washing or using sorbent powders and granules or mates. In the case of disposing the washing liquids, the large volume of oil-in-water emulsion is forming which is gathered in a tank and further transported to the vessel cleaning system. In the case when sorbents are applied in an early phase of oil leakage, the vessel cleaning system is less overloaded which reduce the probability of failure. We report analyses of effectiveness of mineral and organic sorbents. The time-period of incepting of defined amount of oil by define amount of sorbent is applied as the sorption effectiveness parameter. Time plots of oil sorption as well as visualizations of this process are presented. Method to characterize the efficiency of sorbents in relation to used lubricating oil is proposed which will stand as the base for further works directed towards elaborating optimal sorbent-set which can be rapidly used for combat spillages and leaks of oils and even other liquid dangerous payloads carried by ships.
Źródło:
Journal of KONES; 2013, 20, 1; 135-138
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectrum of light absorption as the indicator of lubricate oil dispsersed in the natural water
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/247346.pdf
Data publikacji:
2016
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
lubricate oil
absorption
absorption spectra of dispersed oil oil-in-water emulsion
Opis:
Oil pollutants in the natural water masses – especially in the seawater column – can be found in two forms, namely as dissolved oil or as dispersed one. With a broad set of methods, for studying the complex structure of petroleum products, due to the ability of petroleum products to absorb UV-light, absorbance spectra could be a relevant indicator to oil identification in aquatic environment and could support methods provided by the fluorescence technique. The intention of the study described in this article is to characterise the absorption properties of lubricate oil possible to found in the marine environment. Two types of oil as the representative of lubricate oils using in the ship engines are considered. One form of oil possible to found in the marine environment – oil-in-water emulsion was taken into account for analysis. Dispersed in water lubricate oil samples were prepared for several oil concentration for each type of oil. Spectrofluorometer Aqualog Horiba was used to register the absorbance spectra of oils. Based on the Lambert-Beer law the absorbance spectra were derived and specific parameter – absorption coefficient – for each wavelength of excitation, in the range 240-600 nm, was determined. Obtained results indicate decreasing of the oil absorbance value when excitation wavelength increases. Moreover, basing on the absorbance spectra it could be concluded that the main maximum for this kind of oils is located below 240 nm. However, in the considered range of excitation wavelength small flat peak, centred about 265 nm for both types of oils, was detected. Therefore one could conclude that absorbance of oils could be used as the indicator to detect of oil pollution in the natural environment omitting the labour intensive chemical methodology.
Źródło:
Journal of KONES; 2016, 23, 1; 61-66
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectroscopic methods in application to oil pollution detection in the sea
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/248141.pdf
Data publikacji:
2012
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
marine transport
oil pollution
spectroscopic methods
fluorescence
time-resolved fluorescence
Opis:
The escalating maritime transport as well as offshore crude oil exploitation and pipeline transportation leads to the increase of feasibility of the discharge of petroleum substances to the sea environment events. Therefore, it is necessary to rapidly detect of oil pollution to minimize the extent of contamination in the seawater. The aim of this study is to discuss the assumptions of the optical methods using for detection of oil pollution in the seawater. We consider the different approaches of oil-in-water detection using spectral active and passive techniques with emphasis on fluorescence techniques. The intensive development of scientific apparatus and methods in light spectroscopy leads to build various airborne or underwater specialized devices (UV-, IR-scanners, fluorosensors), which allows to detect oil pollution in relatively large areas of the sea. The possibility of measurements of oil pollution in the seawater is particularly important for monitoring, especially in very difficult weather conditions and highly waved sea surface. Such possibilities should be given by devices for in-situ measurements based on time-resolved fluorescence. Such measurements allow obtaining the significant information about presence of oil in really short time. As we show in this study, the wide-range development of fluorescence techniques opens the diagnostic opportunity not only for detection of the oil-in-water content but also for identification the type of oil directly in seawater or even determination of the source of oil pollution.
Źródło:
Journal of KONES; 2012, 19, 1; 15-20
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectrofluorymetry in application to oil-in-water emulsion characterization
Autorzy:
Otremba, Z.
Baszanowska, E.
Toczek, H.
Powiązania:
https://bibliotekanauki.pl/articles/246063.pdf
Data publikacji:
2011
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
oil
fuels
lubricants
aquatic environment protection
fluorescence spectra
Opis:
The question of identifying the type of oil in exploitation of engine room is associated with both the quality of ship consumables (fuels and lubricants) and the composition and origin of oil in settling tanks or in dumping water. Related issue is the possibility of determining the origin of oil, which is detected in the marine environment. The key question is how oils vary in their ability to fluorescence, understood as the shapes of fluorescence spectra obtained for different wavelengths of light exciting fluorescence. In this paper we present spectra of fluorescence for six chosen oils. Those oils were previously dispersed (emulsified) in the seawater, then extracted into hexane. Fluorescence spectra were obtained using fluorescence spectrometer Perkin Elmer LS55, for excitation wavelengths in the range from 240 nm to 500 nm, and emission wavelengths from 300 nm to 790 nm. In this paper there is shown that in general both total intensity of fluorescence and shapes of spectra of fluorescence depend on the excitation wavelength and are differ for various kinds of oil. In order to visually show the differences in fluorescence abilities of various oils, the results of measurement were placed on a chart of fluorescence intensities in the function of both variables: the excitation wavelength and the emission wavelength (so called the total fluorescence spectra). Analyses of results of the described studies confirm that the different oils fluoresce differently and identification of type of oil is possible by fluorescence spectrophotometry.
Źródło:
Journal of KONES; 2011, 18, 3; 317-321
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectrofluorimetry of chosen distillates of oil after pyrolysis of scrap tires
Autorzy:
Otremba, Z.
Ambrosewicz-Walacik, M.
Powiązania:
https://bibliotekanauki.pl/articles/245271.pdf
Data publikacji:
2018
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
fuels
used car tires
pyrolysis
fluorescence
excitation-emission spectra
Opis:
One of way to obtain liquid hydrocarbons can be pyrolysis of scrap tires. The hydrocarbon substances produced by this method may be an addition to traditional fuels, i.e. gasolines or fuels for diesel engines. In laboratory conditions at Department of Mechatronics of University of Warmia and Mazury there were obtained pyrolytic products and prepared three distillates related to temperatures 160, 204 and 350ºC. Analyses of shapes of fluorescence spectra were carried out in Department of Physics of Gdynia Maritime University. Spectra of fluorescence were prepared applying the spectrofluorimeter Hitachi F-7000 FL, which allows applying of excitation wavelength from 200 nm until 600 nm, whereas analysing of emitted, can be performed until 750 nm. In here reported study excitation and emission range for the most intense fluorescence are presented. There were prepared four solutions of pyrolytic products in the n-hexane: 4 ppm, 20 ppm, 100 ppm and 500 ppm. In order to show dependence of intensity fluorescence and shapes of excitation-emission spectra on type of distillate and concentration both kind of visualization – three-dimensional and as contour maps – are shown in this article. In analysed range of wavelengths, intensity of fluorescence grows with concentration of oil, whereas structure of the shape of spectra simplify when concentration increases. The presented effects associated with the fluorescence of pyrolysis products allow to predict the possibility of developing a method for determining the content of these substances in mixtures with petroleum refining products and other liquid hydrocarbons.
Źródło:
Journal of KONES; 2018, 25, 2; 262-268
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectrofluorimetric characteristics of used lubricating oil
Spektrofluorymetryczna charakterystyka zużytego oleju smarnego
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/328239.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Polskie Towarzystwo Diagnostyki Technicznej PAN
Tematy:
fluorescence
excitation-emission spectra of oil
lubricate oil
ship engine
fluorescencja
zupełne widmo fluorescencji
olej smarny
silnik okrętowy
Opis:
Deterioration of lubricate oil in combustion engines enforces measurements of parameters essential for proper operation of define driving system or to certain engine malfunctions indicate. Since the fluorescence phenomenon is known for oil excited by ultraviolet light - the question arises whether fluorescence spectra evolving with the time of exploitation of oil in the engine. In this paper the introductory studies of excitation-emission spectra (EEMs) for chosen lubricate oil are described. Both fresh and used oil (after 593 h of work in a ship engine), was used to measure EEMs. As a result of comparison of EEMs for both fresh and used lubricate oils more significant transformations in fluorescence spectra of oil caused by their exploitation are indicated. Obtained results allow to predict that spectrofluorimetry method could supplement present methods of used lubricating oil testing.
Pogarszanie się właściwości oleju smarnego w silniku spalinowym skutkuje koniecznością monitorowania jego eksploatacyjnych parametrów. Z racji wykazywania przez oleje fluorescencji w świetle ultrafioletowym - powstaje pytanie, czy widma fluorescencji ewoluują wraz z czasem przebywania oleju w obiegu smarnym silnika. W artykule opisane są wstępne analizy zmian zupełnych widm fluorescencji (EEMs) dla różnych stężeń wybranego oleju smarnego. Do pomiaru EEMs oleju użyto dwóch form oleju – świeżego i przepracowanego w silniku okrętowym w czasie 593 h. W następstwie porównania widm uzyskanych dla świeżego i przepracowanego oleju wskazano na zachodzące najbardziej znaczące zmiany we fluorescencji oleju smarnego. Uzyskane wyniki pozwalają sądzić, że spektrofluorymetria mogłaby uzupełnić obecne metody testowania przepracowanego oleju.
Źródło:
Diagnostyka; 2014, 15, 4; 65-71
1641-6414
2449-5220
Pojawia się w:
Diagnostyka
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ship as a source of the sea pollution with oil
Autorzy:
Stelmaszewski, A.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/247988.pdf
Data publikacji:
2012
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
maritime transport
seawater
petroleum
environmental protection
Gulf of Gdansk
Opis:
The subject of marine vessel as a source of the sea pollution was taken because of very adverse impact of petroleum pollutants on the natural environment. Oil pollutions concern especially marine environment. However, petroleum inflows to the sea from many different sources, exploitation of the fleet are one of the significant causes of oil presence in the marine environment. MARPOL Convention requires the states parties thereto to monitor the state of contamination [3] and this is a second reason of taking this subject. During the past years, several tests of petroleum content in the Gulf of Gdansk were made by the Physics Department of Gdynia Maritime University. In total 115 samples of water were collected and analyzed during the period from 2004 to 2009 year in the Gulf of Gdansk, which is an area of intense ships traffic because of two great complexes of harbours located in Gdansk and in Gdynia. These tests were carried out with the help of Institute of Oceanology Polish Academy of Sciences during cruises of the r.v. “Oceania”. Petroleum concentration in seawater was determined by means of improved fluorescence method. Oil in water concentration ranged from value below of the detection limit, that is 10–9 (less than 1 ppb), up to 3.5ź10–7 (350 ppb). Average concentration of oil was 4.3ź10–8 (43 ppb). Obtained results confirmed that Vistula River could be a source of petroleum pollution of the Gulf of Gdansk. Apart from this, vessels are the significant sources of oil in the seawater too. The most polluted places were founded in the area where ships crossed the Gulf of Gdansk.
Źródło:
Journal of KONES; 2012, 19, 1; 385-389
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Properties of the Baltic crude oil in the oil-in-water emulsion form : excitation-emission spectra
Autorzy:
Baszanowska, E.
Otremba, Z.
Powiązania:
https://bibliotekanauki.pl/articles/246400.pdf
Data publikacji:
2018
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
crude oil
excitation-emission spectra
fluorescence
seawater
ropa naftowa
fluorescencja
woda morska
Opis:
Due to the fact that marine environment contamination by oil substances are not uncommon, it is necessary to improve the ability of determine their origin. Therefore, research on the possibility of recognizing the type of oil using its individual characteristic manifested in the processes of fluorescence excitation has been undertaken. Oil pollutants present in seawater mainly coming from ship drives, tankers, pipelines or sea bottom seeps, moreover oil leaks from offshore extraction equipment also are possible. For this reason, the crude oil extracted from the Baltic Sea deposit in the Polish Maritime Areas has been chosen for tests. Fluorescence properties of water containing small amounts of oil (concentrations from 5.59 to 55.4 ppm) in the form of oil-in-water emulsion were tested. Individual samples were assigned matrices of fluorescent values for different wavelengths, while excited by monochromatic light also for different wavelengths. The obtained matrices were visualized as a contour maps and 3D charts. For considered concentrations of crude oil dispersed in water, the wavelength-independent fluorescence maximum was determined. Obtained result indicates that in the studied wavelength range, the total fluorescence intensity is proportional to the oil concentration only for the lowest oil concentrations. The analysis of the objective parameter of the difference between the shapes of spectra indicates the similarity of the spectral shape for the lowest oil concentrations. These results are the methodological suggestion, that for the purpose of identifying the type of oil dispersed in water, spectra should be determined for sequences of different dilutions, until the excitation-emission spectra shapes become independent from the oil concentration.
Źródło:
Journal of KONES; 2018, 25, 1; 7-14
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł

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