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Tytuł:
A CTS pump with a crossed-coupled output for higher conversion efficiency
Autorzy:
Hsieh, Z. H.
Huang, N. X.
Shiau, M. S.
Wu, H. C.
Yang, S.-Y.
Liu, D.-G.
Powiązania:
https://bibliotekanauki.pl/articles/397847.pdf
Data publikacji:
2010
Wydawca:
Politechnika Łódzka. Wydział Mikroelektroniki i Informatyki
Tematy:
DC-DC przetwornice
CTS ładunek pompy
sprzężenie skrośne ładunku pompy
DC-DC converter
CTS charge pump
cross coupled charge pump
Opis:
In this paper, a novel switching-capacitor DC-DC voltage converter with higher efficiency will be presented. This circuit was designed by modifying the output stage of the conventional static charge-transfer-switch (CTS) charge pump in a cross-coupled configuration. In this design, a control scheme to overcome both the reverse charge sharing and the threshold drops in the CTS pump was also employed. In this study, the capacitances for all the pumping capacitors were selected the same as 0.1 μF. With this design, our circuit can operate with a clock rate up to 1 MHz. The performance of this circuit was first evaluated by simulation by HSPICE with the 0.35-μm technology of TSMC. The results showed that this circuit can pump the low input of 1.5V nearly 5 times at the output. The conversion gain can be around 95%. The performance of the real chip manufactured by TSMC was measured and will be compared with the simulation results.
Źródło:
International Journal of Microelectronics and Computer Science; 2010, 1, 1; 9-14
2080-8755
2353-9607
Pojawia się w:
International Journal of Microelectronics and Computer Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Genome size of the diploid hybrid species Hippophae goniocarpa and its parental species, H. rhamnoides ssp. sinensis and H. neurocarpa ssp. neurocarpa (Elaeagnaceae)
Autorzy:
Zhou, X.
Ma, J.
Wang, W.
Gong, N.
Zhang, Y.
Liu, J.
Powiązania:
https://bibliotekanauki.pl/articles/19367.pdf
Data publikacji:
2010
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Źródło:
Acta Biologica Cracoviensia. Series Botanica; 2010, 52, 2
0001-5296
Pojawia się w:
Acta Biologica Cracoviensia. Series Botanica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nowa metoda analizy drzewa uszkodzeń: rozmyta analiza dynamicznego drzewa uszkodzeń
A new fault tree analysis method: fuzzy dynamic fault tree analysis
Autorzy:
Li, Y. F.
Huang, H. Z.
Liu, Y.
Xiao, N. C.
Li, H.
Powiązania:
https://bibliotekanauki.pl/articles/301632.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Polskie Naukowo-Techniczne Towarzystwo Eksploatacyjne PAN
Tematy:
analiza drzewa uszkodzeń
dynamiczne drzewo uszkodzeń
liczba rozmyta
rozmyty model Markowa
programowanie parametryczne
fault tree analysis (FTA)
dynamic fault tree
fuzzy number
fuzzy Markov model
parametric programming
Opis:
Fault tree analysis (FTA) is a widely used reliability assessment tool for large and complex engineering systems. The conventional fault tree analysis method, which contains AND, OR, and Voting gates, etc., can efficiently build an analytical model to represent combinations of component failures that cause the failure of a system. However, due to its limited modeling capability, we may confront difficulties when modeling dynamic systems which involve complicated dynamic characteristics such as sequence dependency and functional dependency. Markov-based dynamic fault tree analysis (DFTA) extends the static FTA by introducing additional gates to model such complicated interactions among events. In many circumstances, it is quite difficult to obtain an accurate system reliability estimate due to limited data. To overcome this issue, a fuzzy dynamic fault tree model is put forth to assess system reliability. To obtain the membership function of the fuzzy probability for the top event of the studied fault trees, the extension principle is employed to calculate the associated membership function via a pair of parametric programming problems. Finally, a case study is presented to demonstrate the application of the proposed approach for the hydraulic system of a CNC machining centre.
Analiza drzewa uszkodzeń (FTA) znajduje szerokie zastosowanie jako narzędzie oceny niezawodności dużych i złożonych systemów inżynierskich. Tradycyjna metoda analizy drzewa uszkodzeń z bramkami logicznymi typu AND, OR, k-z-n, itd. pozwala na sprawne konstruowanie modeli analitycznych reprezentujących kombinacje uszkodzeń elementarnych składowych systemu, które prowadzą do awarii systemu jako całości. Jednakże ograniczone możliwości modelowania jakie daje ta metoda mogą prowadzić do trudności przy modelowaniu systemów dynamicznych posiadających złożone charakterystyki dynamiczne, takie jak zależność sekwencyjna czy zależność funkcjonalna. Analiza dynamicznych drzew uszkodzeń (DFTA) oparta na metodzie Markowa stanowi rozszerzenie tradycyjnej FTA. Wprowadza ona dodatkowe bramki, pozwalając na modelowanie wspomnianych wyżej złożonych interakcji między zdarzeniami. W wielu okolicznościach, ograniczone dane nie pozwalają na otrzymanie dokładnej oceny niezawodności systemu. By rozwiązać ten problem, zaproponowano zastosowanie rozmytego modelu dynamicznego drzewa uszkodzeń do oceny niezawodności systemu. Aby otrzymać funkcję przynależności rozmytego prawdopodobieństwa wystąpienia zdarzenia szczytowego badanego drzewa uszkodzeń, obliczono, na podstawie pary problemów programowania parametrycznego, skojarzoną funkcję przynależności wykorzystując zasadę rozszerzenia. Na zakończenie przedstawiono studium przypadku, w którym proponowane podejście zastosowano do analizy systemu hydraulicznego centrum obróbkowego CNC.
Źródło:
Eksploatacja i Niezawodność; 2012, 14, 3; 208-214
1507-2711
Pojawia się w:
Eksploatacja i Niezawodność
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Posybilistyczna analiza niezawodnościowa systemu naprawialnego z pominiętym lub opóźnionym efektem uszkodzenia
Possibilistic reliability analysis of repairable system with omitted or delayed failure effects
Autorzy:
Pang, Y.
Huang, H. Z.
Xiao, N. C.
Liu, Y.
Li, Y. F.
Powiązania:
https://bibliotekanauki.pl/articles/301620.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Polskie Naukowo-Techniczne Towarzystwo Eksploatacyjne PAN
Tematy:
pominięty lub opóźniony efekt uszkodzenia
model Markowa
pominięcie czasu naprawy
posybilistyczna gotowość chwilowa
failure effect omitted or delayed
Markov model
repair time omission
instantaneous possibilistic availability
Opis:
Przy rozwiązywaniu problemów praktycznych w inżynierii przemysłowej można czasami pominąć bądź opóźnić efekt uszkodzenia jeśli ma on niewielki wpływ na system. Ściślej, wiodące cechy systemu można opisać w następujący sposób: 1) jeżeli czas naprawy jest wystarczająco krótki (krótszy niż pewna wartość progowa), tak iż nie ma on wpływu na działanie systemu, to można pominąć negatywny efekt uszkodzenia systemu. Przy takim czasie naprawy można uznać że system nie przerwał działania. Nazywa się go wtedy systemem z pominięciem czasu naprawy (pominięty efekt uszkodzenia). 2) Jeżeli czas naprawy jest dłuższy niż dana wartość progowa i efekt uszkodzenia staje się w końcu odczuwalny, to uznajemy, że system pozostawał aktywny od początkowego etapu naprawy aż do momentu, w którym został przekroczony próg czasu naprawy. Nazywa się go wtedy systemem z opóźnionym efektem uszkodzenia. W oparciu o powyższe dwie charakterystyki, wprowadzono w prezentowanej pracy model systemu naprawialnego. Omówiono dwa scenariusze, w których, odpowiednio, przyjęto, że wartość progowa jest wartością stałą lub nieujemną zmienną losową. Sformułowano wskaźniki niezawodnościowe, takie jak posybilistyczna gotowość chwilowa, dla systemu z pominiętym lub opóźnionym efektem uszkodzenia.
Within the practical problems in industrial engineering, the failure effect sometimes can be omitted or delayed if it has less effect on the system. In detail, the prominent features of the system can be described as follows: 1) if a repair time is sufficiently short (less than some threshold value) that does not affect the system operation, i.e. the pessimistic effect of system failure could be ignored. The system can be considered as operating during this repair time. It is called the system with repair time omission (failure effect omitted). 2) if a repair time is longer than the given threshold value and the failure effect is finally suffered. Then the system can be considered to remain operating from the initial stage of the repair till the end of the repair threshold. It is called the system with delayed failure effect. Based on the above two characteristics, model for the related repairable system is introduced in this paper. Two scenarios are discussed where the threshold value is regarded as a constant and non-negative random variable, respectively. Reliability indices such as instantaneous possibilistic availability are formulated for the system with failure effect omitted or delayed.
Źródło:
Eksploatacja i Niezawodność; 2012, 14, 3; 195-202
1507-2711
Pojawia się w:
Eksploatacja i Niezawodność
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Validating performance based critical actions in a high tech start-up
Autorzy:
Vuoti, V. P.
Takala, J.
Mäntylä, A.
Liu, Y.
Yang, W.
binti Abdul Malek, N. A.
Kronman, P.
Kreuzer, A.
Zafar, A.
Powiązania:
https://bibliotekanauki.pl/articles/406824.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
sustainable competitive advantage
sense and respond
manufacturing strategy index
operations strategy
balanced critical factor index
operations start up
case study
Opis:
The objective of this study is to analyze a Finnish manufacturing case company’s operational competitiveness. A proposed analytical model based on analyses the corresponding angles of the strategic triangles (Prospector, Analyzer, and Defender). The model compares the angle differences between the strategy and resource triangles with opinions from different management groups of informants. It was found out that Normalized Scaled Critical Factor Index (NSCFI) model is more scientific comparing to formal ones through validation. Calculations based on the MSI questionnaire resulted in medium high values for the Prospector strategy both for past- and future orientation. S&R calculations regarding the past orientation resulted in low values for all strategy types, except P-NSCFI for Analyzer. Moreover this study covers a case, in where Balanced Critical Factor Index (BCFI) was used defining company annual strategy plan.
Źródło:
Management and Production Engineering Review; 2014, 5, 1; 74-86
2080-8208
2082-1344
Pojawia się w:
Management and Production Engineering Review
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A Dedispersion Transform Method for Extracting the Normal Modes of a Shallow Water Acoustic Signal in the Pekeris Waveguide
Autorzy:
Yang, G.- B.
Lü, L.- G.
Gao, D.- Z.
Jiang, Y.
Liu, H.- N.
Powiązania:
https://bibliotekanauki.pl/articles/177234.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
normal mode extraction
dedispersion transform
Pekeris waveguide
source ranging
Opis:
The normal modes cannot be extracted even in the Pekeris waveguide when the source-receiver distance is very close. This paper introduces a normal mode extraction method based on a dedispersion transform (DDT) to solve this problem. The method presented here takes advantage of DDT, which is based on the waveguide invariant such that the dispersion associated with all of the normal modes is removed at the same time. After performing DDT on a signal received in the Pekeris waveguide, the waveform of resulting normal modes is very close to the source signal, each with different position and amplitude. Each normal mode can be extracted by determining its position and amplitude parameters by applying particle swarm optimization (PSO). The waveform of the extracted normal mode is simply the waveform of the source signal; the real waveform of the received normal mode can then be recovered by applying dispersion compensation to the source signal. The method presented needs only one receiver and is verified with experimental data.
Źródło:
Archives of Acoustics; 2015, 40, 1; 11-18
0137-5075
Pojawia się w:
Archives of Acoustics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analyzing sustainable competitive advantage: strategically managing resource allocations to achieve operational competitiveness
Autorzy:
Malek, N. A.
Shahzad, K.
Takala, J.
Bojnec, S.
Papler, D.
Liu, Y.
Powiązania:
https://bibliotekanauki.pl/articles/406814.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
sustainable competitive advantage
sustainable operations
competitive priorities
sense and respond
manufacturing strategy index
adaptive strategy
Opis:
In today’s dynamic business environment, a key challenge for all companies is to make adaptive adjustments to their manufacturing strategy. This study demonstrates the competitive priorities of manufacturing strategy in hydro-power case company to evaluate the level of sustainable competitive advantage and also to further analyze how business strategies are aligned with manufacturing strategies. This research is based on new holistic analytical evaluation of manufacturing strategy index, sense and respond, and sustainable competitive advantage models. These models help to describe, evaluate, and optimize resource allocation to meet the performance requirements in dynamic decision making. Furthermore, these models evaluate operational competitiveness for manufacturing strategies according to the multi-criteria priority. The results show that the adjustments of competitive priorities in manufacturing strategies by implementing the proposed holistic analytical models are helpful in strategically managing business operations. The discussion derives the most critical attributes in business operations while alignment of resource allocation with competitive priorities help to strategically focus those attributes. In conclusion, we argue that resource allocation and manufacturing strategies have become the most important capabilities in a business environment where companies focus to get a sustainable competitive advantage.
Źródło:
Management and Production Engineering Review; 2015, 6, 4; 70-86
2080-8208
2082-1344
Pojawia się w:
Management and Production Engineering Review
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative investigation of working fluids for an organic Rankine cycle with geothermal water
Autorzy:
Liu, Y.-N.
Xiao, S.
Powiązania:
https://bibliotekanauki.pl/articles/240415.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
geothermal water
energy efficiency
organic Rankine cycle
wody geotermalne
efektywność energetyczna
organiczny obieg Rankine'a
Opis:
In this paper, the thermodynamic investigation on the use of geothermal water (130°C as maximum) for power generation through a basic Rankine has been presented together with obtained main results. Six typical organic working fluids (i.e., R245fa, R141b, R290, R600, R152a, and 134a) were studied with modifying the input pressure and temperature to the turbine. The results show that there are no significant changes taking place in the efficiency for these working fluids with overheating the inlet fluid to the turbine, i.e., efficiency is a weak function of temperature. However, with the increasing of pressure ratio in the turbine, the efficiency rises more sharply. The technical viability is shown of implementing this type of process for recovering low temperature heat resource.
Źródło:
Archives of Thermodynamics; 2015, 36, 2; 75-84
1231-0956
2083-6023
Pojawia się w:
Archives of Thermodynamics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Multi-direction digital moving mask method for fabricating continuous microstructures
Autorzy:
Zhang, Z
Gao, Y
Luo, N
Zhong, K
Liu, Z
Powiązania:
https://bibliotekanauki.pl/articles/175088.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
multi-direction digital moving mask
superposition
quantization
Opis:
The multi-direction digital moving mask method, employing the superposition of the exposure along various moving directions, is developed for fabricating continuous microstructures. The mask pattern corresponding to each moving direction is determined by projecting the target dose profile in the corresponding moving direction. All the mask patterns are dynamically exposed on the same substrate layer by layer so as to form a 3D profile of the exposure dose. The selection criterion of a quantization number and moving-direction number is discussed. For verification of the multi-direction moving method, experiments are performed to fabricate a square pyramid array and square-based microlens array by moving along two orthogonal directions, and round-based microlens array by moving along six directions.
Źródło:
Optica Applicata; 2015, 45, 1; 79-88
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Differential expression of Toll - like receptor 4 signaling pathway genes in Escherichia coli F18 - resistant and - sensitive Meishan piglets
Autorzy:
Liu, Y.
Gan, L.N.
Qin, W.Y.
Sun, S.Y.
Zhu, G.Q.
Wu, S.L.
Bao, W.B.
Powiązania:
https://bibliotekanauki.pl/articles/31946.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Opis:
The Toll-like receptor 4 (TLR4) signaling pathway is an important inflammatory pathways associated with the progression of numerous diseases. The aim of the present study was to investigate the relationship between TLR4 signaling and resistance to Escherichia coli F18 in locally weaned Meishan piglets. Using a real-time PCR approach, expression profiles were determined for key TLR4 signaling pathway genes TLR4, MyD88, CD14, IFN-α, IL-1β and TNF-α in the spleen, thymus, lymph nodes, duodenum and jejunum of E. coli F18-resistant and -sensitive animals. TLR4 signaling pathway genes were expressed in all the immune organs and intestinal tissues, and the expression was generally higher in the spleen and lymph nodes. TLR4 transcription was higher in the spleen of sensitive piglets (p<0.05), but there was no significant difference in TLR4 mRNA levels in other tissues. Similarly, CD14 transcription was higher in lymph nodes of sensitive animals (p<0.05) but not in other tissues. IL-1β expression was higher in the spleen and in the duodenum of resistant piglets (p<0.05, p<0.01, respectively), and there were no significant differences in other tissues. There were also no significant differences in the expression of MyD88, TNF-α and IFN-α between sensitive and resistant piglets (p>0.05). These results further confirm the involvement of the TLR4 signaling pathway in resistance to E. coli F18 in Meishan weaned piglets. The resistance appeared to be mediated via downregulation of TLR4 and CD14, and upregulation of MyD88 that may promote the release of cytokines TNF-α, IL-1β, IFN-α and other inflammatory mediators which help to fight against E. coli F18 infection.
Źródło:
Polish Journal of Veterinary Sciences; 2016, 19, 2
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Heating control of heated twin radiosonde humidity sensor based on DMC
Autorzy:
Sun, N.
Zhang, Y.
Zhang, W
Cheng, E.
Liu, Y.
Powiązania:
https://bibliotekanauki.pl/articles/260018.pdf
Data publikacji:
2016
Wydawca:
Politechnika Gdańska. Wydział Inżynierii Mechanicznej i Okrętownictwa
Tematy:
DMC
twin heated humidity sensor
expanded responsible curve
heating control
Opis:
In order to effectively solve condensation and icing problems of radiosonde in low-temperature environment at high altitude, humidity sensor heated automatic alternately to remove pollution and improve the measurement accuracy. Heat experiments obtained the curve of rising temperature and responsible time on heated twin humidity sensor in normal temperature and pressure, by expanded responsible curve to obtain heated model of twin heated humidity sensor and by the analysis of heating model, use DMC and PID control for heating respectively. Simulation results show that the DMC control meets the practical requirements of measure at high altitude.
Źródło:
Polish Maritime Research; 2016, S 1; 52-58
1233-2585
Pojawia się w:
Polish Maritime Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The distribution of different virulence grass carp reovirus strains in some neglected tissues
Autorzy:
Liang, H.R.
Fu, X.Z.
Li, N.Q.
Liu, L.H.
Lin, Q.
Li, Y.G.
Peng, Y.A.
Huang, Z.B.
Wu, S.Q.
Powiązania:
https://bibliotekanauki.pl/articles/30668.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Źródło:
Polish Journal of Veterinary Sciences; 2016, 19, 4
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Coating of LiBH4 and Its Effect on the Decomposition of RDX and AP
Autorzy:
Ding, X.
Shu, Y.
Chen, Z.
Liu, N.
Gou, B.
Zhang, J.
Wu, M.
Xie, G.
Dang, T.
Powiązania:
https://bibliotekanauki.pl/articles/358086.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
coating
hydride
additive
hygroscopicity
DSC
Opis:
The novel fuel additive LiBH4 was introduced as an energetic component for its outstanding hydrogen content, perfect burning performance and high reactivity. In order to limit the hygroscopicity and to improve the stability in the air, LiBH4 was coated on the surface with wax and polyester carbonate. The final product was characterized by scanning electron microscopy (SEM), X-ray photoelectron energy spectroscopy (XPS) and Raman spectroscopy, while the stability in air was investigated by regular checking of variations in weight. The results show that a uniform coating layer was formed on the surface of the LiBH4, and the coverage was estimated from the boron content as approximately 82%. A healing effect was confirmed on defective surfaces exposed to air; the coating layer improves the relative stability by 50.7%. Furthermore, LiBH4 as an additive to promote the thermal decomposition of 1,3,5-trinitro-1,3,5-trazinane (RDX) and ammonium perchlorate (AP) was explored by differential scanning calorimetry (DSC), in which the catalytic effects of pure LiBH4 and coated LiBH4 were compared, and indicated that the coating does not decrease the reactivity of LiBH4. It is suggested that surface coating with some inert materials is a simple and effective method for improving the storage and performance of LiBH4, while ensuring its reactivity.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 1; 134-151
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Computational Investigation on the Structure and Performance of Novel 4,7-dinitro-furazano-[3,4-d]-pyridazine Derivatives
Autorzy:
Wang, K.
Shu, Y.
Liu, N.
Ding, X.
Wu, Z.
Lu, Y.
Powiązania:
https://bibliotekanauki.pl/articles/358090.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
4,7-dinitro-furazano-[3,4-d]-pyridazine
heat of formation
density
detonation performance
bond dissociation energy
Opis:
Seven novel energetic 4,7-dinitro-furazano-[3,4-d]-pyridazine derivatives were designed, and their optimized structures and performances were studied by density functional theory (DFT) at B3LYP/6-311g(d,p) level. The detonation performances were estimated by the Kamlet-Jacobs equations. The results show that these compounds have high crystal densities (1.818-1.925 g·cm−3), detonation velocities (8.51-9.56 km·s−1) and detonation pressures (32.28-41.70 GPa). The bond dissociation energies (BDEs) of the weakest bond (N–O bond) vary from 70.889 kJ·mol−1 to 173.283 kJ·mol−1, and some of them exhibit higher BDEs than that of RDX (N–NO2 bond, 149.654 kJ·mol−1) and HMX (N–NO2 bond, 154.905 kJ·mol−1). M4 and M5 exhibit similar and higher detonation performance than RDX (8.81 km·s−1, 34.47 GPa). The detonation performance of M7 (9.56 km·s−1, 41.70 GPa) even surpasses that of HMX (9.10 km·s−1, 39.00 GPa). Otherwise, the specific impulse values of M1-M7 (266-279 s) outperform HMX (266 s) by 0-13 s, which indicates that M1-M7 may show better performance as monopropellants. It is concluded that density, heat of formation, stability, detonation performance and specific impulse of the designed compounds depend on the position and number of the N→O oxidation bonds.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 1; 26-46
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative Theoretical Investigation on Energetic Substituted Furazanyl Ethers
Autorzy:
Liu, N.
Wang, K.
Shu, Y.
Zeman, S.
Wang, B.
Wang, W.
Powiązania:
https://bibliotekanauki.pl/articles/358622.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
furazanyl ethers
heats of formation
bond dissociation energy
detonation performance
melting point
Opis:
Furazanyl ether has great potential to be an important candidate as a casting explosive and energetic plasticizer. The density functional theory (DFT) method was used to investigate the heats of formation (HOFs), molecular stability, detonation performance and melting point of a series of substituted furazanyl ethers at B3LYP/6-311G(d,p) level. The results show that the introduction of –N3 or –N(O)=N– groups significantly improves the HOFs values of the derivatives. The bond dissociation energies (BDEs) were analyzed, showing that the N–O bond in the furazan ring is the weakest for most compounds and the ring is vulnerable to cleavage in thermal decomposition. The calculation of density, detonation velocities and detonation pressures suggests that the substitution of –NF2, –CF(NO2)2, furoxan or –N(O)=N– group is an effective method for enhancing their detonation performance. The melting points were determined according to the variation of specific heat capacity, and good estimates were obtained in comparison with the available experimental data. Taking into account the detonation performance and melting point, four compounds are favoured for application in melt cast explosive or energetic plasticizers.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 1; 47-71
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 17

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