- Tytuł:
- 1,1-Dithiolenes: the Good, the Not Bad, and the Ugly
- Autorzy:
-
Cassoux, P.
Bowlas, C. J.
Lahlil, K.
Moradpour, A.
Bonvoisin, J.
Launay, J.-P - Powiązania:
- https://bibliotekanauki.pl/articles/1933327.pdf
- Data publikacji:
- 1995-04
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
33.20.-t
82.40.-g
82.45.+z
33.10.-n
82.30.-b - Opis:
- A series of 1, 1'-dithiolate ligands were used in the attempted preparation of metal complexes. These bidentate sulphur ligands were subsequently used in aromatic nucleophilic substitution reactions giving rise to several novel organic donor molecules. The electrochemistry data of two of the donors and their subsequent use in the preparation of donor-acceptor compounds is presented. One donor-acceptor compound exhibited high room temperature conductivity (up to 900 S cm$\text{}^{-1}$) and remained metallic down to low temperature. One donor containing two tetrathiafulvalene units was studied by near infrared absorption spectroscopy. An intervalence transition in the monocation form of this donor was observed, indicating that it behaves as a class II mixed valence compound.
- Źródło:
-
Acta Physica Polonica A; 1995, 87, 4-5; 743-748
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł