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    Wyświetlanie 1-11 z 11
    Tytuł:
    Comparative study of uni-univalent H⁺/Na⁺ and uni-bivalent H⁺/Ca²⁺ ion exchange reactions using nuclear grade resin Indion-223
    Autorzy:
    Singare, P. U.
    Mohammed, A. L. K.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/411747.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ion exchange reactions
    nuclear grade resins
    cation exchange resins
    enthalpy
    equilibrium constant
    Indion-223
    Opis:
    The present paper deals with the ion exchange equilibrium studies of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223 in H⁺ form towards Na⁺ and Ca²⁺ ions in the solution. It was observed that with rise in temperature the equilibrium constants K values for H⁺/Na⁺ uni-univalet ion exchange reaction increases from 0.01389 to 0.01855. Similarly for H⁺/Ca²⁺ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 38.92 kJ/ mol respectively.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 127-135
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Ion exchange equilibrium studies of uni-univalent H+/Na+ and uni-bivalent H+/Mg2+ ion exchange reactions using nuclear grade resin Indion-223
    Autorzy:
    Singare, P. U.
    Mohammed, A. L. K.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412153.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    cation exchange
    nuclear grade resins
    ion exchangers
    change in enthalpy
    equilibrium constant in standard state
    Indion-223
    Opis:
    In the present investigation the uni-univalent and uni-bivalent ion exchange reactions were studied using nuclear grade anion exchange resin Indion-223 in H+ form. It was observed that for H+/Na+ uni-univalet ion exchange reaction, with rise in temperature the equilibrium constants K values increases from 0.01389 to 0.01855. Similarly increase in K values was observed from 0.000177 to 0.000333 for H+/Mg2+ uni-bivalet ion exchange reaction. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 51.46 kJ/ mol respectively. It is expected that the present study will provide valuable information in order to decide about the selection of those resins for efficient separation of various ionic species present in the industrial waste water effluents.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 199-207
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on preferential selectivity of nuclear grade resin Indion-223 towards some bivalent ions
    Autorzy:
    Singare, P. U.
    Mohammed, A. L. K.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412085.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    bivalent exchange reactions
    nuclear grade resins
    cation exchange
    reaction thermodynamics
    enthalpy change
    ionic selectivity
    equilibrium constant
    Indion-223
    Opis:
    In the present paper attempts are made to understand the selectivity of nuclear grade cation exchange resin Indion-223 in H+ form towards Ca2+ and Mg2+ bivalent ions in the solution based on thermodynamic concept. It was observed that with rise in temperature the equilibrium constant K values for H+/Ca2+ uni-bivalet ion exchange reactions increases from 0.000397 to 0.000639. Similarly for H+/Mg2+ uni-bivalet ion exchange reactions the equilibrium constant K values increases from 0.000177 to 0.000333. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 38.92 and 51.46 kJ/ mol respectively. The difference in K values and enthalpy values were used to predict the selectivity behaviour of the resin towards the Ca2+ and Mg2+ bivalent ions in the solution. The thermodynamic concept of the present study can be applied to understand the selectivity behaviour of different nuclear as well as non-nuclear grade resins towards wide range of ionic species present in the exchanging liquid medium.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 15; 11-21
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Thermodynamics of uni-univalent H+/K+ and uni-bivalent H+/Ca2+ ion exchange reactions using nuclear grade resin Indion-223
    Autorzy:
    Singare, P. U.
    Mohammed, A. L. K.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412388.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ion exchange
    nuclear grade resins
    cation exchangers
    enthalpy change
    standard equilibrium constant
    Indion-223
    Opis:
    The present paper deals with the thermodynamic of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223. It was observed that with rise in temperature the equilibrium constants K values for H+/K+ uni-univalet ion exchange reaction increases from 0.01710 to 0.02374. Similarly for H+/Ca2+ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in K values with rise in temperature for both the reactions indicates its endothermic nature having the enthalpy change values of 22.72 and 38.92 kJ/ mol respectively. The technique used here can be extended further to standardise the process parameters in order to bring about the efficient separation of the desired ionic species from the solution.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 190-198
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Thermodynamic study to evaluate the selectivity behaviour of nuclear grade resin Indion-223 towards some univalent ions
    Autorzy:
    Singare, P. U.
    Mohammed, A. L. K.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/412486.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    uni-univalent ion exchange reactions
    ionic selectivity
    nuclear grade resins
    cation exchangers
    enthalpy change
    equilibrium constant
    Indion-223
    Opis:
    The present paper deals with the application of thermodynamic concept in understanding the preferential selectivity of nuclear grade anion exchange resin Indion-223 in H+ form towards Na+ and K+ ions in the solution. In the study it was observed that the equilibrium constants K values for H+/Na+ and H+/K+ uni-univalet ion exchange reactions increases from 0.01389 to 0.01855 and from 0.01710 to 0.02374 respectively as the temperature increases from 35.0 °C to 45.0 °C. The increase in K values with rise in temperature suggests endothermic ion exchange reactions having the enthalpy change values of 25.55 and 22.72 kJ/ mol respectively. Based on difference in K values and enthalpy values for the two uni-univalent ion exchange reactions, the preferential selectivity of the resin for the univalent ions in the solution was predicted. From the results of present study, it appears that the experimental technique used here can be applied further to understand the ionic selectivity of different industrial grade ion exchange resins. It is expected that such studies will provide valuable information in order to decide about the selection of those resins for efficient separation of various ionic species present in the industrial waste water effluents.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 15; 22-29
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study of uni-univalent H+/K+ and uni-bivalent H+/Mg2+ ion exchange reactions using nuclear grade resin Indion-223
    Autorzy:
    Singare, P. U.
    Mohammed, A. K. L.
    Dixit, N. N.
    Powiązania:
    https://bibliotekanauki.pl/articles/411848.pdf
    Data publikacji:
    2014
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    ion exchange equilibrium
    nuclear grade resins
    cation exchange
    enthalpy change
    equilibrium constant
    Indion-223
    Opis:
    In the present paper the uni-univalent and uni-bivalent ion exchange reactions were investigated using nuclear grade anion exchange resin Indion-223 in H+ form. For both H+/K+ uni-univalet ion exchange reactions and H+/Mg2+ uni-bivalet ion exchange reactions, the equilibrium constant K values increases from 0.01710 to 0.02374 and from 0.000177 to 0.000333 respectively as the reaction temperature rises from 35.0 °C to 45.0 °C. The increase in K values with temperature suggest endothermic ion exchange reactions having the enthalpy change values of 22.72 and 51.46 kJ/ mol respectively. The results of such studies will help in selection of suitable ion exchange resins in order to bring about efficient separation of different ionic species present in the waste water effluents released from nuclear as well as chemical process industries.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 231-239
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Human tissue investigations using PALS technique - free radicals influence
    Autorzy:
    Jasińska, B.
    Zgardzińska, B.
    Chołubek, G.
    Pietrow, M.
    Gorgol, M.
    Wiktor, K.
    Wysogląd, K.
    Białas, P.
    Curceanu, C.
    Czerwiński, E.
    Dulski, K.
    Gajos, A.
    Głowacz, B.
    Hiesmayr, B.
    Jodłowska-Jędrych, B.
    Kamińska, D.
    Korcyl, G.
    Kowalski, P.
    Kozik, T.
    Krawczyk, N.
    Krzemień, W.
    Kubicz, E.
    Mohammed, Muhsin
    Pawlik-Niedźwiecka, M.
    Niedźwiecki, S.
    Pałka, M.
    Raczyński, L.
    Rudy, Z.
    Sharma, N.
    Sharma, S.
    Shopa, R.
    Silarski, M.
    Skurzok, M.
    Wieczorek, A.
    Wiktor, H.
    Wiślicki, W.
    Zieliński, M.
    Moskal, P.
    Powiązania:
    https://bibliotekanauki.pl/articles/1057941.pdf
    Data publikacji:
    2017-11
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    positron annihilation
    positronium
    free radicals
    tissues
    uterine leiomyomas
    Opis:
    The positron annihilation lifetime spectroscopy was applied to the samples of the human uterine leiomyomas and the normal myometrium tissues taken from the selected place of the uterus during a surgery. The method indicated differences in values of the measured positron annihilation lifetime spectroscopy parameters (lifetimes and intensities) between healthy and diseased tissue samples. The additional measurements were performed either in darkness or in presence of visible light which influenced the free radicals present in both kind of tissues and, as a result, made changes in free annihilation and o-Ps decay lifetime and intensity values.
    Źródło:
    Acta Physica Polonica A; 2017, 132, 5; 1556-1558
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    A Method to Produce Linearly Polarized Positrons and Positronium Atoms with the J-PET Detector
    Autorzy:
    Mohammed, Muhsin
    Białas, P.
    Curceanu, C.
    Czerwiński, E.
    Dulski, K.
    Gajos, A.
    Głowacz, B.
    Gorgol, M.
    Hiesmayr, B.
    Jasińska, B.
    Kisielewska, D.
    Korcyl, G.
    Kowalski, P.
    Kozik, T.
    Krawczyk, N.
    Krzemień, W.
    Kubicz, E.
    Pawlik-Niedźwiecka, M.
    Niedźwiecki, S.
    Pałka, M.
    Raczyński, L.
    Raj, J.
    Rudy, Z.
    Sharma, N.
    Sharma, S.
    Shivani, ---
    Skurzok, M.
    Silarski, M.
    Wieczorek, A.
    Wiślicki, W.
    Zgardzińska, B.
    Zieliński, M.
    Moskal, P.
    Powiązania:
    https://bibliotekanauki.pl/articles/1030045.pdf
    Data publikacji:
    2017-11
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    41.75.Fr
    41.75.Ht
    77.22.Ej
    36.10.Dr
    85.75.Mm
    87.57.uk
    Opis:
    A method for creating linearly polarized positrons and ortho-positronium (o-Ps) atoms with the J-PET detector is presented. The unique geometry and properties of the J-PET tomography enable one to design a positron source such that the quantization axis for the estimation of the linear polarization of produced o-Ps can be determined on the event by event basis in a direction of the positron motion. We intend to use ²²Na or other β⁺ decay isotopes as a source of polarized positrons. Due to the parity violation in the beta decay, the emitted positrons are longitudinally polarized. The choice of the quantization axis is based on the known position of the positron emitter and the reconstructed position of the positronium annihilation. We show that the J-PET tomography is equipped with all needed components.
    Źródło:
    Acta Physica Polonica A; 2017, 132, 5; 1486-1489
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Preliminary studies of J-PET detector spatial resolution
    Autorzy:
    Pawlik-Niedźwiecka, M.
    Niedźwiecki, S.
    Alfs, D.
    Białas, P.
    Curceanu, C.
    Czerwiński, E.
    Dulski, K.
    Gajos, A.
    Głowacz, B.
    Gorgol, M.
    Hiesmayr, B.
    Jasińska, B.
    Kisielewska, D.
    Korcyl, G.
    Kowalski, P.
    Kozik, T.
    Krawczyk, N.
    Krzemień, W.
    Kubicz, E.
    Mohammed, M.
    Pałka, M.
    Raczyński, L.
    Raj, J.
    Rudy, Z.
    Shivani, -
    Silarski, M.
    Skurzok, M.
    Sharma, N.
    Sharma, S.
    Shopa, R.
    Strzelecki, A.
    Wieczorek, A.
    Wiślicki, W.
    Zgardzińska, B.
    Zieliński, M.
    Moskal, P.
    Powiązania:
    https://bibliotekanauki.pl/articles/1057928.pdf
    Data publikacji:
    2017-11
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    29.40.Mc
    87.57.uk
    87.10.Rt
    34.50.-s
    Opis:
    The J-PET detector, based on long plastic scintillator strips, was recently constructed at the Jagiellonian University. It consists of 192 modules axially arranged into three layers, read out from both sides by digital constant-threshold front-end electronics. This work presents preliminary results of measurements of the spatial resolution of the J-PET tomograph performed with ²²Na source placed at selected position inside the detector chamber.
    Źródło:
    Acta Physica Polonica A; 2017, 132, 5; 1645-1648
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Analysis Procedure of the Positronium Lifetime Spectra for the J-PET Detector
    Autorzy:
    Dulski, K.
    Zgardzińska, B.
    Białas, P.
    Curceanu, C.
    Czerwiński, E.
    Gajos, A.
    Głowacz, B.
    Gorgol, M.
    Hiesmayr, B.
    Jasińska, B.
    Kisielewska-Kamińska, D.
    Korcyl, G.
    Kowalski, P.
    Kozik, T.
    Krawczyk, N.
    Krzemień, W.
    Kubicz, E.
    Mohammed, Muhsin
    Pawlik-Niedźwiecka, M.
    Niedźwiecki, S.
    Pałka, M.
    Raczyński, L.
    Raj, J.
    Rudy, Z.
    Sharma, N.
    Sharma, S.
    Shivani, Shivani
    Shopa, R.
    Silarski, M.
    Skurzok, M.
    Wieczorek, A.
    Wiślicki, W.
    Zieliński, M.
    Moskal, P.
    Powiązania:
    https://bibliotekanauki.pl/articles/1033298.pdf
    Data publikacji:
    2017-11
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    07.05.Kf
    13.30.Ce
    14.60.-z
    78.47.-p
    Opis:
    Positron annihilation lifetime spectroscopy has shown to be a powerful tool to study the nanostructures of porous materials. Positron emission tomograph is a device allowing imaging of metabolic processes e.g. in human bodies. A newly developed device, the Jagiellonian PET will allow positron annihilation lifetime spectroscopy in addition to imaging, thus combining both analyses providing new methods for physics and medicine. In this contribution we present a computer program that is compatible with the Jagiellonian PET software. We compare its performance with the standard program LT 9.0 by using positron annihilation lifetime spectroscopy data from hexane measurements at different temperatures. Our program is based on an iterative procedure, and our fits prove that it performs as good as LT 9.0.
    Źródło:
    Acta Physica Polonica A; 2017, 132, 5; 1637-1640
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Time Calibration of the J-PET Detector
    Autorzy:
    Skurzok, M.
    Silarski, M.
    Alfs, D.
    Białas, P.
    Shivani, S.
    Curceanu, C.
    Czerwiński, E.
    Dulski, K.
    Gajos, A.
    Głowacz, B.
    Gorgol, M.
    Hiesmayr, B.
    Jasińska, B.
    Kisielewska-Kamińska, D.
    Korcyl, G.
    Kowalski, P.
    Kozik, T.
    Krawczyk, N.
    Krzemień, W.
    Kubicz, E.
    Mohammed, Muhsin
    Pawlik-Niedźwiecka, M.
    Niedźwiecki, S.
    Pałka, M.
    Raczyński, L.
    Raj, J.
    Rudy, Z.
    Sharma, N.
    Sharma, S.
    Shopa, R.
    Wieczorek, A.
    Wiślicki, W.
    Zgardzińska, B.
    Zieliński, M.
    Moskal, P.
    Powiązania:
    https://bibliotekanauki.pl/articles/1033283.pdf
    Data publikacji:
    2017-11
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    06.20.fb
    36.10.Dr
    11.30.Er
    24.80.+y
    Opis:
    The Jagiellonian positron emission tomograph project carried out in the Institute of Physics of the Jagiellonian University is focused on construction and tests of the first prototype of PET scanner for medical diagnostic which allows for the simultaneous 3D imaging of the whole human body using organic scintillators. The J-PET prototype consists of 192 scintillator strips forming three cylindrical layers which are optimized for the detection of photons from the electron-positron annihilation with high time-and high angular resolutions. In this article we present time calibration and synchronization of the whole J-PET detection system by irradiating each single detection module with a ²²Na source and a small detector providing common reference time for synchronization of all the modules.
    Źródło:
    Acta Physica Polonica A; 2017, 132, 5; 1641-1644
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-11 z 11

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