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Wyświetlanie 1-19 z 19
Tytuł:
Effect of Electroless Ni–P Plating on the Bonding Strength of Bi–Te-Based Thermoelectric Modules
Autorzy:
Kim, S. S.
Son, I.
Kim, K. T.
Powiązania:
https://bibliotekanauki.pl/articles/356583.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
thermoelectric
Ni–P plating
bonding strength
Bi–Te
soldering
Opis:
In the present study, electroless Ni–P plating was applied to Bi–Te-based thermoelectric materials as a barrier layer and the effect of the Ni–P plating on the bonding strength of the thermoelectric module was investigated. The bonding strength of the n- and p-type modules increased after being subjected to the electroless Ni–P plating treatment. In the case of the thermoelectric module that was not subjected to electroless Ni–P plating, Sn and Te were interdiffused and formed a brittle Sn–Te-based metallic compound. The shearing mostly occurred on the bonding interface where such an intermetallic compound was formed. On the other hands, it was found from the FE-EPMA analysis of the bonding interface of thermoelectric module subjected to electroless Ni-P plating that the electroless Ni-P plating acted as an anti-diffusion layer, preventing the interdiffusion of Sn and Te. Therefore, by forming such an anti-diffusion layer on the surface of the Bi–Te based thermoelectric element, the bonding strength of the thermoelectric module could be increased.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1225-1229
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation of an odor source in Changwon City using multi-monitoring methods. A case study of Korea
Autorzy:
Prueksakorn, K.
Kim, T.-H.
Powiązania:
https://bibliotekanauki.pl/articles/207109.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
odor
industrial plants
industrial city
odor measurements
odor nuisance
odor pollutants
odorimetry
Changwon City
zapach
zakłady przemysłowe
miasto przemysłowe
pomiary zapachu
uciążliwość zapachowa
badanie zapachu
emisja substancji zapachowych
jakość zapachowa powietrza
metody pomiarowe uciążliwości zapachowych
ocena uciążliwości zapachu
Changwon
Opis:
It is a regular occurrence for residents living near industrial plants to complain regarding odor problems. Those plants may also try to protect themselves from liability by demonstrating some environmental evidence. An investigation to prove whether the accused industrial complex is the major source of released odors among several potential sources of odor problems was carried out using the combination of measurement techniques. The multi-monitoring methods comprise utilizations of olfactory system, questionnaire, electronic detector and chemical analysis. This study demonstrated the achievement of integrating scientific monitoring methods to support the enforcement of odor acts for management in the industrial city.
Źródło:
Environment Protection Engineering; 2015, 41, 4; 109-130
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Causal relationship between supply chain dynamic capabilities, technological innovation, and operational performance
Autorzy:
Ju, K.-J.
Park, B.
Kim, T.
Powiązania:
https://bibliotekanauki.pl/articles/407389.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
supply chain management
dynamic capabilities
supply chain dynamic capabilities
technological innovation
operational performance
Opis:
The aim of this study is to empirically examine the impact of supply chain dynamic capabilities on operational performance, and the mediating effect of technological innovation between dynamic capabilities and operational performance. This study is based on empirical data collected from a survey of 206 small- and medium-size firms in Korea. Structural equation modeling is used to test the research questions. The results show that supply chain dynamic capabilities positively influence technological innovation and operational performance of an enterprise. Additionally, structural equation analyses reveal that technological innovation plays a role as a partial mediator of the relationship between supply chain dynamic capabilities and operational performance. In a dynamic and ever-changing environment, the enforcement of dynamic capabilities in a sustainable supply chain is important for the innovation of technology and the improvement of operational performance. Further investigation is required to understand the differences by industries, characteristics of enterprises, and positions in a supply chain.
Źródło:
Management and Production Engineering Review; 2016, 7, 4; 6-15
2080-8208
2082-1344
Pojawia się w:
Management and Production Engineering Review
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of Additive Element on the Properties of Mechanically Alloyed Fe-Y2O3 Alloys
Autorzy:
Ahn, J.-H.
Kim, T. K.
Ahn, J.
Powiązania:
https://bibliotekanauki.pl/articles/356561.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
mechanical alloying
ODS alloy
nanoparticles
oxide dispersion strengthening
high-energy ball milling
Opis:
In the present work, we have examined the effect of Ti on the properties of Fe-Y2O3 alloys. The result showed that the addition of Ti was effective for improving mechanical properties. This is due to the reduction of oxides by Ti during mechanical alloying and hot-consolidation. In particular, iron oxides are effectively reduced by the addition of Ti. Compared to the pristine Fe-Y2O3 alloys, titanium-added alloys exhibited fine and uniform microstructures, resulting in at least 60% higher tensile strength.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1043-1046
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation Of Fine Grained SiC At Reduced Temperature By Two-Step Sintering
Wytwarzanie drobnoziarnistego SiC w obniżonej temperaturze przez dwuetapowe spiekanie
Autorzy:
Kim, K.-W.
Oh, K.-S.
Lee, H.
Kim, B. S.
Chung, T.-J.
Powiązania:
https://bibliotekanauki.pl/articles/353772.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
SiC
liquid phase
two step sintering
coarsening
hardness
faza ciekła
spiekanie dwuetapowe
odporność
twardość
Opis:
Two-step sintering route was applied for the densification SiC by promoting the role of liquid phase. The specimen contained 8 vol% of liquid phase composed of Al2O3 and Y2O3. The heating schedule consisted with initial rapid heating to 2000°C and immediate quenching to 1700 or 1750°C. By heating at elevated temperature, even distribution of the liquid phase was intended. The heat treatment at reduced temperature was to suppress the evaporative loss of the liquid and to secure the time for densification. The two-step sintering effectively suppressed loss of mass and coarsening. The resultant SiC was thus dense and was composed of fine grains exhibiting hardness of 2321 kgf/mm2.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1539-1542
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Isotopic water separation using AGMD and VEMD
Autorzy:
Kim, J.
Park, S.
Kim, T.-S.
Jeong, D.-Y.
Ko, K.-H.
Powiązania:
https://bibliotekanauki.pl/articles/147314.pdf
Data publikacji:
2004
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
AGMD
VEMD
oxygen isotopes
PET
FDG
Opis:
The 18O isotopic water permeation and separation characteristics of a hydrophobic PTFE membrane using Air Gap Membrane Distillation (AGMD) and Vacuum Enhanced Membrane Distillation (VEMD) were investigated. Permeation fluxes were measured by weighing the collected membrane-permeated water vapor. 18O/16O of each water sample was analyzed by the Tunable Diode Laser Absorption Spectroscopy (TDLAS). We observed the effects of the air filled membrane pores and the temperature gradient applied to the membrane surfaces on the vapor permeation flux and the oxygen isotope separation for the first time. For both AGMD and VEMD, the permeation flux and the degree of 18O separation increased as the membrane interfacial temperature gradient increased. Even though, oxygen isotope separation and the permeation flux for VEMD is slightly higher than AGMD, the latter may be more efficient from the system's operational point of view.
Źródło:
Nukleonika; 2004, 49, 4; 137-142
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fabrication of Cu-Based SiC Composites by Spark Plasma Sintering of Cu-Nitrate Coated SiC Powders
Autorzy:
Jeong, Y.-K.
Kim, Y. S.
Oh, S.-T.
Powiązania:
https://bibliotekanauki.pl/articles/354995.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Cu-SiC composite
Cu-nitrate
spark plasma sintering
microstructure
Opis:
An optimum route to fabricate the Cu-based SiC composites with homogeneous microstructure was investigated. Three methods for developing the densified composites with sound interface between Cu and SiC were compared on the basis of the resulting microstructures. Starting with three powder mixtures of elemental Cu and SiC, elemental Cu and PCS coated SiC or PCS and Cunitrate coated SiC was used to obtain Cu-based SiC composites. SEM analysis revealed that the composite fabricated by spark plasma sintering using elemental SiC and Cu powder mixture showed inhomogeneous microstructure. Conversely, dense microstructure with sound interface was observed in the sintered composites using powder mixture of pre-coated PCS and Cu-nitrate onto SiC. The relationship between powder processing and microstructure was discussed based on the role of coating layer for the wettability.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1407-1410
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect Of Carbon Nanotubes On The Properties Of Spark Plasma Sintered ZrO2/CNT Composites
Wpływ nanorurek węglowych na właściwości spiekanych metodą sps kompozytów ZrO2/CNT
Autorzy:
Shim, D. H.
Jung, S. S.
Kim, H. S.
Cho, H.
Kim, J. K.
Kim, T. G.
Yoon, S. J.
Powiązania:
https://bibliotekanauki.pl/articles/351266.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
CNT
ZrO2
composite
SPS
kompozyty
Opis:
Zirconia matrix ZrO2/CNT composite materials reinforced with multiwall carbon nanotubes were fabricated using a spark plasma sintering technique. The effects of the amount of CNTs addition, sintering temperature and sintering pressure on the properties of the resulting ZrO2/CNT composites were examined. 0 to 9 vol. % CNTs were dispersed in zirconia powder, and the resulting mixture was sintered. The electrical conductivity, hardness, flexural strength, and density were measured to characterize the composites. The friction and wear properties of the composites were also tested. The flexural strength and friction coefficient of the composites were improved with up to 6 vol.% of CNT addition and the flexural strength showed a close relationship with the relative density of the composite. The electrical conductivity increased with increasing proportion of the CNTs, but the efficiency was reduced at more than 6 vol.% CNTs.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1315-1318
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructure Development of Spark Plasma Sintered Ti-Nb Alloy by Heat Treatment
Autorzy:
Haq, M. A.
Abbas, S. F.
Eom, N. S. A.
Kim, T. S.
Lee, B.
Park, K.-T.
Kim, B. S.
Powiązania:
https://bibliotekanauki.pl/articles/355593.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
TiNb alloy
Spark plasma sintering
Heat treatment
Microstructure
β-phase titanium
Opis:
The β-phase Titanium (β-Ti) alloys have been under the spotlight in the recent past for their use as biomedical prosthetic materials owing to their excellent properties such as low elastic modulus, high corrosion resistance and tensile strength. Recently, Niobium (Nb) has gained a lot of attention as a β-phase stabilizing element in Ti alloys to replace Vanadium (V) due to its excellent solubility in Ti, low elastic modulus and biocompatibility. In this work, low cost Ti-20Nb binary alloy has been fabricated via powder metallurgy procedures. The blended powder mixtures of Ti and Nb were sintered at 900°C for 20 mins by the Spark Plasma Sintering (SPS) with an applied uniaxial pressure of 40 MPa. The heating rate was fixed at 50°C/min. The sintered alloy was subject to heat treatments at 1200°C in vacuum condition for various time durations. The characterizations of microstructure obtained during this process were done using FE-SEM, EDS and XRD. By increasing heat treatment time, as understood, the volume of residual Nb particles was decreased resulting in accelerated diffusion of Nb into Ti. Micro hardness of the alloy increased from 340 to 355 HV with the increase in β phase content from 30 to 45%. The resultant alloys had relatively high densities and homogenized microstructures of dispersed lamellar β grains in α matrix.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 3; 1429-1432
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fabrication and Characterization of CoCrFeNiMn High Entropy Alloy Powder Processed by Gas Atomization
Autorzy:
Park, T. G.
Lee, S. H.
Lee, B.
Cho, H. M.
Choi, W. J.
Kim, B. S.
Shin, K. S.
Kim, T.-S.
Powiązania:
https://bibliotekanauki.pl/articles/353649.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
high entropy alloy
gas atomization
spark plasma sintering
CoCrFeNiMn
Opis:
In this study, precisely controlled large scale gas atomization process was applied to produce spherical and uniform shaped high entropy alloy powder. The gas atomization process was carried out to fabricate CoCrFeNiMn alloy, which was studied for high ductility and mechanical properties at low temperatures. It was confirmed that the mass scale, single phase, equiatomic, and high purity spherical high entropy alloy powder was produced by gas atomization process. The powder was sintered by spark plasma sintering process with various sintering conditions, and mechanical properties were characterized. Through this research, we have developed a mass production process of high quality and spherical high entropy alloy powder, and it is expected to expand applications of this high entropy alloy into fields such as powder injection molding and 3D printing for complex shaped components.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 2; 1055-1059
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructure Evolution of Ni-Based ODS Superalloy Powders During Horizontal Rotary Ball Milling
Autorzy:
Lee, H.-E.
Kim, Y. S.
Park, J. K.
Oh, S.-T.
Powiązania:
https://bibliotekanauki.pl/articles/355552.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
high energy ball milling
Ni-base ODS superalloy
particle and crystalline size
microstructure
Opis:
Microstructure evolution of Ni-based oxide dispersion-strengthened alloy powders with milling time is investigated. The elemental powders having a nominal composition of Ni-15Cr-4.5Al-4W-2.5Ti-2Mo-2Ta-0.15Zr-1.1Y2O3 in wt % were ball-milled by using horizontal rotary ball milling with the change of milling velocity. Microstructure observation revealed that large aggregates were formed in the early stages of ball milling, and further milling to 5 h decreased particle size. The average crystalline size, estimated by the peak broadening of XRD, decreased from 28 nm to 15 nm with increasing milling time from 1 h to 5 h. SEM and EPMA analysis showed that the main elements of Ni and Cr were homogeneously distributed inside the powders after ball milling of 5 h.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1253-1255
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fabrication Of Porous Ti By Thermal Decomposition And Sintering Of PMMA/TiH2 Powder Compact
Wytwarzanie porowatego tytanu przez rozkład termiczny i spiekanie wyprasek PMMA/TiH2
Autorzy:
Jeon, K. Ch.
Kim, Y. D.
Suk, M.-J.
Oh, S.-T.
Powiązania:
https://bibliotekanauki.pl/articles/352341.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
porous Ti
PMMA powders
thermal decomposition of TiH2
pore structure
porowaty tytan
PMMA
rozkład termiczny
struktura porów
Opis:
Porous Ti with controlled pore structure was fabricated by thermal decomposition and sintering process using TiH2 powders and Polymethylmethacrylates (PMMA) beads as pore forming agent. The beads sizes of 8 and 50 μm were used as a template for fabricating the porous Ti. The TiH2 powder compacts with 20 and 70 vol% PMMA were prepared by uniaxial pressing and sintered for 2 h at 1100°C. TGA analysis revealed that the PMMA and TiH2 were thermally decomposed at about 400°C forming pores and at about 600°C into metallic Ti phase. The porosity increased with increase in the amount of PMMA addition. Also, the microstructure observation showed that the pore size and shape were strongly dependent on the PMMA shapes.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1375-1377
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of body surface area-based and weight-based dosing format for oral prednisolone administration in small and large-breed dogs
Autorzy:
Nam, A.
Kim, S.M.
Jeong, J.W.
Song, K.H.
Koo, T.S.
Seo, K.W.
Powiązania:
https://bibliotekanauki.pl/articles/2087897.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Źródło:
Polish Journal of Veterinary Sciences; 2017, 3; 611-613
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of Ti, V and Their Oxides-Based Thin Films in the Search for Hydrogen Storage Materials
Autorzy:
Tarnawski, Z.
Zakrzewska, K.
Kim-Ngan, N.-T.
Krupska, M.
Sowa, S.
Drogowska, K.
Havela, L.
Balogh, A.
Powiązania:
https://bibliotekanauki.pl/articles/1401913.pdf
Data publikacji:
2015-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.15.Cd
68.49.-h
61.05.C-
68.60.-p
Opis:
Thin film series consisting of Ti, V, TiO₂ and V₂O₅ layer with different layer geometries, sequences and thicknesses have been prepared by the sputtering technique. The hydrogen depth profile of selected films upon hydrogen charging at 1 bar and/or hydrogenation at pressure up to 102 bar was determined by using secondary ion mass spectrometry and nuclear reaction analysis using a N-15 beam. The highest hydrogen storage with a concentration up to 50 at.% was found in the pure Ti and Ti-contained layer, while it amounts to around 30% in the metallic Ti-V-Ni layer. Hydrogen can diffuse through the TiO₂ layer without accumulation, but can be stored in the VO₂ layer in some cases. Hydrogen can remove the preferential Ti orientation in the films and induce a complete transition of V₂O₅ into VO₂ in the films.
Źródło:
Acta Physica Polonica A; 2015, 128, 3; 431-439
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microstructure and Magnetic Properties of NdFeB Sintered Magnets Diffusion-Treated with Cu/Al Mixed Dyco Alloy-Powder
Autorzy:
Lee, M.-W.
Bae, K.-H.
Lee, S.-R.
Kim, H.-J.
Jang, T.-S.
Powiązania:
https://bibliotekanauki.pl/articles/353351.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Nd-Fe-B sintered magnets
grain boundary diffusion process
low melting point element
DyCo alloy-powder diffusion
Opis:
We investigated the microstructural and magnetic property changes of DyCo, Cu + DyCo, and Al + DyCo diffusion-treated NdFeB sintered magnets. The coercivity of all diffusion treated magnet was increased at 880ºC of 1st post annealing(PA), by 6.1 kOe in Cu and 7.0 kOe in Al mixed DyCo coated magnets, whereas this increment was found to be relatively low (3.9 kOe) in the magnet coated with DyCo only. The diffusivity and diffusion depth of Dy were increased in those magnets which were treated with Cu or Al mixed DyCo, mainly due to comparatively easy diffusion path provided by Cu and Al because of their solubility with Ndrich grain boundary phase. The formation of Cu/Al-rich grain boundary phase might have enhanced the diffusivity of Dy-atoms. Moreover, relatively a large number of Dy atoms reached into the magnet and mostly segregated at the interface of Nd2 Fe14 B and grain boundary phases covering Nd2 Fe14 B grains so that the core-shell type structures were developed. The formation of highly anisotropic (Nd, Dy)2Fe14B phase layer, which acted as the shell in the core-shell type structure so as to prevent the reverse domain movement, was the cause of enhancing the coercivity of diffusion treated NdFeB magnets. Segregation of cobalt in Nd-rich TJP followed by the formation of Co-rich phase was beneficial for the coercivity enhancement, resulting in the stabilization of the metastable c-Nd2O3 phase.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1263-1266
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Carbon Co-Deposition During Gas Reduction of Water-Atomized Fe-Cr-Mo Powder
Autorzy:
Ali, B.
Choi, S. H.
Seo, S. J.
Maeng, D. Y.
Lee, C. G.
Kim, T. S.
Park, K. T.
Powiązania:
https://bibliotekanauki.pl/articles/352709.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
water atomization
Fe-based powder
oxide reduction
powder metallurgy
sinter-hardening alloys
Opis:
The water atomization of iron powder with a composition of Fe-3Cr-0.5Mo (wt.%) at 1600°C and 150 bar creates an oxide layer, which in this study was reduced using a mixture of methane (CH4) and argon (Ar) gas. The lowest oxygen content was achieved with a 100 cc/min flow rate of CH4, but this also resulted in a co-deposition of carbon due to the cracking of CH4. This carbon can be used directly to create high-quality, sinter hardenable steel, thereby eliminating the need for an additional mixing step prior to sintering. An exponential relationship was found to exist between the CH4 gas flow rate and carbon content of the powder, meaning that its composition can be easily controlled to suit a variety of different applications.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1119-1124
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reaction Kinetics and Morphological Study of TiNb2O7 Synthesized by Solid-State Reaction
Autorzy:
Choi, S. H.
Ali, B.
Choi, K. S.
Hyun, S. K.
Sim, J. J.
Choi, W. J.
Joo, W.
Lim, J. H.
Lee, T. H.
Kim, T. S.
Park, K. T.
Powiązania:
https://bibliotekanauki.pl/articles/355326.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
solid state reaction
kinetic analysis
quantitative phase analysis
TiNb2O7 synthesis
Opis:
Although TiNb2O7 is regarded as a material with high application potential in lithium-ion batteries (LIBs) and solid-oxide fuel cells (SOFCs), it has been difficult to find suitable cost-effective conditions for synthesizing it on a commercial scale. In this study, TiNb2O7 compounds were synthesized by a solid state synthesis process. For stoichiometrically precise synthesis of the TiNb2O7 phase, the starting materials, TiO2 and Nb2O5 were taken in a 1:1 molar ratio. Activation energy and reaction kinetics of the system were investigated at various synthesis temperatures (800,1000,1200, and 1400°C) and for various holding durations (1,5,10, and 20 h). Furthermore, change in the product morphology and particle size distribution were also evaluated as a function of synthesis temperature and duration. Additionally, quantitative phase analysis was conducted using the Rietveld refinement method. It was found that increases in the synthesis temperature and holding time lead to increase in the mean particle size from 1 to 4.5 μm. The reaction rate constant for the synthesis reaction was also calculated.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1051-1056
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fabrication of a Spherical Titanium Powder by Combined Combustion Synthesis and DC Plasma Treatment
Autorzy:
Choi, S. H.
Ali, B.
Hyun, S. K.
Sim, J. J.
Choi, W. J.
Joo, W.
Lim, J. H.
Lee, Y. J.
Kim, T. S.
Park, K. T.
Powiązania:
https://bibliotekanauki.pl/articles/356067.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
combustion synthesis
DC plasma treatment
titanium powder
3D printing process
combustion parameters
Opis:
Combustion synthesis is capable of producing many types of refractory and ceramic materials, as well as metals, with a relatively lower cost and shorter time frame than other solid state synthetic techniques. TiO2 with Mg as reductant were dry mixed and hand compacted into a 60 mm diameter mold and then combusted under an Ar atmosphere. Depending on the reaction parameters (Mg concentration 2 ≤ α ≤ 4), the thermocouples registered temperatures between 1160°C and 1710°C . 3 mol of Mg gave the optimum results with combustion temperature (Tc) and combustion velocity (Uc) values of 1372°C and 0.26 cm/s respectively. Furthermore, this ratio also had the lowest oxygen concentration in this study (0.8 wt%). After combustion, DC plasma treatment was carried out to spheroidize the Ti powder for use in 3D printing. The characterization of the final product was performed using X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, and N/O analysis.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1057-1062
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-19 z 19

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