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Tytuł:
Cloud Cooperated Heterogeneous Cellular Networks for Delayed Offloading using Millimeter Wave Gates
Autorzy:
Mohamed, E. M.
Powiązania:
https://bibliotekanauki.pl/articles/227204.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
millimeter wave
delayed offloading
CC-HetNet
ANDSF
C/U splitting
Opis:
Increasing the capacity of wireless cellular network is one of the major challenges for the coming years. A lot of research works have been done to exploit the ultra-wide band of millimeter wave (mmWave) and integrate it into future cellular networks. In this paper, to efficiently utilize the mmWave band while reducing the total deployment cost, we propose to deploy the mmWave access in the form of ultra-high capacity mmWave gates distributed in the coverage area of the macro basestation (Macro BS). Delayed offloading is also proposed to proficiently exploit the gates and relax the demand of deploying a large number of them. Furthermore, a mobility-aware weighted proportional fair (WPF) user scheduling is proposed to maximize the intra-gate offloading efficiency while maintaining the longterm offloading fairness among the users inside the gate. To efficiently link the mmWave gates with the Macro BS in a unified cellular network structure, a cloud cooperated heterogeneous cellular network (CC-HetNet) is proposed. In which, the gates and the Macro BS are linked to the centralized radio access network (C-RAN) via high-speed backhaul links. Using the concept of control/user (C/U) plane splitting, signaling information is sent to the UEs through the wide coverage Macro BS, and most of users’ delayed traffic is offloaded through the ultra-high capacity mmWave gates. An enhanced access network discovery and selection function (eANDSF) based on a network wide proportional fair criterion is proposed to discover and select an optimal mmWave gate to associate a user with delayed traffic. It is interesting to find out that a mmWave gate consisting of only 4 mmWave access points (APs) can offload up to 70 GB of delayed traffic within 25 sec, which reduces the energy consumption of a user equipment (UE) by 99.6 % compared to the case of only using Macro BS without gate offloading. Also, more than a double increase in total gates offloaded bytes is obtained using the proposed eANDSF over using the conventional ANDSF proposed by 3GPP due to the optimality in selecting the associating gate.
Źródło:
International Journal of Electronics and Telecommunications; 2017, 63, 1; 51-64
2300-1933
Pojawia się w:
International Journal of Electronics and Telecommunications
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Minerals content, essential oils composition and physicochemical properties of Citrus jambhiri Lush. (Rough Lemon) from the Sudan
Autorzy:
Mohammed, A. M. H.
Ibrahim, M. A
Omran, A. A.
Mohamed, E. M.
Elsheikh, S. E. M.
Powiązania:
https://bibliotekanauki.pl/articles/412508.pdf
Data publikacji:
2013
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Citrus jambhiri
Rutaceae
atomic absorption spectroscopy (AAS)
Flame Atomic Emission Spectroscopy (FAES)
metal content
essential oils
Opis:
Minerals content of Citrus jambhiri (rough lemon) fruit was qualitatively and quantitatively analyzed using atomic absorption spectroscopy (AAS) and flame atomic emission spectrometry (FAES). The peel, moisture and ash contents of rough lemon were found to be 18.35 %, 23.75 % and 2.04 % respectively. Vitamin C (ascorbic acid) of rough lemon juice was found to be 70.0 mg/100 g. The chemical composition of essential oil of rough lemon peel was determined. The major compound was found to be limonene (84.5 %) followed by sabinene, β-myrcene, α-terpineol, 1,3-tetradecadiene and linalool.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2013, 9, 1; 25-30
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Theoretical Inversion of Amino Acids (Alanine and Aspartic Acid) by Semi-empirical Methods
Autorzy:
Mohamed, M. E.
Powiązania:
https://bibliotekanauki.pl/articles/412336.pdf
Data publikacji:
2013
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
inversion
alanine
aspartic
semi-empirical methods
AM1
Opis:
The inversion reaction coordinate of free amino acids (alanine, aspartic acid) have been computationally calculated by semi-empirical methods AM1. A transition state for free alanine and aspartic acid were obtained as a three membered ring in which the α-C-H and α-C-CH3 are slightly elongated, 1.2 and 2.17 Å respectively in the alanine transition state. The activation energy of alanine is 77.52 kcal/mol in the gas phase and 76.66 kcal/mol in aqueous phase, and for aspartic acid is 54.87 kcal/mol in the gas phase and 50.86 kcal/mol in aqueous phase.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2013, 7, 1; 37-44
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Spectroscopic Characterization of l-aspartic Acid Complexes with Metals of the Lanthanides Family
Autorzy:
Mohamed, M. E.
Powiązania:
https://bibliotekanauki.pl/articles/412075.pdf
Data publikacji:
2013
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
L-aspartic acid
Lanthanides (III) complexes
IR and NMR
Opis:
The complexes between l-aspartic acid and metals of lanthanide series (La3+, Pr3+, Eu3+, Gd3+) have been prepared and characterized using a variety of techniques including, infrared spectroscopy, 1H NMR, 13C NMR, elemental analysis and metal contents. The sought metal effect on the electronic environment of the chiral carbon and its neighbouring atoms was observed in case of Europium and Praseodymium. The 13C downfield shift indicates a lower electron density at the carbon with consequent downfield shift observed on the ?-H attached to it increasing its acidity.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2013, 6; 91-115
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Experimental and Computational Vibration Study of Amino Acids
Autorzy:
Mohammed, M. E.
Mohamed, A. M. A.
Powiązania:
https://bibliotekanauki.pl/articles/412478.pdf
Data publikacji:
2013
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Vibrational studies
Amino Acids
semi-empirical methods (PM6 and RM1)
ab initio methods (B3LYP/6-31+G(d)
Opis:
Vibrational studies of amino acids experimentally and theoretically have been performed. The Semi-empirical methods optimization by PM6 and RM1 on the l- and d-amino acids (alanine, phenylalanine, aspartic and glutamic acid), showed no difference in energy between l-and d-isomers. The vibrational frequencies were calculated by semi-emprical methods (PM6 and RM1) and ab initio methods (B3LYP/6-31+G(d) and were scaled down by factors of 0.925 (RM1), 1.09 (PM6) and 0.89 (B3LYP/6-31+G(d)). The calculated and experimental vibrational frequencies have shown good general agreement.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2013, 10, 1; 1-17
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cotton leaf blight disease caused by Alternaria alternata in Sudan
Autorzy:
Mohamed, O.E.
Beshir, M.M.
Ahmed, N.E.
Powiązania:
https://bibliotekanauki.pl/articles/2084617.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Alternaria alternata
conidia
Gossypium spp.
internal transcribed spacer
(ITS)
morphological variability
pathogenicity
Opis:
Genetically modified Bt cotton (Gossypium hirsutum) leaves with typical symptoms of Alternaria early blight disease resembling that of tomato and potato were observed in the main cotton growing schemes in Sudan. Symptoms on leaves appeared as either brown 2leaf spot with gray centers or leaf blight with concentric rings. Pathogenicity tests using isolates with both symptoms showed that the isolated fungi were highly pathogenic to both G. hirsutum and G. barbadense cotton varieties. Alternaria alternata isolated from infected tomato and potato leaves with early blight symptoms was included for comparison. Microscopic examination showed that the mean length of conidia from cotton, tomato and potato isolates ranged from 26.25 to 45.45 µm, while the width ranged from 9.56 to 13.64 µm. The mean number of transverse septa among all isolates was 3.4 to 5.7 and the peak length ranged from 3.75 to 7.8 µm. Based on morphological characteristics the two isolates from cotton were identified as A. alternata. Genomic DNA was extracted directly from fungal cultures grown on potato dextrose agar (PDA) plates using a Zymo Research Quick DNA kit. A species-specific primer using the internal transcribed spacer ribosomal DNA (ITS rDNA) PCR scoring indicated the presence of A. alternata using primer pair ITS4/ITS5. Amplifications of the internal transcribed spacer region of 600 bp revealed 100% identity of the isolated fungus from cotton with A. alternata from tomato and potato. These data oblige us to reconsider the presence of A. alternata in the four main cotton growing schemes in Sudan while these symptoms have always been described for tomato and potato early blight disease.
Źródło:
Journal of Plant Protection Research; 2019, 59, 3; 412-417
1427-4345
Pojawia się w:
Journal of Plant Protection Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Proton conductivity and free volume properties in per-fluorinated sulfonic acid/PTFE copolymer for fuel cell
Autorzy:
Mohamed, H.
Abdel-Hady, E.
Abdel-Hamed, M.
Powiązania:
https://bibliotekanauki.pl/articles/1057956.pdf
Data publikacji:
2017-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.70.Bj
82.47.Nj
72.80.Le
36.10.Dr
88.30.J-
88.30.pf
Opis:
The proton conductivity mechanism in per-fluorinated sulfonic acid/PTFE copolymer Fumapem® membranes for polymer electrolyte membranes has been investigated. Three samples of Fumapem® F-950, F-1050 and F-14100 membranes with different ion exchange capacity 1.05, 0.95, and 0.71 meq/g, respectively, were used in this study after drying. The o-Ps hole volume size (V_{FV,Ps}) was quantified using the positron annihilation lifetime technique while the proton conductivities (σ ) were measured using LCR Bridge as function of temperature. It was found that as the ion exchange capacity increases, the proton conductivity increases and the free volume expands. Temperature dependences of proton conductivity and the o-Ps hole volume size (V_{FV,Ps}) reflect the glass transition temperature of the membrane. A good linear correlation between the reciprocal of the o-Ps hole volume size (1/V_{FV,Ps}) and log(σ)+Δ E_a/2.303k_{B}T, (where ΔE_a is the activation energy, T is the absolute temperature and k_{B} is the Boltzmann constant) at different temperatures indicate that the ionic motion in dry Fumapem® is governed by the free volume. A linear relationship between the critical hole size γ V*_{i} and the ion exchange capacity was also achieved.
Źródło:
Acta Physica Polonica A; 2017, 132, 5; 1509-1514
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructure characterization of Nafion® HP JP as a proton exchange membrane for fuel cell: Positron annihilation study
Autorzy:
Mohamed, Hamdy
Abdel-Hady, E.
Abdel-Hamed, M.
Said, M.
Powiązania:
https://bibliotekanauki.pl/articles/1057926.pdf
Data publikacji:
2017-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.70.Bj
82.47.Nj
72.80.Le
36.10.Dr
88.30.J-
88.30.pf
Opis:
Free volume size V_{f} and proton conductivity σ of a novel polymer electrolyte membrane were investigated as a function of temperature and relative humidity up to 140°C and 80%, respectively. The free volume size V_{f} for Nafion® HP JP reflect the α-transition temperature at about 98°C. In addition the free volume size V_{f} for Nafion® HP JP is smaller than that for Nafion® NRE212 membrane which leads to lower methanol permeability of the former membrane. The proton conductivity σ for Nafion® HP JP decreases with increase of temperature up to transition temperature due to free and bound water loss, then it starts to increase due to dynamic segmental motion. It increases for Nafion® HP JP with the increase of the relative humidity. A good correlation between V_{f} and σ was successfully established for both membranes which indicates that σ is governed by the free volume. In conclusion, Nafion® HP JP is a suitable membrane for a proton exchange membrane fuel cell application.
Źródło:
Acta Physica Polonica A; 2017, 132, 5; 1543-1547
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Properties of~Rf Plasma Nitrided Silicon Thin Films at Different Rf Plasma Processing Powers
Autorzy:
Mohamed, S.
Raaif, M.
Abd El-Rahman, A.
Shaaban, E.
Powiązania:
https://bibliotekanauki.pl/articles/1493713.pdf
Data publikacji:
2011-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.15.Dj
61.05.cp
73.61.-r
78.66.-w
Opis:
Nitrided surfaces and composition gradients in thin films exhibit interesting mechanical, electrical and optical properties. Therefore, silicon (Si) thin films were prepared by electron beam evaporation and nitrided by an inductively coupled rf plasma. The effects of successive plasma processing power on structural and optical properties as well as electrical resistivity were examined by different characterization techniques. The Si thin films were transformed gradually into nitrides compound thin films and the amount of nitrogen in the film increased with increasing the rf processing power. The Si nitrided films showed structural, optical and electrical properties that depend on the nitriding power. Increasing the rf plasma processing power caused amorphization, reduced the thickness, increased transmittance, increased resistivity and decreased the reflectance of the Si films. The electrical resistivity increased about eight orders of magnitude when the sample nitrided at 500 W. Different optical band gap were determined indicating the presence of different competing phases in the same film. The decrease in refractive index with plasma treatment power is attributed to the possible change in the bucking density as well as to the increase in the band gap.
Źródło:
Acta Physica Polonica A; 2011, 120, 3; 552-557
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sintering of Egyptian iron ore
Efektywność procesu rozdziału w osadzarce
Autorzy:
Fouzi, S.M.
Kahlifa, M.G.
Ahmed, Y.M.Z.
Mohamed, F.M.
Shalabi, M.E.H.
Powiązania:
https://bibliotekanauki.pl/articles/350128.pdf
Data publikacji:
2006
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
egipskie rudy żelaza
spiekanie
Egyptian iron ores
sintering
Opis:
There are many parameters affecting of the sintering process such as: amount of water added, basicity of sinter, amount of sinter return, amount of coke breeze, any addition of iron bearing material (mill scale) and time of ignition. Thus the aim of this work is devoted to study the optimum condition for sintering process of the Egyptian iron ore.
Istnieje wiele parametrów mających wpływ na proces spiekania: ilość dodanej do procesu wody, odczyn pH spieku, ilość pyłu koksowego, każdy dodatek stopu żelaza oraz czas zapłonu. Celem pracy jest określenie optymalnych warunków dla procesów spiekania rud żelaza w Egipcie.
Źródło:
Górnictwo i Geoinżynieria; 2006, 30, 3/1; 91-107
1732-6702
Pojawia się w:
Górnictwo i Geoinżynieria
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Free Volume of PVA/SSA Proton Exchange Membrane Studied by Positron Annihilation Lifetime Spectroscopy
Autorzy:
Gomaa, M.
Hugenschmidt, C.
Dickmann, M.
Abdel-Hamed, M.
Abdel-Hady, E.
Mohamed, H.
Powiązania:
https://bibliotekanauki.pl/articles/1033241.pdf
Data publikacji:
2017-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.47.Gh
78.70.Bj
Opis:
Humidity control and water management in polymer electrolyte membranes for fuel cells are still of high importance to improve the fuel cells' efficiencies. In this study, poly (vinyl alcohol) (PVA)was crosslinked using 15 wt% sulfosuccinic acid (SSA) by a solution casting method and additionally thermally crosslinked at 100°C. Positron annihilation lifetime spectroscopy was used to study the mean free volume size and the distribution at different humidity. A slight decrease in the free volume was found up to a relative humidity of 30% whereas it increases strongly for a relative humidity of more than 30%. The volume of the voids duplicates from 0.036 to 0.078 nm³ by changing the relative humidity from 30 to 80%. Thermogravimetric analyzer was used to determine the thermal stability of the membrane. From thermogravimetric analyzer data, it was found that the PVA with 15 wt% SSA membrane are chemically stable up to 200°C.
Źródło:
Acta Physica Polonica A; 2017, 132, 5; 1519-1522
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The isotherm and kinetic studies of the biosorption of heavy metals by non-living cells of Chlorella vulgaris
Autorzy:
Ali, Mohamed H.
Hussian, Abd-Ellatif M.
Abdel-Satar, Amaal M.
Goher, Mohamed E.
Napiórkowska-Krzebietke, Agnieszka
El-Monem, Ahmed M. Abd
Powiązania:
https://bibliotekanauki.pl/articles/962750.pdf
Data publikacji:
2016
Wydawca:
Uniwersytet Warmińsko-Mazurski w Olsztynie / Polskie Towarzystwo Magnezologiczne im. Prof. Juliana Aleksandrowicza
Opis:
In general, the biosorption of heavy metals by various types of non-living organisms appears to be a very effective, low-cost and innovative method for their removal from aquatic environments. The aim of this study was to determine the applicability of adsorption isotherms and kinetic models during the biosorbent activity of non-living Chlorella to the removal of Cd, Cu and Pb. Dead cells of Chlorella vulgaris were used to remove these heavy metals from aqueous solution in experimental conditions, i.e. under various condition of pH, biosorbent dosage and contact time. Afterwards, the Langmuir and Freundlich adsorption isotherm models and the sorption kinetic (pseudo-first and pseudo-second order models, and intraparticle diffusion) were applied to the experimental data to check the effectiveness of the removal process. The removal of heavy metals on C. vulgaris following the order of Pb+2 > Cu+2 > Cd+2 was confirmed by the maximum biosorption capacities (qmax), the Langmuir constant (b), separation factor (RL) and Freundlich intensity parameter (1/n) values. The equilibrium data were well fitted with the Langmuir and Freundlich isotherm models. The adsorption process followed the pseudo-second-order model and it suggested that such kinetics is the most effective. The present results confirmed highly efficient biosorbent activity of C. vulgaris in the removal of heavy metals, especially Cd, Cu and Pb, from aqueous solution. The environmentally friendly origin indicates that non-living cells of C. vulgaris could find many broad-scale, cost-effective and alternative applications.
Źródło:
Journal of Elementology; 2016, 21, 4
1644-2296
Pojawia się w:
Journal of Elementology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Potential toxicity assessment of novel selected pesticides against sand termite, Psammotermes hypostoma Desneux workers (Isoptera: Rhinotermitidae) under field conditions in Egypt
Autorzy:
Ahmed, M.A.I.
Eraky, E.-S.A.
Mohamed, M.F.
Soliman, A.-A.S.
Powiązania:
https://bibliotekanauki.pl/articles/66459.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Opis:
The sand termite, Psammotermes hypostoma Desneux is a major pest in the New Valley Governorate, Egypt. Great efforts have been taken to control the pest. We evaluated the toxicity of four selected neonicotinoids [acetamiprid (20% SP), imidacloprid (20% SL), thiamethoxam (18.6% SC), and thiamethoxam (40% WG)], and one organophosphate pesticide [chlorpyrifos (48% EC)] against P. hypostoma workers. The investigation was done under field conditions, using the palm fronds method. However, the reduction percentages in palm fronds was recorded as the height of the sandy clay formed by termite workers on palm frond surfaces, when the fronds had been treated with a different concentration of each pesticide. The results were recorded after 15, 30, 45, and 60 days. Chlorpyrifos (48% EC) was considered the most potent pesticide among all the pesticides tested, but acetamiprid (20% SP) was considered the most toxic among the neonicotinoid pesticides tested. Moreover, the formulation of thiamethoxam (18.6% SC) was more powerful than thaimethoxam (40% WG). Furthermore, the reduction percentages on palm fronds increased significantly with an increase of the exposure period (from 15 to 60 days), as a result of the surface foraging activity of the sand termite workers. These results are given as unique and encouraging trends in controlling sand termites in Egypt.
Źródło:
Journal of Plant Protection Research; 2015, 55, 2
1427-4345
Pojawia się w:
Journal of Plant Protection Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Field and modelling study for deficit irrigation strategy on roots volume and water productivity of wheat
Autorzy:
Abdelraouf, Ramadan E.
El-Shawadfy, Mohamed A.
Dewedar, Osama M.
Hozayn, Mahmoud
Powiązania:
https://bibliotekanauki.pl/articles/1844310.pdf
Data publikacji:
2021
Wydawca:
Instytut Technologiczno-Przyrodniczy
Tematy:
irrigation
roots volume
SALTMED model
soil moisture
water productivity
wheat
Opis:
In many regions of the world, including Egypt, water shortages threaten food production. An irrigation deficient strategy in dry areas has been widely investigated as a valuable and sustainable approach to production. In this study, the dry matter and grain yield of wheat was decreased by reducing the amount of irrigation water as well as the volume of the root system. As a result of this, there was an increase the soil moisture stress. This negatively affected the absorption of water and nutrients in the root zone of wheat plants, which ultimately had an effect on the dry matter and grain yield of wheat. The values of dry matter and grain yield of wheat increased with the ʻSakha 94ʼ variety compared to the ʻSakha 93ʼ class. It is possible that this was due to the increase in the genetic characteristic of the root size with the ʻSakha 94ʼ variety compared to the ʻSakha 93ʼ class, as this increase led to the absorption of water and nutrients from a larger volume of root spread. Despite being able to increase the water productivity of wheat by decreasing the amount of added irrigation water, the two highest grain yield values were achieved when adding 100% and 80% of irrigation requirements (IR) needed to irrigate the wheat and no significant differences between the yield values at 100% and 80% of IR were found. Therefore, in accordance with this study, the recommended irrigation for wheat is at 80% IR which will provide 20% IR. When comparing the water productivity of two wheat varieties in study, it becomes clear that ʻSakha 94ʼ was superior to ʻSakha 93ʼ when adding the same amount of irrigation water, and this resulted in increased wheat productivity for ʻSakha 94ʼ. The SALTMED results confirmed good accuracy (R2: 0.92 to 0.98) in simulating soil moisture, roots volume, water application efficiency, dry matter, and grain yield for two varieties of wheat under deficit irrigation conditions. Whilst using sprinkler irrigation system under sandy soils in Egypt.
Źródło:
Journal of Water and Land Development; 2021, 49; 129-138
1429-7426
2083-4535
Pojawia się w:
Journal of Water and Land Development
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Inhibition of Brass Corrosion in Acid Medium Using Thiazoles
Autorzy:
Taha, K. K.
Mohamed, M. E.
Khalil, S. A.
Talab, S. A.
Powiązania:
https://bibliotekanauki.pl/articles/411634.pdf
Data publikacji:
2013
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Benzothiazoles
Brass Corrosion Inhibitors
Perchloric Acid
Opis:
Brass as an alloy composed mainly of copper is great industrial uses such as heat exchangers and similar other facility due to its good thermal properties. Due to the presence of the considerable ratio of zinc the alloy suffers from zinc dissolution or dezincification. Dezincification rate increases with the increase in the ratio of zinc in the alloy. In this study benzothiazole (BTH) and its substituent’s 2-methylbenzothiazole (MeBTH), 2-aminobenzothiazole (ABTH), 2-mercaptobenzothiazole (MBTH) and 2-phenylbenzothiazole (PhBTH) have been used as corrosion inhibitors for α-brass in stirred 0.1 M HClO4. The methods of investigation include weight loss, Tafel and linear polarizations and electrochemical impedance spectroscopy. The order of inhibition efficiency (% E) was calculated and the values obtained has indicated the sequence of inhibition efficiency was found to be BTH < MeBTH < ABTH < PhBTH < MBTH. The calculated values of thermodynamic parameters support this order. The inhibitors were found to suppress the corrosion rate by the formation of films which were identified by IR, SEM and EDAX techniques.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2013, 9, 2; 87-102
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
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