- Tytuł:
- Investigations on the Anisotropic g Factors of the $Ni^{3+}$ Site in $La_2Ni_{0.5}Li_{0.5}O_4$
- Autorzy:
-
Kuang, M.
Wu, S.
Zhang, Z.
Song, B. - Powiązania:
- https://bibliotekanauki.pl/articles/1400149.pdf
- Data publikacji:
- 2013-04
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
76.30.Fc
71.70.Ch
75.10.Dg - Opis:
- The anisotropic g factors $g_{∥}$ and $g_{⊥}$ of $La_2Ni_{0.5}Li_{0.5}O_4$ are theoretically investigated using the perturbation formulae of the g factors for a low spin $(S=1//2) 3d^7$ ion in tetragonally elongated octahedra. The studied $Ni^{3+} (3d^7)$ center arises from the original $Ni^{2+}$ capturing one hole by $Li^{+}$ doping. The positive anisotropy $\Delta g (= g_{⊥}-g_{∥})$ can be ascribed to the lowest $\text{}^2 A_{1g}$ state due to the obvious (about 0.14 Å) tetragonal elongation of the oxygen octahedron around the $Ni^{3+}$ site via the Jahn-Teller effect, and the effective magnetic moment is also interpreted in a uniform way. The calculated results show good agreement with the experimental data, and the imperfection of the previous studies based on various adjusted tetragonal energy splittings without correlating to the local structure of the magnetic center is thus overcome in this work.
- Źródło:
-
Acta Physica Polonica A; 2013, 123, 4; 734-736
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł