- Tytuł:
- Long-Range Interactions and the Oscillator Strength for the $\text{}^{1}1_{u}, \text{}^{1}0_{u}^{+}$ ← X $\text{}^{1}0_{g}^{+}$ Transitions in Zn$\text{}_{2}$
- Autorzy:
-
Kubkowska, M. K.
Szczęśniak, T. M.
Grycuk, T. - Powiązania:
- https://bibliotekanauki.pl/articles/2037211.pdf
- Data publikacji:
- 2004-04
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
32.70.-n
32.70.Cs
32.70.Jz
33.70.-w
34.20.-b - Opis:
- The interaction potentials for Zn$\text{}_{2}$ electronic states $\text{}^{1}1\text{}_{u}$ and $\text{}^{1}0_{u}^{+}$ correlated with (4 $\text{}^{1}P_{1}$+4 $\text{}^{1}S_{0}$) asymptote in the long-range region (10-25) Å and the oscillator strength f for the absorption transition to these states are derived experimentally from a careful analysis of the self-broadened resonance 213.8 nm line of Zn. It is found that although the interatomic interactions at so long distances are dominated by resonance potential of the form C$\text{}_{3}$/R$\text{}^{3}$ resulting in the Lorentzian line shape, the parameter C$\text{}_{3}$ and thus f value significantly decrease with R decreasing. This effect proved to be a linear function of R$\text{}^{-1}$ yielding the oscillator strength for the considered line f$\text{}_{0}$=1.456 $\pm$ 0.010 from $R \rightarrow \infty$ extrapolation. This value seems to be the most accurate experimental result as yet and shows that the best theoretical values for this quantity are overestimated. It is suggested that the long-range behaviour of the potential energy curves observed here for the first time represents the effective potentials including dominating resonance interactions and a possible slight contribution of the dispersion interactions as well as the R-dependent spin-orbit interaction.
- Źródło:
-
Acta Physica Polonica A; 2004, 105, 4; 317-328
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł