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Tytuł:
Recovery of Proteins from Sweet Potato Cell Liquid by Acidification via Inoculation-Enhanced Fermentation and Determination of Functional Properties of Protein Products
Autorzy:
Li, Qingshuai
Liu, Liping
Han, Yanlei
Zhao, Xiangying
Yao, Mingjing
Ma, Jing
Han, Mo
Zhang, Jiaxiang
Powiązania:
https://bibliotekanauki.pl/articles/28408449.pdf
Data publikacji:
2024-02-09
Wydawca:
Instytut Rozrodu Zwierząt i Badań Żywności Polskiej Akademii Nauk w Olsztynie
Tematy:
sweet potato proteins
Leuconostoc citreum
protein precipitation
digestibility
emulsification
foaming
Opis:
Starch production from fresh sweet potatoes generates process wastewater called sweet potato cell liquid (SPCL), which is rich in sweet potato protein (SPP). Currently, the commonly used protein recovery methods, such as isoelectric point precipitation and ultrafiltration, were not suitable for SPP recovery due to the low protein content of SPCL and the high cost of recovery. The feasibility of recovering SPP by SPCL acidification via inoculation-assisted fermentation was investigated in this study. The results indicated that the pH of SPCL could be reduced to approximately 4.0 within 6 h of fermentation with inoculation, resulting in an SPP extraction yield of 55.45% and purity of 66.23 g protein/100 g. With the addition of heating treatment, the extraction yield of SPP increased to 76.97–95.34%, while it maintained the purity of 66.36–70.12 g protein/100 g. The composition analysis revealed that SPP products contained sugars (below 11.5 g/100 g) in addition to protein and trace amounts of lignin and phenolics. Functional properties analysis showed that the SPP recovered by inoculation-enhanced fermentation exhibited better emulsifying and foaming properties, and higher digestibility compared to the SPP precipitated using hydrochloric acid. The method of extracting SPP from SPCL by inoculation-enhanced fermentation, as developed in this study, was a straightforward and cost-effective process that fosters significant potential for industrial applications.
Źródło:
Polish Journal of Food and Nutrition Sciences; 2024, 74, 1; 49-58
1230-0322
2083-6007
Pojawia się w:
Polish Journal of Food and Nutrition Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A pedological study attempting to combine soil taxonomy and WRB classification systems
Autorzy:
Zayed, Adel M.A.
Abdel Ghaffar, Mamdouh K.
Ali, Faiza S.
Ewida, Esmail H.
Powiązania:
https://bibliotekanauki.pl/articles/27312660.pdf
Data publikacji:
2023
Wydawca:
Instytut Technologiczno-Przyrodniczy
Tematy:
North-East Nile Delta
pedological study
physiographic units
soil classification
Opis:
The study area is located in the North-Eastern part of the Nile Delta, northern of Ismailia canal and western Suez Canal. It comprises an area of about 3,058.8 km 2 (728,285.38 feddans). This work aims to identify the main physiographic units and its features, as well as emphasise the importance of combining soil taxonomy (2014) and WRB classification (2022) systems. Two main physiographic units were distinguished in the study area according to the previous studies, interpretation of satellite image and digital elevation model (DEM) as well as field observations; the first consists of fluvio-marine flats and the second river terraces which include the fluvial and deltaic origin. According to field morphological descriptions as well as chemical and physical analyses, representative profiles are classified by using both Soil Taxonomy and WRB systems. The current study is the third manuscript to emphasise the importance of using both systems together in order to obtain maximum possible characteristics of the earth. Below are examples that illustrate this importance. Soils of profile No. 4 which represent the fluvio-marine soils are classified according to soil taxonomy as follows: Typical Haplosalids, fine silty, mixed, thermic. While these soils are classified according to WRB as follows: Fluvic Sodic Solonchaks (Siltic/Loamy/Clayic, Chloridic, Evapocrustic, Ochric, Hypersalic). Soils of gypsiferous which represent soils of profile No. 6 are classified according to Soil Taxonomy as: Gypsic Aquisalids, loamy over sandy, mixed, thermic, whereas the application of the WRB system reveals the following: Fluvic Calcic Gypsic Sodic Gleyic Solonchaks (Loamic, Chloridic, Hypersalic).
Źródło:
Journal of Water and Land Development; 2023, 57; 197--203
1429-7426
2083-4535
Pojawia się w:
Journal of Water and Land Development
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A posteriori error estimates for beams with inexact flexural stiffness representation
Autorzy:
Torii, André J.
Gracite, Paula M.A.
Miguel, Leandro F.F.
Lopez, Rafael H.
Powiązania:
https://bibliotekanauki.pl/articles/24201505.pdf
Data publikacji:
2023
Wydawca:
Politechnika Częstochowska. Wydawnictwo Politechniki Częstochowskiej
Tematy:
beam
error estimate
inexact stiffness
belka
oszacowanie błędów
Opis:
In this work, we present a posteriori error estimates for the Euler-Bernoulli beam theory with inexact flexural stiffness representation. This is an important subject in practice because beams with non-uniform flexural stiffness are frequently modeled using a mesh of elements with constant stiffness. The error estimates obtained in this work are validated by means of two numerical examples. The estimates presented here can be employed for adaptive mesh refinement.
Źródło:
Journal of Applied Mathematics and Computational Mechanics; 2023, 22, 2; 62--74
2299-9965
Pojawia się w:
Journal of Applied Mathematics and Computational Mechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Armature MMF and electromagnetic performance analysis of dual three-phase 10-pole/24-slot permanent magnet synchronous machine
Autorzy:
Chen, Zhenfei
Xing, Ning
Ma, Hongzhong
Li, Zhixin
Li, Jiayu
Fan, Chenyang
Powiązania:
https://bibliotekanauki.pl/articles/2202550.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
dual three-phase winding
fractional-slot
concentrated winding
permanent magnet synchronous machines (SCW-PMSMs)
MMF harmonic analysis
space harmonics
magnet eddy-current loss (ECL)
SVPWM voltage supply
Opis:
Fractional-slot concentrated-winding permanent magnet synchronous machines (FSCW-PMSMs) have a good prospect of application in the drive system of electric and hybrid electric vehicles. However, the armature magnetomotive force (MMF) of FSCWPMSM contains a large number of space harmonics, which induce large magnet eddycurrent loss (ECL). To solve this problem, a dual three-phase 10-pole and 24-slot winding layout is proposed.MMFharmonic analysis shows that the 1st, 7th and 17th space-harmonic winding factors of the proposed winding can be reduced by 100%, 87% and 87% respectively, compared with a dual three-phase 10-pole and 12-slot winding. Electromagnetic performances of the proposed machine under rated sinusoidal current supply and space vector pulse-width-modulated (SVPWM) voltage supply are investigated based on 2D finite-element analysis. It is shown that the proposed machine can meet the requirement of torque and efficiency in the full speed range. Especially, magnet ECL can be reduced greatly due to the reduction of the 7th and 17th space harmonics.
Źródło:
Archives of Electrical Engineering; 2023, 72, 1; 189--210
1427-4221
2300-2506
Pojawia się w:
Archives of Electrical Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative Study on Drying Characteristics and Quality of Apple Cubes Dried in Two Different Microwave Dryers
Autorzy:
Ma, Yuhe
Tian, Xiaoju
Wang, Yingqiang
Zhao, Hongxia
Song, Jialing
Powiązania:
https://bibliotekanauki.pl/articles/24024624.pdf
Data publikacji:
2023-11-28
Wydawca:
Instytut Rozrodu Zwierząt i Badań Żywności Polskiej Akademii Nauk w Olsztynie
Tematy:
diced apple
microwave drying
heating characteristics
scorching rate
texture
color parameters
sensory quality
Opis:
A rotary plate microwave dryer (RMD) and a newly-developed microwave convection coupled dryer (MCD) were used to dry apple cubes. The effects of microwave output power on drying, heating characteristics and quality attributes including scorching rate, color parameters, rehydration ratio, shrinkage, hardness, and sensory scores of the apple cubes were investigated and compared. The results showed that the microwave power required to complete drying in RMD was only 1/6 of that in MCD at the same microwave power density. Total drying time was 120, 60 and 30 min at 70, 210 and 350 W in RMD, respectively, while 160, 90, 80 and 60 min at 400; 800; 1,200; and 1,600 W in MCD, respectively. Compared with the products dried using hot air, the apple cubes dried in both dryers at the low microwave power had better rehydration capacity, less shrinkage and lower hardness as well as a* and b* value of color. Application of microwave power of over 800 W in MCD and over 210 W in RMD caused the increase in scorching rate as well as decreased the L* value and the sensory quality of the apple cubes. Microwave drying in MCD with temperature control improved the quality of the dried product. The microwave drying conditions suitable for the apple cubes were 400 W in MCD and 1,600 W in MCD with temperature control followed by 70 W in RMD; the products obtained under these three condition variants had superior or comparable quality to the products obtained upon conventional hot air-drying.
Źródło:
Polish Journal of Food and Nutrition Sciences; 2023, 73, 4; 367-374
1230-0322
2083-6007
Pojawia się w:
Polish Journal of Food and Nutrition Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Construction deviation control method of transverse super large inclined asphalt pavement
Autorzy:
Qi, Yongzheng
Ma, Wengang
Zhang, Jiesheng
Powiązania:
https://bibliotekanauki.pl/articles/27312134.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
poligon samochodowy
pętla szybkich prędkości
powierzchnia bardzo duża
powierzchnia nachylona
nawierzchnia drogi
nawierzchnia asfaltowa
odchylenie konstrukcji
metoda kontroli
automobile testing ground
high speed loop
super large surface
inclined surface
road surface
asphalt pavement
construction deviation
control method
Opis:
The speed of test vehicles on the high-speed car track of the automobile test field is very high. Reducing the construction error of asphalt pavement is very important to ensure the safety of the test vehicle. In order to realize the paving of asphalt concrete pavement with super-large lateral inclination in the curve section of the high-speed car track in the automobile test field, a special paving control device and control method for the construction on the curve section with super-large lateral inclination were developed. Use the direction of the hanging hammer under the GPS device of paver to adjust the position of GPS device in real time, so that the geometric centre line of GPS device is always perpendicular to the horizontal plane. The reference control line is preset in the paver operation control device, and the lateral displacement deviation of the paver is adjusted to synchronize the data of the paver control device with the travel route. The precise control of the paver’s forward route is realized, the construction precision of the super-large inclined asphalt pavement on the high-speed car track of the automobile test field is achieved, and the construction efficiency is greatly improved. It has important reference value for similar projects such as automobile testing field and racing track.
Źródło:
Archives of Civil Engineering; 2023, 69, 2; 165--176
1230-2945
Pojawia się w:
Archives of Civil Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cracking control technique for continuous steel-concrete composite girders under negative bending moment
Autorzy:
Cai, Min
Li, Wenjie
Wan, Zhiyong
Sheng, Jianjun
Tan, Juliang
Ma, Chao
Powiązania:
https://bibliotekanauki.pl/articles/27312132.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
dźwigar ciągły
dźwigar zespolony
dźwigar stalowo-betonowy
odporność na pękanie
wzmocnienie
beton ultra wysokiej wartości
continuous girder
steel-concrete composite girder
hogging moment
cracking control
strengthening
ultra high performance concrete
Opis:
Continuous steel-concrete composite girder can fully utilize material strength and possess large spanning ability for bridge constructions. However, the weak cracking resistance at the negative bending moment region of the girder seriously harms its durability and serviceability. This paper investigates practical techniques to improve the cracking performance of continuous steel-concrete composite girders subjected to hogging moment.Areal continuous girderwas selected as the background bridge and introduced for numerical analysis. Modeling results show that under the serviceability limit state, the principle stress of concrete slabs near the middle piers of the bridgewas far beyond the allowable material strength, producing a maximum tensile stress of 10.0 MPa. Approaches for strengthening concrete decks at the negative moment region were developed and the effectiveness of each approach was assessed by examing the tensile stress in the slabs. Results indicate that the temporary counterweight approach decreased the maximum tensile stress in concrete slabs by 22%. Due to concrete shrinkage and creep, more than 65% of the prestressed compressive stresses in concrete slabs were finally dispersed to the steel beams. A thin ultra-high performance concrete (UHPC) overlay at the hogging moment region effectively increased the cracking resistance of the slabs, and practical engineering results convicted the applicability of the UHPC technique.
Źródło:
Archives of Civil Engineering; 2023, 69, 3; 239--251
1230-2945
Pojawia się w:
Archives of Civil Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Extrusion on the Functional Properties and Bioactive Compounds of Tamarind (Tamarindus indica L.) Shell
Autorzy:
Aguilar-Avila, Dalia S.
Martinez-Flores, Hector E.
Morales-Sanchez, Eduardo
Reynoso-Camacho, Rosalía
Garnica-Romo, Ma. Guadalupe
Powiązania:
https://bibliotekanauki.pl/articles/16538555.pdf
Data publikacji:
2023-08-31
Wydawca:
Instytut Rozrodu Zwierząt i Badań Żywności Polskiej Akademii Nauk w Olsztynie
Tematy:
thermomechanical treatment
tamarind shell
dietary fiber
phenolic compounds
antioxidant capacity
Opis:
The food-use of the tamarind (Tamarindus indica L.) fruit produces shell and seeds as by-products. In this work, the effects of the tamarind shell moisture content and the temperature of their extrusion on the dietary fiber content and physiochemical properties, such as water absorption capacity (WAC), oil absorption capacity (OAC), and glucose dialysis retardation index (GDRI) of the extrudates, were estimated. Moreover, the effects of the extrusion variables on the total phenolic and total flavonoid contents and on the antioxidant capacity of the tamarind shell were evaluated. The dry powdered tamarind shell was conditioned to have 32 or 39 g of water per 100 g of shell, prior to being subjected to extrusion. Subsequently, the conditioned samples were processed at 90°C, 100°C and 110°C in a single screw extruder. A non-extruded tamarind shell was taken as a control. The extrusion resulted in a 138.3% increase in the soluble dietary fiber content, along with 40.3% and 18.4% reductions of total phenolic and total flavonoid contents, respectively. The antioxidant capacity of the tamarind shell with moisture content of 32 g/100 g extruded at 100°C and 110°C was similar to that of non-extruded material. Moreover, the extruded products had the higher OAC compared to that of the control and they displayed an excellent response with regard to controlling the GDRI. The extrusion advantageously modified properties of the tamarind shell particularly when material with a moisture content of 32 g/100 g at 100°C was processed.
Źródło:
Polish Journal of Food and Nutrition Sciences; 2023, 73, 3; 278-288
1230-0322
2083-6007
Pojawia się w:
Polish Journal of Food and Nutrition Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Extraction of rubidium ion from brine solutions by dicyclohexano-18-crown-6 / ionic liquid system
Autorzy:
Huang, Dongfang
Ma, Guixiang
Lv, Peng
Zhou, Quanbao
Powiązania:
https://bibliotekanauki.pl/articles/2204138.pdf
Data publikacji:
2023
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Rubidium
Ionic liquid
Dicyclohexano-18-crown-6
Solvent extraction
Opis:
Separation among rubidium and potassium ions from salt lake brines remains challenging. In this work, a typical room temperature ionic liquid 1-ethyl-3-metyhlimidazaolium bis(trifluoromethylsulfonyl)imide ([C2mim+][NTf2-]) was used as diluent and synergistic extractant, dicyclohexano-18-crown-6 (DCH18C6) was used as extractant to extract rubidium ions from brine solutions which contain high concentrations of potassium ions was investigated. Under the optimal conditions, the single extraction efficiency of rubidium ions was up 93.63%. The thermodynamic parameters of the rubidium ion extraction were obtained. Based on the slope analysis method, the extracted species in the organic phase were ascertained as 1:1 complex. UV-visible has been performed to investigate the ion concentration of ionic liquid before and after the interaction of metal ions and ligands. Rubidium ions in [Rb · DCH18C6]+ complex were stripped by 2.5 mol · L–1 NH4NO3. The extraction system offers high efficiency, simplicity and environmentally friendly application prospect to separate rubidium from brine solutions.
Źródło:
Polish Journal of Chemical Technology; 2023, 25, 1; 61--68
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Incidence and molecular characterization of extended-spectrum beta-lactamase (ESBL)-producing Salmonella enterica and Escherichia coli of avifauna origin in Pakistan
Autorzy:
Saeed, M.A.
Waheed, U.
Ehtisham-ul-Haque, S.
Khan, A.U.
Kashif, M.
Qamar, M.F.
Ghafoor, A.
Saqlain, M.
Asghar, J.
Powiązania:
https://bibliotekanauki.pl/articles/16647457.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
ESBL
genotypic characterization
Salmonella enterica
Escherichia coli
avifauna
Pakistan
Opis:
Members of Enterobacteriaceae are known to produce extended-spectrum beta-lactamases (ESBL) which hydrolyze the beta-lactam group of antibiotics. The existence of ESBL-producing Salmonella enterica (S. enterica) and Escherichia coli (E. coli) harbored by urban avifauna was investigated in this study. Dropping samples (n= 180) were collected from six different bird species in the district Jhang, Punjab province, Pakistan. Isolation and identification of ESBL isolates were made by using cefotaxime- (4 mg/L) supplemented MacConkey agar and double disc synergy test (DDST). Polymerase chain reaction (PCR) was performed for the detection of four different ESBL genes including bla CTX-M, bla TEM, bla SHV and bla OXA. A total of 42.69% isolates were confirmed as ESBL via DDST including 30.64% S. enterica and 49.54% E. coli. The incidence of ESBL S. enterica and ESBL E. coli was found highest in egret (Ardea alba) and pigeon (Columba livia) as 64.28% and 78.95%, respectively. The bla CTX-M gene was detected in 57.89% and 64.81% of isolates of S. enterica and E. coli, respectively. Among other genes in S. enterica and E. coli, bla TEM (21.05%, 20.4%); bla SHV (15.78%, 9.26%), and bla OXA (5.26%, 5.56%) were detected, respectively. All of the tested isolates were found resistant to at least one of the thirteen antimicrobial agents except meropenem. To the best of our knowledge, this is the first study reporting the incidence and genetic diversity of ESBL bacteria associated with urban avifauna in Pakistan. The urban avifauna can serve as a potential subject of bio-surveillance to monitor the emergence of antimicrobial-resistant bacteria.
Źródło:
Polish Journal of Veterinary Sciences; 2023, 26, 1; 47-55
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of impact load form on dynamic response of chock-shield support
Autorzy:
Meng, Zhaosheng
Ma, Chen
Xie, Yunyue
Powiązania:
https://bibliotekanauki.pl/articles/27312794.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Polskie Naukowo-Techniczne Towarzystwo Eksploatacyjne PAN
Tematy:
hydraulic support
dynamic load
reliability analysis
mechanical-hydraulic co-simulation
Opis:
Chock-shield support is usually used in undergroud coal mining to protect the roof. However, as the mining depth gets deeper, impact load that came from the roof becomes stronger and more frequent. This causes the support to bear a large number of dynamic loads, and reducing its reliability. To improve the support performance of the chock-shield support, the mixed-kinetic model was established using the mechanical-hydraulic co-simulation method. The load distribution law of the support joint under impact load form different stability forces, impact load amplitude, and impact frequency is discussed. The mechanical-hydraulic cooperative response of the chock-shield support are obtained. The results show that different joints show typical non-uniformity characteristic during the loading process. The proposed mechanical-hydraulic co-simulation method can more accurately obtain the dangerous points of hydraulic support reliability. The results of this study will help to improve the reliability of the chock-shield support.
Źródło:
Eksploatacja i Niezawodność; 2023, 25, 3; art. no. 168316
1507-2711
Pojawia się w:
Eksploatacja i Niezawodność
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of the converter transformer valve-side bushing fault on commutation reactance protection and improvement scheme
Autorzy:
Zhang, Yanxia
Dong, Guanghao
Wei, Le
Ma, Jinting
Du, Shanshan
Powiązania:
https://bibliotekanauki.pl/articles/27309943.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
commutation reactance
converter transformer
improvement scheme
overcurrent protection
valve-side bushing fault
VSC HVDC system
Opis:
Commutation reactance is an important component in the voltage-source converter-based high-voltage direct current (VSC–HVDC) transmission system. Due to its connection to the converter, when there is a fault occurring on the valve-side bushing of a converter transformer, the nonlinearity operation of the converter complicates the characteristics of current flowing through commutation reactance, which may lead to maloperation of its overcurrent protection. It is of great significance to study the performance of commutation reactance overcurrent protection under this fault condition and propose corresponding improvement measures to ensure the safe and stable operation of AC and DC systems. In the VSC–HVDC system with the pseudo-bipolar structure of a three-phase two-level voltage source converter, the valve has six working periods in a power frequency cycle, and each period is divided into five working states. According to the difference between the fault phase and non-fault phase of the conductive bridge arms at the time of fault occurrence, these five working states are merged into two categories. On this basis, various faults of the valve-side bushing of a converter transformer are analyzed, and the conclusion is drawn that the asymmetric fault of valve-side bushing can lead to the maloperation of the commutation reactance overcurrent protection. Based on the characteristics that the current flowing through the commutation reactance after the asymmetric fault of the valve-side bushing contains decaying aperiodic components in addition to the fundamental frequency wave, a scheme to prevent the maloperation of commutation reactance overcurrent protection is proposed, which uses the unequal of two half cycle integral values with different starting points to realize the blocking of commutation reactance overcurrent protection, and it makes up the deficiency of existing protection in this aspect. Finally, this paper builds a VSC–HVDC system simulation model in the PSCAD/EMTDC platform to verify the effectiveness of the scheme.
Źródło:
Archives of Electrical Engineering; 2023, 72, 3; 715--735
1427-4221
2300-2506
Pojawia się w:
Archives of Electrical Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Interface Diffusion Behavior of Co40Al-X (X = Ni, Cr, Ti) System by Diffusion Multiple
Autorzy:
Shang, Hang
Gao, Qiuzhi
Jiang, Yujiao
Ma, Qingshuang
Li, Huijun
Zhang, Hailian
Powiązania:
https://bibliotekanauki.pl/articles/2203747.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Co-Al-X system
diffusion multiple
interface
diffusion
mechanical properties
Opis:
Diffusion multiple method was applied to investigate the alloying elements distribution and interface diffusion reactions in Co-Al-X system, in order to accelerate the alloy development. The diffusion regions of Co-Al-X system at 1173 K were investigated by scanning electron microscope (SEM) and nanoindentation. SEM images show that phases of Co-Al-Ni diffusion interface consisted of β-CoAl + γ Co, γ Co, γ + γ'-(Co, Ni)3Al and γ Ni, while Co-Al-Cr diffusion interface is shaped with δ + γ + β, γ and σ region. TiNiX diffusion layer with high Ni-content was formed in Co-Al-Ti diffusion interface. The diffusion layers during diffusion multiple play an important role in mechanical properties in these alloying systems. The γ + γ' diffusion layer in Co-Al-Ni diffusion interface presented the best comprehensive performance, while the highest hardness (17.48 GPa) was confirmed in Co-Al-Cr diffusion interface due to a large number of brittle phases. Darken method was applied to determine the interdiffusion coefficients of alloying elements in pseudo-binary phase, accordingly the diffusion capacities of alloying elements can be ordered as Al > Ni > Cr in Co-based alloys.
Źródło:
Archives of Metallurgy and Materials; 2023, 68, 1; 275--286
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kinetic of Oil Sludge Thermolysis Process in Presence of Nickel, Cobalt and Iron-Supported Microsilicate
Autorzy:
Tyanakh, Sairagul
Baikenov, Murzabek
Yun, Ma Feng
Khamitova, Tolkyn
Balpanova, Nazerke
Tulebayeva, Balzhan
Kyzkenova, Aikorkem
Karimova, Aliya
Rakhimzhanova, N.Z.
Kochegina, E.V.
Powiązania:
https://bibliotekanauki.pl/articles/27315657.pdf
Data publikacji:
2023
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
thermokinetic parameters
thermogravimetry
kinetics
nanocatalyst
microsilicate
oil sludge
iron
nickel
cobalt
Opis:
The article is devoted to the experimental determination of thermokinetic parameters of oil sludge thermal degradation using the model-free Ozawa-Flynn-Wall method in the presence of a nanocatalyst (nickel, cobalt and iron-supported microsilicate) by calculating Arrhenius kinetic parameters (activation energy and pre-exponential factor). The phase composition of the reflex microsilicate was established – 4.12; 2.51 Å – SiO2, nickel-supported microsilicate reflexes: 2.09; 1.48 Å – NiO, reflexes: 4.25 Å – SiO2 and acid numbers of microsilicate – 64 μmol/g of prepared nanocatalysts. Using the method of Brunauer, Emmett and Teller, the specific surface area of the microsilicate was established – 18.3 ± 0.3 m2 /g, the microsilicate with nickel applied – 20.9 ± 0.2 m2 /g and the adsorption isotherm of the prepared nanocatalysts (microsilicate with nickel, cobalt and iron). Thermokinetic parameters of thermal decomposition of oil sludge without a catalyst and with a catalyst at an increment of 0.9 are 99.0 and 93.3 kJ/mol nickel-supported microsilicate, 51.9 kJ/mol cobalt-supported microsilicate, 111.3 kJ/mol iron-supported microsilicate and non-metal-supported microsilicate 173.7 kJ/mol, respectively. The study of the kinetic parameters of pyrolysis of oil sludge using various catalysts makes it possible to assess their influence on the process of decomposition of organic components. The results of the experiments showed that the use of catalysts significantly affects the destruction of oil sludge. Dynamic thermal analysis at different heating rates studied the dynamics of oil sludge decomposition. The study of the effect of catalysts on the kinetic parameters of oil sludge pyrolysis is an important step in the development of new methods for the disposal of petroleum products and the reduction of their negative impact on the environment. The obtained experimental data on thermal degradation kinetics of oil sludge will find application in designing a reactor for the process of destructive hydrogenation of heavy hydrocarbon raw materials.
Źródło:
Polish Journal of Chemical Technology; 2023, 25, 3; 101--109
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kinetics of simultaneous recovering of Au and Ag from CTs by chloridizing volatilization methods
Autorzy:
Weiwei, Wang
Zhengyao, Li
Shanshan, Yang
Kai, Ma
Xin, Gao
Shaoqi, Han
Shaochun, Hou
Hecheng, Miao
Powiązania:
https://bibliotekanauki.pl/articles/27323663.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
cyanide tailings
chloridizing volatilization
gold
silver
kinetics
Opis:
Cyanide Tailings (CTs) are known as hazardous resources that accumulate hundreds of millions of tons, threatening the ecological environment. This work proposes an eco-friendly and efficient way to recover gold and silver from CTs. The effects of calcium chloride dosage, silicon dioxide dosage, pellet moisture content, roasting temperature, and roasting time on Au and Ag chloridizing volatilization were studied. The kinetics of simultaneously recovering of gold and silver from cyanide Tailings by chlorination roasting was investigated. It was determined that the chloridizing volatilization rates increased with increasing calcium chloride dosage, temperature and decreasing silicon dioxide dosage, pellet moisture content. The chloridizing volatilization kinetics followed a shrinking core model, with inter-diffusion through gangue layer as the rate determining step. This finding is in accordance with the apparent activation energy (Ea) of 24.01 kJ•mol-1 (Au) and 24.62 kJ•mol-1 (Ag). The orders of reaction with respect to moisture content, temperature, calcium chloride dosage and silicon dioxide dosage were also achieved. The rate of reaction based on diffusion-controlled process can be expressed by semi-empirical equations. The control steps of the gold and silver recovery process were investigated by the kinetic study, which provided theoretical guidance for the optimization of the method.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 172522
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł

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