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Wyszukujesz frazę "Mandal, S.K." wg kryterium: Autor


Wyświetlanie 1-6 z 6
Tytuł:
Historical occurrences of marine microalgal blooms in Indian Peninsula: Probable causes and implications
Autorzy:
Oyeku, O.G.
Mandal, S.K.
Powiązania:
https://bibliotekanauki.pl/articles/2079002.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
marine environment
algal bloom
microalga
sea surface
water temperature
Indian Peninsula
Opis:
The Indian marine environment supports employment for over 200 million people, including revenue of nearly $7 billion per annum. However, ecological goods and services of the shallow coast and the marine environment of the Indian peninsula are being affected by recurrent blooms of microalgae. One hundred and six published literature, starting from the first report in 1908 to 2017, were reviewed to investigate the historical occurrences of marine microalgal blooms (MMBs) around the Indian peninsula. 154 MMBs comprising 24 genera and 7 classes were reported during the study period. Noctiluca (dinophyceae) and Trichodesmium (cyanophyceae) bloom contributed 34.4% and 31.8% of total blooms. PCA revealed that high sea surface temperature (SST) and salinity were significant driving forces for Trichodesmium blooms formation, while high nutrients (NO3-N, PO4-P, and SiO4-Si) and low salinity triggered prymnesiophyceae, raphidophyceae, bacillariophyceae and most of the dinophyceae blooms. Noctiluca blooms were linked with both eutrophication and the abundance of prey organisms. HABs were generally dinophyceae dominated and were associated with mass mortality of aquatic fauna, human intoxication, paralytic, and ciguatera shellfish poisoning and even death. Increasing SST and anthropogenic influences around the Indian peninsula could increase the occurrences of MMBs (including HABs) and the number of causative taxa. Proper safety measures such as routine monitoring of phycotoxin levels in the environment and local seafood are required to be put in place in other to protect the health of the public.
Źródło:
Oceanologia; 2021, 63, 1; 51-70
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Assay of the Insensitive High Explosive 3-Nitro-1,2,4-triazol-5-one (NTO) by Acid-Base Titration
Autorzy:
Nandi, A. K.
Singh, S. K.
Kunjir, G. M.
Singh, J.
Mandal, A. K.
Pandey, R. K.
Powiązania:
https://bibliotekanauki.pl/articles/358351.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
NTO
purity
acid-base titration
HPLC
quality control
Opis:
The insensitive high explosive 3-nitro-1,2,4-triazol-5-one (NTO) is a weak acid (pKa 3.76) due to the labile N–H bond. The weakly acidic character of this compound is exploited for its assay by aqueous acid-base titration. The NTO sample was dissolved in water and the resultant solution was titrated against 0.07 N NaOH solution using phenolphthalein as indicator. Regular batch samples were assayed by this method and the results were compared with those obtained by the HPLC method. The aqueous acid-base titration method was found to be suitable for the quality control of the product.
Źródło:
Central European Journal of Energetic Materials; 2013, 10, 1; 113-122
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Assay of the Insensitive High Explosive FOX-7 by Non-Aqueous Titration
Autorzy:
Nandi, A. K.
Paramasivan, P.
Singh, S. K.
Mandal, A. K.
Pandey, R. K.
Powiązania:
https://bibliotekanauki.pl/articles/358156.pdf
Data publikacji:
2012
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
1,1-diamino-2,2-dinitroethene
FOX-7
non-aqueous titration
N,N-dimethylformamide
Opis:
A non-aqueous titration method was developed to assay the insensitive high explosive 1,1-diamino-2, 2-dinitroethene (FOX-7). The weak acidic nature of FOX-7 (pKa 10.6) was exploited in the assay method. The sample was dissolved in the protophilic solvent N, N-dimethylformamide and titrated against sodium methoxide solution in benzene/methanol using azo violet as indicator. FOX-7 samples obtained from regular batch operations were assayed by this method and the results were compared with that of a recrystallized sample. The method is simple, rapid and has good accuracy and precision.
Źródło:
Central European Journal of Energetic Materials; 2012, 9, 4; 343-352
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Process Optimization for the Gas-Liquid Heterogeneous Reactive Crystallization Process Involved in the Preparation of the Insensitive High Explosive TATB
Autorzy:
Nandi, A. K.
Kshirsagar, A. S.
Thanigaivelan, U.
Bhattacharyya, S. C.
Mandal, A. K.
Pandey, R. K.
Bhattacharya, B.
Powiązania:
https://bibliotekanauki.pl/articles/358228.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
TATB
TCTNB
amination
reaction crystallization
chloride impurity
particle size
Opis:
The thermally stable, insensitive, high explosive 1,3,5-triamino-2,4,6- trinitrobenzene (TATB) is manufactured by amination of 1,3,5-trichloro-2,4,6- trinitrobenzene (TCTNB) in toluene with NH3 gas. It is an isothermal, single-feed, semi-batch, gas-liquid heterogeneous, reaction crystallization process. The amination process is discussed by applying the chemical engineering methodology of mass transfer and reactive crystallization processes based on Two-Film Mass- Transfer (TFMT) theory. Kinetic expressions have been developed to define the chemical reactions as well as the physical phenomena (mass transfer) associated with this process. A single expression has been derived to explain the dependence of the ammonia consumption rate on various process parameters. Subsequently, the influence of various process parameters on the product quality (particle size and chloride impurity content) has been studied on the laboratory scale. Finally, the process has been established in the pilot plant, with optimized process conditions, to realize TATB of desired particle size and chloride content. The effects of feeding excess ammonia, and the presence of mercaptans/hydrogen sulphide impurities in poor quality toluene on the formation of certain undesirable by-products in TATB, are also discussed.
Źródło:
Central European Journal of Energetic Materials; 2014, 11, 1; 31-57
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Thermomechanical Controlled Processing and Quenching & Tempering on the Structure and Properties of Bainite-Martensite Steels
Autorzy:
Mandal, G.
Ghosh, S. K.
Chatterjee, S.
Powiązania:
https://bibliotekanauki.pl/articles/353508.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
steels
TMCP
heat treatment
microstructure
mechanical properties
Opis:
In the present time, advanced high strength steel (AHSS) has secured a dominant place in the automobile sector due to its high strength and good toughness along with the reduced weight of car body which results in increased fuel efficiency, controlled emission of greenhouse gases and increased passengers’ safety. In the present study, four new advanced high strength steels (AHSS) have been developed using three different processing routes, i.e., thermomechanical controlled processing (TMCP), quenching treatment (QT ), and quenching & tempering (Q&T) processes, respectively. The current steels have achieved a better combination of the high level of strength with reasonable ductility in case of TMCP as compared to the other processing conditions. The achievable ultrahigh strength is primarily attributed to mixed microstructure comprising lower bainite and lath martensite as well as grain refinement and precipitation hardening.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 2; 861-868
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optimization of Ammonium Sulfamate Nitration for the Preparation of Ammonium Dinitramide
Autorzy:
Mandal, A. K.
Kunjir, G. M.
Singh, J.
Adhav, S. S.
Singh, S. K.
Pandey, R. K.
Bhattacharya, B.
Lakshmi Kantam, M.
Powiązania:
https://bibliotekanauki.pl/articles/358022.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Opis:
The reaction kinetics for the preparation of ammonium dinitramide (ADN) is described. ADN is the ammonium salt of the dinitramide anion, and belongs to the group of inorganic oxidizers, mainly useful for energetic rocket propellant formulations, particularly for underwater applications. It is also a potential candidate to replace ammonium perchlorate (AP), in order to develop chlorine-free, green propellants. At HEMRL, ADN is prepared by the nitration of ammonium sulfamate (AS) using mixed acid, followed by hydrolysis, neutralization with ammonia (g) and rectification using solvent. The nitration of ammonium sulfamate (AS) is carried out at a subzero temperature of -40 ±1 °C. The yield of ADN is reliant on the formation of dinitramidic acid, an intermediate product formed during the hydrolysis step, and its stability is predominantly dependent upon the level of acidity and temperature of the reaction medium. Prior to these kinetics studies, process optimization of the nitration of ammonium sulfamate (AS) was performed and gave the final mole ratio of AS:HNO3:H2SO4. Since the nitration of AS is sensitive to temperature, the rate of reaction was studied at fixed temperatures with variation of time, keeping all of the other parameters, such as vessel volume, agitator speed, feed rate etc., constant. During these studies, predetermined quantities of ammonium sulfamate (AS) and mixed acid were allowed to react at a fixed temperature (-40 ±1 °C) for different reaction periods to generate the concentration profile of AS. Using this concentration profile, the reaction order and reaction rate constant were evaluated. In order to find the effect of temperature on the reaction rate and yield, experiments were conducted at other temperatures such as -30 and -50 °C. In the present studies, it was found that the optimum temperature of nitration is -40 ±1 °C and that the rate of reaction follows a pseudo second order process with rate constant 0.01113 (min-1)•(mol/L)-1. The reaction time evaluated for 55 to 60% conversion is about 70-80 minutes at -40 ±1 °C, based on this kinetics. The activation energy of AS nitration was found to be -4.6 kcal/mol, using the reaction kinetic data based on the temperature dependent rate equation derived from Arrhenius’s law.
Źródło:
Central European Journal of Energetic Materials; 2014, 11, 1; 83-97
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-6 z 6

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